CH714955B8 - anti-reflective coating. - Google Patents

anti-reflective coating. Download PDF

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Publication number
CH714955B8
CH714955B8 CH01151/19A CH11512019A CH714955B8 CH 714955 B8 CH714955 B8 CH 714955B8 CH 01151/19 A CH01151/19 A CH 01151/19A CH 11512019 A CH11512019 A CH 11512019A CH 714955 B8 CH714955 B8 CH 714955B8
Authority
CH
Switzerland
Prior art keywords
layers
refractive index
surface areas
reflective coating
differ
Prior art date
Application number
CH01151/19A
Other languages
German (de)
Other versions
CH714955B1 (en
Inventor
Dirk Apitz Dr
Ulf Brauneck Dr
Bourquin Sébastian
Original Assignee
Schott Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schott Ag filed Critical Schott Ag
Publication of CH714955B1 publication Critical patent/CH714955B1/de
Publication of CH714955B8 publication Critical patent/CH714955B8/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • C03C17/3417Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • C03C17/3429Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
    • C03C17/3435Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising a nitride, oxynitride, boronitride or carbonitride
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/113Anti-reflection coatings using inorganic layer materials only
    • G02B1/115Multilayers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/73Anti-reflective coatings with specific characteristics
    • C03C2217/734Anti-reflective coatings with specific characteristics comprising an alternation of high and low refractive indexes
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/78Coatings specially designed to be durable, e.g. scratch-resistant

Abstract

Ziel der Erfindung ist es, ein hinsichtlich der optischen Eigenschaften auf unebenen Oberflächen möglichst unempfindliches Antireflex-System bereit zu stellen Dazu ist ein Verfahren zur Herstellung eines transparentes Element (1) vorgesehen, wobei das transparente Element (1) umfasst ein transparentes Substrat (3) und auf diesem Substrat (3), eine mehrlagige Antireflex-Beschichtung (5), welche zumindest sechs Lagen umfasst, wobei sich Lagen (51, 53, 55) mit hohem Brechungsindex mit Lagen (50, 52, 54, 56) mit niedrigerem Brechungsindex abwechseln, und wobei die Lagen (51, 53, 55) mit höherem Brechungsindex eine größere Härte als die Lagen (50, 52, 54, 56) mit niedrigerem Brechungsindex aufweisen, und wobei die oberste Lage (60) der mehrlagigen Antireflex-Beschichtung (5) eine Lage mit niedrigerem Brechungsindex ist, und wobei das Substrat (3) zumindest zwei Oberflächenbereiche (30, 32) aufweist, die sich hinsichtlich ihrer Neigung unterscheiden, wobei die Antireflex-Beschichtung (5) die Oberflächenbereiche (30, 32) unterschiedlicher Neigung bedeckt, und wobei für die Antireflex-Beschichtung (5) auf den Oberflächenbereichen (30, 32) zumindest eines der folgenden Merkmale gilt die Farben der Restreflexion jeweils unter 0° Einfallswinkel auf die Oberflächenbereiche (30, 32) unterscheiden sich im CIE xyz-Farbsystem voneinander um nicht mehr als Δx=0 05, Δy=0 05, bevorzugt nicht mehr als Δx=0 03, Δy=0 03, besonders bevorzugt um nicht mehr als Δx=0 02, Δy=0 02, die photopischen Reflektivitäten unter 0° Einfallswinkel der Oberflächenbereiche (30, 32) unterscheiden sich voneinander um nicht mehr als ΔR_ph=1 5%The aim of the invention is to provide an antireflection system that is as insensitive as possible with regard to the optical properties on uneven surfaces. For this purpose, a method for producing a transparent element (1) is provided, the transparent element (1) comprising a transparent substrate (3) and on this substrate (3), a multi-layer anti-reflection coating (5) comprising at least six layers, layers (51, 53, 55) with a high refractive index and layers (50, 52, 54, 56) with a lower refractive index alternate, and wherein the layers (51, 53, 55) with a higher refractive index have a greater hardness than the layers (50, 52, 54, 56) with a lower refractive index, and wherein the top layer (60) of the multilayer anti-reflective coating ( 5) a layer with a lower refractive index, and wherein the substrate (3) has at least two surface areas (30, 32) which differ in terms of their inclination, wherein the anti-reflective coating (5) the Surface areas (30, 32) with different inclinations are covered, and at least one of the following features applies to the anti-reflective coating (5) on the surface areas (30, 32): the colors of the residual reflection each at an angle of incidence of 0° on the surface areas (30, 32 ) differ from each other in the CIE xyz color system by no more than Δx=0 05, Δy=0 05, preferably no more than Δx=0 03, Δy=0 03, particularly preferably by no more than Δx=0 02, Δy= 0 02, the photopic reflectivities at 0° angle of incidence of the surface areas (30, 32) differ from each other by no more than ΔR_ph=1 5%

