CN100372974C - High-efficient diaphragm and mfg. method - Google Patents
High-efficient diaphragm and mfg. method Download PDFInfo
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- CN100372974C CN100372974C CNB2005100605965A CN200510060596A CN100372974C CN 100372974 C CN100372974 C CN 100372974C CN B2005100605965 A CNB2005100605965 A CN B2005100605965A CN 200510060596 A CN200510060596 A CN 200510060596A CN 100372974 C CN100372974 C CN 100372974C
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Abstract
The present invention relates to a high-efficiency membrane and a manufacturing method thereof, the high-efficiency membrane is formed by compounding basal body layers and main body layers, wherein the basal body layers are made of polypropylene fiber needled-punched felts, and the main body layers with a teflon microporous membranes are compounded on at least one lateral face of each of the basal body layers; the thickness of the basal body layers is from 1 to 2 millimeters; the main body layers with teflon microporous membranes are respectively compounded on two sides of the basal body layers; the thickness of the main body layers with teflon microporous membranes is from 1 micrometer and 9 micrometers, and the hole diameter of micropores is from 0.4 to 0.5 mu m; the manufacturing method has the following steps: selecting conventional polypropylene fiber needled-punched felts as the basal body layers, and cutting the polypropylene fiber needled-punched felts into various needed shapes; selecting teflon materials to pull into the microporous membranes as the main body layers after hydrophile processing, forming a high efficiency membrane with a single side tectorial membrane or bilateral tectorial membranes by sticking adhesives onto one side of each of the basal body layers. The present invention has the characteristics of low electricity, high intensity, long service life time and easy use, and is capable of keeping electrolysis environment stable in the operating process of equipment and making the equipment operate stably, etc.
Description
Technical field
What the present invention relates to is a kind of high-efficient diaphragm and making method that is exclusively used in the electrolysis chlorine dioxide generator.
Background technology
In the prior art, electrolysis chlorine dioxide generator is the equipment that method that saturated common salt aqueous solution is separated in a kind of electricity consumption produces dioxide peroxide and chlorine, and barrier film is one of pass part parts wherein, and membranous quality directly influences the stability of equipment, the size of gas production rate, the height of electrolytic efficiency.On the Chinese patent communique, disclose relevant electrolysis chlorine dioxide generator technology contents, disclose " electrolysis chlorine dioxide generator " and " electrolytic process high efficiency chlorine dioxide producer " respectively as ZL89209620.9 and ZL99204871.0.Barrier film commonly used at present has woven asbesto, little plate, poly-tetrafluoro woven cloth, the Polypropylene etc. of oozing of polyethylene, these films owing to course of processing aperture difference apart from big or owing to the reason of material itself, in use film blocks easily, life-span of gas production rate instability, film is short etc., because the existence of these shortcomings has directly influenced machine performance.
Summary of the invention
The object of the present invention is to provide a kind of electrolysis chlorine dioxide generator that is exclusively used in high-efficient diaphragm and making method, defective such as it can overcome, and the film that exists in the prior art blocks easily, the life-span of gas production rate instability, film is short.
The objective of the invention is to finish by following technical solution, a kind of high-efficient diaphragm, it is composited by base layer and body layer, and wherein base layer is made by the polypropylene fibre Nomex, is compounded with the poly-tetrafluoro microporous membrane body layer that is drawn into again after hydrophilic treatment at least one side of this base layer.
The thickness of described base layer is at the 1-2 millimeter.
Respectively be compounded with a strata tetrafluoro microporous membrane body layer on two faces of described base layer.
The thickness of described poly-tetrafluoro microporous membrane body layer is between the 1-9 micron, and the aperture of micropore is at 0.4-0.5 μ m.
A kind of method of making foregoing high-efficient diaphragm, it selects conventional polypropylene fibre Nomex for use is base layer, is cut into various desired shapes; Select for use poly-PTFE after hydrophilic treatment, to be drawn into microporous membrane again, adhere to the high-efficient diaphragm that constitutes one-sided overlay film or bilateral overlay film on side of base layer or the bilateral by tackiness agent as body layer.
Described poly-PTFE is made into the microporous membrane body layer of micropore size at 0.4-0.5 μ m.
Described base layer is made into 1-2 millimeter thickness, is made into the 1-9 micron thickness at the body layer of its surface recombination, and it is compounded on the one or both sides of base layer.
