CN100354562C - High alloy steel seamless steel pipe and production method thereof - Google Patents
High alloy steel seamless steel pipe and production method thereof Download PDFInfo
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- CN100354562C CN100354562C CNB2006100130848A CN200610013084A CN100354562C CN 100354562 C CN100354562 C CN 100354562C CN B2006100130848 A CNB2006100130848 A CN B2006100130848A CN 200610013084 A CN200610013084 A CN 200610013084A CN 100354562 C CN100354562 C CN 100354562C
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Abstract
The present invention relates to a high alloy steel seamless steel pipe and a production method thereof. The high alloy steel seamless steel pipe comprises the following chemical components: 0.08 to 0.12 wt% of C, 0.20 to 0.50 wt% of Si, 0.30 to 0.60 wt% of Mn, 8 to 9.5 wt% of Cr, 0.85 to 1.05 wt% of Mo, 0.01 to 0.04 wt% of Al, 0 to 0.4 wt% of Ni, 0.06 to 0.10 wt% of Cb, P which is less than 0.02 wt%, S which is less than 0.010 wt%, 0.18 to 0.25 wt% of V, 0.03 to 0.07 wt% of N and Fe as the rest. The production method comprises the steps that sponge iron and scrap steel are used as steel making raw materials and are melted into molten steel by an electric arc furnace; after the molten steel is refined outside the furnace and is degassed in vacuum, the molten steel is continuously cast into a circular pipe blank, and the cooled continuous casting pipe blank is heated in an annular heating furnace and carries out heating centering, heating perforation, continuous extension and rolling, heat treatment and flaw detection at last. The high alloy steel seamless steel pipe of the present invention has the advantages of good thermal stability and impact toughness, stable lasting plasticity, and high heat resistance and corrosion resistance, and is suitable for the high-pressure requirements of boilers of a fire power station and a nuclear power station, pipelines of a petroleum cracking device, steam pipes of a chemical industry pressure vessel, etc., superheater pipes and reheater pipes.
Description
Technical field
The present invention relates to a kind of heat-resisting, corrosion resistant seamless steel pipe that is used for employed steam tubes such as high-pressure autoclave, energy industry and chemical industry equipment, superheater tube, reheater tubing, relate in particular to a kind of high alloy steel seamless steel pipe and production method thereof.
Background technique
Fields such as high-pressure autoclave, heat power station, nuclear energy power generation station, cracking of oil device and chemical engineering industry are extensive use of high alloy steel seamless steel pipe, be one of product of these fields urgent needs, high alloy steel seamless steel pipe also is the product of high added value, high economic benefit.In utility boiler, use also extensive use in toolings such as the cracking of petrochemical industry, anti-sulphur, hydrogenation as superheater, reheater and main steam pipe road.At present, the main dependence on import of the high alloy steel seamless steel pipe of China, the difficult point of its manufacturing is:
Because the heat-resisting and decay resistance that the deviation of materials chemistry composition produces is low, perforation, continuous rolling, decide manufacturings high alloy steel seamless steel pipe technological problemses such as reducing and rolling, heat treatment and aligning and makes the high alloy steel seamless steel pipe appearance be out of shape defectives such as inequality, crackle, folding, absciss layer and surface oxidising.
Summary of the invention
Main purpose of the present invention is to solve the problem of above-mentioned high alloy steel seamless steel pipe, a kind of good thermal stability is provided, has good impact toughness, stable rupture ductility, high heat resistance energy and the high alloy steel seamless steel pipe and the production method thereof of decay resistance.
The technical solution adopted for the present invention to solve the technical problems is:.
It is C 0.08-0.12 that the chemical composition of high alloy steel seamless steel pipe is formed (weight %), Si 0.20-0.50, Mn 0.30-0.60, Cr 8-9.5, Mo 0.85-1.05, Al 0.01-0.04, Ni 0-0.4, Cb 0.06-0.10, P＜0.02, S＜0.010, V 0.18-0.25, N 0.03-0.07, surplus is Fe.
Be applicable to employed heat-resisting, corrosion-resistant high alloy steel seamless steel pipe and production methods thereof such as high-pressure autoclave, cracking of oil and chemical industry equipment, with the needs of the high temperature resistant and high pressure of the steam tube of the pipeline of the boiler that satisfies firepower power station and nuclear power station, cracking of oil equipment and pressure vessels for the chemical industry etc., superheater tube, reheater tube.High alloy steel seamless steel pipe is a T91 grade of steel seamless steel pipe, produces and check the ASTM standard of carrying out the U.S..
