CN100393842C - Coke metallurgical carbon-coating reinforcer - Google Patents

Coke metallurgical carbon-coating reinforcer Download PDF

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Publication number
CN100393842C
CN100393842C CNB2005100686341A CN200510068634A CN100393842C CN 100393842 C CN100393842 C CN 100393842C CN B2005100686341 A CNB2005100686341 A CN B2005100686341A CN 200510068634 A CN200510068634 A CN 200510068634A CN 100393842 C CN100393842 C CN 100393842C
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China
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coke
carbon
quenching
chassis
reinforcer
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CNB2005100686341A
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CN1854249A (en
Inventor
廖洪强
包向军
马刚平
李东涛
赵鹏
程晓光
张向伟
薛立民
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Shougang Group Co Ltd
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Shougang Corp
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Abstract

The present invention relates to a coke metallurgical carbon-coating reinforcer which relates to the field of quenching dry coke, particularly to the coke metallurgical carbon-coating reinforcer containing methane gas as a coke quenching medium. The reinforcer is characterized in that methane in the coke quenching medium is decomposed into hydrogen gas and graphitic carbon by using red coke sensible heat. The graphitic carbon is absorbed on the surface of the coke and is filled in coke pores to form a dense film which is covered on the outer surface of the coke and blocks the inner pores of the coke. The reinforcer has an integral sealed cover, and the front end of the sealed cover is connected with a red coke receiving hopper connected with a coke quenching carbon plating trolley by a piston feeding machine. A gas collecting box is arranged at the bottom of the coke quenching carbon plating trolley. The coke quenching medium enters a coke layer from trolley grate bars on the upper part of the gas collecting box. A cold coke receiving hopper is arranged below the tail of the coke quenching carbon plating trolley. A water seal belt conveyor is arranged below the cold coke receiving hopper. Coke reactivity can be decreased, and the post-reaction strength of metallurgical coke can be enhanced by using the reinforcer.

