CN100403593C - 6-HK(M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery - Google Patents
6-HK(M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery Download PDFInfo
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- CN100403593C CN100403593C CNB2005100693133A CN200510069313A CN100403593C CN 100403593 C CN100403593 C CN 100403593C CN B2005100693133 A CNB2005100693133 A CN B2005100693133A CN 200510069313 A CN200510069313 A CN 200510069313A CN 100403593 C CN100403593 C CN 100403593C
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Abstract
The present invention puts forward a dry charge type sealing lead acid accumulator of a 6-HK(M)-55 type with high energy and maintenance free. The performance of the accumulator can meet the requirement of a GJB606-88 standard for a 6-HKA-55 type accumulator, and the basic performance of the accumulator is improved in vast scale. The novel dry charge type lead acid accumulator of a 6-HK(M)-55 type has the advantages of high energy, dry charge type, full sealing and maintenance free.
Description
Technical field:
The present invention proposes a kind of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, belongs to the novel energy field.
Background technology:
6-HKA-55 type lead acid accumulator is one of main on-board batteries of air force.When aircraft master electric power system broke down, as aircraft emergency service power supply, its importance was conspicuous.
Airborne emergency power supply mainly contains lead acid accumulator, nickel-cadmium cell and silver-zinc battery.
The leading indicator of 12V-50Ah nickel-cadmium cell is: weight is 36.2kg, and gravimetric specific energy is 16.57Wh/kg, and volume is 372mm * 304mm * 254mm=28.72dm
3, volumetric specific energy is 20.89Wh/dm
3, level is real to be belonged to generally.Yet the major advantage of nickel-cadmium cell is: have good heavy-current discharge performance.For example: 1CA can reach about 60 minutes discharge time, and the lead acid accumulator Nippon Standard only required to discharge 27 minutes; The 3CA of nickel-cadmium cell, 5CA, 7CA discharge performance are fine in addition.But cadmium is hypertoxic element.The severe contamination of cadmium receives whole world environmentalist's concern, in addition, nickel-cadmium cell price height, a 12V-50Ah nickel-cadmium cell is wanted about 6000 yuan, is 6～8 times of lead acid accumulator.
The feature performance benefit of silver-zinc battery is: gravimetric specific energy reaches 70Wh/kg～130Wh/kg, and volumetric specific energy reaches 200Wh/dm
3But, the costing an arm and a leg of silver-zinc battery, one group of airborne 14V-50Ah battery price is wanted hundreds thousand of yuans, and silver-colored in addition resource has seldom limited promoting the use of of silver-zinc battery.
The major defect of 6-HKA-55 type common lead acid accumulator is:
1) gravimetric specific energy is low, only is 22.76h/kg, and volumetric specific energy only is 49.03Wh/dm
3
2) high-rate discharge ability is poor, and the 1CA discharge only can be emitted 45% of nominal capacity;
3) battery produces a large amount of acid mists when charging;
4) battery meeting escape sulfuric acid electrolyte in installation, use;
5) battery needs periodic maintenance, adds sulfuric acid electrolyte.
Invent a kind of high-energy dry-charged formula full sealed non-maintenance type on-board batteries for this reason, under the condition that does not change 6-HKA-55 type battery volume and weight, the key property that improves battery is to replace nickel-cadmium cell, and this is useful for aviation industry, and the object of the present invention is achieved like this.