The production method of high alloy steel seamless steel pipe comprises and adopts sponge iron and steel scrap to do steelmaking feed, is fused into molten steel with electric arc furnaces, after external refining and vacuum outgas, the circular pipe of continuous casting heats cooled continuously cast billet for pipe-making in rotary heating furnace, heat centering, hot piercing, extension is rolling continuously, after deciding reducing and rolling, cooling, fixed length sawing, aligning, flaw detection, intimately handles, tempering, hot size, thermal straightening, flaw detection at last.
The present invention is the steelmaking feed that drops in electric arc furnaces by steel scrap 65-75 part and sponge iron 25-35 part, the energising heating, furnace charge is fused into molten steel gradually, adopt Control Based Bottom-blown Stirring, quicken the fusing of steel and the homogenization of heating, the furnace temperature of final electric arc furnaces arrives 1550～1650 ℃, and has made the slag of melt down.
Because the metal ingredient in the steel scrap is slightly had any different, for adjusting its composition, the input ratio of sponge iron and steel scrap is different, general steel scrap roughly 70 ± 5%, and all the other are sponge iron.After steel scrap and spongy iron drop into electric arc furnaces, adopt Control Based Bottom-blown Stirring, quicken the fusing of steel and the homogenization of heating, the steel scrap fusing point is reduced, quicken fusing, thereby effect such as obtain to cut down the consumption of energy, shorten the heat.Begin oxygen blast at furnace bottom, play the purpose of fluxing, change slag, saving power.Simultaneously, flux, thereby because carbon has reduced the scaling loss of iron prior to the iron oxidation in the oxygen blast of melt down.
In electric arc furnaces, drop into active lime stone 0.2375-0.2625 part, the nozzle molten bath in stove that is arranged on the electric arc furnaces bottom is blown into oxygen and argon gas, the top generation slag of molten steel, detect the Chemical composition of molten steel in real time, Chemical composition proportion requirement on demand drops into sponge iron or other ferro-alloy in electric arc furnaces.
Temperature reaches after 1550～1650 ℃ in stove, drops into active lime stone in electric arc furnaces, from furnace bottom oxygen blast gas and blowing argon gas in stove, stirs the molten steel molten bath and form foam in molten steel, can make the molten steel boiling, gas and be mingled with come-up.High-purity oxygen can fast controllable ground decarburization, helps that the eliminating of gas and slag inclusion forms foamed slag at molten steel surface in the steel, completely cuts off contacting of molten steel and gas.Simultaneously, generate the slag of certain basicity, and remove steel inclusion and harmful element, as phosphorus, sulphur etc.Dephosphorization rate reaches 80%, and desulfurization degree reaches 50%, the phosphorus content after the smelting＜0.02%.
Oxygen blast can make carbon and oxygen reaction cause the molten bath to stir, promote slag-metal reaction, helps early stage dephosphorization.In the reducing and smelting phase, active reaction between carbon and oxygen has enlarged steel one slag interface, helps further dephosphorization, helps the homogenization of molten steel component and temperature and gas, floating foreign, and active reaction between carbon and oxygen helps the formation of foamed slag.Adopt bottom blowing process to shorten the heat, reduce power consumption, improve dephosphorization, desulfurization operations, make molten steel composition, more uniform temperature, thereby improve steel quality, reduce cost, boost productivity.Molten steel to fusing carries out oxygen blast, the carbon in the oxidation molten steel, phosphorus; Remove gas and slag inclusion, make the even heat temperature raising of molten steel.Make molten metal and slag in the electric arc furnaces produce motion, to improve the dynamic conditions of metallurgical reaction.To pass through melt down, oxidation and take off four-stages such as charcoal phase, refining period, reducing period.
The chemical composition of the described needs of high alloy steel seamless steel pipe of the present invention is by weight percentage: C0.08-012, Si 0.20-0.50, Mn 0.30-0.60, Cr 8-9.5, Mo 0.85-1.05, Al 0.01-0.04, Ni0-0.4, Cb 0.06-0.10, P＜0.02, S＜0.010, V 0.18-0.25, N 0.03-0.07, surplus is Fe.
Adopt eccentric furnace bottom tapping, this tapping steel makes and leaves a part (10%～15%) molten steel and whole slag (not containing slag in the molten steel of pouring out) in the stove, and this is for next stove quickens fusing, early stage dephosphorization has been created condition; Simultaneously, improved control and reduced interference to power supply system.
