CN103556069B - A kind of gas cylinder seamless large-diameter pipes and manufacture method thereof - Google Patents

A kind of gas cylinder seamless large-diameter pipes and manufacture method thereof Download PDF

Info

Publication number
CN103556069B
CN103556069B CN201310536736.6A CN201310536736A CN103556069B CN 103556069 B CN103556069 B CN 103556069B CN 201310536736 A CN201310536736 A CN 201310536736A CN 103556069 B CN103556069 B CN 103556069B
Authority
CN
China
Prior art keywords
steel
molten steel
pipe
electric arc
diameter pipes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201310536736.6A
Other languages
Chinese (zh)
Other versions
CN103556069A (en
Inventor
张永峰
邓春锋
任方杰
武春学
常磊
邵飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CSSC Shuangrui Luoyang Special Equipment Co Ltd
Original Assignee
Luoyang Sunrui Special Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Luoyang Sunrui Special Equipment Co Ltd filed Critical Luoyang Sunrui Special Equipment Co Ltd
Priority to CN201310536736.6A priority Critical patent/CN103556069B/en
Publication of CN103556069A publication Critical patent/CN103556069A/en
Application granted granted Critical
Publication of CN103556069B publication Critical patent/CN103556069B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Heat Treatment Of Articles (AREA)

Abstract

The invention belongs to metallurgical technology field, propose a kind of gas cylinder seamless large-diameter pipes and manufacture method thereof.Chemical composition and the mass percent of a kind of gas cylinder seamless large-diameter pipes proposed are: C0.30% ~ 0.60%, Si:0.20 ~ 0.50%, Mn:0.20 ~ 0.60%, P :≤0.010%, S :≤0.010%, Cr:0.90 ~ 1.70%, Ni:2.50 ~ 3.50%, Mo:0.25 ~ 0.55%, V:0.05 ~ 0.25%, surplus is Fe; Manufacture method adopts sponge iron and steel scrap to do steelmaking feed.The Heat stability is good of the seamless large-diameter pipes that the present invention obtains, intensity are high, and have good impelling strength, stable rupture ductility, high thermostrength, excellent corrosion resistance nature and anti-fatigue performance, and its yield strength is not less than 1000MPa.

