CN100351177C - Process for preparing magnesium oxide powder for fire-proof cable - Google Patents
Process for preparing magnesium oxide powder for fire-proof cable Download PDFInfo
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- CN100351177C CN100351177C CNB200610046002XA CN200610046002A CN100351177C CN 100351177 C CN100351177 C CN 100351177C CN B200610046002X A CNB200610046002X A CN B200610046002XA CN 200610046002 A CN200610046002 A CN 200610046002A CN 100351177 C CN100351177 C CN 100351177C
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- fire
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- proof cable
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- oxide powder
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Abstract
The present invention relates to a preparation process of preparing magnesia powder for a fire-proof cable, which comprises the following procedures: step 1, Ai2O3 powder and SiO2 powder are mixed in a weight proportion Ai2O3: SiO2 =3: 1 to prepare modified additives which can be used, wherein the granularity of the Ai2O3 powder and the SiO2 powder are not lower than 200 mesh; step 2, white sand, the magnesia content of which is not lower than 95%, is ground and screened, and is mixed according to required granularity distribution; step 3, iron removal of materials in the step 2 is carried out through a dry magnetic separator; step 4, iron-eliminated materials of the step 3 are baked for one to two hours in the temperature of 400 DEG C; step 5, the modified additives of the step 1 are added to the materials, the dosage of the modified additives is 1% to 2% of the weight of the materials, the mixture is uniformly mixed, and the magnesia powder for a fire-proof cable is obtained. The performance of the magnesia powder prepared by using the method can meet the requirement of the fire-proof cable, the magnesia powder can replace imported products, and the production cost of the fire-proof cable can be greatly reduced.
Description
One, technical field
The present invention relates to electrothermal insulating magnesia material, be specially a kind of preparation method of magnesium oxide powder for fire-proof cable packing material.
Two, background technology
In case, occurred so-called fireproof cable in the world in recent years for the supply cable that uses under some occasion can not be burnt during presence of fire around very soon.This cable is to utilize magnesian high temperature resistantly and at high temperature still have the characteristics of good electrical insulativity, and magnesia powder as the packing material between the cable conductor, is played the effects such as high temperature that attached cable lead, insulation and anti-fire cause.
At present, China makes the production unit of fireproof cable and also introduces by external, and its used magnesia powder packing material is also by import.Because the magnesium oxide powder for fire-proof cable price height (nearly ten thousand yuans per ton) of external import, the fireproof cable production cost that causes China to make is also high.Therefore, domestic present urgent need performance can satisfy the fireproof cable requirement, thereby can substitute import, simultaneously the low again magnesium oxide powder for fire-proof cable packing material of its manufacturing cost.
For magnesium oxide powder for fire-proof cable, except technic indexs such as its density and flow velocity will satisfy the requirement of electrical cable-making apparatus, its electrical property (according to the imported product test) requires normality (to use diameter 6.5mm, the 304 stainless steels test electrothermal tube test of length 500mm, down together) resistance is not less than 500M Ω, the withstand voltage 2000V that is not less than; It is hot that (with described test electrothermal tube, energising is 15 minutes under 110V voltage, power 500W, load 6W/cm
2, down with) resistance is not less than 3M Ω, the withstand voltage 1300V that is not less than, leakage current is not more than 0.2mA.
Utilize domestic present production be used to prepare the electrically molten magnesia powder that senior middle school's temperature electrothermal tube uses and make raw material, though also can process the magnesia powder packing material that performance satisfies the fireproof cable requirement, but this electrically molten magnesia powder production cost height, produce magnesium oxide powder for fire-proof cable with it, be more or less the same with the imported product price, can not obviously reduce the manufacturing cost of fireproof cable.
Three, summary of the invention
The objective of the invention is to provide a kind of preparation method of magnesium oxide powder for fire-proof cable at above-mentioned needs.With the magnesium oxide powder for fire-proof cable of this method preparation not only performance can satisfy the fireproof cable requirement, and its manufacturing cost can reduce greatly.