Pour CaO-Al in the LF casting refining bag
2O
3Base refining slag 0.304-0.336 part will be injected LF casting refining bag through the molten steel that just refining back composition is qualified in the electric arc furnaces, and construction materials contract melts in the stove of oxidizing atmosphere, insulation, dephosphorization, decarburization and master alloyingization, stirs molten steel simultaneously.
The qualified molten steel of composition that just refined in the electric arc furnaces is moved on in the LF refining bag, at first construction materials contract melts (insulation), dephosphorization, decarburization and master alloyingization (this will follow the stirring of molten steel) in the stove of oxidizing atmosphere, then, elder generation is blown inert gas in bag, outgas, the stirring of deoxidation, desulfurization (this will follow and drop into pure metal powder, silk in molten steel), remove slag inclusion and carry out trimming etc., next, vacuumize in will wrapping, reduce the hydrogen in the steel.This stage will guarantee that the composition of Finished Steel all meets standard-required, accurately is controlled at the composition of steel in the narrow scope.The refractory material that the concise steel lining of LF is used is except that the working lining at slag line position, with 70%～80%Al
2O
3High-alumina brick, slag lining uses magnesite-chrome brick or magnesia carbon brick.
Blowing argon gas in casting refining bag again is blown into argon gas with the strong mixing condition of 110L/ (mint), outgases, deoxidation, desulfurization, drops into pure metal powder, silk simultaneously while stirring in molten steel, removes slag inclusion and carries out trimming.
Composition on request, ratio are with CaO-Al
2O
3The base refining slag (pour in the cast refining ladle by adding 3.2 ± 5%kg) per ton, hang arc furnace tapping (copper smelter slag does not flow out with molten steel) then, the steel of electric arc furnaces is poured in the refining ladle, impact by tapping steel stream makes synthetic slag emulsification, slag and steel fully mix, then calm, the slag of emulsification drips come-up, simultaneously, strong mixing condition with 110L/ (mint) is blown into argon gas, this flow process more than ten minute altogether, refining tasks such as its desulfurization, deoxidation (part is finished), removal nonmetal inclusion are just finished in this short time.
To cast vacuumizes in the refining bag again, reduces the hydrogen in the steel.Drop into silicon (Si) and carry out deoxidation under the condition of vacuum in molten steel, boiling phenomenon takes place in molten steel immediately, and gas is overflowed in the steel, and slag inclusion also enters slag along with boiling stirring face come-up, carries out operations such as dehydrogenation, denitrogenation.
Casting refining bag vacuumizes, furnace bottom blown inert gas in bag, keeps certain degree of vacuum.Drop into silicon (Si) and carry out deoxidation in molten steel, and then under the condition of vacuum, boiling phenomenon takes place molten steel immediately, gas is overflowed in the steel, and slag inclusion also enters slag along with boiling stirring face come-up, carries out operations such as dehydrogenation, denitrogenation.The result can make steel pure.The purpose of vacuum outgas mainly is in order to reduce the harmful gas in the steel, particularly hydrogen.What the present invention used is the Finkel method, is commonly referred to the VD method in China.Under vacuum condition, can outgas to molten steel effectively.In degree of vacuum is under the condition of 65Pa (0.5mmHg), can be to about the 1ppm with the hydrogen in the steel, and the ability of vacuum decarburization significantly improves simultaneously, utilizes this characteristics, and vacuum refining can obtain very pure steel, and refining time is 40min.
External refining is also referred to as double refining.In whole steelmaking process,, also require finish decarburization, dephosphorization in varying degrees, take off bag, desulfurization, removal gas, removing and be mingled with, adjust temperature and be adjusted to the metallurgical task of grading except that raw material are fused into the liquid state.Therefore, utilize the advantage of ultra high power arc furnace melting waste steel, other smelting task is finished in the double refining process.Substep carries out like this, to create best metallurgy condition, raises the efficiency.
Purpose is to transfer to make the dynamic conditions of metallurgical reaction preferably.For the steel making furnace of routine, when under the oxidability condition, carrying out decarburization,, can make reactant and reaction product that bigger transmission rate is arranged owing to lift in the molten bath that the carbon monoxide discharge causes.But, in electric arc furnace smelting technology,, make the speed of some metallurgical reactions quite slow because the reaction interface of furnace hearth is long-pending little, the superiority of electric arc furnace smelting reducing period can not be given full play to.For addressing this problem, the one, it is long-pending to improve slag steel contact interface, the 2nd, in the bottom of ladle air brick is installed and is blown into argon gas, the slag that relies on the Argon Bubble adhesion emulsification of floating in the molten steel drips, and the stirring of the caused molten steel of come-up bubble, the collision that promotes slag to drip merges and quickens come-up, and the 3rd, adopt the Argon stirring mean, quicken the mass transport process between the slag steel.Argon intensity is 109～218l/mint.