Description

Coke metallurgical carbon-coating reinforcer
Technical field
The invention belongs to the dry coke quenching field, especially utilize and be rich in the coke metallurgical carbon-coating reinforcer of methane gas for the quenching medium.
Background technology
Because blast furnace maximizes and the increase of pulverized coal injection amount, blast furnace requires the support frame effect of coke more and more outstanding, and this just needs coke oven to smelt the high strength coke.It is raw material that but coke oven smelting high-strength coke needs a large amount of coking coals, and coking coal belongs to worldwide coking coal in short supply, can't satisfy the needs of Iron and Steel Production.From existing coking coal resource situation and future development trend, require further to expand coking coal resource, adopt weakly caking coal and steam coal coking as far as possible, but the coke that these coals are produced is difficult to satisfy the requirement of blast furnace STRENGTH ON COKE intensity, therefore needs development of new high strength coke smelting technology and coke enhancement techniques.
People such as Shigeno disclose a kind of method of coke top layer carburizing of utilizing and have improved coke strenth in the patent 08/5486216 of U. S. application, this invention describes in detail and utilizes the gaseous media that is rich in methane, under hot conditions with the coke effect, make methane decomposition produce uncombined carbon, uncombined carbon is deposited on the coke pore surface, reduce the specific surface area of coke, thereby reach the purpose that improves coke strenth, this invention has proposed the ultimate principle and the method for coke carburizing, but how explanation does not realize this method industrial, does not propose corresponding processing unit yet.
Dry Quenching Technology belongs to typical Iron And Steel Industry clearer production technology, it utilizes rare gas element to pass red burnt layer in shaft furnace, reclaim red burnt sensible heat, not water quenching, reduced problem of environmental pollution and water resource waste problem, simultaneously, because the speed of red Jiao in the gas cooling process is well below using water-cooled speed, reduce the coke crackle, can improve the cold strength index of coke to a certain extent.But also there are some problems in dry coke quenching in actual moving process, mainly concentrate on the following aspects: (1) initial cost is huge; (2) the hot strength improvement effect of STRENGTH ON COKE is not remarkable; (3) coke is in dropping process, and between wall, air-flow and coke mechanical friction takes place, and forms a large amount of dust, causes complete burnt rate to descend; (4) high temperature gas flow after the heat exchange is carried a large amount of dust secretly, causes the serious wear of rear portion equipment.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of coke metallurgical carbon-coating reinforcer that can reduce coke reactivity, improve the metallurgical coke post-reaction strength.
For solving the problems of the technologies described above, coke metallurgical carbon-coating reinforcer of the present invention comprises integrative sealing cover, and quenching plating carbon chassis is arranged in the seal closure, and the cover top is provided with the gas exit pipeline; The front end of seal closure links to each other with red burnt hopper, red burnt hopper top and environmental communication, the bottom plug feeding machine of taking over a job, piston feeding machine can be done the reciprocating machine motion in the pusher groove, the outlet of pusher groove passage is provided with sealing baffle, the sealing baffle bottom is slant chute, slant chute is positioned at the front end top of quenching plating carbon chassis, and the chassis face of quenching plating carbon chassis is made of the castor bar, and grid section has ventilative aperture, the bottom is the coal gas plenum chamber, evenly arranges the gas entry pipeline in the coal gas plenum chamber; The tailstock below of quenching plating carbon chassis is cold burnt hopper, and there is water sealed tank cold burnt hopper discharge port lower end, and water sealed tank is immersed under water, and constitutes seal water system with hopper, and endless belt conveyor is positioned at the below of cold burnt hopper.
Above-mentioned quenching plating carbon chassis chassis face top is provided with blocking material plate, can prevent that coke is scattered; Seal closure inside is pouring fireproof material, outward covered with the welding steel plate; The piston feeding machine adopts refractory materials and Heat resisting cast steel to do and cuts somebody's hair; Endless belt conveyor comprises scraper conveyor with angle and drag conveyer; Gas exit pipeline internal surface is covered with certain thickness refractory casting material.
Adopt the device of this spline structure can reduce coke reactivity, improve the metallurgical coke post-reaction strength, mainly contain following advantage:
(1) can prevent the leakage of quenching medium, because total system is all moved in seal closure, adopt the baffle plate sealing in red burnt ingress, guaranteed the sealing effectiveness of quenching medium in a cycle of operation of piston push rod, water seal is adopted in cold burnt outlet, has also solved the leakage problem of quenching medium;
(2) can stop entering of outside air, total system has only red burnt inlet and cold burnt outlet might bring air into, because water seal is adopted in the cold burnt outlet of afterbody, stopped the air admission system, though red burnt ingress and environmental communication,, in red Jiao under the effect of carbonaceous incendiary, with oxide compound perfect combustion, so total system can be stopped entering of air;