Description

A kind of gas cylinder seamless large-diameter pipes and manufacture method thereof
Technical field
The invention belongs to metallurgical technology field, be specifically related to a kind of gas cylinder seamless large-diameter pipes and manufacture method thereof.
Background technology
Large volume seamless steel gas cylinder is applied comparatively wide at home, is mainly used in the fields such as the transport of the industrial gasses such as natural gas liquids.The operating pressure of early stage seamless gas cylinder is lower, and unit weight is smaller, and its material is mainly soft steel.In recent years, along with the raising of seamless gas cylinder operating pressure, the continuous increase of volume to weight ratio, seamless steel gas cylinder steel from soft steel to medium carbon steel, C-Mn steel and Cr-Mo steel development, Cr-Mo system steel alloy has the advantage keeping high strength simultaneously to have good toughness plasticity, is thus subject to widespread use.At present, the large volume seamless steel gas cylinder operating pressure of domestic use mostly is 20 ~ 25MPa, its material multiselect 30CrMo steel or 35CrMo steel.But along with the continuous progress of technology, require to improve further to the volume to weight ratio of steel cylinder, operating pressure requires higher than Cr-Mo system steel alloys such as existing 25MPa, 35CrMo because intensity can not be satisfied the demand lower than design requirements.
Summary of the invention
For solving the problems of the technologies described above, object of the present invention proposes a kind of gas cylinder seamless large-diameter pipes and manufacture method thereof.
The present invention adopts following technical scheme for completing above-mentioned purpose:
A kind of gas cylinder seamless large-diameter pipes, the chemical composition of described seamless large-diameter pipes and mass percent are: C:0.30% ~ 0.60%, Si:0.20 ~ 0.50%, Mn:0.20 ~ 0.60%, P :≤0.010%, S :≤0.010%, Cr:0.90 ~ 1.70%, Ni:2.50 ~ 3.50%, Mo:0.25 ~ 0.55%, V:0.05 ~ 0.25%, surplus is Fe.
C be solid solution in the substrate or as Carbide Precipitation, be the principal element of the intensity increasing steel, along with C content in steel increases, its yield-point and tensile strength raise, but toughness plasticity reduces; In the present invention, for guaranteeing desired intensity, C content must more than 0.30%, if but more than 0.60%, then the toughness plasticity of steel worsens; Therefore, C content is limited to the scope of 0.30% ~ 0.60%.
Si is good reductor, adds silicon as reductive agent and reductor in steelmaking process, and meanwhile, Si can be dissolved in the hardness and intensity that improve steel in ferrite and austenite, and its effect is only second to P, and comparatively the element such as Mn, Ni, Cr, W, Mo and V is strong; But during containing Si more than 2.0%, will significantly reduce plasticity and the toughness of steel; Therefore, Si is limited to the scope of 0.01 ~ 2.0%; But, from the viewpoint of intensity-toughness plasticity balance, preferably Si content is limited in the scope of 0.20 ~ 0.50%.
Mn is good reductor and sweetening agent, adds a certain amount of Mn in steel, can eliminate or weaken the red brittleness of the steel caused by S, thus improve the hot workability of steel; Mn in steel and Fe form sosoloid, improve ferrite and austenitic hardness and intensity in steel; Be again carbide forming element, enter in cementite and replace a part of Fe atom, Mn can reduce critical transition temperature, plays the effect of refine pearlite simultaneously, also indirectly plays and improves perlitic steel intensity; It is that the ability of austenite structure is only second to Ni that Mn stablizes, and also strongly increases the hardening capacity of steel; But Mn easily causes grain growth when content is more in steel, steel grade is caused to become essential coarse-grained steel; Meanwhile, Mn easily forms MnS with S, causes the solidity to corrosion of steel to decline, thus in steel Mn content generally not higher than 0.6%; Therefore, Fe content is preferably on the low side, but considers from economy when producing, then allow its scope to be 0.20 ~ 0.60%.
In the ordinary course of things, P is harmful element in steel, can increase the cold shortness of steel, reduces toughness plasticity, cold-bending property is degenerated; Therefore the P content of weldless steel tube is less than or equal to 0.010%.
S is also harmful element under normal conditions, makes steel produce red brittleness, reduces ductility and the toughness of steel, causes crackle when forging and rolling; But S can reduce the erosion resistance of steel, so usually require that S content is less than 0.055%, the S content of weldless steel tube is less than or equal to 0.010%.
Cr can increase the hardening capacity of steel and have secondary hardening effect, improves the intensity of steel, hardness and wear resistance and does not make steel become fragile, but can reduce unit elongation and relative reduction in area; The Main Function of Cr in modified structure iron improves hardening capacity, makes steel after Q-tempering, have good comprehensive mechanical property, can also form the carbide containing Cr in converted steel, thus improve the wear resistance of material surface; Thus the Cr content in structural alloy steel generally higher than 0.9%, to ensure the intensity of steel, hardness and hardening capacity; When in steel during Cr too high levels, the ductile-brittle transition temperature of steel significantly improves, and meanwhile, steel belt roof bolt fragility significantly increases, therefore Cr content in this kind of steel is general not higher than 1.7%, and namely the Cr content of weldless steel tube is restricted to 0.90 ~ 1.70%.