For achieving the above object, the present invention at first starts with from raw material, seek a kind of raw material of cheap preparation magnesium oxide powder for fire-proof cable, Here it is adopts the electric smelting method to prepare " white skin sand " (industry is commonly called as) of handling as scrap stock at last in the big crystal magnesium oxide process of producing product at present.
Though the main component of white skin sand also is a magnesium oxide, the content higher (generally more than 3%) of iron, various light metal and detrimental impurity such as heavy metal, potassium, sodium, calcium oxide and sulphur.Undressed white skin sand room temperature resistance is all below 100M Ω, below the withstand voltage 800V; Hot resistance is below 0.1M Ω, and is withstand voltage less than 1V, and leakage current is more than 5mA, and its electrical property does not far reach the requirement of fireproof cable.
May further comprise the steps according to the method that is the feedstock production magnesium oxide powder for fire-proof cable with white skin sand provided by the invention:
(1) granularity is not less than 200 purpose Al
2O
3Powder and SiO
2Powder is by weight Al
2O
3: SiO
2Mix at=3: 1, is mixed with property-modifying additive, stand-by;
(2) content of magnesia is not less than 95% white skin sand and pulverizes, screening, and size-grade distribution on request (technic index that is required by electrical cable-making apparatus decides) is mixed;
(3) material in (2) is carried out deironing by dry-type magnetic extractor;
(4) material after the deironing in (3) was dried by the fire 1-2 hour under 400 ℃ of temperature;
(5) property-modifying additive in (1) is mixed in the material of (4), the consumption of property-modifying additive is the 1-2% of weight of material, and mixing behind the admixture promptly makes magnesium oxide powder for fire-proof cable.
Magnesium oxide powder for fire-proof cable prepared in accordance with the present invention, after testing the proof, its normality and hot under electrical property obviously improve, can satisfy the requirement of fireproof cable.Simultaneously, because raw materials used white skin sand market price low (per ton be no more than 1000 yuans), add that energy consumption is not high in the whole process of production, the property-modifying additive consumption seldom, this production cost that just makes this magnesium oxide powder for fire-proof cable is less than 1/2nd of imported product price, produce fireproof cable with its alternative import, the production cost of fireproof cable is reduced greatly.
Four, embodiment
Embodiment 1
Prepare magnesium oxide powder for fire-proof cable according to the following steps:
(1) with granularity is 200 purpose Al
2O
3Powder and SiO
2Powder is by weight Al
2O
3: SiO
2Mix at=3: 1, is mixed with property-modifying additive;
(2) getting content of magnesia is that 95% white skin sand is pulverized, and sieve+60 orders ,+120 orders ,+200 orders and the varigrained material of-250 orders, described varigrained material is taken by weighing and mixes by (weight ratio) 0.2%, 17.5%, 26% and 57.3% successively;
(3) be that the dry-type magnetic extractor of 15000GS carries out deironing with above-mentioned blended material by magneticstrength;
(4) material after the above-mentioned deironing was dried by the fire 1.5 hours under 400 ℃ of temperature;
(5) take by weighing material in 100 grams (4), mix property-modifying additive in 1 gram (1) therein, make magnesium oxide powder for fire-proof cable behind the mixing.
After testing, the compacted density of this magnesia powder (TD) is 2.1g/cm
3, flow velocity (FR) is 185s/100g, electrical property is: room temperature resistance 500M Ω, withstand voltage 2500V; Hot leakage current O.13mA, resistance 3.5M Ω, withstand voltage 1800V.Every index satisfies the fireproof cable requirement.
Embodiment 2
(1), (2), (3), (4) step be identical with embodiment 1, only the property-modifying additive incorporation changes 1.2 grams in (5) step, makes magnesium oxide powder for fire-proof cable.
After testing, compacted density of this magnesia powder (TD) and flow velocity (FR) do not have big the variation with embodiment 1, and electrical property is: room temperature resistance 600M Ω, withstand voltage 2500V; Hot leakage current O.10mA, resistance 4.OM Ω, withstand voltage 1800V.Every index satisfies the fireproof cable requirement.