(3) utilize gases such as the coke-oven gas be rich in methane or Sweet natural gas as the quenching medium, the coke surfaces externally and internally is also filled in the absorption of the uncombined carbon of methane pyrolytic decomposition, has the effect of remarkable increase coke strenth;
(4) utilize the coking production operation of Iron And Steel Industry, by-product hydrogen from coke-oven gas or methane gas has the clean energy transition function of metallurgical industry;
(5) adopt novel horizontal dry coke quenching auxiliary system, in quenching and plating carbon process, relative movement does not take place between coke granule, significantly reduce coke dust generation in the conventional dry extinguishing technique, reduce environmental pollution, and increase the metallurgical coke rate.
Description of drawings
The present invention is further detailed explanation below in conjunction with the drawings and specific embodiments.
Fig. 1 is the structure iron of coke metallurgical carbon-coating reinforcer of the present invention.
Among the figure: 1. red burnt hopper, 2. piston material feeder, 3. pusher groove, 4. sealing baffle, 5. slant chute, 6. quenching plating carbon chassis, 7. blocking material plate, 8. plenum chamber, 9. gas entry pipeline, 10. cold burnt hopper, 11. water sealed tank, 12. endless belt conveyor, 13. seal closures, 14. gas exit pipelines.
Embodiment
In Fig. 1, this device comprises integrative sealing cover 13, and quenching plating carbon chassis 6 is arranged in the seal closure 13, and the cover top is provided with a gas exit pipeline 14; The front end of seal closure 13 links to each other with red burnt hopper 1, red burnt hopper 1 top and environmental communication, inlet for red Jiao, lower openings, take over a job and fill in feeding machine 2, piston feeding machine 2 can be done the reciprocating machine motion in pusher groove 3, pusher groove 3 passages are rectangle, the outlet of passage is provided with sealing baffle 4, and sealing baffle 4 bottoms are slant chute 5, and slant chute 5 is positioned at the front end top of quenching plating carbon chassis 6, the chassis face of quenching plating carbon chassis 6 is made of the castor bar, grid section has ventilative aperture, and the bottom is a coal gas plenum chamber 8, evenly arranges gas entry pipeline 9 in the coal gas plenum chamber 8; The tailstock below of quenching plating carbon chassis 6 is cold burnt hopper 10, there is water sealed tank 11 cold burnt hopper 10 discharge port lower ends, water sealed tank 11 is immersed under water, and constitute seal water system with hopper, endless belt conveyor 12 is positioned at the below of cold burnt hopper 10, quenching plating carbon chassis 6 chassis faces top is provided with blocking material plate 7, can prevent that coke is scattered; Seal closure 13 inside are pouring fireproof material, outward covered with the welding steel plate; Piston feeding machine 2 adopts refractory materials and Heat resisting cast steel to do and cuts somebody's hair; Endless belt conveyor 12 adopts scraper conveyor and drag conveyer with angle; Gas exit pipeline 14 internal surfaces are covered with certain thickness refractory casting material, and the refractory materials outside is a seamless tube.
Whole device has only a coke inlet and a coke export, a gas line inlet and a gas line outlet, and all equipment is all in seal closure 13.Like this, quenching medium and environment are kept apart.Red Jiao in the coking production process is when sending into red burnt hopper 1, because red Jiao's high temperature action will be brought the air perfect combustion of hopper into, when piston push rod pushed quenching plating carbon chassis 6 with red Jiao, red burnt surface had not had combustion-supporting oxidizing substance.Red Jiao enters quenching plating carbon chassis 6 along slant chute 5, and forward in the operational process, red Jiao forms certain piling height on the chassis surface at coke plating carbon chassis 6.The quenching medium enters bellows by pipeline, and scurries out from the grid section aperture with certain flow velocity, enters the red burnt layer of chassis surface sediment.Red Jiao has flourishing pore texture and very strong adsorptive power, and the form of quenching medium by flowing and spreading entered red burnt inner by red burnt surface.Under suitable temperature condition, concentration conditions and pressure condition, part methane in the quenching medium begins to decompose, form free graphite carbon and hydrogen, wherein free graphite carbon begins deposition in red burnt pore texture, and formation compact film, cover and the outside surface of obstruction coke and the hole of coke, reach the purpose of remarkable reduction coke reactivity and raising metallurgical coke post-reaction strength, the hydrogen that the pyrolysis of quenching medium produces is along with unreacted gas is discharged by gas exit pipeline 14.Red Jiao is along with the 6 constantly operations forward of coke plating carbon chassis, and cold quenching medium also constantly enters bellows from gas line, and by the bogie grates aperture, with the red burnt convective heat exchange that takes place, the reddest burnt temperature cools down, and becomes cold Jiao.Cold Jiao enters the hopper of chassis afterbody, by water seal, sends system by endless belt conveyor 12.
Quenching plating carbon chassis 6 integral body are in seal closure 13, and therefore, the drive unit head-tail star gear of chassis is in seal closure 13, and speed change mechanism is then outside seal closure 13, and the mode by pneumostop can seal the drive shaft of chassis fully.The quenching medium is when entering chassis seal closure 13, and whole tightness system adopts micro-pressure operation, like this, has stopped the phenomenon that the high temperature gas flow after the heat exchange is carried a large amount of dust secretly.