Ni can while raising hardness of steel, little compared with the impact of other alloying elements on the infringement of the toughness of steel, plasticity and other processing performances; For medium carbon steel, because Ni reduces perlitic transformation temperature, perlite is attenuated; Again because Ni reduces the ni content of eutectoid point, thus with the carbon steel ratio of identical C content, its pearlite fraction is more, makes the carbon steel of the more identical C content of intensity of the pearlitic ferrite steel containing Ni high; Ni namely can improve steel to the drag of fatigue and reduce steel to the susceptibility of breach, can reduce again the low temperature brittleness transition temperature of steel, this has epochmaking meaning to Cryogenic Steel; In addition, Ni adds can not only be acidproof in steel, and energy alkali resistant, has resistance to corrosion to air and salt; Because this steel grade is to the toughness of material, ductile-brittle transition temperature, notch sensitivities etc. require higher, and the Ni content thus in steel is higher than 2.5%; But because domestic Ni content is less, Ni price is high, Cr-Ni steel easily produces temper brittleness and white point simultaneously, and consider from factors such as costs, Ni content is not higher than 3.5%; Therefore the Ni content of weldless steel tube controls 2.50 ~ 3.50%.
Mo can improve hardening capacity and heat resistance in steel, and crystal grain thinning prevents temper brittleness, increases the corrosion stability of steel in some medium; Enough intensity and creep resisting ability is kept when high temperature; In quenched and tempered steel, Mo can make to quench deeply compared with the part of big cross section, through hardening, improves temper resistance or the temper resistance of steel, makes part can tempering at relatively high temperatures, thus more effectively eliminates unrelieved stress, improves plasticity; In structural alloy steel, Mo constituent content generally just plays good action after 0.25%, and when Mo content is more than 0.55%, then high temper steel can be made on the contrary to become fragile; Therefore in weldless steel tube, the content of Mo controls 0.25 ~ 0.55%.
V mainly exists with the form of carbide in steel; Its Main Function is tissue and the crystal grain of refinement steel, reduces the superheated susceptivity of steel, improves intensity and the toughness of steel; V can increase the temper resistance of hardened steel, and produces secondary hardening effect; For keeping V can thinning microstructure crystal grain, improve obdurability and hardening capacity, the general >0.05% of V content in structural alloy steel, in structural alloy steel, in order to avoid temper brittleness, the content of V should not higher than 0.25%, and therefore in weldless steel tube, the content of V controls 0.05 ~ 0.25%.
A kind of preparation method of gas cylinder seamless large-diameter pipes, described manufacture method adopts sponge iron and steel scrap to do steelmaking feed, molten steel is fused into electric arc furnace, after external refining and vacuum outgas, be molded into circular pipe, cooled die casting pipe is heated in rotary heating furnace, heat centering, hot piercing, periodically rolling, through determining reducing and rolling, cooling, fixed length sawing, aligning; After flaw detection, carry out normalizing thermal treatment, tempering, hot size, hot straightening, finally detect a flaw; Concrete steps are as follows:
(1), the proportioning of raw material: steel scrap 75 ~ 85 parts, sponge iron 15 ~ 25 parts;
(2), by raw material drop in electric arc furnace, after electrified regulation, raw material is melted into molten steel gradually, and adopt simultaneously and blow end stirring technique, accelerate the fusing of steel and the homogenizing of heating, the furnace temperature of final electric arc furnace reaches 1500 ~ 1600 DEG C, and has made the slag of melting period;
(3), in electric arc furnace, drop into 0.246 ~ 0.274 part, quickened lime stone, be blown into oxygen and argon gas by the nozzle be arranged on bottom electric arc furnace to molten bath in electric arc furnace simultaneously, make the sulphur in molten steel, phosphorus impurities element forms slag on molten steel; And the chemical composition of Real-Time Monitoring molten steel, when the chemical composition of molten steel does not reach the necessary chemical composition of seamless large-diameter pipes, in electric arc furnace, drop into sponge iron or other iron alloy; The chemical composition in molten steel is made to arrive the necessary chemical composition of seamless large-diameter pipes;
(4), in LF cast refining bag, CaO-Al is poured into 2o 3base essence 0.30 ~ 0.33 part, slag, and then molten steel qualified for the composition obtained in step (3) is injected LF cast refining bag, carry out oxygen blast in electric arc furnace, molten steel and CaO-Al simultaneously 2o 3base essence slag carries out melting in the electric arc furnace of oxidizing atmosphere, be incubated, dephosphorization, decarburization and alloying; Stir molten steel simultaneously;
