CN100374501C - 蜜胺树脂薄片和/或薄膜用于涂覆三维结构表面和/或模制品的用途 - Google Patents
蜜胺树脂薄片和/或薄膜用于涂覆三维结构表面和/或模制品的用途 Download PDFInfo
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- CN100374501C CN100374501C CNB2004800023169A CN200480002316A CN100374501C CN 100374501 C CN100374501 C CN 100374501C CN B2004800023169 A CNB2004800023169 A CN B2004800023169A CN 200480002316 A CN200480002316 A CN 200480002316A CN 100374501 C CN100374501 C CN 100374501C
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- Prior art keywords
- melamine
- weight
- iii
- mixture
- melamine resin
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- 229920000877 Melamine resin Polymers 0.000 title claims abstract description 70
- 239000004640 Melamine resin Substances 0.000 title claims abstract description 47
- 239000011248 coating agent Substances 0.000 title claims abstract description 11
- 238000000576 coating method Methods 0.000 title claims abstract description 11
- 239000011888 foil Substances 0.000 title abstract description 3
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000007864 aqueous solution Substances 0.000 claims abstract description 11
- 239000002657 fibrous material Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 31
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 25
- 239000007859 condensation product Substances 0.000 claims description 20
- 239000000835 fiber Substances 0.000 claims description 17
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 13
- 229920003002 synthetic resin Polymers 0.000 claims description 10
- 239000000057 synthetic resin Substances 0.000 claims description 10
- 238000007598 dipping method Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000002023 wood Substances 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 4
- 125000003368 amide group Chemical group 0.000 claims description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 238000005470 impregnation Methods 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229920003043 Cellulose fiber Polymers 0.000 claims description 2
- 238000006424 Flood reaction Methods 0.000 claims description 2
- 238000006482 condensation reaction Methods 0.000 claims description 2
