CL2011003196A1 - Un método adecuado para su uso en las reacciones de conversión de óxidos de carbono que comprende formar una composición de una mezcla intima de partículas individuales; recuperar y secar la composición; someter a reducción; pasivar las superficies de cobre reducidas, y moldear la composición reducida y pasivada en un pellet por compresión. - Google Patents
Un método adecuado para su uso en las reacciones de conversión de óxidos de carbono que comprende formar una composición de una mezcla intima de partículas individuales; recuperar y secar la composición; someter a reducción; pasivar las superficies de cobre reducidas, y moldear la composición reducida y pasivada en un pellet por compresión.Info
- Publication number
- CL2011003196A1 CL2011003196A1 CL2011003196A CL2011003196A CL2011003196A1 CL 2011003196 A1 CL2011003196 A1 CL 2011003196A1 CL 2011003196 A CL2011003196 A CL 2011003196A CL 2011003196 A CL2011003196 A CL 2011003196A CL 2011003196 A1 CL2011003196 A1 CL 2011003196A1
- Authority
- CL
- Chile
- Prior art keywords
- composition
- reduced
- copper
- compounds
- compression
- Prior art date
Links
- 239000010949 copper Substances 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052802 copper Inorganic materials 0.000 title abstract 6
- 230000006835 compression Effects 0.000 title abstract 5
- 238000007906 compression Methods 0.000 title abstract 5
- 239000008188 pellet Substances 0.000 title abstract 4
- 239000011872 intimate mixture Substances 0.000 title abstract 3
- 229910002090 carbon oxide Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000002245 particle Substances 0.000 title abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000005749 Copper compound Substances 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 150000001880 copper compounds Chemical class 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 229910052715 tantalum Inorganic materials 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 229910052721 tungsten Inorganic materials 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- -1 rare earth compounds Chemical class 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/31—Density
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/392—Metal surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/12—Oxidising
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un método adecuado para su uso en las reacciones de conversion de oxidos de carbono en Ia forma de un pellet formado por compresion de un polvo de catalizador reducido y pasivado, que comprende cobre en un rango de concentracion de 10-80% en peso, oxido de zinc en un rango de 20-90% en peso, alumina en un rango de 5-60% en peso y opcionalmente compuestos promotores de óxidos seleccionados de compuestos de Mg, Cr, Mn, V, Ti, Zr, Ta, Mo, W, Si y tierras raras en el rango de concentracion de 0,01-10% en peso; en donde dicho pellet tiene una resistenca a Ia compresion media en su forma resultante >= 6,5 kg, una razon de resistencia a la compresiôn horizontal media, entre las uriidades reducidas y las unidades en su forma resultante >= 0,5:1 y un area superficial de cobre sobre los 60 m2/g de Cu, que comprende las etapas de: formar, en un medio acuoso, una composicion que comprende una mezcla intima de particulas individuales de compuestos de cobre, zinc, aluminio y opcionalmente uno o más compuestos metalicos promotores seleccionados de compuestos de Mg, Cr, Mn, V, Ti, Zr, Ta, Mo, W, Si y tierras raras; recuperar y secar Ia composicion para formar un precursor catalitico; someter a Ia composicion del precursor catalitico seco a condiciones de reduccion, de manera tal, que los compuestos de cobre en ella sean convertidos en cobre; pasivar las superficies de cobre reducidas; y moldear Ia composición reducida y pasivada en un pellet por compresion, donde previo a Ia reduccion de los compuestos de cobre, Ia mezcla intima es sometida a una etapa de secado a una temperatura en el rango de 180-240°C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0910364.9A GB0910364D0 (en) | 2009-06-17 | 2009-06-17 | Carbon oxides conversion process |