(5), at 130L/(mint) strong mixing condition under to pour into a mould in refining bag to LF and be blown into argon gas, carry out degassed, deoxidation, desulfurization process, in molten steel, drop into pure metal powder while stirring, object is removal of inclusions and carries out trimming simultaneously;
(6), by LF pour into a mould in refining bag and vacuumize, reduce the hydrogen in steel; In molten steel, dropping into silicon under vacuum carry out deoxidation, there is boiling phenomenon in molten steel immediately, gas effusion in steel, and inclusion also forms slag along with boiling stirring surface floats, and carries out the operation of dehydrogenation, denitrogenation;
(7), by molten steel being poured onto cross section is in circular grinding tool, is cooled to close to room temperature, carries out cogging subsequently, and excision cap mouth and some unwanted parts, can obtain chemical composition necessary with seamless large-diameter pipes and require consistent steel billet;
(8) enter straightener after the steel billet, to step (7) obtained carries out throwing, after completing and solidifying, cut into the die casting pipe of scale until strand aligning by cutting unit;
(9), heat being cooled to the die casting pipe of less than 650 DEG C to send in rotary heating furnace, the homogeneous temperature of pipe is made to reach 1250 ~ 1280 DEG C, 1240 ~ 1260 DEG C time, heat centering is carried out to die casting pipe, 1150 ~ 1230 DEG C time, hot piercing is carried out to die casting pipe, 1050 ~ 1150 DEG C time, periodicity tandem rolling is carried out to die casting pipe; When carrying out periodicity rolling, because the different circumference of steel pipe is all subject to the effect of even rolling load; By the roll location in controlled rolling process and roll gap, thus reach the object controlling thickness of steel pipe and form variations, prevent thickness of steel pipe uneven excessive with ovality; Meanwhile, due to periodicity continuous rolling process, the linearity of steel pipe is higher, and sinuousness is less;
(10), after determining reducing and rolling, cooling, fixed length sawing, aligning, flaw detection, heat-treat, 1000 ~ 1050 DEG C time, use normalizing furnace normalizing, prevent oxidation;
(11), 680 ~ 720 DEG C time tempering is carried out with annealing furnace, to eliminate the unrelieved stress in steel pipe; Carry out hot size when being cooled to 600 ~ 620 DEG C after tempering, carry out hot straightening when being cooled to 500 ~ 550 DEG C after hot size, finally detect a flaw, be made into circular pipe.
The mechanical property of the weldless steel tube adopting aforesaid method to prepare samples and sample preparation according to the ASTM standard-required of the U.S., and the index that its mechanical property reaches is as follows:
Yield strength (R p0.2):>=1000MPa;
Tensile strength (R m):>=1200MPa;
Unit elongation (A): >=20%;
Hardness (HB): 296 ~ 400;
Impelling strength: >=80J (-20 DEG C);
Wall thickness deviation :≤± 8.5t%(t is the wall thickness of weldless steel tube);
Outside diameter tolerance :≤± 0.5d%(d is the diameter of weldless steel tube).
A kind of gas cylinder seamless large-diameter pipes that the present invention proposes and manufacture method thereof, seamless steel pipe for gas cylinder is made to have uniform wall thickness by periodicity continuous rolling process, surface quality is high, the features such as fine microstructures, by follow-up thermal treatment (normalizing+tempering) and straightening process, make the mechanical property of seamless steel pipe for gas cylinder body, hot strength, corrosion resistance nature and anti-fatigue performance reach the level required by standard, in its pressure run and temperature range, there is sufficient safety margin, the requirement of the anticorrosive of body and antifatigue can be met simultaneously, by periodicity tandem rolling and follow-up tempering process, the geometrical dimension of effective control steel pipe, unrelieved stress and form variations, the mechanical property of body can be ensured, hot strength, corrosion resistance nature and anti-fatigue performance, be applicable to the gas cylinder of operating pressure higher than 25MPa, in sum, the Heat stability is good of the seamless large-diameter pipes that the present invention adopts above-mentioned manufacture method to obtain, intensity are high, and there is good impelling strength, stable rupture ductility, high thermostrength, excellent corrosion resistance nature and anti-fatigue performance, its yield strength is not less than 1000MPa.
Embodiment
In conjunction with specific embodiments the present invention is described further:
Chemical composition and the mass percent of more than 25MPa operating pressure gas cylinder seamless large-diameter pipes are C0.35, Si0.35, Mn0.27, Cr1.35, Ni2.95, Mo0.35, V0.14, P0.007, S0.005, and other is Fe.
A kind of preparation method of gas cylinder seamless large-diameter pipes, described manufacture method adopts sponge iron and steel scrap to do steelmaking feed, molten steel is fused into electric arc furnace, after external refining and vacuum outgas, be molded into circular pipe, cooled die casting pipe is heated in rotary heating furnace, heat centering, hot piercing, periodically rolling, through determining reducing and rolling, cooling, fixed length sawing, aligning; After flaw detection, carry out normalizing thermal treatment, tempering, hot size, hot straightening, finally detect a flaw; Concrete steps are as follows:
(1), the proportioning of raw material: steel scrap 75 ~ 85 parts, sponge iron 15 ~ 25 parts;