- HANVTCGOAROXMV-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine;urea Chemical compound O=C.NC(N)=O.NC1=NC(N)=NC(N)=N1 HANVTCGOAROXMV-UHFFFAOYSA-N 0.000 claims description 2
- 239000010408 film Substances 0.000 claims 5
- 239000010409 thin film Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 239000004815 dispersion polymer Substances 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000002759 woven fabric Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- -1 vinyl aromatic compounds Chemical class 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- PWMWNFMRSKOCEY-UHFFFAOYSA-N 1-Phenyl-1,2-ethanediol Chemical compound OCC(O)C1=CC=CC=C1 PWMWNFMRSKOCEY-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- GMSWRMUHJLKEIL-UHFFFAOYSA-N azane;ethene Chemical compound N.C=C GMSWRMUHJLKEIL-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/32—Modified amine-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12611—Oxide-containing component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/254—Polymeric or resinous material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31942—Of aldehyde or ketone condensation product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31942—Of aldehyde or ketone condensation product
- Y10T428/31946—Next to second aldehyde or ketone condensation product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31942—Of aldehyde or ketone condensation product
- Y10T428/31949—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
Abstract
本发明涉及由含有纤维素的纤维材料制成的蜜胺树脂薄片和/或薄膜用于涂覆三维结构表面和/或模制品的用途，该纤维材料用含有(i)蜜胺-甲醛缩合物、(ii)醚化的蜜胺-甲醛缩合物和(iii)聚合物分散体的水溶液进行后浸渍或预浸渍和后浸渍。
Description
本发明涉及由纤维素纤维材料生产的蜜胺树脂薄片和/或薄膜用于涂覆三维结构表面和/或模制品(3D涂覆)的用途，该纤维素纤维材料用含有下列成分的水溶液进行后浸渍或预浸渍和后浸渍：
(i)蜜胺-甲醛缩合物，
(ii)醚化的蜜胺-甲醛缩合物，和
(iii)聚合物分散体。
本发明进一步涉及特定的含水合成树脂混合物。
对于材料的3D涂覆，通常使用热塑性薄片，例如为了涂覆家具工业的木基材料。目前这些热塑性薄片的显著优势是它们的弹性；缺点包括尤其是由于另外使用粘合剂而产生的高生产成本以及预期的高处理成本。人们希望使用自粘的便宜蜜胺树脂薄膜，例如用于家具工业以提高平滑表面的级别，以及用于涂覆三维结构区域。纯的蜜胺树脂太脆而不能用于该应用。按照DE-A 23 09 334使用带有醚化羟甲基的蜜胺树脂获得了改进的柔韧性。这些树脂主要用于生产复合材料如蜜胺树脂薄片。为了生产这些复合材料，用蜜胺树脂浸渍例如纸、机织物或非织造布并且在100-180℃的温度下固化。这些蜜胺树脂薄膜尤其用于增强木基材料如碎料板、硬质纤维板和木块芯板(blockboard)的表面。为此目的，使用适当的粘合剂将蜜胺树脂薄片粘合到木基材料的表面或边缘上，并在适当的情况下施加热和压力。用蜜胺树脂薄片进行涂覆是为了改进木基材料对机械应力的抵抗力及其防水性。