The base layer material that the present invention selects for use has following principal feature: its intensity is big, and it is very thin that matrix can be done; Easy to use, cutting is convenient, can be cut into different shape to it easily, and after the cutting in addition deburring just can use; The water permeability of material is good; And acid and alkali-resistance, resistance to oxidation; Substantially not flexible in the electrolysis chlorine dioxide generator operating temperature range.Selected body layer material has good hydrophilicity, thickness has only several microns, film infiltration itself, its infiltration aperture is less than one micron, such aperture is easy to exchange at the electrolytic process intermediate ion, and the liquids and gases on both sides are not easy exchange, so electrolytic environments can keep stable in the operational process of equipment, make equipment steady running.The present invention compared with prior art, have electricity decrease low, intensity is big, the life-span is long, easy to use, characteristics such as manufacture craft is simple, and cost is low.
Description of drawings
Figure 1 shows that individual layer structure of film synoptic diagram of the present invention.
Figure 2 shows that double-deck structure of film synoptic diagram of the present invention.
Embodiment
The present invention will be described in detail below in conjunction with accompanying drawing: the present invention is composited by base layer 1 and body layer 2, and wherein base layer 1 is made by the polypropylene fibre Nomex; On a side of this base layer 1, be compounded with the poly-tetrafluoro microporous membrane body layer 2 that after hydrophilic treatment, is drawn into again, see shown in Figure 1.
Described base layer 1 intensity is big, and it is very thin that base layer can be done, and thickness is substantially at the 1-2 millimeter; Easy to use, cutting is convenient, can be cut into different shape to it easily, and after the cutting in addition deburring just can use; The water permeability of material is good; And acid and alkali-resistance, resistance to oxidation; Substantially not flexible in the electrolysis chlorine dioxide generator operating temperature range.The present invention respectively is compounded with a strata tetrafluoro microporous membrane body layer 2 on two faces of described base layer 1, see shown in the accompanying drawing 2.
The thickness of poly-tetrafluoro microporous membrane body layer 2 of the present invention is between the 1-9 micron, and the aperture of micropore is at 0.4-0.5 μ m.These body layer 2 materials have good hydrophilicity, thickness has only several microns, film infiltration itself, its infiltration aperture is less than one micron, such aperture is easy to exchange at the electrolytic process intermediate ion, and the liquids and gases on both sides are not easy exchange, so electrolytic environments can keep stable in the operational process of equipment, make equipment steady running.
Manufacture craft of the present invention is simple, and it selects conventional polypropylene fibre Nomex for use is base layer, is cut into various desired shapes; Select for use poly-PTFE after the hydrophilic treatment of routine, to be drawn into microporous membrane again, adhere to the high-efficient diaphragm that constitutes one-sided overlay film or bilateral overlay film on side of base layer or the bilateral by tackiness agent as body layer.
Described poly-PTFE is made into the microporous membrane body layer of micropore size at 0.4-0.5 μ m.
Described base layer is made into 1-2 millimeter thickness, is made into the 1-9 micron thickness at the body layer of its surface recombination, and it is compounded on the one or both sides of base layer.
Claims (7)
1. high-efficient diaphragm, it is characterized in that it is composited by base layer (1) and body layer (2), wherein base layer (1) is made by the polypropylene fibre Nomex, is compounded with the poly-tetrafluoro microporous membrane body layer (2) that is drawn into again after hydrophilic treatment at least one side of this base layer (1).
2. high-efficient diaphragm according to claim 1, the thickness that it is characterized in that described base layer (1) is at the 1-2 millimeter.
3. according to claim 1 or 2 described high-efficient diaphragms, it is characterized in that respectively being compounded with a strata tetrafluoro microporous membrane body layer (2) on two faces of described base layer (1).
4. high-efficient diaphragm according to claim 3, the thickness that it is characterized in that described poly-tetrafluoro microporous membrane body layer (2) are between the 1---9 micron, and the aperture of micropore is at 0.4-0.5 μ m.
5. the method for a making such as claim 1 or 2 or 3 or 4 described high-efficient diaphragms, it selects conventional polypropylene fibre Nomex for use is base layer, is cut into various desired shapes; Select for use poly-PTFE after hydrophilic treatment, to be drawn into microporous membrane again, adhere to the high-efficient diaphragm that constitutes one-sided overlay film or bilateral overlay film on side of base layer or the bilateral by tackiness agent as body layer.