(2), by raw material drop in electric arc furnace, after electrified regulation, raw material is melted into molten steel gradually, and adopt simultaneously and blow end stirring technique, accelerate the fusing of steel and the homogenizing of heating, the furnace temperature of final electric arc furnace reaches 1500 ~ 1600 DEG C, and has made the slag of melting period;
(3), in electric arc furnace, drop into 0.246 ~ 0.274 part, quickened lime stone, be blown into oxygen and argon gas by the nozzle be arranged on bottom electric arc furnace to molten bath in stove simultaneously, make the sulphur in molten steel, phosphorus impurities element forms slag on molten steel; And the chemical composition of Real-Time Monitoring molten steel, when the chemical composition of molten steel does not reach the necessary chemical composition of seamless large-diameter pipes, in electric arc furnace, drop into sponge iron or other iron alloy; The chemical composition in molten steel is made to arrive the necessary chemical composition of seamless large-diameter pipes; Other iron alloy comprises containing Si, Mn, Cr, Ni, Mo, V alloy element, and its add-on is specifically determined by molten steel composition;
(4), in LF cast refining bag, CaO-Al is poured into 2o 3base essence 0.30 ~ 0.33 part, slag, then molten steel qualified for the composition obtained in step (3) is injected LF and pour into a mould refining bag, the object pouring CaO-Al2O3 base essence slag into is when being poured in refining ladle by molten steel, impact by molten steel makes synthetic slag emulsification, slag and steel fully mix, and then calm, the slag of emulsification drips floating, to complete the refining task of desulfurization, part deoxidation, removal nonmetal inclusion, then molten steel and CaO-Al 2o 3base essence slag carries out melting in the stove of oxidizing atmosphere, be incubated, dephosphorization, decarburization and alloying; Stir molten steel simultaneously;
(5), at 130L/(mint) strong mixing condition under to pour into a mould in refining bag to LF and be blown into argon gas, carry out degassed, deoxidation, desulfurization process, in molten steel, drop into pure metal powder while stirring, object is removal of inclusions and carries out trimming simultaneously;
(6), by LF pour into a mould in refining bag and vacuumize, reduce the hydrogen in steel; In molten steel, dropping into silicon under vacuum carry out deoxidation, there is boiling phenomenon in molten steel immediately, gas effusion in steel, and inclusion also forms slag along with boiling stirring surface floats, and carries out the operation of dehydrogenation, denitrogenation;
(7), molten steel being poured onto cross section is in circular grinding tool, be cooled to close to room temperature, carry out cogging subsequently, due in cap mouth place steel billet because solidifying time speed of cooling and gas etc. affect and make this place's impurity content higher, therefore excise cap mouth and some unwanted parts, chemical composition necessary with seamless large-diameter pipes can be obtained and require consistent steel billet;
(8) enter straightener after the steel billet, to step (7) obtained carries out throwing, after completing and solidifying, cut into the die casting pipe of scale until strand aligning by cutting unit;
(9), heat being cooled to the die casting pipe of less than 650 DEG C to send in rotary heating furnace, the homogeneous temperature of pipe is made to reach 1250 ~ 1280 DEG C, 1240 ~ 1260 DEG C time, heat centering is carried out to die casting pipe, 1150 ~ 1230 DEG C time, carry out hot piercing to die casting pipe, the PQF tri-roller limiting mandrel tandem rolling pipe machine adopting German SMSMeer/INNSE company to produce 1050 ~ 1150 DEG C time carries out periodicity tandem rolling to die casting pipe; When carrying out periodicity rolling, because the different circumference of steel pipe is all subject to the effect of even rolling load; By the roll location in controlled rolling process and roll gap, thus reach the object controlling thickness of steel pipe and form variations, prevent thickness of steel pipe uneven excessive with ovality; Meanwhile, due to periodicity continuous rolling process, the linearity of steel pipe is higher, and sinuousness is less.
(10), after determining reducing and rolling, cooling, fixed length sawing, aligning, flaw detection, heat-treat, 1000 ~ 1050 DEG C time, use normalizing furnace normalizing, prevent oxidation;
(11), 680 ~ 720 DEG C time tempering is carried out with annealing furnace, to eliminate the unrelieved stress in steel pipe; Carry out hot size when being cooled to 600 ~ 620 DEG C after tempering, carry out hot straightening when being cooled to 500 ~ 550 DEG C after hot size, finally detect a flaw, be made into circular pipe.
The mechanical property of the weldless steel tube adopting aforesaid method to prepare samples and sample preparation according to the ASTM standard-required of the U.S., and the index that its mechanical property reaches is as follows:
Yield strength (R p0.2):>=1000MPa;
Tensile strength (R m):>=1200MPa;
Unit elongation (A): >=20%;
Hardness (HB): 296 ~ 400;
Impelling strength: >=80J (-20 DEG C);
Wall thickness deviation :≤± 8.5t%(t is the wall thickness of weldless steel tube);
Outside diameter tolerance :≤± 0.5d%(d is the diameter of weldless steel tube).
In the manufacture method of above-mentioned weldless steel tube, the melting of molten steel, refining, the shaping of die casting pipe are proven technique in prior art, do not do too much explanation at this.