为了获得例如涂覆圆边所要求的弹性和柔韧性，对蜜胺树脂进行改性：例如通过加入如DE-A 44 39 156所述的胍胺树脂或通过加入如DE-A 38 37965所述的少量含水合成树脂分散体。DE-A 37 00 344指出氨基树脂和丙烯酸酯分散体的组合在生产的薄片中产生了特定的弹性。上述专利专门公开了称为软边缘的那些的生产。当使用这些蜜胺树脂薄片涂覆软边缘时，如实施例所述，需要粘合剂以将树脂薄片固定到边缘上。
关于可变形性的性质，已知的蜜胺树脂薄片还需要改进。尤其在家具生产方面为了均匀涂覆三维结构体的表面(如某些家具风格(乡村风格的家具)所面临的情况)和/或均匀涂覆模制品存在的需要是能够使用蜜胺树脂薄片或蜜胺树脂薄膜，该薄片或薄膜与其已知的同等产品相比具有改进的弹性并且具有至少相等(如果没有同样得到改进)的其它性能。此外，还需要能够由一种材料对带有锋利边缘部分的三维结构体进行二维涂覆。应当指出优选3D涂覆用于改性引起的自粘的蜜胺树脂薄膜，目前这些薄膜仅适合平滑表面的涂覆。从审美的角度且同时为了简化生产，涂覆操作应该以单一压制操作进行。该类薄片和薄膜的主要特征在于它们在压制操作过程中的可变形性。
本发明的目的是具体说明适合对三维结构表面、模制品和具有锋利边缘部分的三维结构物品进行二维涂覆，但同时呈现蜜胺树脂薄片或薄膜的通常性质特征的蜜胺树脂薄片和/或薄膜。本发明进一步提供了一种特别有利地适合用于浸渍纤维素纤维材料以生产用于3D涂覆的蜜胺树脂薄膜的合成树脂混合物。
我们发现此目的通过将由纤维素纤维材料或机织物制得的蜜胺树脂薄片和/或薄膜用于涂覆三维结构表面和/或模制品(3D涂覆)而实现，其中纤维素纤维材料或机织物用含有下列成分的水溶液进行后浸渍或预浸渍和后浸渍：
(i)蜜胺-甲醛缩合物，
(ii)醚化的蜜胺-甲醛缩合物，和
(iii)聚合物分散体。
已经发现如果所述水溶液包含下列物质：
(i)5-50重量％，特别是10-30重量％的蜜胺-甲醛缩合物，
(ii)5-50重量％，特别是10-40重量％的醚化蜜胺-甲醛缩合物，和
(iii)20-90重量％，特别是30-80重量％的聚合物分散体，则该水溶液特别适合对纤维素纤维材料进行后浸渍或预浸渍和后浸渍。
组分(i)、(ii)和(iii)的量总和为100重量％，并且基于液体树脂混合物。
还可向本发明的蜜胺树脂混合物中加入助剂和添加剂，实例是0.1-50重量％，优选0.2-30重量％，特别是0.5-20重量％的脲、己内酰胺、苯基二甘醇、丁二醇和/或蔗糖，基于100重量％的(i)-(iii)的混合物。其还可以进一步包含常规添加剂如润湿剂、固化剂和催化剂。
还发现了特别有利地适合生产用于3D涂覆的蜜胺树脂薄膜和薄片的新型合成树脂混合物。该混合物的组成如下：
(i)5-50重量％，特别是10-20重量％的蜜胺-甲醛缩合物，
(ii)5-50重量％，特别是10-30重量％的醚化蜜胺-甲醛缩合物，和
(iii)40-90重量％，特别是50-80重量％的水分散体形式的共聚物，该共聚物可通过缩合反应交联，并且是优选含有羧基、羟基、酰胺基、缩水甘油基、羰基、N-羟甲基、N-烷氧基甲基、氨基和/或联亚氨基的丙烯酸酯的共聚物。
组分(i)、(ii)和(iii)的量总和为100重量％，并且基于液体树脂混合物。
下面是各合成组分的细节：
将蜜胺-甲醛缩合物用作合成组分(i)。合成组分(i)的制备是公知知识。通常首先使1mol蜜胺与1.4-2mol甲醛在pH为7-9和温度为40-100℃下缩合直到达到适当的缩合程度。
在合成组分(ii)中，蜜胺-甲醛缩合物用C1-C4链烷醇如甲醇、乙醇、丙醇和/或丁醇进行醚化。优选甲醇和乙醇。合成组分(ii)的制备是公知知识。蜜胺-甲醛缩合物通常与20-30mol甲醇混合，并且在pH为1-5和温度为40-80℃下进行醚化。缩合条件受到树脂需要的水稀释度的控制，稀释度为至少1∶6。缩合后，通过蒸馏除去蜜胺树脂中过量的醇和甲醛。任何残留的甲醛通过在室温至90℃，优选60-70℃的温度下加入脲而转化。
将共聚物分散体用作合成组分(iii)，所述共聚物优选含有羧基、羟基、酰胺基、缩水甘油基、羰基、N-羟甲基、N-烷氧基甲基、氨基和/或联亚氨基。共聚物中的这些官能团通过共聚带有这些官能团的相应单体以常规方式得到。
共聚物通常以这样的用量含有上述官能团：使所述共聚物可在其共聚形式中含有基于共聚物为0.1-50重量％，优选0.3-20重量％的含有官能团的这些单体。
适于含有上述基团的共聚单体的主要单体包括可以与所述共聚单体共聚合的常规烯属不饱和单体，实例是丙烯酸和甲基丙烯酸的C1-C12烷基酯，优选C1-C8烷基酯，例如丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸丙酯、甲基丙烯酸丙酯、丙烯酸丁酯、甲基丙烯酸丁酯、丙烯酸(2-乙基己基)酯、甲基丙烯酸(2-乙基己基)酯、丙烯酸月桂酯和甲基丙烯酸月桂酯；C2-C4羧酸的乙烯基酯，例如乙酸乙烯酯和丙酸乙烯酯，马来酸和富马酸的C1-C4二烷基酯，乙烯基芳族化合物如苯乙烯、α-甲基苯乙烯和乙烯基甲苯；丙烯腈、甲基丙烯腈、丙烯酰胺、甲基丙烯酰胺，还有含3-10个碳原子的乙烯基醚、乙烯基卤化物如氨乙烯和1，1-二氯乙烯；多烯属不饱和化合物如丁二烯和异戊二烯，以及上述单体的混合物，只要它们相互可以共聚合。
为了制备合成树脂混合物，在加入其它组分之前通常将聚合物分散体的pH调整为7.5-10。