Continuous casting of the present invention is to adopt fixed crystallizer, even with fixed crystallizer water-cooled, that the bottom is uncovered.Mainly partly form by ladle, tundish, crystallizer, mold oscillation loading amount, secondary cooling and strand guiding loading amount, throwing straightener, cutting device, knockout mechanism etc.
Casting refining bag is moved to the top of casting machine from the top of oven, molten steel is injected in the tundish by the molten steel outlet of ladle bottom, adjust the position of middle water containing opening in advance, aim at the crystallizer of casting machine, after opening the tundish slide gate nozzle, molten steel flows in the water mold of end opening by the dummy head shutoff.
Move to the top of casting machine from the top of oven with filling with LF refining bag that composition and temperature all reach the molten steel of defined requirement, the molten steel outlet of molten steel by ladle bottom is injected into after (position of middle water containing opening is mixed up in advance to aim at the crystallizer of following casting machine) opens the tundish slide gate nozzle in the tundish, and molten steel flows in the water mold of end opening by the dummy head shutoff.
The molten steel that comes out from electrical arc furnace is injected in the ladle, is transported to the top of casting machine after double refining is handled, and molten steel is re-introduced in the tundish by the mouth of a river of ladle bottom.The position of middle water containing opening is mixed up in advance to aim at following crystallizer.After opening the tundish slide gate nozzle, molten steel flows in the water mold of end opening by the dummy head shutoff.
In crystallizer, molten steel is condensed into box hat gradually along its periphery, when the shell thickness of the strand in outlet port, crystallizer lower end reaches 20mm when above, start Blank drawing machine and mould vibration device, the strand that has the liquid heart is entered the arcuate guide section, and strand descending one side, one side in the arcuate guide section forces cooling to continue to solidify with atomized water.
In crystallizer, molten steel is condensed into box hat gradually along its periphery.When outlet port, crystallizer lower end base shell has certain thickness, start Blank drawing machine and mould vibration device simultaneously, the arcuate guide section that the strand that has the liquid heart is entered form by some nip rolls.Here strand is descending on one side, continues to solidify Yi Bian stand the pressure cooling of the atomized water of many nozzle ejections of arranging according to certain rules in the secdondary cooling zone.After dummy bar goes out The drawing straightener, itself and strand are thrown off.After treating that strand is aligned and solidified fully, be cut into the scale strand, transport to the appointed place by the specific chi strand of knockout mechanism at last by cutting device.
Enter straightening machine behind the throwing, after treating strand aligning and solidifying fully, cut into the continuously cast billet for pipe-making of scale by cutting device.Send in the rotary heating furnace and heat being cooled to continuously cast billet for pipe-making below 600 ℃, make the temperature of pipe evenly reach 1260～1280 ℃, in the time of 1250～1260 ℃, continuously cast billet for pipe-making is carried out heat centering, in the time of 1160～1260 ℃, continuously cast billet for pipe-making is carried out hot piercing, in the time of 1080～1140 ℃, extend rolling continuously continuously cast billet for pipe-making.
After deciding reducing and rolling, cooling, fixed length sawing, aligning, flaw detection, heat-treat, in the time of 1040～1060 ℃,, prevent the steel tube surface oxidation with bright normalizing furnace normalizing.
In the time of 770～790 ℃, carry out tempering, in the time of 580～610 ℃, carry out hot size then, in the time of 500～550 ℃, carry out thermal straightening, detect a flaw at last, be made into circular pipe with annealing furnace.
Adopt sponge iron and steel scrap to do steelmaking feed, with being fused into molten steel in the electric arc furnaces, after external refining and vacuum outgas, obtain Chemical composition as mentioned above, continuous casting becomes the circle base.Cooled continuous casting billet is heated in rotary heating furnace, furnace temperature is 1260～1280 ℃, 1250～1260 ℃ of heat centering,, extend rolling continuously at 1000～1150 ℃ 1200～1240 ℃ of hot piercings, after deciding reducing and rolling, cooling, fixed length sawing, aligning, flaw detection, heat-treat: at 850～930 ℃ with bright heat treatment furnace normalizing (preventing the steel tube surface oxidation), 770～790 ℃ of tempering, then at 580～610 ℃ of hot sizes, 500～550 ℃ of thermal straightenings, flaw detection at last.
