CN100359744C - 12-HK(M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery - Google Patents

12-HK(M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery Download PDF

Info

Publication number
CN100359744C
CN100359744C CNB2005100693129A CN200510069312A CN100359744C CN 100359744 C CN100359744 C CN 100359744C CN B2005100693129 A CNB2005100693129 A CN B2005100693129A CN 200510069312 A CN200510069312 A CN 200510069312A CN 100359744 C CN100359744 C CN 100359744C
Authority
CN
China
Prior art keywords
add
lead
battery
type high
pure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2005100693129A
Other languages
Chinese (zh)
Other versions
CN1688060A (en
Inventor
陈有孝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CNB2005100693129A priority Critical patent/CN100359744C/en
Publication of CN1688060A publication Critical patent/CN1688060A/en
Application granted granted Critical
Publication of CN100359744C publication Critical patent/CN100359744C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

The present invention puts forward a dry charge type sealing lead acid accumulator of a 12-HK(M)-28 type with high energy and maintenance free. The performance of the accumulator can meet the requirement of a GJB606-88 standard for a 12-HKA-28 type accumulator, and the basic performance of the accumulator is improved in vast scale. The novel dry charge type lead acid accumulator of a 12-HK(M)-28 type has the advantages of high energy, dry charge type, full sealing and maintenance free.