Claims (1)

1. the preparation method of a gas cylinder seamless large-diameter pipes, the chemical composition of described seamless large-diameter pipes and mass percent are: C:0.30% ~ 0.60%, Si:0.20 ~ 0.50%, Mn:0.20 ~ 0.60%, P :≤0.010%, S :≤0.010%, Cr:0.90 ~ 1.70%, Ni:2.50 ~ 3.50%, Mo:0.25 ~ 0.55%, V:0.05 ~ 0.25%, surplus is Fe; The preparation method of seamless large-diameter pipes is: iron and steel scrap do steelmaking feed, molten steel is fused into electric arc furnace, after external refining and vacuum outgas, be molded into circular pipe, cooled die casting pipe is heated in rotary heating furnace, heat centering, hot piercing, periodically rolling, through determining reducing and rolling, cooling, fixed length sawing, aligning; After flaw detection, carry out normalizing thermal treatment, tempering, hot size, hot straightening, finally detect a flaw; Concrete steps are as follows:
(1), the proportioning of raw material: steel scrap 75 ~ 85 parts, sponge iron 15 ~ 25 parts;
(2), by raw material drop in electric arc furnace, after electrified regulation, raw material is melted into molten steel gradually, and adopt simultaneously and blow end stirring technique, accelerate the fusing of steel and the homogenizing of heating, the furnace temperature of final electric arc furnace reaches 1500 ~ 1600 DEG C, and has made the slag of melting period;
(3), in electric arc furnace, drop into 0.246 ~ 0.274 part, quickened lime stone, be blown into oxygen and argon gas by the nozzle be arranged on bottom electric arc furnace to molten bath in electric arc furnace simultaneously, make the sulphur in molten steel, phosphorus impurities element forms slag on molten steel; And the chemical composition of Real-Time Monitoring molten steel, when the chemical composition of molten steel does not reach the necessary chemical composition of seamless large-diameter pipes, in electric arc furnace, drop into sponge iron or other iron alloy; The chemical composition in molten steel is made to arrive the necessary chemical composition of seamless large-diameter pipes;
(4), in LF cast refining bag, CaO-Al is poured into 2o 3base essence 0.30 ~ 0.33 part, slag, and then molten steel qualified for the composition obtained in step (3) is injected LF cast refining bag, carry out oxygen blast in electric arc furnace, molten steel and CaO-Al simultaneously 2o 3base essence slag carries out melting in the electric arc furnace of oxidizing atmosphere, be incubated, dephosphorization, decarburization and alloying; Stir molten steel simultaneously;
(5), at 130L/(mint) strong mixing condition under to pour into a mould in refining bag to LF and be blown into argon gas, carry out degassed, deoxidation, desulfurization process, in molten steel, drop into pure metal powder while stirring, object is removal of inclusions and carries out trimming simultaneously;
(6), by LF pour into a mould in refining bag and vacuumize, reduce the hydrogen in steel; In molten steel, dropping into silicon under vacuum carry out deoxidation, there is boiling phenomenon in molten steel immediately, gas effusion in steel, and inclusion also forms slag along with boiling stirring surface floats, and carries out the operation of dehydrogenation, denitrogenation;
(7), by molten steel being poured onto cross section is in circular grinding tool, is cooled to close to room temperature, carries out cogging subsequently, and excision cap mouth and some unwanted parts, can obtain chemical composition necessary with seamless large-diameter pipes and require consistent steel billet;
(8) enter straightener after the steel billet, to step (7) obtained carries out throwing, after completing and solidifying, cut into the die casting pipe of scale until strand aligning by cutting unit;
(9), heat being cooled to the die casting pipe of less than 650 DEG C to send in rotary heating furnace, the homogeneous temperature of pipe is made to reach 1250 ~ 1280 DEG C, 1240 ~ 1260 DEG C time, heat centering is carried out to die casting pipe, 1150 ~ 1230 DEG C time, hot piercing is carried out to die casting pipe, 1050 ~ 1150 DEG C time, die casting pipe is rolled;
(10), after determining reducing and rolling, cooling, fixed length sawing, aligning, flaw detection, heat-treat, 1000 ~ 1050 DEG C time, use normalizing furnace normalizing, prevent oxidation;
(11), 680 ~ 720 DEG C time tempering is carried out with annealing furnace, to eliminate the unrelieved stress in steel pipe; Carry out hot size when being cooled to 600 ~ 620 DEG C after tempering, carry out hot straightening when being cooled to 500 ~ 550 DEG C after hot size, finally detect a flaw, be made into circular pipe; It is characterized in that: periodically tandem rolling is adopted to the rolling that die casting pipe carries out; When carrying out periodicity rolling, because the different circumference of steel pipe is all subject to the effect of even rolling load; By the roll location in controlled rolling process and roll gap, thus reach the object controlling thickness of steel pipe and form variations, prevent thickness of steel pipe uneven excessive with ovality; Meanwhile, due to periodicity continuous rolling process, the linearity of steel pipe is higher, and sinuousness is less.
CN201310536736.6A 2013-11-04 2013-11-04 A kind of gas cylinder seamless large-diameter pipes and manufacture method thereof Active CN103556069B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310536736.6A CN103556069B (en) 2013-11-04 2013-11-04 A kind of gas cylinder seamless large-diameter pipes and manufacture method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310536736.6A CN103556069B (en) 2013-11-04 2013-11-04 A kind of gas cylinder seamless large-diameter pipes and manufacture method thereof