Embodiment 3
(1), (2), (3), (4) step be identical with embodiment 1, only the property-modifying additive incorporation changes 2 grams in (5) step, makes magnesium oxide powder for fire-proof cable.
After testing, compacted density of this magnesia powder (TD) and flow velocity (FR) do not have big the variation with embodiment 1, and electrical property is: room temperature resistance 530M Ω, withstand voltage 2500V; Hot leakage current 0.13mA, resistance 3.0M Ω, withstand voltage 1500V.Every index satisfies the fireproof cable requirement.
Claims (2)
1, a kind of preparation method of magnesium oxide powder for fire-proof cable is characterized in that, may further comprise the steps:
(1) granularity is not less than 200 purpose Al
2O
3Powder and SiO
2Powder is by weight Al
2O
3: SiO
2Mix at=3: 1, is mixed with property-modifying additive, stand-by;
(2) content of magnesia is not less than 95% white skin sand and pulverizes, screening, and size-grade distribution on request is mixed;
(3) with material in (2) by carry out deironing in the formula magnetic separator;
(4) material after the deironing in (3) was dried by the fire 1-2 hour under 400 ℃ of temperature;
(5) property-modifying additive in (1) is mixed in the material of (4), the consumption of property-modifying additive is the 1-2% of weight of material, and mixing behind the admixture promptly makes magnesium oxide powder for fire-proof cable.
2, the preparation method of magnesium oxide powder for fire-proof cable according to claim 1 is characterized in that, the consumption of property-modifying additive is 1.2% of a weight of material in described (5).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610046002XA CN100351177C (en) | 2006-03-10 | 2006-03-10 | Process for preparing magnesium oxide powder for fire-proof cable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610046002XA CN100351177C (en) | 2006-03-10 | 2006-03-10 | Process for preparing magnesium oxide powder for fire-proof cable |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1821079A CN1821079A (en) | 2006-08-23 |
| CN100351177C true CN100351177C (en) | 2007-11-28 |
Family
ID=36922679
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|---|---|---|---|
| CNB200610046002XA Expired - Fee Related CN100351177C (en) | 2006-03-10 | 2006-03-10 | Process for preparing magnesium oxide powder for fire-proof cable |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102179643B (en) * | 2011-04-20 | 2013-03-20 | 大石桥市美尔镁制品有限公司 | Preparation method of magnesium oxide powder for welding electrode coating |
| CN108584997B (en) * | 2018-07-11 | 2021-04-27 | 营口松辽镁业有限公司 | Preparation method of magnesium oxide powder for fireproof cable |
| CN116469609B (en) * | 2023-04-29 | 2024-01-30 | 开开电缆科技有限公司 | Mineral insulated cable and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02307821A (en) * | 1988-04-06 | 1990-12-21 | Shin Nippon Kagaku Kogyo Co Ltd | Electrical insulating filler for high-temperature use and its production |
| JPH03250504A (en) * | 1990-02-28 | 1991-11-08 | Shin Nippon Kagaku Kogyo Co Ltd | High temperature electric insulating filler and sheath heater filled therewith |
| CN1344678A (en) * | 2001-08-17 | 2002-04-17 | 白朝洪 | Magnesia producing process |
-
2006
- 2006-03-10 CN CNB200610046002XA patent/CN100351177C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02307821A (en) * | 1988-04-06 | 1990-12-21 | Shin Nippon Kagaku Kogyo Co Ltd | Electrical insulating filler for high-temperature use and its production |
| JPH03250504A (en) * | 1990-02-28 | 1991-11-08 | Shin Nippon Kagaku Kogyo Co Ltd | High temperature electric insulating filler and sheath heater filled therewith |
| CN1344678A (en) * | 2001-08-17 | 2002-04-17 | 白朝洪 | Magnesia producing process |
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| Publication number | Publication date |
|---|---|
| CN1821079A (en) | 2006-08-23 |
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Granted publication date: 20071128 Termination date: 20100310 |