Description

High-energy dry-charged sealed maintenance-free lead-acid battery
Technical field: the present invention proposes a kind of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, belongs to the novel energy field.
Background technology: 12-HKA-28 type lead acid accumulator is one of main on-board batteries of air unit.When aircraft master electric power system broke down, as aircraft emergency service power supply, its importance was conspicuous.
Airborne emergency power supply mainly contains lead acid accumulator, nickel-cadmium cell and silver-zinc battery.
The leading indicator of 24V-20Ah nickel-cadmium cell is: weight is 22.5kg, and gravimetric specific energy is 21.3Wh/kg, and volume is 361mm * 180mm * 168mm=10.9166dm 3, volumetric specific energy is 43.96Wh/dm 3, level is real to be belonged to generally.Yet the major advantage of nickel-cadmium cell is: have good heavy-current discharge performance.For example: 1CA can reach about 50 minutes discharge time, and the lead acid accumulator Nippon Standard only required to discharge 27 minutes; The 3CA of nickel-cadmium cell, 5CA, 7CA discharge performance are fine in addition.But cadmium is hypertoxic element.The severe contamination of cadmium receives whole world environmentalist's concern, in addition, nickel-cadmium cell price height, a 24V-20Ah nickel-cadmium cell is wanted about 5000 yuan, is 5～7 times of lead acid accumulator.
The feature performance benefit of silver-zinc battery is: gravimetric specific energy reaches 70Wh/kg～130Wh/kg, and volumetric specific energy reaches 200Wh/dm 3But, the costing an arm and a leg of silver-zinc battery, one group of airborne 28.5V-20Ah battery price is wanted hundreds thousand of yuans, and silver-colored in addition resource has seldom limited promoting the use of of silver-zinc battery.
The major defect of 12-HKA-28 type common lead acid accumulator is:
1) gravimetric specific energy is low, only is 23.5Wh/kg, and volumetric specific energy only is 49.918Wh/dm 3
2) high-rate discharge ability is poor, and the 1CA discharge only can be emitted 45% of nominal capacity;
3) battery produces a large amount of acid mists when charging;
4) battery meeting escape sulfuric acid electrolyte in installation, use;
5) battery needs periodic maintenance, adds sulfuric acid electrolyte.
Invent a kind of high-energy dry-charged formula full sealed non-maintenance type on-board batteries for this reason, under the condition that does not change 12-HKA-28 type battery volume and weight, the key property that improves battery is to replace nickel-cadmium cell, and this is useful for aviation industry, and the object of the present invention is achieved like this.
Summary of the invention: a kind of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
1, the positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.06%～0.08%Ca+0.01%～0.08%Al+0.01%～0.08%Cu+0.02%～0.09%In+0.2%～1.2%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
2, the negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.09%～0.12%Ca+0.01%～0.05%Al+0.01%～0.06%Cu+0.05%～0.15%Bi+0.2%～1.2%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
3, the positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3～1.25g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 100g～500g, add acrylic staple fibre 100g～500g, add 400 order Al 2O 3100g～600g adds 400 order ZrO 250g～300g adds 300 order SnO 50g～500g, adds 300 order CoSO 450g～300g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.2g/cm 3～4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
4, the composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3～1.25g/cm 3Sulfuric acid solution, add 100g～500g BaSO 4Add 200g～600g humic acid, add 100g～600g alpha-or beta-naphthoic acid, add 50g～400g diffusion agent N, add 50g～300g Ou Telawen W, add 50g～300g bismuth metal, add 100g～500g anisotropy graphite, add 100g～300g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3～4.3g/cm 3, be applied among the negative electrode grid;
5, the curing by routine, change into and make ripe pole plate;
6, the electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.30g/cm 3～1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.02%～0.1%Na 2SO 4, add 0.02%～0.08% hydroxyl sodium phosphate, add 0.01%～0.05%ZnSO 4, add 0.01%～0.08%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
7, be assembled into 12-HK (M)-28 type battery.