The mechanical property of high alloy steel seamless steel pipe of the present invention is by the sampling of ASTM standard-required and the sample preparation of the U.S., and the index that its mechanical property reaches is as follows:
Yield strength (σ
s) 415MPa;
Tensile strength (σ
b) 〉=580MPa;
Specific elongation 〉=20%;
Hardness≤200HB;
Impact toughness: minimum value is calculated by the ASTM standard of the U.S.;
Wall thickness deviation :≤± 8.5t% (t is the wall thickness of seamless steel pipe);
Outside diameter tolerance :≤± 0.5d% (d is the diameter of seamless steel pipe).
The present invention is high alloy steel seamless steel pipe and production method thereof.The good thermal stability of high alloy steel seamless steel pipe material has good impact toughness, stable rupture ductility, high heat resistance energy and decay resistance, and its yield strength is not less than 450MPa.By heat treatment (1040～1060 ℃ bright heat treatment furnace normalizing and 770～790 ℃ tempering) and straightening process (thermal straightening, straightening temperature is controlled at more than 500 ℃), make mechanical property, creep strength, hot strength and the decay resistance of high alloy steel seamless steel pipe body reach the desired level of standard, in the pressure and temperature range of its operation, sufficient margin of safety is arranged, can satisfy the anti-oxidant and erosion-resisting requirement of body simultaneously.Physical dimension, residual stress, form variations and Chemical composition by the control body can guarantee the mechanical property of body, high temperature resistant and decay resistance.Be applicable to employed heat-resisting, corrosion-resistant high alloy steel seamless steel pipe and production methods thereof such as high-pressure autoclave, cracking of oil and chemical industry equipment, can satisfy the needs of high temperature resistant and high pressure of steam tube, superheater tube, the reheater tube of the pipeline of boiler, cracking of oil equipment of firepower power station and nuclear power station and pressure vessels for the chemical industry etc.
The mechanical property of the body of high alloy steel seamless steel pipe of the present invention and high-temperature capability all reach the level of the desired high alloy steel seamless steel pipe of American Society of Mechanical Engineers ASTM boiler and pressure vessel material ATSC Advanced Television Systems Committee standard.
Below in conjunction with embodiment to the detailed description of the invention.
Embodiment
Embodiment 1 (high dose)
It is C 0.12 that the chemical composition of high alloy steel seamless steel pipe is formed (weight %), and Si 0.50, and Mn 0.60, and Cr 9.5, and Mo 1.05, and Al 0.04, and Ni 0.4, and Cb 0.10, P＜0.02, and S＜0.010, V 0.25, and N 0.07, and surplus is Fe.
Embodiment 2 (low dosage)
It is C 0.08 that the chemical composition of high alloy steel seamless steel pipe is formed (weight %), and Si 0.20, and Mn 0.30, and Cr 8, and Mo 0.85, and Al 0.01, and Ni 0.1, and Cb 0.06, P＜0.02, and S＜0.010, V 0.18, and N 0.03, and surplus is Fe.
Embodiment 3 (median dose)
It is C 0.1 that the chemical composition of high alloy steel seamless steel pipe is formed (weight %), and Si 0.35, and Mn 0.45, Cr 8-9.5, and Mo 0.95, and Al 0.025, and Ni 0.2, and Cb 0.08, P＜0.02, S＜0.010, V 0.215, and N 0.05, and surplus is Fe.
Embodiment 4 (high dose)
In electric arc furnaces, drop into (every part of 1.5t of weight meter) steelmaking feed by steel scrap 112.5t and sponge iron 37.5t, the energising heating, furnace charge is fused into molten steel gradually, adopt Control Based Bottom-blown Stirring, quicken the fusing of steel and the homogenization of heating, the furnace temperature of final electric arc furnaces arrives 1550～1650 ℃, and has made the slag of melt down.
In electric arc furnaces, drop into active lime stone 393.75kg, the nozzle molten bath in stove that is arranged on electric arc furnaces bottom is blown into oxygen and argon gas, and the top generation slag of molten steel detects the Chemical composition of molten steel in real time, Chemical composition proportion requirement on demand drops into sponge iron or other alloy in electric arc furnaces.