6. the method for making high-efficient diaphragm according to claim 5 is characterized in that described poly-PTFE is made into the microporous membrane body layer of micropore size at 0.4-0.5 μ m.
7. according to the method for claim 5 or 6 described making high-efficient diaphragms, it is characterized in that described base layer is made into 1-2 millimeter thickness, be made into the 1-9 micron thickness at the body layer of its surface recombination, and it is compounded on the one or both sides of base layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100605965A CN100372974C (en) | 2005-08-23 | 2005-08-23 | High-efficient diaphragm and mfg. method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100605965A CN100372974C (en) | 2005-08-23 | 2005-08-23 | High-efficient diaphragm and mfg. method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1752294A CN1752294A (en) | 2006-03-29 |
| CN100372974C true CN100372974C (en) | 2008-03-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2005100605965A Expired - Fee Related CN100372974C (en) | 2005-08-23 | 2005-08-23 | High-efficient diaphragm and mfg. method |
Country Status (1)
| Country | Link |
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| CN (1) | CN100372974C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101372752B (en) * | 2007-08-21 | 2010-12-08 | 天津工业大学 | High temperature resistant alkaline water electrolytic cell barrier diaphragm and preparation thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4081350A (en) * | 1976-10-29 | 1978-03-28 | Olin Corporation | Diaphragms for use in the electrolysis of alkali metal chlorides |
| CN2069863U (en) * | 1990-05-23 | 1991-01-23 | 北京海淀永航技术开发公司 | Chlorine dioxide codisinfectant generator |
| CN2175236Y (en) * | 1993-09-13 | 1994-08-24 | 薛志文 | Electrolytic bath of generator for producing chlorine dioxide disinfectant |
| CN2192629Y (en) * | 1994-06-01 | 1995-03-22 | 申承绪 | Chlorine dioxide generator |
| JP2000300921A (en) * | 1999-04-21 | 2000-10-31 | Nitto Denko Corp | Air filter material and air filter unit using the same |
| US6299939B1 (en) * | 2000-04-28 | 2001-10-09 | Ppg Industries Ohio, Inc. | Method of preparing a diaphragm for an electrolytic cell |
| CN1404170A (en) * | 2001-08-23 | 2003-03-19 | 北京有色金属研究总院 | Reinforced diaphragm material for battery and its making process |
| CN1415540A (en) * | 2002-11-19 | 2003-05-07 | 华东理工大学 | Method for removing sulfate ion from solution containing sodium chloride with high concentration |
| CN2841680Y (en) * | 2005-08-23 | 2006-11-29 | 陈维军 | Efficient diaphragm for chlorine dioxide generator by electrolytic process |
-
2005
- 2005-08-23 CN CNB2005100605965A patent/CN100372974C/en not_active Expired - Fee Related
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4081350A (en) * | 1976-10-29 | 1978-03-28 | Olin Corporation | Diaphragms for use in the electrolysis of alkali metal chlorides |
| CN2069863U (en) * | 1990-05-23 | 1991-01-23 | 北京海淀永航技术开发公司 | Chlorine dioxide codisinfectant generator |
| CN2175236Y (en) * | 1993-09-13 | 1994-08-24 | 薛志文 | Electrolytic bath of generator for producing chlorine dioxide disinfectant |
| CN2192629Y (en) * | 1994-06-01 | 1995-03-22 | 申承绪 | Chlorine dioxide generator |
| JP2000300921A (en) * | 1999-04-21 | 2000-10-31 | Nitto Denko Corp | Air filter material and air filter unit using the same |
| US6299939B1 (en) * | 2000-04-28 | 2001-10-09 | Ppg Industries Ohio, Inc. | Method of preparing a diaphragm for an electrolytic cell |
| CN1404170A (en) * | 2001-08-23 | 2003-03-19 | 北京有色金属研究总院 | Reinforced diaphragm material for battery and its making process |
| CN1415540A (en) * | 2002-11-19 | 2003-05-07 | 华东理工大学 | Method for removing sulfate ion from solution containing sodium chloride with high concentration |
| CN2841680Y (en) * | 2005-08-23 | 2006-11-29 | 陈维军 | Efficient diaphragm for chlorine dioxide generator by electrolytic process |
Non-Patent Citations (1)
| Title |
|---|
| 丙纶针刺毡滤布在真空过滤机上的试验及应用. 何孔群.冶金动力，第1期. 1999 * |
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| CN1752294A (en) | 2006-03-29 |
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