CH01151/19A 2017-03-14 2018-03-14 anti-reflective coating. CH714955B8 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102017105372.7A DE102017105372B4 (en) 2017-03-14 2017-03-14 Transparent element with an anti-reflective coating and method of making same
PCT/EP2018/056344 WO2018167126A1 (en) 2017-03-14 2018-03-14 Antireflection coating

Publications (2)

Publication Number Publication Date
CH714955B1 CH714955B1 (en) 2018-09-22
CH714955B8 true CH714955B8 (en) 2022-03-15

Family

ID=61691476

Family Applications (1)

Application Number Title Priority Date Filing Date
CH01151/19A CH714955B8 (en) 2017-03-14 2018-03-14 anti-reflective coating.

Country Status (4)

Country Link
CN (1) CN110431122B (en)
CH (1) CH714955B8 (en)
DE (1) DE102017105372B4 (en)
WO (1) WO2018167126A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2928504T3 (en) * 2020-01-28 2022-11-18 Cnbm Res Institute For Advanced Glass Materials Group Co Ltd Colored facade element with composite panel structure
CN113629156B (en) * 2021-08-11 2023-10-27 无锡中微晶园电子有限公司 Color uniformity adjustment method suitable for photoelectric detector
CN116969691A (en) * 2022-04-22 2023-10-31 荣耀终端有限公司 Scratch-resistant antireflection glass, display screen of electronic equipment and electronic equipment

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JP2856173B2 (en) * 1996-09-17 1999-02-10 日本電気株式会社 Antireflection structure and pattern forming method
FR2793889B1 (en) 1999-05-20 2002-06-28 Saint Gobain Vitrage TRANSPARENT SUBSTRATE WITH ANTI-REFLECTIVE COATING
EP1148037A1 (en) 2000-04-19 2001-10-24 Blösch Holding AG Process for the production of an anti-reflective coating on watchcover glasses
DE20106167U1 (en) 2001-04-07 2001-06-21 Schott Glas Hob with a glass ceramic plate as the cooking surface
FR2833256B1 (en) 2001-12-11 2004-09-17 Snc Eurokera VITROCERAMIC PLATES, COOKING PLATES COMPRISING SAME AND METHODS OF MAKING SAME
JP4887612B2 (en) * 2004-10-20 2012-02-29 日油株式会社 Anti-reflection material and electronic image display device using the same
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DE202012013052U1 (en) 2011-02-23 2014-09-29 Schott Ag Sapphire glass disc with antireflection coating and its use
DE102014108058A1 (en) * 2014-06-06 2015-12-17 Schott Ag Optical element with high scratch resistance
US9588266B2 (en) * 2011-05-17 2017-03-07 Canon Denshi Kabushiki Kaisha Optical filter and optical apparatus
DE102012002927A1 (en) * 2012-02-14 2013-08-14 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. An article with reflection-reducing coating and process for its production
US9201172B2 (en) * 2012-09-14 2015-12-01 Ricoh Imaging Company, Ltd. Anti-reflection coating, optical member having it, and optical equipment comprising such optical member
JP6470274B2 (en) * 2013-07-05 2019-02-13 エシロール アンテルナショナルEssilor International Optical article comprising an antireflective coating having very low reflection in the visible region
DE102014104798B4 (en) 2014-04-03 2021-04-22 Schott Ag Hard anti-reflective coatings as well as their manufacture and use
US9335444B2 (en) 2014-05-12 2016-05-10 Corning Incorporated Durable and scratch-resistant anti-reflective articles
KR20220084430A (en) * 2014-05-23 2022-06-21 코닝 인코포레이티드 Low Contrast Anti-Reflection Articles With Reduced Scratch and Fingerprint Visibility
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DE102016125689A1 (en) 2016-12-23 2018-06-28 Schott Ag Substrate comprising anti-reflection coating system with hard material coating and method for its production

Also Published As

Publication number Publication date
CH714955B1 (en) 2018-09-22
CN110431122B (en) 2022-03-18
DE102017105372B4 (en) 2022-05-25
DE102017105372A1 (en) 2018-09-20
WO2018167126A1 (en) 2018-09-20
CN110431122A (en) 2019-11-08

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