The chemical composition of the described needs of high alloy steel seamless steel pipe of the present invention is by weight percentage: C0.08-0.12, Si 0.20-0.50, Mn 0.30-0.60, Cr 8-9.5, Mo 0.85-1.05, Al 0.01-0.04, Ni 0-0.4, Cb 0.06-0.10, P＜0.02, S＜0.010, V 0.18-0.25, N 0.03-0.07, surplus is Fe.
Embodiment 5 (low dosage)
In electric arc furnaces, drop into (every part of 1.5t of weight meter) steelmaking feed by steel scrap 97.5t and sponge iron 52.5t, the energising heating, furnace charge is fused into molten steel gradually, adopt Control Based Bottom-blown Stirring, quicken the fusing of steel and the homogenization of heating, the furnace temperature of final electric arc furnaces arrives 1550～1650 ℃, and has made the slag of melt down.
In electric arc furnaces, drop into active lime stone 356.25kg, the nozzle molten bath in stove that is arranged on electric arc furnaces bottom is blown into oxygen and argon gas, and the top generation slag of molten steel detects the Chemical composition of molten steel in real time, Chemical composition proportion requirement on demand drops into sponge iron or other alloy in electric arc furnaces.
The chemical composition of the described needs of high alloy steel seamless steel pipe of the present invention is by weight percentage: C0.08-0.12, Si 0.20-0.50, Mn 0.30-0.60, Cr 8-9.5, Mo 0.85-1.05, Al 0.01-0.04, Ni 0-0.4, Cb 0.06-0.10, p＜0.02, S＜0.010, V 0.18-0.25, N 0.03-0.07, surplus is Fe.
Embodiment 6 (median dose)
In electric arc furnaces, drop into (every part of 1.5t of weight meter) steelmaking feed by steel scrap 105t and sponge iron 45t, the energising heating, furnace charge is fused into molten steel gradually, adopt Control Based Bottom-blown Stirring, quicken the fusing of steel and the homogenization of heating, the furnace temperature of final electric arc furnaces arrives 1550～1650 ℃, and has made the slag of melt down.
In electric arc furnaces, drop into active lime stone 375kg, the nozzle molten bath in stove that is arranged on electric arc furnaces bottom is blown into oxygen and argon gas, and the top generation slag of molten steel detects the Chemical composition of molten steel in real time, Chemical composition proportion requirement on demand drops into sponge iron or other alloy in electric arc furnaces.
The chemical composition of the described needs of high alloy steel seamless steel pipe of the present invention is by weight percentage: C0.08-0.12, Si 0.20-0.50, Mn 0.30-0.60, Cr 8-9.5, Mo 0.85-1.05, Al 0.01-0.04, Ni 0-0.4, Cb 0.06-0.10, P＜0.02, S＜0.010, V 0.18-0.25, N 0.03-0.07, surplus is Fe.
Embodiment 7 (high dose)
Pour (every part of 1.5t of weight meter) CaO-Al in the LF casting refining bag
2O
3Base refining slag 504kg will inject LF casting refining bag through the molten steel that just refining back composition is qualified in the electric arc furnaces, and construction materials contract melts in the stove of oxidizing atmosphere, insulation, dephosphorization, decarburization and master alloyingization, stirs molten steel simultaneously.
Blowing argon gas in casting refining bag again is blown into argon gas with the strong mixing condition of 110L/ (mint), outgases, deoxidation, desulfurization, drops into pure metal powder, silk simultaneously while stirring in molten steel, removes slag inclusion and carries out trimming.
To cast vacuumizes in the refining bag again, reduces the hydrogen in the steel.Drop into silicon (Si) and carry out deoxidation under the condition of vacuum in molten steel, boiling phenomenon takes place in molten steel immediately, and gas is overflowed in the steel, and slag inclusion also enters slag along with boiling stirring face come-up, carries out operations such as dehydrogenation, denitrogenation.
Embodiment 8 (low dosage)
Pour (every part of 1.5t of weight meter) CaO-Al in the LF casting refining bag
2O
3Base refining slag 456kg will inject LF casting refining bag through the molten steel that just refining back composition is qualified in the electric arc furnaces, and construction materials contract melts in the stove of oxidizing atmosphere, insulation, dephosphorization, decarburization and master alloyingization, stirs molten steel simultaneously.
Blowing argon gas in casting refining bag again is blown into argon gas with the strong mixing condition of 110L/ (mint), outgases, deoxidation, desulfurization, drops into pure metal powder, silk simultaneously while stirring in molten steel, removes slag inclusion and carries out trimming.