Publications (2)

Publication Number Publication Date
CN103556069A CN103556069A (en) 2014-02-05
CN103556069B true CN103556069B (en) 2016-02-17

Family

ID=50010412

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310536736.6A Active CN103556069B (en) 2013-11-04 2013-11-04 A kind of gas cylinder seamless large-diameter pipes and manufacture method thereof

Country Status (1)

Country Link
CN (1) CN103556069B (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104942539A (en) * 2015-06-02 2015-09-30 苏州晓锋知识产权运营管理有限公司 Preparation method of alloy material, preparation method of soldering bit and electric soldering iron
CN104878310B (en) * 2015-06-11 2017-03-15 成都格瑞特高压容器有限责任公司 A kind of high-pressure seamless gas storage cylinder and manufacturing process
CN105127200B (en) * 2015-09-29 2017-07-25 中国钢研科技集团有限公司 The manufacture method of nuclear power plant voltage stabilizer Surge line piping
CN105619085B (en) * 2016-02-29 2018-11-06 扬州诚德钢管有限公司 The big volume seamless steel gas cylinder production technologies of diameter 914mm
CN106319347B (en) * 2016-10-27 2018-12-11 钢铁研究总院淮安有限公司 A kind of silicon vanadium steel plate and manufacturing method improving ballistic performance
CN107746908B (en) * 2017-09-19 2019-07-12 舞阳钢铁有限责任公司 A kind of low-phosphorous low silicon Cr-Mo steel ingot smelting process of low-sulfur
CN110788141B (en) * 2019-10-24 2021-10-15 衡阳华菱钢管有限公司 Seamless steel tube, manufacturing method and high-pressure gas cylinder thereof
CN112111694B (en) * 2020-09-07 2021-11-12 鞍钢股份有限公司 Seamless steel pipe for impactor and manufacturing method thereof
CN112238141B (en) * 2020-09-29 2022-09-30 江苏天淮钢管有限公司 Hot continuous rolling production method of 508 mm large-caliber extra-thick-wall seamless steel pipe
WO2022077366A1 (en) * 2020-10-15 2022-04-21 Cummins Inc. Fuel system components
CN113106347B (en) * 2021-04-13 2022-07-15 无锡恒丰祥钢管科技有限公司 High-temperature-resistant seamless steel tube and preparation method thereof
CN113817956B (en) * 2021-08-02 2022-09-20 包头钢铁(集团)有限责任公司 700 MPa-level economical seamless gas cylinder steel pipe and manufacturing method thereof
CN114032353A (en) * 2021-10-25 2022-02-11 云南永钢钢铁集团巨利达钢铁有限公司 System for preheating scrap steel by utilizing waste heat and steelmaking process for improving scrap steel ratio
CN116972327A (en) * 2022-04-24 2023-10-31 江苏申强特种设备有限公司 Inside and outside acid-alkali-resistant wear-resistant air storage tank and processing method
CN115161550B (en) * 2022-06-01 2023-10-20 江阴兴澄特种钢铁有限公司 High-strength fastener steel for large hydraulic impact crusher and manufacturing method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2020184C1 (en) * 1991-10-14 1994-09-30 Пермский машиностроительный завод им.В.И.Ленина Steel
JP2669178B2 (en) * 1991-05-08 1997-10-27 住友金属工業株式会社 High toughness and high strength seamless steel pipe
CN101706020A (en) * 2009-11-23 2010-05-12 天津商业大学 Method for preparing high alloy steel seamless steel pipe