Summary of the invention:
The present invention proposes a kind of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
1, the positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
The pure Pb of 100kg (Pb content＞99.994%)+alloy of 0.06%～0.08%Ca+0.01%～0.08%Al+0.01%～0.08%Cu+0.02%～0.09%In+0.2%～1.2%Sn is put into lead pan and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid;
2, the negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
The alloy of the pure Pb of 100kg (Pb content＞99.994%)+0.09%～0.12%Ca+0.01%～0.05%Al+0.01%～0.06%Cu+0.05%～0.15%Bi+0.2%～1.2%Sn is put into lead pan, be heated to 500 ℃～520 ℃, cast negative electrode grid;
3, the positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in 100kg lead powder (oxidizability is 76%～78%) is 1.22g/cm
3～1.25g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 100g～500g, add acrylic short fiber 100g～500g, add 400 order Al
2O
3100g～600g adds 400 order ZrO
250g～300g adds 300 order SnO 50g～500g, adds 300 order CoSO
450g～300g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.2g/cm
3～4.25g/cm
3, this anode diachylon is applied among the anode plate grid;
4, the composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in 100kg lead powder (oxidizability is 76%～78%) is 1.22g/cm
3～1.25g/cm
3Sulfuric acid solution, add 100g～500g BaSO
4Add 200g～600g humic acid, add 100g～600g alpha-or beta-naphthoic acid, add 50g～400g diffusion agent N, add 50g～300g Ou Telawen W, add 50g～300g bismuth metal, add 100g～500g opposite sex graphite, add 100g～300g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3～4.3g/cm
3, be applied among the negative electrode grid;
5, the curing by routine, change into and make ripe pole plate;
6, the electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.30g/cm
3～1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.02%～0.1%Na
2SO
4, add 0.02%～0.08% hydroxyl sodium phosphate, add 0.01%～0.05%ZnSO
4, add 0.01%～0.08%CdSO
4, in 6 (disjunctor or the monomer) plastic bottles of packing into, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes;
7, be assembled into 6-HK (M)-55 type battery.
Description of drawings:
Accompanying drawing 1 is 6-HK (M)-55 a type high-energy dry-charged sealed maintenance-free lead-acid battery shell sizes schematic diagram.(1) is the long 372mm of battery cell case among the figure, and (2) are the wide 166mm of battery cell case, and (3) are the height overall 218mm of battery cell case, and (4) are the high 22mm of the loam cake of battery cell case.
Accompanying drawing 2 is 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery shell schematic diagrames of going to the bottom.(5) are the storage battery high 196mm that goes to the bottom among the figure, (6) upper cover part 14mm for inserting.
Accompanying drawing 3 is 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery loading electrolytes with 12 disjunctor plastic bottle cross-sectional schematic.(7) are disjunctor plastic bottle beam overall 373mm among the figure, and (8) are disjunctor plastic bottle height overall 165mm.
Embodiment:
Embodiment:
According to the GJB606-88 standard, 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery shell sizes is: long 372mm, and wide 166mm, high 218mm, as shown in Figure 1.The loam cake that is designed to sealed, maintenance-free battery will keep enough air chamber height and get 22mm, goes to the bottom highly to be 196mm, as shown in Figure 2.Pole adopts internal thread directly to go out the shape pole, and cell height is 218mm for this reason.Positive plate monolithic capacity 20Ah.
Producing 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery manufacture method is:
1, the positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
The pure Pb of 100kg (Pb content＞99.994%)+alloy of 80gCa+20gAl+20gCu+80gIn+960Sn is put into lead pan and is melted, and is warming up to 500 ℃～520 ℃, casts anode plate grid;
2, the negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
The alloy of the pure Pb of 100kg (Pb content＞99.994%)+90gCa+30gAl+20gCu+100gBi+980Sn is put into lead pan, is heated to 500 ℃～520 ℃, casts negative electrode grid;
3, the positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in 100kg lead powder (oxidizability is 76%～78%) is 1.22g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 300g, add acrylic short fiber 280g, add 400 order Al
2O
3200g adds 400 order ZrO
2100g adds 300 order SnO 150g, adds CoSO
4100g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3, this anode diachylon is applied among the anode plate grid;
4, the composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in 100kg lead powder (oxidizability is 76%～78%) is 1.22g/cm
3Sulfuric acid solution, add 300g BaSO
4, add the 300g humic acid, add the 280g alpha-or beta-naphthoic acid, add the 200g diffusion agent N, add 180g Ou Telawen W, add the 120g bismuth metal, add 280g opposite sex graphite, add 150g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm
3, be applied among the negative electrode grid;
5, the curing by routine, change into and make ripe pole plate;
6, the electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 50g Na
2SO
4, add 80g hydroxyl sodium phosphate, add 40g ZnSO
4, add 60g CdSO
4, in 6 (disjunctor or the monomer) plastic bottles of packing into, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes;
7, be assembled into 6-HK (M)-55 type battery.
