CH713313A2 - Dressing room with decor for a watch or jewel and its manufacturing process. - Google Patents

Dressing room with decor for a watch or jewel and its manufacturing process. Download PDF

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Publication number
CH713313A2
CH713313A2 CH01666/16A CH16662016A CH713313A2 CH 713313 A2 CH713313 A2 CH 713313A2 CH 01666/16 A CH01666/16 A CH 01666/16A CH 16662016 A CH16662016 A CH 16662016A CH 713313 A2 CH713313 A2 CH 713313A2
Authority
CH
Switzerland
Prior art keywords
strip
substrate
face
bracelet
extrusion
Prior art date
Application number
CH01666/16A
Other languages
French (fr)
Inventor
Rannoux Claire
François Nicolas
Original Assignee
Swatch Group Res & Dev Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Swatch Group Res & Dev Ltd filed Critical Swatch Group Res & Dev Ltd
Priority to CH01666/16A priority Critical patent/CH713313A2/en
Publication of CH713313A2 publication Critical patent/CH713313A2/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • B29C48/154Coating solid articles, i.e. non-hollow articles
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    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/414Translucent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/418Refractive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536Hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/71Resistive to light or to UV
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • B32B2307/7248Odour barrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/732Dimensional properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00Decorative or ornamental articles

Abstract

La présente invention se rapporte à un procédé de fabrication d’une pièce d’habillage pour montre ou bijou, notamment d’un bracelet (5), comportant les étapes de: mise à disposition d’un substrat (1) comportant une première face opposée à une seconde face, revêtement par co-extrusion sur la première face et sur la seconde face dudit substrat (1) avec respectivement une première et une seconde bandes (2) en matériau synthétique; la première bande (2) formant sur la première face une couche transparente ou translucide permettant de maintenir en tout ou en partie le substrat (1) visible.The present invention relates to a method of manufacturing a dressing part for a watch or jewel, in particular a bracelet (5), comprising the steps of: providing a substrate (1) comprising a first face opposed to a second face, coating by coextrusion on the first face and on the second face of said substrate (1) with respectively first and second strips (2) of synthetic material; the first band (2) forming on the first face a transparent or translucent layer for maintaining all or part of the visible substrate (1).

Description

DescriptionDescription

OBJET DE L’INVENTION [0001] La présente invention se rapporte au domaine de l’horlogerie et de la bijouterie. Plus particulièrement, elle se rapporte à un procédé de revêtement par co-extrusion sur un substrat pour fabriquer, entre autres, des bracelets.OBJECT OF THE INVENTION The present invention relates to the field of watchmaking and jewelry. More particularly, it relates to a method of coating by co-extrusion on a substrate for manufacturing, inter alia, bracelets.

ARRIÈRE-PLAN TECHNOLOGIQUE ET ÉTAT DE LA TECHNIQUE [0002] Les bracelets en plastique présentant des couleurs différentes, des décors ou intégrant des effets visuels particuliers sont très prisés par les clients. Ce type de bracelet peut être fabriqué par moulage, surmoulage ou bi-injection de matières plastiques de différentes couleurs. Ce sont des procédés de fabrication en lots à étapes multiples, ce qui les rend peu appropriés à une production industrielle de masse peu coûteuse.TECHNOLOGICAL BACKGROUND AND STATE OF THE ART [0002] Plastic bracelets presenting different colors, decorations or incorporating particular visual effects are very popular with customers. This type of bracelet can be manufactured by molding, overmolding or bi-injection of plastic materials of different colors. These are multi-step batch manufacturing processes, making them unsuitable for inexpensive mass industrial production.

[0003] Dans le passé, il a été proposé de réaliser des bracelets par un procédé d’extrusion qui est un procédé moins onéreux. La fabrication de bracelets par extrusion s’est généralement limitée à la fabrication de bracelets de forme simple, unicolores et réalisés dans un même matériau comme décrit dans le document FR 2 121 864. Dernièrement, il a été proposé dans la demande EP 16 150 493 de co-extruder des matériaux de couleurs ou de propriétés différentes pour former des bracelets aux géométries et aux propriétés plus élaborées.In the past, it has been proposed to make bracelets by an extrusion process which is a less expensive process. The manufacture of bracelets by extrusion has generally been limited to the manufacture of bracelets of simple shape, single-colored and made of the same material as described in document FR 2 121 864. Lately, it has been proposed in application EP 16 150 493 co-extrude materials of different colors or properties to form bracelets with more elaborate geometries and properties.