在不损害其它性质的情况下，按照本发明使用的蜜胺树脂薄片和/或薄膜具有涂覆三维结构表面和/或模制品和/或具有锋利边缘部分的结构物品所需要的必要高弹性。锋利边缘部分尤其表示相交的两个或更多个平面产生的确定角所形成的边缘、角和点。
按照本发明使用的蜜胺树脂薄片或薄膜使用吸收性的纤维素纤维材料或机织物或装饰性纸以常规方式生产。
纤维素纤维材料用本发明的蜜胺树脂混合物(i)-(iii)或用蜜胺-甲醛浸渍树脂或用蜜胺-甲醛浸渍树脂和涂覆树脂的混合物或用脲-甲醛树脂和蜜胺-脲-甲醛树脂的混合物进行预浸渍。基于蜜胺树脂混合物的固体含量，每100重量份使用25-85重量份蜜胺树脂混合物。浸渍的纤维材料随后例如在140-200℃的温度下在热空气流中以常规方式固化成为蜜胺树脂薄片或蜜胺树脂薄膜。蜜胺树脂薄片或蜜胺树脂薄膜通过用蜜胺树脂混合物(i)-(iii)对其进行后浸渍并且将其粘合在具有待涂覆三维结构表面的材料组份上而进一步加工，若合适的话，粘合操作在加热和加压下进行。优选的材料是木基材料，例如乡村风格的家具和定向纤维板(OSB)。优选以单一加工步骤进行二维粘合，即在一个压制操作中使用单一的蜜胺树脂薄膜或薄片涂覆三维结构表面，该薄膜或薄片覆盖整个结构体。
对本发明而言，蜜胺树脂薄片是非自粘薄片，而蜜胺树脂薄膜是自粘薄膜。
所得表面明显且有效地闭合，并具有良好的可变形性。
本发明的优点还在于避免了目前使用的热塑性薄片的昂贵且麻烦的生产和处理成本。
实施例
组分(i)：蜜胺-甲醛缩合物
来自BASF Aktiengesellschaft的Kauramin浸渍树脂753，包含改性蜜胺-甲醛缩合物的水溶液(改性剂：丁二醇)。
组分(ii)：醚化的蜜胺-甲醛缩合物
在270g甲醛存在下在pH为8.5和温度为40-70℃下羟甲基化126g蜜胺。所得的加合化合物使用甲酸调节到pH为4并且使用900g甲醇在60℃的温度下醚化15分钟。用氢氧化钠溶液中和后，反应溶液通过浓缩(蒸馏)除去未反应的甲醛和过量甲醇。
组分(iii)：聚合物分散体
来自BASF Aktiengeseilschaft的LuhydranS 937 T，包含基于丙烯酸酯和甲基丙烯酸酯以及苯乙烯的共聚物的含羟基含水分散体的共聚物。
实施例1
在pH为7-9和温度为20-30℃下混合20g组分(i)、30g组分(ii)和40g组分(iii)。所得的合成树脂混合物是至少24小时储存稳定的。
应用实施例：
基重为80g/m2的装饰性纸用组分(i)(基于纸重施用70％的树脂)进行预浸渍。来自实施例1的合成树脂混合物与基于合成树脂混合物为0.5重量％的固化剂(例如来自BASF Aktiengesellschaft的Hrter 529 Flüssig[固化剂529，液体])混合，然后通过刮刀式涂布施加到预浸渍的装饰性纸上并随后干燥，从而使装饰性纸具有120-130％的固体含量，并且具有6-10％的残余水分含量。
对比例：
在加入基于组分(i)为0.5重量％的固化剂(例如来自BASFAktiengesellschaft的Hrter 529 Flüssig)后，使用组分(i)浸渍重量为80g/m2的装饰性纸并且干燥，从而使装饰性纸具有120-130％的完全浸渍的固体含量，并且具有6-10％的残余水分含量。
3D涂覆及表征：
将所得的蜜胺树脂薄膜压到直径为16.5cm并包含3D结构的MDF(中密度纤维)板上。3D结构表示具有圆形和平直区域和/或有确定角度的边缘的轮廓。压制操作在45kN的压力下和在150-160℃的实验室压机中进行，且持续时间为30-60秒。
评价压到包含3D结构的MDF板上的蜜胺树脂薄膜的可变形性和粘合性。对良好的可变形性而言，涂层应当完全与结构体相符合并且牢固地粘合到其上而没有撕裂或破裂。
表面的表征：
所得的蜜胺树脂薄膜在160-165℃的温度和25Kp的压力下压到MDF板上，且持续时间为110秒。进行下列测试：
固化
通过使0.004重量％的若丹明B溶液着色的0.2N盐酸作用在涂覆的MDF板上16小时而测定固化的质量。如果表面没有被酸侵蚀，则固化是有效的。可以根据变红的程度评价侵蚀的程度。
评价：
0＝没有侵蚀
1＝浅粉色着色
2＝明显的变红
3＝严重变红
4＝严重变红且轻微的表面膨胀
5＝严重变红且严重的表面膨胀
6＝破坏的表面
不渗透性：
涂覆表面的不渗透性或孔隙率用于评价对污物的敏感性。将黑鞋油擦到测试表面上然后再用布擦掉。孔隙中残余的鞋油可评价表面的不渗透性。
按照下面的级别评价表面不渗透性：
0＝无孔隙
1＝孤立孔隙
2＝几个孔隙
3＝许多孔隙
4＝大量的开放区域
5＝很大量的开放区域
6＝没有不透性
黑度：
使用带有Tint Sensor亮度测量头的Tint Tester 527按照D 3265测量黑度。测量范围覆盖0-99.99亮度单位，零为最低亮度级别(绝对黑)。即使在＞0.8的值也可识别出明显的变灰。
在用标准校准设备之后，对测试样品进行三次测量，并且以平均值报告黑度。
结果显示在表1中。
表1
| 外观 | 固化 | 不渗透性 | 黑度 | |
| 对比例 | 纸在尖锐点破裂 | 2 | 4 | 0.58 |
| 实施例1 | 纸完全被3D表面覆盖 | 2 | 2 | 0.67 |
Claims (12)