The quenching medium adopts the self-produced coke-oven gas in certain coke-oven plant, and wherein hydrogen content is 55~60%, and methane content is 22~27%, and carbon monoxide is 7~12%, and all the other are carbonic acid gas, heavy hydrocarbon, nitrogen and oxygen.Send into red burnt hopper 1 from coke furnace carbonization chamber about 1000 ℃ of red Jiao that come out by the existing handling equipment in coke-oven plant, the size suitable for reading and the handling equipment of red burnt hopper 1 are complementary, end opening size and piston push rod mechanism are complementary, the height of hopper is determined by red Jiao's that prestores amount, red burnt hopper 1 a part of material that can prestore, the continuity of assurance system operation, simultaneously, under red burnt high temperature action, the little air that red Jiao is brought into burnouts.Red Jiao falls into piston material pushing groove 3 by the hopper end opening under action of gravity, the pusher groove is a rectangle, and the width of piston push rod is slightly less than the width of quenching plating carbon chassis 6, and the height of push rod is determined according to a coke pushing amount.Piston push rod adopts cycle reciprocating machine motion, and red Jiao enters tightness system along pusher groove 3 under the push rod effect.Piston material pushing groove 3 end outlets are provided with rotary type sealing baffle 4.When piston advanced, sealing baffle 4 was opened under thrust, and material enters the slant chute 5 of pusher groove 3 belows, and this moment, piston and red Jiao stopped up the upper end feeding mouth, prevented that the quenching medium from scurrying outward; When piston was regained, sealing baffle 4 was closed automatically because of action of gravity, prevented that outside air from scurrying into quenching plating carbon reactive system.3 outlets of piston material pushing groove are connected to slant chute 5, and slant chute 5 tops link to each other with pusher groove 3 outlet lower edges, and the bottom is welded on chassis blocking material plate 7 sides, apart from chassis face 30~50cm.Temperature is that the coke about 1000 ℃ is fallen on the quenching plating carbon chassis 6 from slant chute, forming piling height between quenching plating carbon chassis blocking material plate 7 is the coke layer of 60~80cm, and plate carbon chassis 6 integral levels with quenching and move, quenching plating carbon chassis 6 speed of moving horizontally are 0.2m~0.4m/min, under this translational speed condition, do not have relative movement between the coke granule, effectively prevent the generation of coke powder.Coke-oven gas enters the coal gas bellows by gas entry pipeline 9, and the top of coal gas bellows is the grid section of quenching plating carbon chassis 6, has the aperture of 1~3mm on the grid section of chassis, and aperture is along chassis uniform distribution in a lateral direction, and per 2~3cm has one.Cold coke-oven gas enters coke layer along the aperture on the grid section, and between the coke of heat convective heat exchange takes place, simultaneously, and a large amount of coke-oven gas of absorption in the coke hole.At red Jiao Qu, the methane gas in the coke-oven gas issues estranged separating at high temperature action, generates free graphite carbon and hydrogen, and free graphite carbon deposits in the coke hole, and forms the carbon film of one deck densification.Hydrogen flow, under diffusion and the effect of mass transmitting, enter in the coal gas by coke inside, and along with coal gas flows out along gas exit pipeline 14 together, because gas exit pipeline 14 is at the front end of seal closure, be subjected to the thermal-radiating effect of red Jiao, between 650~700 ℃ of the temperature of gas exit pipeline 14.Along with coke plating carbon chassis 6 carries constantly operation forward of coke, convective heat exchange constantly takes place between cooled coal gas and the coke, coke temperature reduces gradually, when coke temperature is lower than 750 ℃, methane decomposition speed in the coke-oven gas reduces, interaction between coke-oven gas and the coke only shows as convective heat exchange, and coke temperature constantly reduces, and reaches the temperature of processing requirement at the afterbody of chassis.At this moment, coke enters cold burnt hopper 10, and the top of cold burnt hopper 10 links to each other with coke plating carbon chassis 6 afterbodys, the bottom is immersed in the water, and link to each other with scraper plate machine in the water, cold coke passes through water-cooled through water seal, further reduce coke temperature, simultaneously, fill large quantity of moisture in the hole of coke, the coke-oven gas in the hole is cemented out, through the coke of water seal, send system by the scraper plate machine.
According to the variation of coke temperature system, whole technology can be divided into plating carbon district and the dried district of putting out on chassis length, and the partition ratio in two zones is 1: 3.The air feed system of coke-oven gas also can be divided into two zones, plating carbon district and the dried district of putting out, what use in plating carbon district is original coke-oven gas, and what put out that the district adopts is the circulation coke-oven gas dried, and original coke-oven gas and circulation coke-oven gas account for 20% and 80% of total tolerance respectively.This two portions gas is discharged from a gas exit pipeline 14, and a part is given the user behind cooling and dedusting, and another part adopts the metacyclic mode of cooling and dedusting to send system back to.