[0004] Cependant, ces procédés ne permettent pas de réaliser des motifs complexes qui impliquent des géométries particulières et une très grande précision comme dans le cas de paysages, de figurines, de messages, etc. Il est en outre difficile d’intégrer des matières autres que des matières plastiques qui pourraient conduire à un effet esthétique original.However, these methods do not allow complex patterns to be produced which imply particular geometries and very high precision as in the case of landscapes, figurines, messages, etc. It is also difficult to integrate materials other than plastics which could lead to an original aesthetic effect.

[0005] En général, les bracelets avec des motifs complexes sont réalisés par impression numérique sur des substrats unicolores fabriqués par moulage. L’impression numérique permet d’accéder à une grande variété de designs. En revanche, le procédé présente plusieurs inconvénients: le motif est uniquement en surface, il est donc sensible à l’usure mécanique. Cela signifie qu’au fil du temps, le motif s’efface. Cette usure est en général non régulière ce qui conduit à un aspect esthétique du bracelet très rapidement non satisfaisant. Le motif est également sensible aux agressions UV et aux agressions chimiques. Les bracelets fabriqués par ce type de procédé possèdent donc des motifs qui évoluent dans le temps avec l’apparition d’effets non désirés et non esthétiques. Le document FR 2 639 870 résout ce problème en proposant un bracelet formé avec un corps thermoplastique, un film imprimé et une couche protectrice transparente. Cependant le procédé de fabrication proposé dans ce document est un procédé de moulage par injection II s’ensuit des problèmes de positionnement et de maintien en place du film imprimé dans le moule. De plus le procédé est long (impression et découpe du film imprimé, positionnement du film dans le moule, moulage, et réalisation de la couche de protection transparente) et nécessite plusieurs opérations manuelles. Ceci empêche des cadences élevées..In general, bracelets with complex patterns are produced by digital printing on single-color substrates produced by molding. Digital printing provides access to a wide variety of designs. However, the process has several drawbacks: the pattern is only on the surface, so it is sensitive to mechanical wear. This means that over time, the pattern fades. This wear is generally irregular, which leads to an aesthetic appearance of the bracelet that is very quickly unsatisfactory. The pattern is also sensitive to UV and chemical attack. The bracelets produced by this type of process therefore have patterns that change over time with the appearance of unwanted and unaesthetic effects. Document FR 2 639 870 solves this problem by proposing a bracelet formed with a thermoplastic body, a printed film and a transparent protective layer. However, the manufacturing process proposed in this document is an injection molding process II follows from the problems of positioning and holding the printed film in place in the mold. In addition, the process is long (printing and cutting the printed film, positioning the film in the mold, molding, and making the transparent protective layer) and requires several manual operations. This prevents high rates.

[0006] Un autre inconvénient de l’impression en surface du bracelet est le manque d’adhésion des encres d’impression numérique sur des bracelets en plastique type silicone qui ont des énergies de surface faible. De plus, une modification de la formulation plastique de base du bracelet implique souvent de réadapter la formulation de l’encre.Another disadvantage of printing on the surface of the bracelet is the lack of adhesion of digital printing inks on plastic bracelets of the silicone type which have low surface energies. In addition, a change in the basic plastic formulation of the bracelet often involves readjusting the ink formulation.

RÉSUMÉ DE L’INVENTION [0007] La présente invention a pour objet de fabriquer des pièces d’habillage et plus particulièrement des bracelets présentant des motifs complexes à l’aide d’un procédé simple et peu coûteux et pouvant être compatible avec des cadences de production élevées. La présente invention vise plus précisément à intégrer au sein de la pièce d’habillage un décor et, ce, sans problème de positionnement ou d’adhésion de l’encre dans le cas d’un décor imprimé. La présente invention vise aussi à mettre au point un procédé de fabrication garantissant la stabilité dans le temps du décor imprimé.SUMMARY OF THE INVENTION The object of the present invention is to manufacture coverings and more particularly bracelets with complex patterns using a simple and inexpensive process which can be compatible with production rates. high production. The present invention more specifically aims to integrate a decoration into the dressing room, without any problem of positioning or adhesion of the ink in the case of a printed decoration. The present invention also aims to develop a manufacturing process guaranteeing the stability over time of the printed decoration.