Technical scheme 2:12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.06%～0.065%Ca+0.0 1%～0.02%Al+0.01%～0.03%Cu+0.02%～0.03%In+0.2%～0.4%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.09%～0.095%Ca+0.01%～0.02%Al+0.01%～0.02%Cu+0.05%～0.06%Bi+0.2%～0.5%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 1 00kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 100g～200g, add acrylic staple fibre 100g～150g, add 400 order Al 2O 3100g～200g adds 400 order ZrO 250g～80g adds 300 order SnO 50g～100g, adds 300 order CoSO 450g～80g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm 3Sulfuric acid solution, add 100g～150g BaSO 4Add 200g～250g humic acid, add 100g～200g alpha-or beta-naphthoic acid, add 50g～100g diffusion agent N, add 50g～100g Ou Telawen W, add 50g～80g bismuth metal, add 100g～200g anisotropy graphite, add 100g～120g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.02%～0.04%Na 2SO 4, add 0.02%～0.03% hydroxyl sodium phosphate, add 0.01%～0.02%ZnSO 4, add 0.01%～0.02%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
Technical scheme 3:12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.065%～0.068%Ca+0.02%～0.04%Al+0.03%～0.05%Cu+0.03%～0.04%In+0.4%～0.6%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.095%～0.1%Ca+0.02%～0.025%Al+0.02%～0.03%Cu+0.06%～0.08%Bi+0.5%～0.8%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.23g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 200g～300g, add acrylic staple fibre 150g～200g, add 400 order Al 2O 3200g～300g adds 400 order ZrO 280g～120g adds 300 order SnO100g～200g, adds 300 order CoSO 480g～100g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 150g～200g BaSO 4Add 250g～300g humic acid, add 200g～300g alpha-or beta-naphthoic acid, add 100g～200g diffusion agent N, add 100g～150g Ou Telawen W, add 80g～100g bismuth metal, add 200g～250g anisotropy graphite, add 120g～150g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.26g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.04%～0.06%Na 2SO 4, add 0.03%～0.04% hydroxyl sodium phosphate, add 0.02%～0.03%ZnSO 4, add 0.02%～0.03%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
Technical scheme 4:12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.068%～0.07%Ca+0.04%～0.05%Al+0.05%～0.06%Cu+0.04%～0.06%In+0.6%～0.8%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.1%～0.11%Ca+0.025%～0.03%Al+0.03%～0.04%Cu+0.08%～0.1%Bi+0.8%～0.9%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 300g～350g, add acrylic staple fibre 200g～300g, add 400 order Al 2O 3300g～400g adds 400 order ZrO 2120g～200g adds 300 order SnO200g～300g, adds 300 order CoSO 4100g～150g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.23g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.23g/cm 3Sulfuric acid solution, add 200g～300g BaSO 4Add 300g～400g humic acid, add 300g～400g alpha-or beta-naphthoic acid, add 200g～300g diffusion agent N, add 150g～200g Ou Telawen W, add 100g～150g bismuth metal, add 250g～300g anisotropy graphite, add 150g～180g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.06%～0.07%Na 2SO 4, add 0.04%～0.06% hydroxyl sodium phosphate, add 0.03%～0.04%ZnSO 4, add 0.05%～0.06%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
Technical scheme 5:12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.07%～0.075%Ca+0.05%～0.06%Al+0.06%～0.07%Cu+0.06%～0.07%In+0.8%～1.0%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.11%～0.115%Ca+0.03%～0.04%Al+0.04%～0.05%Cu+0.01%～0.12%Bi+0.9%～1.0%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 350g～400g, add acrylic staple fibre 300g～400g, add 400 order Al 2O 3400g～500g adds 400 order ZrO 2200g～250g adds 300 order SnO300g～400g, adds 300 order CoSO 4150g～200g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.23g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 300g～400g BaSO 4Add 400g～500g humic acid, add 400g～500g alpha-or beta-naphthoic acid, add 300g～350g diffusion agent N, add 200g～250g Ou Telawen W, add 150g～200g bismuth metal, add 300g～400g anisotropy graphite, add 180g～250g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.07%～0.08%Na 2SO 4, add 0.06%～0.07% hydroxyl sodium phosphate, add 0.04%～0.05%ZnSO 4, add 0.06%～0.07%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