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS599154A (en) * 1982-07-05 1984-01-18 Kawasaki Steel Corp Material for tool for manufacturing seamless steel pipe
JPH02179843A (en) * 1988-12-29 1990-07-12 Sumitomo Metal Ind Ltd Tool material for hot tube making
DE102006025241A1 (en) * 2006-05-29 2007-12-06 Rheinmetall Waffe Munition Gmbh Method for producing forged steel for highly stressed weapons, tube blanks and a weapon equipped therewith

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2669178B2 (en) * 1991-05-08 1997-10-27 住友金属工業株式会社 High toughness and high strength seamless steel pipe
RU2020184C1 (en) * 1991-10-14 1994-09-30 Пермский машиностроительный завод им.В.И.Ленина Steel
CN101706020A (en) * 2009-11-23 2010-05-12 天津商业大学 Method for preparing high alloy steel seamless steel pipe

Also Published As

Publication number Publication date
CN103556069A (en) 2014-02-05

Similar Documents

Publication Publication Date Title
CN103556069B (en) A kind of gas cylinder seamless large-diameter pipes and manufacture method thereof
CN106591700B (en) High intensity cutting steel wire gren rod and its production method
CN113846260B (en) Production method of high-strength steel plate for engineering machinery
CN101413088B (en) Sulfurated hydrogen stress etching-resisting petroleum casing pipe and manufacturing method thereof
CN100462466C (en) Method of producing low-temperature high-toughness steel and steel plate
CN105925899B (en) A kind of quenched and tempered state X52 hydrogen sulfide corrosion resistant seamless line pipes and preparation method thereof
CN103451398B (en) Manufacture method of 50CrVA alloy structural steel type hot rolled round steel bar
CN102699628B (en) Diameter is the production method of the pipeline with hydrogen sulfide corrosion resistance seamless steel pipe of 508mm
CN101892443A (en) High strength and high toughness petroleum casing pipe at steel grade with yield strength of 170-180ksi and manufacturing method thereof
CN105525226A (en) Martensitic stainless steel wire rod and production method thereof
CN105369150B (en) A kind of superhigh intensity armor manufacture method
CN103966515B (en) A kind of method utilizing electric arc furnace to prepare low-alloy high-strength toughness cast steel adding
CN102732792B (en) Steel with thickness no lower than 100mm used in vessel in hydrogen environment, and production method thereof
CN103469091A (en) Large size rolled steel integral wheel used for railway vehicle and production method thereof
CN108660377A (en) The preparation method of seamless steel pipe and seamless steel pipe
CN108070789A (en) The special thick steel of not less than 480MPa grades Ultra-fine Graineds of yield strength and preparation method
CN104131238B (en) High molding high durable Ultra-thin hot rolled steel plate and CSP production technology thereof
CN111926236B (en) Method for producing steel plate with excellent Z-direction performance for welding structure by adopting continuous casting billet under condition of small compression ratio
CN109930063B (en) Steel for engineering machinery crawler chassis wheel body and production method thereof
CN103966498A (en) High-chromium white abrasion-resistant cast iron abrasion-resistant material and production method thereof
CN111304532B (en) Heat-resistant austenitic stainless steel and preparation method thereof
CN108374121A (en) One kind C110 containing rare earth steel level oil bushings and its production method
JP2012052224A (en) Steel material excelling in toughness of weld heat-affected zone
CN113136526B (en) Steel 35CrNiMo for large-specification steel pull rod for bridge and production method thereof
CN115747657A (en) HY950CF steel plate for high-strength hydropower engineering and production method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: 471000, Binhe Road, hi tech Development Zone, Henan, Luoyang, 32

Patentee after: CSSC Shuangrui (Luoyang) special equipment Co.,Ltd.

Address before: 471000, Binhe Road, hi tech Development Zone, Henan, Luoyang, 32

Patentee before: LUOYANG SUNRUI SPECIAL EQUIPMENT Co.,Ltd.