Publications (1)
Publication Number | Publication Date |
---|---|
CL2011003196A1 true CL2011003196A1 (es) | 2012-05-25 |
Family
ID=40940895
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CL2011003196A CL2011003196A1 (es) | 2009-06-17 | 2011-12-16 | Un método adecuado para su uso en las reacciones de conversión de óxidos de carbono que comprende formar una composición de una mezcla intima de partículas individuales; recuperar y secar la composición; someter a reducción; pasivar las superficies de cobre reducidas, y moldear la composición reducida y pasivada en un pellet por compresión. |
Country Status (14)
Country | Link |
---|---|
US (1) | US9492809B2 (es) |
EP (1) | EP2442904A1 (es) |
CN (1) | CN102458650B (es) |
AU (1) | AU2010261571B2 (es) |
BR (1) | BRPI1014129A2 (es) |
CA (1) | CA2764341A1 (es) |
CL (1) | CL2011003196A1 (es) |
EG (1) | EG27012A (es) |
GB (1) | GB0910364D0 (es) |
MY (1) | MY155850A (es) |
NZ (1) | NZ596845A (es) |
RU (1) | RU2524951C2 (es) |
WO (1) | WO2010146379A1 (es) |
ZA (1) | ZA201109101B (es) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9295978B2 (en) | 2012-02-15 | 2016-03-29 | Basf Corporation | Catalyst and method for the direct synthesis of dimethyl ether from synthesis gas |
US20160318006A1 (en) * | 2013-12-16 | 2016-11-03 | Cool Planet Energy Systems, Inc. | Low Pressure Dimethyl Ether Synthesis Catalyst |
EA035796B1 (ru) | 2015-10-29 | 2020-08-12 | Джонсон Мэтти Паблик Лимитед Компани | Катализатор конверсии водяного газа |
GB201519139D0 (en) | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
GB201519133D0 (en) * | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
RU2603641C1 (ru) * | 2015-12-28 | 2016-11-27 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Ивановский государственный химико-технологический университет" (ИГХТУ) | Способ приготовления катализатора среднетемпературной конверсии оксида углерода водяным паром |
EP3208258A1 (en) * | 2016-02-16 | 2017-08-23 | Fundació Privada Institut Català d'Investigació Química (ICIQ) | Methanol production process |
WO2018004994A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Fluidized bed membrane reactor |
US9981896B2 (en) | 2016-07-01 | 2018-05-29 | Res Usa, Llc | Conversion of methane to dimethyl ether |
WO2018004993A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Reduction of greenhouse gas emission |
CN106964363B (zh) * | 2017-04-14 | 2018-09-25 | 山东科技大学 | 一种抗砷co耐硫变换催化剂及制备方法 |
GB201905293D0 (en) * | 2019-04-15 | 2019-05-29 | Johnson Matthey Plc | Copper-containing catalysts |
CN114073990A (zh) * | 2020-08-18 | 2022-02-22 | 中石化南京化工研究院有限公司 | 一种无需焙烧的铜基加氢催化剂制备方法 |
EP4219403A1 (en) | 2020-09-24 | 2023-08-02 | Sekisui Chemical Co., Ltd. | Oxygen carrier, method for producing oxygen carrier, and method for producing gas |
GB202016050D0 (en) * | 2020-10-09 | 2020-11-25 | Johnson Matthey Plc | Hydrogen process |
GB202100248D0 (en) * | 2021-01-08 | 2021-02-24 | Johnson Matthey Plc | Catalyst passivation method |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1010871A (en) | 1962-08-24 | 1965-11-24 | Ici Ltd | Water-gas conversion and catalysts therefor |