1.由纤维素纤维材料生产的蜜胺树脂薄片和/或薄膜用于涂覆三维结构表面和/或模制品(3D涂覆)的用途，该纤维素纤维材料使用含有下列成分的水溶液进行后浸渍或预浸渍和后浸渍：
(i)5-50重量％的蜜胺-甲醛缩合物，
(ii)5-50重量％的醚化的蜜胺-甲醛缩合物，和
(iii)20-90重量％的聚合物分散体，
组分(i)、(ii)和(iii)的量总和为100重量％，并且基于液体树脂混合物；其中分散体(iii)包含含有羧基、羟基、酰胺基、缩水甘油基、羰基、N-羟甲基、N-烷氧基甲基、氨基和/或联亚氨基的丙烯酸酯的共聚物。
2.如权利要求1所要求的用途，其中基于100重量％的(i)-(iii)的混合物，水溶液进一步包含0.1-50重量％的脲。
3.如权利要求1所要求的用途，其中水溶液包含
(i)10-30重量％的蜜胺-甲醛缩合物，
(ii)10-40重量％的醚化的蜜胺-甲醛缩合物，和
(iii)30-80重量％的聚合物分散体，
组分(i)、(ii)和(iii)的量总和为100重量％，并且基于液体树脂混合物。
4.如权利要求1-3中任一项所要求的用途，用于涂覆具有3D表面和/或锋利边缘部分的物品。
5.如权利要求1-3中任一项所要求的用途，使用单一蜜胺树脂薄片和/或薄膜进行涂覆。
6.如权利要求1-3中任一项所要求的用途，用于涂覆木基材料。
7.如权利要求1-3中任一项所要求的用途，用于涂覆定向纤维板(OSB)。
8.如权利要求1所要求的用途，其中纤维素纤维材料使用蜜胺-甲醛浸渍树脂或使用蜜胺-甲醛浸渍树脂和涂覆树脂的混合物或使用脲-甲醛树脂和蜜胺-脲-甲醛树脂的混合物进行预浸渍并使用如权利要求1定义的(i)-(iii)的水溶液进行后浸渍。
9.一种用于浸渍纤维素纤维材料的合成树脂混合物，该混合物包含
(i)5-50重量％的蜜胺-甲醛缩合物，
(ii)5-50重量％的醚化的蜜胺-甲醛缩合物，和
(iii)40-90重量％的水分散体形式的共聚物，该共聚物可通过缩合反应交联，
组分(i)、(ii)和(iii)的量总和为100重量％，并且基于液体树脂混合物；其中该混合物将含有羧基、羟基、酰胺基、缩水甘油基、羰基、N-羟甲基、N-烷氧基甲基、氨基和/或联亚氨基的丙烯酸酯的共聚物用作组分(iii)。
10.一种使用如权利要求9所要求的合成树脂混合物浸渍的蜜胺树脂薄片或薄膜。
11.一种3D涂覆的方法，该方法包括在一项操作中将权利要求10所要求的蜜胺树脂薄片和/或薄膜二维涂覆到材料的三维结构上。
12.一种3D涂覆的方法，该方法包括由纤维素纤维材料生产蜜胺树脂薄片和/或薄膜，其中纤维素纤维材料使用权利要求1的水溶液进行后浸渍或预浸渍和后浸渍，以及将蜜胺树脂薄片和/或薄膜涂覆到待涂覆的三维结构表面和/或模制品上。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2003101901 DE10301901A1 (de) | 2003-01-17 | 2003-01-17 | Verwendung von Melaminharzfolien und/oder -filmen zur Beschichtung von dreidimensional strukturierten Oberflächen und/oder Formkörpern |
| DE10301901.4 | 2003-01-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1738863A CN1738863A (zh) | 2006-02-22 |
| CN100374501C true CN100374501C (zh) | 2008-03-12 |
Family
ID=32602747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800023169A Expired - Fee Related CN100374501C (zh) | 2003-01-17 | 2004-01-10 | 蜜胺树脂薄片和/或薄膜用于涂覆三维结构表面和/或模制品的用途 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7306842B2 (zh) |
| EP (1) | EP1587870A1 (zh) |
| JP (1) | JP2006516935A (zh) |
| CN (1) | CN100374501C (zh) |
| CA (1) | CA2512890A1 (zh) |
| DE (1) | DE10301901A1 (zh) |
| PL (1) | PL378346A1 (zh) |
| WO (1) | WO2004065484A1 (zh) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004034528A1 (de) * | 2004-07-15 | 2006-02-16 | Basf Ag | Verwendung von Metaminharzfolien und/oder -filmen zur 3D-Beschichtung |