Technical scheme 6:12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.075%～0.08%Ca+0.06%～0.08%Al+0.07%～0.08%Cu+0.07%～0.09%In+1.0%～1.2%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.115%～0.12%Ca+0.04%～0.05%Al+0.05%～0.06%Cu+0.12%～0.15%Bi+1.0%～1.2%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 400g～500g, add acrylic staple fibre 400g～500g, add 400 order Al 2O 3500g～600g adds 400 order ZrO 2250g～300g adds 300 order SnO400g～500g, adds 300 order CoSO 4200g～300g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400g～500g BaSO 4Add 500g～600g humic acid, add 500g～600g alpha-or beta-naphthoic acid, add 350g～400g diffusion agent N, add 250g～300g Ou Telawen W, add 200g～300g bismuth metal, add 400g～500g anisotropy graphite, add 250g～300g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.08～0.1%Na 2SO 4, add 0.07～0.08% hydroxyl sodium phosphate, add 0.02～0.05%ZnSO 4, add 0.07～0.08%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
Technical scheme 7:12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.06%Ca+0.03%Al+0.05%Cu+0.02%In+0.8%Sn and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.1%Ca+0.03%Al+0.04%Cu+0.08%Bi+1.0%Sn, is heated to 500 ℃～520 ℃, casts negative electrode grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 250g, add acrylic staple fibre 400g, add 400 order Al 2O 3600g adds 400 order ZrO 2200g adds 300 order SnO 100g, adds 300 order CoSO 4300g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 200g BaSO 4, add the 600g humic acid, add the 300g alpha-or beta-naphthoic acid, add the 100g diffusion agent N, add 200g Ou Telawen W, add the 100g bismuth metal, add 500g anisotropy graphite, add the 100g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.03%Na 2SO 4, add 0.05% hydroxyl sodium phosphate, add 0.05%ZnSO 4, add 0.04%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
Technical scheme 8:12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.08%Ca+0.06%Al+0.08%Cu+0.09%In+0.5%Sn and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.12%Ca+0.04%Al+0.05%Cu+0.06%Bi+0.9%Sn, is heated to 500 ℃～520 ℃, casts negative electrode grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 200g, add acrylic staple fibre 300g, add 400 order Al 2O 3400g adds 400 order ZrO 2260g adds 300 order SnO 400g, adds 300 order CoSO 4180g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm 3Sulfuric acid solution, add 400g BaSO 4, add the 300g humic acid, add the 420g alpha-or beta-naphthoic acid, add the 400g diffusion agent N, add 80g Ou Telawen W, add the 220g bismuth metal, add 300g anisotropy graphite, add the 160g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.06%Na 2SO 4, add 0.06% hydroxyl sodium phosphate, add 0.04%ZnSO 4, add 0.02%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
Technical scheme 9:12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.065%Ca+0.05%Al+0.02%Cu+0.05%In+1.0%Sn and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.09%Ca+0.035%Al+0.035%Cu+0.12%Bi+0.8%Sn, is heated to 500 ℃～520 ℃, casts negative electrode grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.24g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 300g, add acrylic staple fibre 200g, add 400 order Al 2O 3200g adds 400 order ZrO 2150g adds 300 order SnO 200g, adds 300 order CoSO 4200g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 500g BaSO 4, add the 350g humic acid, add the 550g alpha-or beta-naphthoic acid, add the 200g diffusion agent N, add 250g Ou Telawen W, add the 150g bismuth metal, add 250g anisotropy graphite, add the 200g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.09%Na 2SO 4, add 0.02% hydroxyl sodium phosphate, add 0.03%ZnSO 4, add 0.05%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
Technical scheme 10:12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.07%Ca+0.01%Al+0.03%Cu+0.06%In+0.9%Sn and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.09%Ca+0.028%Al+0.02%Cu+0.13%Bi+0.6%Sn, is heated to 500 ℃～520 ℃, casts negative electrode grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 400g, add acrylic staple fibre 150g, add 400 order Al 2O 3300g adds 400 order ZrO 2120g adds 300 order SnO 150g, adds 300 order CoSO 490g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 150g BaSO 4, add the 400g humic acid, add the 200g alpha-or beta-naphthoic acid, add the 350g diffusion agent N, add 100g Ou Telawen W, add the 50g bismuth metal, add 120g anisotropy graphite, add the 280g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.05%Na 2SO 4, add 0.04% hydroxyl sodium phosphate, add 0.02%ZnSO 4, add 0.06%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
Description of drawings:
Accompanying drawing 1 is 12-HK (M)-28 a type high-energy dry-charged sealed maintenance-free lead-acid battery shell sizes schematic diagram.(1) is the long 372mm of battery cell case among the figure, and (2) are the wide 166mm of battery cell case, and (3) are the height overall 218mm of battery cell case, and (4) are the high 22mm of the loam cake of battery cell case.
Accompanying drawing 2 is 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery shell schematic diagrames of going to the bottom.(5) are the storage battery high 196mm that goes to the bottom among the figure, (6) upper cover part 14mm for inserting.
Accompanying drawing 3 is 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery loading electrolytes with 12 disjunctor plastic bottle cross-sectional schematic.(7) are disjunctor plastic bottle beam overall 373mm among the figure, and (8) are disjunctor plastic bottle height overall 100mm.
Embodiment:
Embodiment:
According to the GJB606-88 standard, 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery shell sizes is: long 372mm, and wide 166mm, high 218mm, as shown in Figure 1.The loam cake that is designed to sealed, maintenance-free battery will keep enough air chamber height and get 22mm, goes to the bottom highly to be 196mm, as shown in Figure 2.Pole adopts internal thread directly to go out the shape pole, and cell height is 218mm for this reason.Positive plate monolithic capacity 10Ah.
Producing 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery manufacture method is:
1, the positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
The pure Pb of 100kg (Pb content＞99.994%)+alloy of 80gCa+20gAl+20gCu+80gIn+960Sn is put into lead pan and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid;
2, the negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
The alloy of the pure Pb of 100kg (Pb content＞99.994%)+90gCa+30gAl+20gCu+100gBi+980Sn is put into lead pan, is heated to 500 ℃～520 ℃, casts negative electrode grid;
3, the positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in 100kg lead powder (oxidizability is 78%) is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 300g, add acrylic staple fibre 280g, add 400 order Al 2O 3200g adds 400 order ZrO 2100g adds 300 order SnO 150g, adds CoSO 4100g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
4, the composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in 100kg lead powder (oxidizability is 78%) is 1.22g/cm 3Sulfuric acid solution, add 300g BaSO 4, add the 300g humic acid, add the 280g alpha-or beta-naphthoic acid, add the 200g diffusion agent N, add 180g Ou Telawen W, add the 120g bismuth metal, add 280g anisotropy graphite, add the 150g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
5, the curing by routine, change into and make ripe pole plate;
6, the electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 50g Na 2SO 4, add 80g hydroxyl sodium phosphate, add 40g ZnSO 4, add 60g CdSO 4, in 12 (disjunctor or the monomer) plastic bottles of packing into, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes;
7, be assembled into 12-HK (M)-28 type battery.
Assembling scheme one:
With 10 of positive plates, 11 of negative plates, the battery actual capacity of assembling reaches 100Ah, promptly becomes 12-HK (M)-100 battery.28Ah exceeds 257% than the GJB606-88 standard-required; Battery weight is 48kg, and gravimetric specific energy reaches 50Wh/kg, and volumetric specific energy is 178Wh/dm 3, cell discharge performance improves 200% than GJB606-88 standard, has improved the coefficient of safety of flight;
Assembling scheme two:
The control battery weight is 28.5kg (according to the GJB606-88 standard-required);
Select: 6 of positive plates, 7 of negative plates; The battery actual capacity is 60Ah, exceeds 114% than GJB606-88 standard; The gravimetric specific energy of battery is 50.5Wh/kg, and the battery case size can be reduced into 228mm * 166mm * 218mm, and volume reduces 38%;
The index that assembling scheme two reaches is:
1) the constant 28.5kg of weight (according to the GJB606-88 standard-required);
2) battery capacity improves 114%, reaches 60Ah, and battery performance improves 100% than GJB606-88 standard;
3) the battery volume can reduce 38%, can save 4.148dm 3The space;
Assembling scheme three:
Accomplish 28Ah according to the GJB606-88 standard-required; Get 3 of positive plates, 4 of negative plates, the battery volume can be reduced to 126m * 166mm * 128mm, and volume reduces 66.14%, and weight can be decreased to 15kg, and weight has reduced 46%.Battery performance can satisfy the requirement of GJB606-88 standard to 12-HKA-28 type battery.