GB1159035A (en) | 1965-08-18 | 1969-07-23 | Ici Ltd | Methanol Synthesis. |
GB1296212A (es) | 1969-03-04 | 1972-11-15 | ||
GB1405012A (en) | 1972-01-21 | 1975-09-03 | Ici Ltd | Method of making composition convertible to a catalyst precursor and catalyst and methanol synthesis using the catalyst |
US4256682A (en) * | 1980-03-05 | 1981-03-17 | W. R. Grace & Co. | Method of preparing silica gel pellets |
US4441927A (en) * | 1982-11-16 | 1984-04-10 | Cabot Corporation | Tantalum powder composition |
DE3317725A1 (de) * | 1983-05-16 | 1984-11-22 | Süd-Chemie AG, 8000 München | Katalysator fuer die methanolsynthese |
DE3571797D1 (en) | 1984-03-02 | 1989-08-31 | Ici Plc | Process for producing ammonia synthesis gas |
GB8512684D0 (en) | 1985-05-20 | 1985-06-26 | Ici Plc | Oxidation process |
FR2585582B1 (fr) * | 1985-08-05 | 1987-11-13 | Vincent Yvon | Patins a roulettes propulseurs |
GB8521650D0 (en) * | 1985-08-30 | 1985-10-02 | Ici Plc | Catalyst |
GB8714539D0 (en) | 1987-06-22 | 1987-07-29 | Ici Plc | Catalysts |
UA26198C2 (uk) * | 1994-02-14 | 1999-07-19 | Державний Науково-Дослідний І Проектний Інститут Хімічних Технологій "Хімтехнологія" | Спосіб приготуваhhя каталізатора |
US5972207A (en) * | 1998-10-08 | 1999-10-26 | Texaco Inc. | Catalytic reforming process for heavy cracked naphtha |
DE10111198A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Methanolreformierungskatalysator mit verringertem Volumenschwund |
DE10111197A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Verfahren zur Herstellung von Katalysatoren mit geringem Volumenschwund |
US20080033218A1 (en) | 2006-08-03 | 2008-02-07 | Lattner James R | Alcohol and olefin production from syngas |
GB0620793D0 (en) | 2006-10-20 | 2006-11-29 | Johnson Matthey Plc | Process |
GB0710022D0 (en) | 2007-05-25 | 2007-07-04 | Johnson Matthey Plc | Methonal process |
-
2009
- 2009-06-17 GB GBGB0910364.9A patent/GB0910364D0/en not_active Ceased
-
2010
- 2010-05-24 NZ NZ596845A patent/NZ596845A/xx not_active IP Right Cessation
- 2010-05-24 CN CN201080026705.0A patent/CN102458650B/zh not_active Expired - Fee Related
- 2010-05-24 MY MYPI2011006121A patent/MY155850A/en unknown
- 2010-05-24 EP EP10720309A patent/EP2442904A1/en not_active Withdrawn
- 2010-05-24 WO PCT/GB2010/050843 patent/WO2010146379A1/en active Application Filing
- 2010-05-24 RU RU2012101351/04A patent/RU2524951C2/ru not_active IP Right Cessation
- 2010-05-24 US US13/378,589 patent/US9492809B2/en not_active Expired - Fee Related
- 2010-05-24 CA CA2764341A patent/CA2764341A1/en not_active Abandoned
- 2010-05-24 AU AU2010261571A patent/AU2010261571B2/en not_active Ceased
- 2010-05-24 BR BRPI1014129A patent/BRPI1014129A2/pt not_active Application Discontinuation
-
2011
- 2011-12-09 ZA ZA2011/09101A patent/ZA201109101B/en unknown
- 2011-12-13 EG EG2011122085A patent/EG27012A/xx active
- 2011-12-16 CL CL2011003196A patent/CL2011003196A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
NZ596845A (en) | 2013-01-25 |
MY155850A (en) | 2015-12-15 |
US20120202681A1 (en) | 2012-08-09 |
RU2524951C2 (ru) | 2014-08-10 |
EP2442904A1 (en) | 2012-04-25 |
GB0910364D0 (en) | 2009-07-29 |
BRPI1014129A2 (pt) | 2016-04-12 |
CN102458650A (zh) | 2012-05-16 |
RU2012101351A (ru) | 2013-07-27 |
CN102458650B (zh) | 2014-05-21 |
US9492809B2 (en) | 2016-11-15 |
AU2010261571A1 (en) | 2012-01-12 |
CA2764341A1 (en) | 2010-12-23 |
ZA201109101B (en) | 2012-08-29 |
AU2010261571B2 (en) | 2014-04-24 |
WO2010146379A1 (en) | 2010-12-23 |
EG27012A (en) | 2015-03-31 |
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