| DE102005035691A1 (de) * | 2005-07-27 | 2007-02-01 | Basf Ag | Aminoplastharzfilm zur Beschichtung von Substraten |
| JP2009541506A (ja) * | 2006-06-20 | 2009-11-26 | ビーエーエスエフ ソシエタス・ヨーロピア | ナノ多孔性被覆した多孔性材料 |
| CN101589198B (zh) * | 2007-01-24 | 2012-10-03 | 巴斯夫欧洲公司 | 具有研磨表面的挠性片状基材 |
| JP5377637B2 (ja) * | 2008-07-24 | 2013-12-25 | ビーエーエスエフ ソシエタス・ヨーロピア | 研磨表面を有するフレキシブルな平面状基材 |
| EP2388295A1 (de) | 2010-05-21 | 2011-11-23 | Wietec Technologie KG | Verfahren zur Herstellung eines transparenten Kunststoffmaterials |
| JP6447557B2 (ja) * | 2016-03-24 | 2019-01-09 | 日亜化学工業株式会社 | 発光装置の製造方法 |
| EP3263560A1 (en) | 2016-06-29 | 2018-01-03 | Borealis Agrolinz Melamine GmbH | Novel triazine-precondensate-aldehyde condensation products and method for obtaining the same |
| EP3263561A1 (en) | 2016-06-29 | 2018-01-03 | Borealis Agrolinz Melamine GmbH | Novel triazine precondensate and method for obtaining the same |
| BR112023000209A2 (pt) * | 2020-07-10 | 2023-01-31 | Basf Se | Material fibroso impregnado com resina na forma de uma lâmina ou folha, processos para produzir um material fibroso impregnado com resina e para prover um painel com uma superfície de plástico, uso do material fibroso de lâmina impregnado com resina, e, painel tendo uma superfície de plástico |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0268809A2 (de) * | 1986-10-24 | 1988-06-01 | CASSELLA Aktiengesellschaft | Verfahren zur Herstellung von Melaminharzfolien |
| US5330846A (en) * | 1988-11-09 | 1994-07-19 | Basf Aktiengesellschaft | Heat-curable, aqueous synthetic resin mixtures for coating woodworking materials |
| US5670572A (en) * | 1994-11-04 | 1997-09-23 | Hoechst Aktiengesellschaft | Impregnating resins for films and edgings |
| DE19937759A1 (de) * | 1999-08-10 | 2001-02-15 | Basf Ag | Verfahren zur Herstellung von Platten mit dekorativer Oberfläche |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3936547A (en) * | 1973-02-24 | 1976-02-03 | Cassella Farbwerke Mainkur Aktiengesellschaft | Process of preparing melamine resin films by impregnation of paper, cellulose, fleece or fabric |
| JPS5113208U (zh) * | 1974-07-17 | 1976-01-30 | ||
| SE417849B (sv) | 1974-11-20 | 1981-04-13 | Billingsfors Bruks Ab | Forfarande for tillverkning av impregnerad och ytbehandlad folie |