Assembling scheme one:
With 9 of positive plates, 10 of negative plates, the battery actual capacity of assembling reaches 180Ah, promptly becomes 6-HK (M)-180 battery.55Ah exceeds 227% than the GJB606-88 standard-required; Battery weight is 43kg, and gravimetric specific energy reaches 50.2Wh/kg, and volumetric specific energy is 160.47Wh/dm
3, 6-HK (M)-180 type cell discharge performance improves 200% than GJB606-88 standard, has improved the coefficient of safety of flight;
Assembling scheme two:
The control battery weight is 29kg (according to the GJB606-88 standard-required);
Select: 6 of positive plates, 7 of negative plates; The battery actual capacity is 120Ah, exceeds 118% than GJB606-88 standard; The gravimetric specific energy of battery is 48.8Wh/kg, and the battery case size can be reduced into 248mm * 166mm * 218mm, and volume reduces 33.3%;
The index that assembling scheme two reaches is:
1) the constant 29kg of weight (according to the GJB606-88 standard-required);
2) battery capacity improves 118%, reaches 120Ah, and battery performance improves 100% than GJB606-88 standard;
3) the battery volume can reduce 33.3%, can save 4.44dm
3The space;
Assembling scheme three:
Only accomplish that 55Ah (according to the GJB606-88 standard-required) gets 3 of positive plates, 4 of negative plates, the battery volume can be reduced to 126m * 166mm * 128mm, and volume reduces 66.14%, and weight can be decreased to 15kg, and weight has reduced 46%.Battery performance can satisfy the requirement of GJB606-88 standard to 6-HKA-55 type battery.
Claims (10)
1. a 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.06%～0.08%Ca+0.01%～0.08%Al+0.01%～0.08%Cu+0.02%～0.09%In+0.2%～1.2%Sn of 99.994% and is melted, be warming up to 500 ℃～520 ℃, cast anode plate grid, above-mentioned composition percentage by weight is based on the pure Pb of 100kg;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is put into lead pan greater than the alloy of pure Pb100kg+0.09%～0.12%Ca+0.01%～0.05%Al+0.01%～0.06%Cu+0.05%～0.15%Bi+0.2%～1.2%Sn of 99.994%, be heated to 500 ℃～520 ℃, cast negative electrode grid, above-mentioned composition percentage by weight is based on the pure Pb of 100kg;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3～1.25g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 100g～500g, add acrylic short fiber 100g～500g, add 400 order Al
2O
3100g～600g adds 400 order ZrO
250g～300g adds 300 order SnO 50g～500g, adds 300 order CoSO
450g～300g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.2g/cm
3～4.25g/cm
3, this anode diachylon is applied among the anode plate grid;
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3～1.25g/cm
3Sulfuric acid solution, add 100g～500g BaSO
4Add 200g～600g humic acid, add 100g～600g alpha-or beta-naphthoic acid, add 50g～400g diffusion agent N, add 50g～300g Ou Telawen W, add 50g～300g bismuth metal, add 100g～500g opposite sex graphite, add 100g～300g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3～4.3g/cm
3, be applied among the negative electrode grid;
Curing by routine, change into and make ripe pole plate;
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.30g/cm
3～1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.02%～0.1%Na
2SO
4, add 0.02%～0.08% hydroxyl sodium phosphate, add 0.01%～0.05%ZnSO
4, add 0.01%～0.08%CdSO
4, in pack into 6 disjunctors or the monomer plastic bottle, treat to inject the electrolyte among the battery when battery uses, can use after 20 minutes;
Be assembled into 6-HK (M)-55 type battery.