Claims (6)

1. a coke metallurgical carbon-coating reinforcer is characterized in that: comprise integrative sealing cover (13), quenching plating carbon chassis (6) is arranged in the seal closure (13), cover the top and be provided with gas exit pipeline (14); The front end of seal closure (13) links to each other with red burnt hopper (1), red burnt hopper (1) top and environmental communication, take over a job and fill in feeding machine (2) in the bottom, piston feeding machine (2) can be done the reciprocating machine motion in pusher groove (3), the outlet of pusher groove (3) passage is provided with sealing baffle (4), sealing baffle (4) bottom is slant chute (5), slant chute (5) is positioned at the front end top of quenching plating carbon chassis (6), the chassis face of quenching plating carbon chassis (6) is made of the castor bar, grid section has ventilative aperture, the bottom is coal gas plenum chamber (8), evenly arranges gas entry pipeline (9) in the coal gas plenum chamber (8); The tailstock below of quenching plating carbon chassis (6) is a cold burnt hopper (10), there is water sealed tank (11) cold burnt hopper (10) discharge port lower end, water sealed tank (11) is immersed under water, and constitutes seal water system with hopper, and endless belt conveyor (12) is positioned at the below of cold burnt hopper (10).
2. according to the described coke metallurgical carbon-coating reinforcer of claim 1, it is characterized in that: quenching plating carbon chassis (6) chassis face top is provided with blocking material plate (7), prevents that coke is scattered.
3. according to the described coke metallurgical carbon-coating reinforcer of claim 1, it is characterized in that: seal closure (13) is inner for pouring fireproof material, outward covered with the welding steel plate.
4. according to the described coke metallurgical carbon-coating reinforcer of claim 1, it is characterized in that: piston feeding machine (2) adopts refractory materials and Heat resisting cast steel to do and cuts somebody's hair.
5. according to the described coke metallurgical carbon-coating reinforcer of claim 1, it is characterized in that: described endless belt conveyor (12) comprises scraper conveyor with angle and drag conveyer.
6. according to the described coke metallurgical carbon-coating reinforcer of claim 1, it is characterized in that: gas exit pipeline (14) internal surface is covered with certain thickness refractory casting material.
CNB2005100686341A 2005-04-27 2005-04-27 Coke metallurgical carbon-coating reinforcer Expired - Fee Related CN100393842C (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101880537B (en) * 2010-07-27 2014-11-05 张乃文 Semi coke furnace dry quenching system
CN108298985A (en) * 2018-01-30 2018-07-20 青岛三联石墨制品有限公司 The preparation method of graphite jig

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4310386A (en) * 1977-06-14 1982-01-12 Siderurgie Maritime (Maritieme Staalnijverheid) Sidmar S.A. Method of and apparatus for the dry quenching of coke
JPS57123285A (en) * 1981-01-23 1982-07-31 Nippon Kokan Kk <Nkk> Apparatus for charging raw material in dry-process quenching equipment for coke
JPS58149981A (en) * 1982-03-01 1983-09-06 Mitsubishi Heavy Ind Ltd Dry quenching equipment for coke
DE19532587A1 (en) * 1995-09-04 1997-03-06 Siemens Ag Conveyor with worm conveyor screw

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4310386A (en) * 1977-06-14 1982-01-12 Siderurgie Maritime (Maritieme Staalnijverheid) Sidmar S.A. Method of and apparatus for the dry quenching of coke
JPS57123285A (en) * 1981-01-23 1982-07-31 Nippon Kokan Kk <Nkk> Apparatus for charging raw material in dry-process quenching equipment for coke
JPS58149981A (en) * 1982-03-01 1983-09-06 Mitsubishi Heavy Ind Ltd Dry quenching equipment for coke
DE19532587A1 (en) * 1995-09-04 1997-03-06 Siemens Ag Conveyor with worm conveyor screw

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