| JPS6285938A (ja) * | 1985-10-11 | 1987-04-20 | 住友ベークライト株式会社 | メラミン樹脂化粧板 |
| DE4139961A1 (de) * | 1991-12-04 | 1993-06-09 | Basf Ag, 6700 Ludwigshafen, De | Traenkharzloesung zum impraegnieren von papierbahnen |
| JP3789694B2 (ja) * | 1999-10-04 | 2006-06-28 | 住友ベークライト株式会社 | メラミン樹脂化粧シート |
| DE19954189A1 (de) * | 1999-11-11 | 2001-05-17 | Basf Ag | Melaminharzdispersionen |
| EP1136537A1 (en) * | 2000-03-20 | 2001-09-26 | Akzo Nobel N.V. | Adhesive system |
-
2003
- 2003-01-17 DE DE2003101901 patent/DE10301901A1/de not_active Withdrawn
-
2004
- 2004-01-10 WO PCT/EP2004/000121 patent/WO2004065484A1/de active Application Filing
- 2004-01-10 CN CNB2004800023169A patent/CN100374501C/zh not_active Expired - Fee Related
- 2004-01-10 PL PL37834604A patent/PL378346A1/pl not_active Application Discontinuation
- 2004-01-10 US US10/542,305 patent/US7306842B2/en not_active Expired - Fee Related
- 2004-01-10 CA CA 2512890 patent/CA2512890A1/en not_active Abandoned
- 2004-01-10 JP JP2006500542A patent/JP2006516935A/ja active Pending
- 2004-01-10 EP EP04701297A patent/EP1587870A1/de not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0268809A2 (de) * | 1986-10-24 | 1988-06-01 | CASSELLA Aktiengesellschaft | Verfahren zur Herstellung von Melaminharzfolien |
| US5330846A (en) * | 1988-11-09 | 1994-07-19 | Basf Aktiengesellschaft | Heat-curable, aqueous synthetic resin mixtures for coating woodworking materials |
| US5670572A (en) * | 1994-11-04 | 1997-09-23 | Hoechst Aktiengesellschaft | Impregnating resins for films and edgings |
| DE19937759A1 (de) * | 1999-08-10 | 2001-02-15 | Basf Ag | Verfahren zur Herstellung von Platten mit dekorativer Oberfläche |
Non-Patent Citations (1)
| Title |
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| "高固含量醚化蜜胺甲醛树脂制备及其稳定性". 杨惊.热固性树脂，第1期. 2005 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE10301901A1 (de) | 2004-07-29 |
| JP2006516935A (ja) | 2006-07-13 |
| PL378346A1 (pl) | 2006-03-20 |
| WO2004065484A1 (de) | 2004-08-05 |
| US20060051606A1 (en) | 2006-03-09 |
| CA2512890A1 (en) | 2004-08-05 |
| CN1738863A (zh) | 2006-02-22 |
| EP1587870A1 (de) | 2005-10-26 |
| US7306842B2 (en) | 2007-12-11 |
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