2. press claims 1 described 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb100kg+0.06%～0.065%Ca+0.01%～0.02%Al+0.01%～0.03%Cu+0.02%～0.03%In+0.2%～0.4%Sn of 99.994%;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb100kg+0.09%～0.095%Ca+0.01%～0.02%Al+0.01%～0.02%Cu+0.05%～0.06%Bi+0.2%～0.5%Sn of 99.994%;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 100g～200g, add acrylic short fiber 100g～150g, add 400 order Al
2O
3100g～200g adds 400 order ZrO
250g～80g adds 300 order SnO 50g～100g, adds 300 order CoSO
450g～80g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm
3Sulfuric acid solution, add 100g～150g BaSO
4Add 200g～250g humic acid, add 100g～200g alpha-or beta-naphthoic acid, add 50g～100g diffusion agent N, add 50g～100g Ou Telawen W, add 50g～80g bismuth metal, add 100g～200g opposite sex graphite, add 100g～120g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm
3
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.02%～0.04%Na
2SO
4, add 0.02%～0.03% hydroxyl sodium phosphate, add 0.01%～0.02%ZnSO
4, add 0.01%～0.02%CdSO
4
3. press claims 1 described 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb100kg+0.065%～0.068%Ca+0.02%～0.04%Al+0.03%～0.05%Cu+0.03%～0.04%In+0.4%～0.6%Sn of 99.994%;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb100kg+0.095%～0.1%Ca+0.02%～0.025%Al+0.02%～0.03%Cu+0.06%～0.08%Bi+0.5%～0.8%Sn of 99.994%;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.23g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 200g～300g, add acrylic short fiber 150g～200g, add 400 order Al
2O
3200g～300g adds 400 order ZrO
280g～120g adds 300 order SnO 100g～200g, adds 300 order CoSO
480g～100g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 150g～200g BaSO
4Add 250g～300g humic acid, add 200g～300g alpha-or beta-naphthoic acid, add 100g～200g diffusion agent N, add 100g～150g Ou Telawen W, add 80g～100g bismuth metal, add 200g～250g opposite sex graphite, add 120g～150g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.26g/cm
3
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.04%～0.06%Na
2SO
4, add 0.03%～0.04% hydroxyl sodium phosphate, add 0.02%～0.03%ZnSO
4, add 0.02%～0.03%CdSO
4
4. press claims 1 described 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb 100kg+0.068%～0.07%Ca+0.04%～0.05%Al+0.05%～0.06%Cu+0.04%～0.06%In+0.6%～0.8%Sn of 99.994%;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb100kg+0.1%～0.11%Ca+0.025%～0.03%Al+0.03%～0.04%Cu+0.08%～0.1%Bi+0.8%～0.9%Sn of 99.994%;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 300g～350g, add acrylic short fiber 200g～300g, add 400 order Al
2O
3300g～400g adds 400 order ZrO
2120g～200g adds 300 order SnO 200g～300g, adds 300 order CoSO
4100g～150g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.23g/cm
3
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.23g/cm
3Sulfuric acid solution, add 200g～300g BaSO
4Add 300g～400g humic acid, add 300g～400g alpha-or beta-naphthoic acid, add 200g～300g diffusion agent N, add 150g～200g Ou Telawen W, add 100g～150g bismuth metal, add 250g～300g opposite sex graphite, add 150g～180g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.06%～0.07%Na
2SO
4, add 0.04%～0.06% hydroxyl sodium phosphate, add 0.03%～0.04%ZnSO
4, add 0.05%～0.06%CdSO
4
5. press claims 1 described 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb 100kg+0.07%～0.075%Ca+0.05%～0.06%Al+0.06%～0.07%Cu+0.06%～0.07%In+0.8%～1.0%Sn of 99.994%;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb100kg+0.11%～0.115%Ca+0.03%～0.04%Al+0.04%～0.05%Cu+0.01%～0.12%Bi+0.9%～1.0%Sn of 99.994%;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 350g～400g, add acrylic short fiber 300g～400g, add 400 order Al
2O
3400g～500g adds 400 order ZrO
2200g～250g adds 300 order SnO 300g～400g, adds 300 order CoSO
4150g～200g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.23g/cm
3
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 300g～400g BaSO