To cast vacuumizes in the refining bag again, reduces the hydrogen in the steel.Drop into silicon (Si) and carry out deoxidation under the condition of vacuum in molten steel, boiling phenomenon takes place in molten steel immediately, and gas is overflowed in the steel, and slag inclusion also enters slag along with boiling stirring face come-up, carries out operations such as dehydrogenation, denitrogenation.
Embodiment 9 (median dose)
Pour (every part of 1.5t of weight meter) CaO-Al in the LF casting refining bag
2O
3Base refining slag 480kg will inject LF casting refining bag through the molten steel that just refining back composition is qualified in the electric arc furnaces, and construction materials contract melts in the stove of oxidizing atmosphere, insulation, dephosphorization, decarburization and master alloyingization, stirs molten steel simultaneously.
Blowing argon gas in casting refining bag again is blown into argon gas with the strong mixing condition of 110L/ (mint), outgases, deoxidation, desulfurization, drops into pure metal powder, silk simultaneously while stirring in molten steel, removes slag inclusion and carries out trimming.
To cast vacuumizes in the refining bag again, reduces the hydrogen in the steel.Drop into silicon (Si) and carry out deoxidation under the condition of vacuum in molten steel, boiling phenomenon takes place in molten steel immediately, and gas is overflowed in the steel, and slag inclusion also enters slag along with boiling stirring face come-up, carries out operations such as dehydrogenation, denitrogenation.
Embodiment 10
Casting refining bag is moved to the top of casting machine from the top of oven, molten steel is injected in the tundish by the molten steel outlet of ladle bottom, adjust the position of middle water containing opening in advance, aim at the crystallizer of casting machine, after opening the tundish slide gate nozzle, molten steel flows in the water mold of end opening by the dummy head shutoff.
In crystallizer, molten steel is condensed into box hat gradually along its periphery, when the shell thickness of the strand in outlet port, crystallizer lower end reaches 20mm when above, start Blank drawing machine and mould vibration device, the strand that has the liquid heart is entered the arcuate guide section, and strand descending one side, one side in the arcuate guide section forces cooling to continue to solidify with atomized water.
Enter straightening machine behind the throwing, after treating strand aligning and solidifying fully, cut into the continuously cast billet for pipe-making of scale by cutting device.Send in the rotary heating furnace and heat being cooled to continuously cast billet for pipe-making below 600 ℃, make the temperature of pipe evenly reach 1260～1280 ℃, in the time of 1250～1260 ℃, continuously cast billet for pipe-making is carried out heat centering, in the time of 1160～1260 ℃, continuously cast billet for pipe-making is carried out hot piercing, in the time of 1080～1140 ℃, extend rolling continuously continuously cast billet for pipe-making.
After deciding reducing and rolling, cooling, fixed length sawing, aligning, flaw detection, heat-treat, in the time of 1040～1060 ℃,, prevent the steel tube surface oxidation with bright normalizing furnace normalizing.
In the time of 770～790 ℃, carry out tempering, in the time of 580～610 ℃, carry out hot size then, in the time of 500～550 ℃, carry out thermal straightening, detect a flaw at last, be made into circular pipe with annealing furnace.
Claims (2)
1, a kind of high alloy steel seamless steel pipe is characterized in that the chemical composition composition (weight %) of this steel is C 0.08-0.12, Si 0.20-0.50, Mn 0.30-0.60, Cr 8-9.5, Mo 0.85-1.05, Al0.010.04, Ni 0-0.4, Cb 0.06-0.10, P＜0.02, S＜0.010, V 0.18-0.25, N0.03-0.07, surplus is Fe.