Claims (10)

1, a kind of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.06%～0.08%Ca+0.01%～0.08%Al+0.01%～0.08%Cu+0.02%～0.09%In+0.2%～1.2%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.09%～0.12%Ca+0.01%～0.05%Al+0.01%～0.06%Cu+0.05%～0.15%Bi+0.2%～1.2%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3～1.25g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 100g～500g, add acrylic staple fibre 100g～500g, add 400 order Al 2O 3100g～600g adds 400 order ZrO 250g～300g adds 300 order SnO 50g～500g, adds 300 order CoSO 450g～300g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.2g/cm 3～4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3～1.25g/cm 3Sulfuric acid solution, add 100g～500g BaSO 4Add 200g～600g humic acid, add 100g～600g alpha-or beta-naphthoic acid, add 50g～400g diffusion agent N, add 50g～300g Ou Telawen W, add 50g～300g bismuth metal, add 100g～500g anisotropy graphite, add 100g～300g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3～4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.30g/cm 3～1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.02%～0.1%Na 2SO 4, add 0.02%～0.08% hydroxyl sodium phosphate, add 0.01%～0.05%ZnSO 4, add 0.01%～0.08%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
2, by the described 12-HK of claim 1 (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.06%～0.065%Ca+0.01%～0.02%Al+0.01%～0.03%Cu+0.02%～0.03%In+0.2%～0.4%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.09%～0.095%Ca+0.01%～0.02%Al+0.01%～0.02%Cu+0.05%～0.06%Bi+0.2%～0.5%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 100g～200g, add acrylic staple fibre 100g～150g, add 400 order Al 2O 3100g～200g adds 400 order ZrO 250g～80g adds 300 order SnO 50g～100g, adds 300 order CoSO 450g～80g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm 3Sulfuric acid solution, add 100g～150g BaSO 4Add 200g～250g humic acid, add 100g～200g alpha-or beta-naphthoic acid, add 50g～100g diffusion agent N, add 50g～100g Ou Telawen W, add 50g～80g bismuth metal, add 100g～200g anisotropy graphite, add 100g～120g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.02%～0.04%Na 2SO 4, add 0.02%～0.03% hydroxyl sodium phosphate, add 0.01%～0.02%ZnSO 4, add 0.01%～0.02%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
3, by the described 12-HK of claim 1 (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.065%～0.068%Ca+0.02%～0.04%Al+0.03%～0.05%Cu+0.03%～0.04%In+0.4%～0.6%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.095%～0.1%Ca+0.02%～0.025%Al+0.02%～0.03%Cu+0.06%～0.08%Bi+0.5%～0.8%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.23g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 200g～300g, add acrylic staple fibre 150g～200g, add 400 order Al 2O 3200g～300g adds 400 order ZrO 280g～120g adds 300 order SnO100g～200g, adds 300 order CoSO 480g～100g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 150g～200g BaSO 4Add 250g～300g humic acid, add 200g～300g alpha-or beta-naphthoic acid, add 100g～200g diffusion agent N, add 100g～150g Ou Telawen W, add 80g～100g bismuth metal, add 200g～250g anisotropy graphite, add 120g～150g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.26g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.04%～0.06%Na 2SO 4, add 0.03%～0.04% hydroxyl sodium phosphate, add 0.02%～0.03%ZnSO 4, add 0.02%～0.03%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
4, by the described 12-HK of claim 1 (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.068%～0.07%Ca+0.04%～0.05%Al+0.05%～0.06%Cu+0.04%～0.06%In+0.6%～0.8%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.1%～0.11%Ca+0.025%～0.03%Al+0.03%～0.04%Cu+0.08%～0.1%Bi+0.8%～0.9%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 300g～350g, add acrylic staple fibre 200g～300g, add 400 order Al 2O 3300g～400g adds 400 order ZrO 2120g～200g adds 300 order SnO200g～300g, adds 300 order CoSO 4100g～150g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.23g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.23g/cm 3Sulfuric acid solution, add 200g～300g BaSO 4Add 300g～400g humic acid, add 300g～400g alpha-or beta-naphthoic acid, add 200g～300g diffusion agent N, add 150g～200g Ou Telawen W, add 100g～150g bismuth metal, add 250g～300g anisotropy graphite, add 150g～180g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.06%～0.07%Na 2SO 4, add 0.04%～0.06% hydroxyl sodium phosphate, add 0.03%～0.04%ZnSO 4, add 0.05%～0.06%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
5, by the described 12-HK of claim 1 (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.07%～0.075%Ca+0.05%～0.06%Al+0.06%～0.07%Cu+0.06%～0.07%In+0.8%～1.0%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.11%～0.115%Ca+0.03%～0.04%Al+0.04%～0.05%Cu+0.01%～0.12%Bi+0.9%～1.0%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 350g～400g, add acrylic staple fibre 300g～400g, add 400 order Al 2O 3400g～500g adds 400 order ZrO 2200g～250g adds 300 order SnO300g～400g, adds 300 order CoSO 4150g～200g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.23g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 300g～400g BaSO 4Add 400g～500g humic acid, add 400g～500g alpha-or beta-naphthoic acid, add 300g～350g diffusion agent N, add 200g～250g Ou Telawen W, add 150g～200g bismuth metal, add 300g～400g anisotropy graphite, add 180g～250g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.07%～0.08%Na 2SO 4, add 0.06%～0.07% hydroxyl sodium phosphate, add 0.04%～0.05%ZnSO 4, add 0.06%～0.07%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