4Add 400g～500g humic acid, add 400g～500g alpha-or beta-naphthoic acid, add 300g～350g diffusion agent N, add 200g～250g Ou Telawen W, add 150g～200g bismuth metal, add 300g～400g opposite sex graphite, add 180g～250g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm
3
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.07%～0.08%Na
2SO
4, add 0.06%～0.07% hydroxyl sodium phosphate, add 0.04%～0.05%ZnSO
4, add 0.06%～0.07%CdSO
4
6. press claims 1 described 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb100kg+0.075%～0.08%Ca+0.06%～0.08%Al+0.07%～0.08%Cu+0.07%～0.09%In+1.0%～1.2%Sn of 99.994%;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than pure Pb100kg+0.115%～0.12%Ca+0.04%～0.05%Al+0.05%～0.06%Cu+0.12%～0.15%Bi+1.0%～1.2%Sn of 99.994%;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 400g～500g, add acrylic short fiber 400g～500g, add 400 order Al
2O
3500g～600g adds 400 order ZrO
2250g～300g adds 300 order SnO 400g～500g, adds 300 order CoSO
4200g～300g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 400g～500g BaSO
4Add 500g～600g humic acid, add 500g～600g alpha-or beta-naphthoic acid, add 350g～400g diffusion agent N, add 250g～300g Ou Telawen W, add 200g～300g bismuth metal, add 400g～500g opposite sex graphite, add 250g～300g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm
3
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.08～0.1%Na
2SO
4, add 0.07～0.08% hydroxyl sodium phosphate, add 0.02～0.05%ZnSO
4, add 0.07～0.08%CdSO
4
7. press claims 1 described 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than 99.994% pure Pb100kg+0.06%Ca+0.03%Al+0.05%Cu+0.02%In+0.8%Sn;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than 99.994% pure Pb100kg+0.1%Ca+0.03%Al+0.04%Cu+0.08%Bi+1.0%Sn;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 250g, add acrylic short fiber 400g, add 400 order Al
2O
3600g adds 400 order ZrO
2200g adds 300 order SnO 100g, adds 300 order CoSO
4300g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 200g BaSO
4, add the 600g humic acid, add the 300g alpha-or beta-naphthoic acid, add the 100g diffusion agent N, add 200g Ou Telawen W, add the 100g bismuth metal, add 500g opposite sex graphite, add 100g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm
3
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.03%Na
2SO
4, add 0.05% hydroxyl sodium phosphate, add 0.05%ZnSO
4, add 0.04%CdSO
4
8. press claims 1 described 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than 99.994% pure Pb100kg+0.08%Ca+0.06%Al+0.08%Cu+0.09%In+0.5%Sn;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than 99.994% pure Pb100kg+0.12%Ca+0.04%Al+0.05%Cu+0.06%Bi+0.9%Sn;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 200g, add acrylic short fiber 300g, add 400 order Al
2O
3400g adds 400 order ZrO
2260g adds 300 order SnO 400g, adds 300 order CoSO
4180g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.25g/cm
3Sulfuric acid solution, add 400g BaSO
4, add the 300g humic acid, add the 420g alpha-or beta-naphthoic acid, add the 400g diffusion agent N, add 80g Ou Telawen W, add the 220g bismuth metal, add 300g opposite sex graphite, add 160g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm
3
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.06%Na
2SO
4, add 0.06% hydroxyl sodium phosphate, add 0.04%ZnSO
4, add 0.02%CdSO
4
9. press claims 1 described 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than 99.994% pure Pb100kg+0.065%Ca+0.05%Al+0.02%Cu+0.05%In+1.0%Sn;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than 99.994% pure Pb100kg+0.09%Ca+0.035%Al+0.035%Cu+0.12%Bi+0.8%Sn;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.24g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 300g, add acrylic short fiber 200g, add 400 order Al
2O
3200g adds 400 order ZrO
2150g adds 300 order SnO 200g, adds 300 order CoSO
4200g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 500g BaSO
4, add the 350g humic acid, add the 550g alpha-or beta-naphthoic acid, add the 200g diffusion agent N, add 250g Ou Telawen W, add the 150g bismuth metal, add 250g opposite sex graphite, add 200g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm
3
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.09%Na
2SO
4, add 0.02% hydroxyl sodium phosphate, add 0.03%ZnSO
4, add 0.05%CdSO
4
10. press claims 1 described 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery, it is characterized in that:
The positive grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than 99.994% pure Pb100kg+0.07%Ca+0.01%Al+0.03%Cu+0.06%In+0.9%Sn;
The negative plate grid alloy prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Content is greater than 99.994% pure Pb100kg+0.09%Ca+0.028%Al+0.02%Cu+0.13%Bi+0.6%Sn;
The positive electrode active compound composition of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 400 orders opposite sex graphite 400g, add acrylic short fiber 150g, add 400 order Al
2O
3300g adds 400 order ZrO
2120g adds 300 order SnO 150g, adds 300 order CoSO
490g stirs in closing the cream machine, and transferring to the lead plaster apparent gravity with pure water is 4.25g/cm
3
The composition of cathode active materials of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
Adding 10L～12L proportion in the 100kg oxidizability is 76%～78% lead powder is 1.22g/cm
3Sulfuric acid solution, add 150g BaSO
4, add the 400g humic acid, add the 200g alpha-or beta-naphthoic acid, add the 350g diffusion agent N, add 100g Ou Telawen W, add the 50g bismuth metal, add 120g opposite sex graphite, add 280g acrylic short fiber, transferring to the lead plaster apparent gravity with pure water is 4.3g/cm
3
The electrolyte prescription of 6-HK (M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery is:
With proportion is 1.33g/cm
3The 100kg sulfuric acid electrolyte in add 0.05%Na
2SO
4, add 0.04% hydroxyl sodium phosphate, add 0.02%ZnSO
4, add 0.06%CdSO
4
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100693133A CN100403593C (en) | 2005-05-13 | 2005-05-13 | 6-HK(M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100693133A CN100403593C (en) | 2005-05-13 | 2005-05-13 | 6-HK(M)-55 type high-energy dry-charged sealed maintenance-free lead-acid battery |
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| Publication Number | Publication Date |
|---|---|
| CN1688061A CN1688061A (en) | 2005-10-26 |
| CN100403593C true CN100403593C (en) | 2008-07-16 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035740A (en) * | 1988-03-07 | 1989-09-20 | 宜宾市蓄电池厂 | Lead acid accumulator plate grid material and manufacture method thereof |
| US5401278A (en) * | 1992-04-09 | 1995-03-28 | Matsushita Electric Industrial Co., Ltd. | Method of making battery plates for lead acid storage batteries |
| JPH08115718A (en) * | 1994-10-13 | 1996-05-07 | Japan Storage Battery Co Ltd | Manufacture of lead-acid battery |
| CN1538544A (en) * | 2003-04-15 | 2004-10-20 | 上海飞轮有色冶炼厂 | High performance battery plate grid alloy |
| CN1591957A (en) * | 2004-02-18 | 2005-03-09 | 陈有孝 | High-energy all-sealed lead-acid battery without maintaining for submarine |
-
2005
- 2005-05-13 CN CNB2005100693133A patent/CN100403593C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035740A (en) * | 1988-03-07 | 1989-09-20 | 宜宾市蓄电池厂 | Lead acid accumulator plate grid material and manufacture method thereof |
| US5401278A (en) * | 1992-04-09 | 1995-03-28 | Matsushita Electric Industrial Co., Ltd. | Method of making battery plates for lead acid storage batteries |
| JPH08115718A (en) * | 1994-10-13 | 1996-05-07 | Japan Storage Battery Co Ltd | Manufacture of lead-acid battery |
| CN1538544A (en) * | 2003-04-15 | 2004-10-20 | 上海飞轮有色冶炼厂 | High performance battery plate grid alloy |
| CN1591957A (en) * | 2004-02-18 | 2005-03-09 | 陈有孝 | High-energy all-sealed lead-acid battery without maintaining for submarine |
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| CN1688061A (en) | 2005-10-26 |
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