[0008] A cette fin l’invention concerne un procédé de fabrication d’une pièce d’habillage pour montre ou bijou, notamment d’un bracelet, comportant les étapes de:To this end, the invention relates to a method of manufacturing a covering piece for a watch or piece of jewelry, in particular a bracelet, comprising the steps of:

- mise à disposition d’un substrat comportant une première face opposée à une seconde face, revêtement par co-extrusion sur la première face et sur la seconde face dudit substrat avec respectivement une première et une seconde bandes en matériau synthétique; la première bande formant sur la première face une couche transparente ou translucide permettant de maintenir en tout ou en partie le substrat visible.- provision of a substrate comprising a first face opposite to a second face, coating by co-extrusion on the first face and on the second face of said substrate with respectively a first and a second strip of synthetic material; the first strip forming on the first face a transparent or translucent layer making it possible to maintain all or part of the visible substrate.

[0009] Selon un mode réalisation avantageux du procédé de fabrication de l’invention, une étape d’impression et/ou gravure d’un décor sur la première face du substrat est prévue avant l’étape de revêtement par co-extrusion des première et deuxième faces du substrat et de préférence une pluralité de décors distincts sont imprimés et/ou gravés l’un à la suite de l’autre sur la première face du substrat.According to an advantageous embodiment of the manufacturing method of the invention, a step of printing and / or etching a decoration on the first face of the substrate is provided before the step of coating by co-extrusion of the first and second faces of the substrate and preferably a plurality of distinct decorations are printed and / or engraved one after the other on the first face of the substrate.

[0010] Selon une variante préférée une étape de mise à disposition de fichiers 2D ou 3D comprenant les données personnalisées relatives à l’impression ou au gravage de chaque décor est prévue avant l’étape d’impression.According to a preferred variant, a step of making available 2D or 3D files comprising personalized data relating to the printing or engraving of each decoration is provided before the printing step.

[0011] D’autres formes d’exécution particulières sont reprises dans les revendications dépendantes.Other particular embodiments are included in the dependent claims.

CH 713 313 A2CH 713 313 A2

BRÈVE DESCRIPTION DES FIGURES [0012] Les caractéristiques et avantages de la présente invention apparaîtront à la lecture de la description détaillée ci-dessous faisant référence aux figures suivantes.BRIEF DESCRIPTION OF THE FIGURES The characteristics and advantages of the present invention will appear on reading the detailed description below referring to the following figures.

La fig. 1 représente une vue schématique des extrudeuses en amont de la filière de co-extrusion pour la réalisation du procédé selon l’invention.Fig. 1 shows a schematic view of the extruders upstream of the co-extrusion die for carrying out the process according to the invention.

La fig. 2 illustre le procédé d’impression de séquences de motifs différents sur une bande vierge. La bande ainsi décorée est utilisée comme substrat dans le procédé de revêtement par co-extrusion selon l’invention.Fig. 2 illustrates the process of printing sequences of different patterns on a blank strip. The strip thus decorated is used as a substrate in the co-extrusion coating process according to the invention.

La fig. 3 représente selon l’invention une vue schématique de l’extrudat multicouche issu de la filière de co-extrusion et de ce même extrudat après découpe et étampage. Selon cette variante, le bracelet est co-extrudé dans le sens longitudinal du bracelet.Fig. 3 shows according to the invention a schematic view of the multilayer extrudate from the co-extrusion die and this same extrudate after cutting and stamping. According to this variant, the bracelet is co-extruded in the longitudinal direction of the bracelet.

A la fig. 4, une autre variante est présentée où le bracelet est co-extrudé dans le sens transversal du bracelet.In fig. 4, another variant is presented where the bracelet is co-extruded in the transverse direction of the bracelet.

L’extrudat après découpe est également représenté. Il présente à ses extrémités latérales des structures tubulaires creuses utiles pour la fixation ultérieure du bracelet au boîtier.The extrudate after cutting is also shown. It has at its lateral ends hollow tubular structures useful for the subsequent fixing of the bracelet to the case.

La fig. 5 représente une vue partielle en perspective d’une montre avec un bracelet obtenu selon le procédé de l’invention et fixé au boîtier avec une construction de type NATO.Fig. 5 shows a partial perspective view of a watch with a bracelet obtained according to the method of the invention and fixed to the case with a NATO type construction.