6, by the described 12-HK of claim 1 (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.075%～0.08%Ca+0.06%～0.08%Al+0.07%～0.08%Cu+0.07%～0.09%In+1.0%～1.2%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.115%～0.12%Ca+0.04%～0.05%Al+0.05%～0.06%Cu+0.12%～0.15%Bi+1.0%～1.2%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 400g～500g, add acrylic staple fibre 400g～500g, add 400 order Al 2O 3500g～600g adds 400 order ZrO 2250g～300g adds 300 order SnO400g～500g, adds 300 order CoSO 4200g～300g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400g～500g BaSO 4Add 500g～600g humic acid, add 500g～600g alpha-or beta-naphthoic acid, add 350g～400g diffusion agent N, add 250g～300g Ou Telawen W, add 200g～300g bismuth metal, add 400g～500g anisotropy graphite, add 250g～300g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.08～0.1%Na 2SO 4, add 0.07～0.08% hydroxyl sodium phosphate, add 0.02～0.05%ZnSO 4, add 0.07～0.08%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
7, by the described 12-HK of claim 1 (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.06%Ca+0.03%Al+0.05%Cu+0.02%In+0.8%Sn and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.1%Ca+0.03%Al+0.04%Cu+0.08%Bi+1.0%Sn, is heated to 500 ℃～520 ℃, casts negative electrode grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 250g, add acrylic staple fibre 400g, add 400 order Al 2O 3600g adds 400 order ZrO 2200g adds 300 order SnO 100g, adds 300 order CoSO 4300g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 200g BaSO 4, add the 600g humic acid, add the 300g alpha-or beta-naphthoic acid, add the 100g diffusion agent N, add 200g Ou Telawen W, add the 100g bismuth metal, add 500g anisotropy graphite, add the 100g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.03%Na 2SO 4, add 0.05% hydroxyl sodium phosphate, add 0.05%ZnSO 4, add 0.04%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
8, by the described 12-HK of claim 1 (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.08%Ca+0.06%Al+0.08%Cu+0.09%In+0.5%Sn and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.12%Ca+0.04%Al+0.05%Cu+0.06%Bi+0.9%Sn, is heated to 500 ℃～520 ℃, casts negative electrode grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 200g, add acrylic staple fibre 300g, add 400 order Al 2O 3400g adds 400 order ZrO 2260g adds 300 order SnO 400g, adds 300 order CoSO 4180g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm 3Sulfuric acid solution, add 400g BaSO 4, add the 300g humic acid, add the 420g alpha-or beta-naphthoic acid, add the 400g diffusion agent N, add 80g Ou Telawen W, add the 220g bismuth metal, add 300g anisotropy graphite, add the 160g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.06%Na 2SO 4, add 0.06% hydroxyl sodium phosphate, add 0.04%ZnSO 4, add 0.02%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
9, by the described 12-HK of claim 1 (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.065%Ca+0.05%Al+0.02%Cu+0.05%In+1.0%Sn and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.09%Ca+0.035%Al+0.035%Cu+0.12%Bi+0.8%Sn, is heated to 500 ℃～520 ℃, casts negative electrode grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.24g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 300g, add acrylic staple fibre 200g, add 400 order Al 2O 3200g adds 400 order ZrO 2150g adds 300 order SnO 200g, adds 300 order CoSO 4200g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 500g BaSO 4, add the 350g humic acid, add the 550g alpha-or beta-naphthoic acid, add the 200g diffusion agent N, add 250g Ou Telawen W, add the 150g bismuth metal, add 250g anisotropy graphite, add the 200g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.09%Na 2SO 4, add 0.02% hydroxyl sodium phosphate, add 0.03%ZnSO 4, add 0.05%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
10, by the described 12-HK of claim 1 (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.07%Ca+0.01%Al+0.03%Cu+0.06%In+0.9%Sn and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of 99.994% pure Pb100kg+0.09%Ca+0.028%Al+0.02%Cu+0.13%Bi+0.6%Sn, is heated to 500 ℃～520 ℃, casts negative electrode grid, and above-mentioned composition percentage is based on the pure Pb of 100kg;
The positive electrode active compound composition of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 400 order anisotropy graphite 400g, add acrylic staple fibre 150g, add 400 order Al 2O 3300g adds 400 order ZrO 2120g adds 300 order SnO 150g, adds 300 order CoSO 490g stirs in paste mixing machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm 3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm 3Sulfuric acid solution, add 150g BaSO 4, add the 400g humic acid, add the 200g alpha-or beta-naphthoic acid, add the 350g diffusion agent N, add 100g Ou Telawen W, add the 50g bismuth metal, add 120g anisotropy graphite, add the 280g acrylic staple fibre, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm 3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 12-HK (M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm 3The 100kg sulfuric acid electrolyte in add 0.05%Na 2SO 4, add 0.04% hydroxyl sodium phosphate, add 0.02%ZnSO4, add 0.06%CdSO 4, in the plastic bottle of pack into 12 disjunctors or monomer, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes, above-mentioned composition degree is the mass percent based on the 100Kg sulfuric acid electrolyte;
Be assembled into 12-HK (M)-28 type battery.
CNB2005100693129A 2005-05-13 2005-05-13 12-HK(M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery Expired - Fee Related CN100359744C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2005100693129A CN100359744C (en) 2005-05-13 2005-05-13 12-HK(M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2005100693129A CN100359744C (en) 2005-05-13 2005-05-13 12-HK(M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery

Publications (2)

Publication Number Publication Date
CN1688060A CN1688060A (en) 2005-10-26
CN100359744C true CN100359744C (en) 2008-01-02

Family

ID=35306100

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2005100693129A Expired - Fee Related CN100359744C (en) 2005-05-13 2005-05-13 12-HK(M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery

Country Status (1)

Country Link
CN (1) CN100359744C (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000048812A (en) * 1998-07-30 2000-02-18 Shin Kobe Electric Mach Co Ltd Positive electrode plate for lead-acid battery
CN1430305A (en) * 2002-01-04 2003-07-16 李天佐 High-molecular battery
JP2004327299A (en) * 2003-04-25 2004-11-18 Furukawa Battery Co Ltd:The Sealed lead-acid storage battery
CN1560944A (en) * 2004-02-18 2005-01-05 北京天睿力迈科技有限公司 High-energy full-closed lead-acid battery for communication system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000048812A (en) * 1998-07-30 2000-02-18 Shin Kobe Electric Mach Co Ltd Positive electrode plate for lead-acid battery
CN1430305A (en) * 2002-01-04 2003-07-16 李天佐 High-molecular battery
JP2004327299A (en) * 2003-04-25 2004-11-18 Furukawa Battery Co Ltd:The Sealed lead-acid storage battery
CN1560944A (en) * 2004-02-18 2005-01-05 北京天睿力迈科技有限公司 High-energy full-closed lead-acid battery for communication system

Also Published As

Publication number Publication date
CN1688060A (en) 2005-10-26

Similar Documents

Publication Publication Date Title
US3457112A (en) Lead-acid storage battery
CN100399620C (en) Valve control type lead acid accumulator for metro vehicle
US3765942A (en) Accumulator or battery with sulfuric acid electrolyte containing phosphoric acid
CN100508269C (en) Colloid lead-cloth batteries in high energy, and preparation method
CN101916861A (en) Cathode lead plaster capable of prolonging fast charge-discharge circulating life of battery and preparation method thereof
CN103594738A (en) High-temperature valve regulated sealed lead-acid storage battery
CN108878872A (en) A kind of lead-acid accumulator anode diachylon and preparation method thereof
CN105633399A (en) High-specific-energy lead-acid battery easy for formation
KR100832375B1 (en) A Gel electrolyte of Long Life Valve regulated sealed lead acid battery for Solar and Wind Power
CN103594748A (en) Internal battery formation method
CN103337609B (en) Manufacture the method for superhigh temperature overcharging resisting long-life nickel-hydrogen battery
CN100359744C (en) 12-HK(M)-28 type high-energy dry-charged sealed maintenance-free lead-acid battery
CN108365301A (en) One kind can charging/discharging type liquid metal cell
CN100403593C (en) 6-HK(M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery
CN1688057A (en) 12-HK(M)-30 type high-energy dry-charged sealed maintenance-free lead-acid battery
CN100355140C (en) 12-TK(M)-100 type high-energy dry-charged sealed maintenance-free load-acid battery for armoured car
CN203445164U (en) Sealing cover of maintenance-free lead-acid battery and maintenance-free lead-acid battery
CN1591957B (en) High-energy all-sealed lead-acid battery without maintaining for submarine
CN102340042A (en) Solar photovoltaic battery
CN2237282Y (en) Sealed maintenance-free tube colloid accumulator
CN108417840A (en) A kind of valve-regulated rare earth energy storing battery
CN1560952A (en) 7-HK-182 type high-energy full-closed lead-acid battery for aviation
CN103594740A (en) Composite colloid comprising organic components and inorganic components for battery container formation
CN108400390A (en) A kind of high energy-storage battery of new structure nano-colloid
CN100377412C (en) 12-TK(M)-220 type high-energy dry-charged sealed maintance-free lead-acid battery for tank

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Tianjin Development Zone Shen Ma Technology Development Co. Ltd.

Assignor: Chen Youxiao

Contract fulfillment period: 2009.6.25 to 2014.6.25 contract change

Contract record no.: 2009120000135

Denomination of invention: 12-HK(M)-30 type high-energy dry-charged sealed maintenance-free lead-acid battery

Granted publication date: 20080102

License type: Exclusive license

Record date: 2009.7.22

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.6.25 TO 2014.6.25; CHANGE OF CONTRACT

Name of requester: TIANJIN DEVELOPMENT ZONE SHENMA SCIENCE AND TECHNO

Effective date: 20090722

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20080102

Termination date: 20130513