2, a kind of production method of high alloy steel seamless steel pipe comprises and adopts sponge iron and steel scrap to do steelmaking feed, is fused into molten steel with electric arc furnaces, after external refining and vacuum outgas, the circular pipe of continuous casting heats cooled continuously cast billet for pipe-making in rotary heating furnace, heat centering, hot piercing, extend continuously rolling, after deciding reducing and rolling, cooling, fixed length sawing, aligning, flaw detection, heat-treat, hot size, thermal straightening, flaw detection at last; It is characterized in that: in electric arc furnaces, drop into steelmaking feed by steel scrap 65-75 part and sponge iron 25-35 part, the energising heating, furnace charge is fused into molten steel gradually, adopt Control Based Bottom-blown Stirring, quicken the fusing of steel and the homogenization of heating, the furnace temperature of final electric arc furnaces arrives 1550～1650 ℃, and has made the slag of melt down; In electric arc furnaces, drop into active lime stone 0.2375-0.2625 part, the nozzle molten bath in stove that is arranged on the electric arc furnaces bottom is blown into oxygen and argon gas, the top generation slag of molten steel, detect the Chemical composition of molten steel in real time, Chemical composition proportion requirement on demand drops into sponge iron or other ferro-alloy in electric arc furnaces; The chemical composition of described needs is by weight percentage: C 0.08-0.12, Si 0.20-0.50, Mn0.30-0.60, Cr 8-9.5, Mo 0.85-1.05, Al 0.01-0.04, Ni 0-0.4, Cb 0.06-0.10, P＜0.02, S＜0.010, V 0.18-0.25, N 0.03-0.07, surplus is Fe; Pour CaO-Al in the LF cast refining bag
2O
3Base refining slag 0.304-0.336 part will be injected LF cast refining bag through the molten steel that just refining back composition is qualified in the electric arc furnaces, and construction materials contract melts in the stove of oxidizing atmosphere, insulation, dephosphorization, decarburization and master alloyingization, stirs molten steel simultaneously; Blowing argon gas in cast refining bag again is blown into argon gas with the strong mixing condition of 110L/ (mint), outgases, deoxidation, desulfurization, drops into pure metal powder, silk simultaneously while stirring in molten steel, removes slag inclusion and carries out trimming; To pour into a mould in the refining bag again and vacuumize the hydrogen in the minimizing steel; Drop into silicon and carry out deoxidation under the condition of vacuum in molten steel, boiling phenomenon takes place in molten steel immediately, and gas is overflowed in the steel, and slag inclusion also enters slag along with boiling stirring face come-up, carries out the operation of dehydrogenation, denitrogenation; The refining bag is moved to the top of casting machine from the top of oven, molten steel is injected in the tundish by the molten steel outlet of ladle bottom, adjust the position of middle water containing opening in advance, aim at the crystallizer of casting machine, after opening the tundish slide gate nozzle, molten steel flows in the water mold of end opening by the dummy head shutoff; In crystallizer, molten steel is condensed into box hat gradually along its periphery, when the shell thickness of the strand in outlet port, crystallizer lower end reaches 20mm when above, start Blank drawing machine and mould vibration device, the strand that has the liquid heart is entered the arcuate guide section, and strand descending one side, one side in the arcuate guide section forces cooling to continue to solidify with atomized water; Enter straightening machine behind the throwing, after treating strand aligning and solidifying fully, cut into the continuously cast billet for pipe-making of scale by cutting device; Send in the rotary heating furnace and heat being cooled to continuously cast billet for pipe-making below 600 ℃, make the temperature of pipe evenly reach 1260～1280 ℃, in the time of 1250～1260 ℃, continuously cast billet for pipe-making is carried out heat centering, in the time of 1160～1260 ℃, continuously cast billet for pipe-making is carried out hot piercing, in the time of 1080～1140 ℃, extend rolling continuously continuously cast billet for pipe-making; After deciding reducing and rolling, cooling, fixed length sawing, aligning, flaw detection, heat-treat, in the time of 1040～1060 ℃,, prevent the steel tube surface oxidation with bright normalizing furnace normalizing; In the time of 770～790 ℃, carry out tempering, in the time of 580～610 ℃, carry out hot size then, in the time of 500～550 ℃, carry out thermal straightening, detect a flaw at last, be made into circular pipe with annealing furnace.
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| CN101694250B (en) * | 2009-10-13 | 2011-04-06 | 天津钢管集团股份有限公司 | 500MPa-grade VN alloying non-tempering seamless steel tube and manufacturing method thereof |
| CN101691895B (en) * | 2009-11-03 | 2011-02-02 | 烟台台海玛努尔核电设备有限公司 | Manufacturing process for main pipe line of primary loop in AP1000 nuclear power technology |
| CN101706020B (en) * | 2009-11-23 | 2011-01-19 | 天津商业大学 | Method for preparing high alloy steel seamless steel pipe |
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| CN103741058A (en) * | 2013-12-23 | 2014-04-23 | 马鞍山市盈天钢业有限公司 | Heat-resistant steel pipe material and preparation method thereof |
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| CN105483504B (en) * | 2015-12-07 | 2018-04-27 | 攀钢集团成都钢钒有限公司 | The production method of -195 DEG C of ultralow temperature seamless steel tube blank steel |
| CN113751678B (en) * | 2021-09-08 | 2023-06-20 | 广东华域重工有限公司 | High-strength heavy steel production process and processing equipment thereof |
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