La fig. 6 représente une vue en perspective d’une montre avec un bracelet fabriqué selon le procédé de co-extrusion de l’invention. La bande supérieure du bracelet présentent des zones en relief séparées par des creusures. Bien que non illustré, la bande supérieure est transparente ou translucide pour visualiser le décor de la bande centrale.Fig. 6 shows a perspective view of a watch with a bracelet made according to the co-extrusion method of the invention. The upper band of the bracelet has raised areas separated by recesses. Although not illustrated, the upper strip is transparent or translucent to visualize the decoration of the central strip.

DESCRIPTION DÉTAILLÉE DE L’INVENTION [0013] La présente invention se rapporte à un procédé de fabrication de pièces d’habillage pour l’horlogerie ou la bijouterie par revêtement d’un substrat par co-extrusion, communément co-extrusion coatingen anglais. On entend par pièces d’habillage notamment le bracelet, la boite de montre et ses éléments constitutifs, la lunette ou encore le cadran. Ce procédé est plus particulièrement décrit ici pour la fabrication de bracelets. Le procédé consiste à enrober un substrat présentant un décor complexe et/ou une texture avec des bandes de matières synthétiques. La fig. 1 illustre schématiquement le procédé avec la bobine de bande décorative formant le substrat 1 revêtue respectivement sur chaque face par co-extrusion d’une matière 2 synthétique. Selon l’invention, le revêtement en regard du décor est au moins en partie transparent ou translucide afin de pouvoir visualiser les motifs du décor.DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a process for manufacturing cladding parts for watchmaking or jewelry by coating a substrate by co-extrusion, commonly co-extrusion coating in English. By covering pieces is understood in particular the bracelet, the watch case and its constituent elements, the bezel or even the dial. This process is more particularly described here for the manufacture of bracelets. The method consists in coating a substrate having a complex decoration and / or a texture with strips of synthetic materials. Fig. 1 schematically illustrates the process with the reel of decorative strip forming the substrate 1 coated respectively on each side by co-extrusion of a synthetic material 2. According to the invention, the coating facing the decoration is at least partly transparent or translucent in order to be able to visualize the patterns of the decoration.

[0014] La bande décorative est formée de n’importe quel substrat souple et capable de résister pendant quelques secondes à des températures élevées de l’ordre de 200 °C. Elle a typiquement une épaisseur comprise entre 50 pm et 2 mm et préférentiellement entre 100 et 500 pm.The decorative strip is formed from any flexible substrate capable of withstanding high temperatures in the order of 200 ° C for a few seconds. It typically has a thickness between 50 μm and 2 mm and preferably between 100 and 500 μm.

[0015] Le motif peut être uniforme tout le long de la bande. Par exemple, la bande décorative peut être une bande textile naturelle ou synthétique (non tissé, unidirectionnel, tissé, tressé, tricoté) notamment réalisée dans les matières suivantes: lin, coton, chanvre, laine, polyester, polyamidepolyurethanne. La bande décorative peut être également une bande de papier photo, une feuille métallique, une bande adhésive intégrant des particules minérales comme du sable, des particules organiques comme des fibres de bois, des matières végétales ou des particules métalliques comme des feuilles d’or. La bande décorative peut être également une bande de thermoplastique élastomère tel que: une bande en TPU, TPI, TPE-0 (Oléfines thermoplastiques), en TPE-S - (thermoplastiques styréniques), en TPE-E (thermoplastique copolyester), en TPE-A (thermoplastique copolyamide) ou en en TPE-V et TPSi-V (combinaison de thermoplastique et de silicone réticulé). La bande décorative peut également être une bande en PVC, en PET, en certaines variétés de polycarbonate ou PC, en caoutchouc naturel ou synthétique. La bande peut être utilisée brute et, dans ce cas, le décor est apporté par la matière elle-même avec son aspect fibre naturelle, son éclat métallique, etc. La bande peut être aussi décorée par les procédés d’impression classique tels que, par exemple, la tampographie, la sérigraphie, l’offset, la flexographie, l’impression numérique. En particulier, l’impression sur substrat peut permettre d’intégrer dans le décor des pigments colorés, des composés ayant des propriétés fluorescentes, phosphorescentes, thermochromiques ou photochromiques. La bande peut être aussi décorée par les procédés de gravure en ligne type calandrage. D’un point de vue industriel, ce procédé est bien adapté à la fabrication de collections de bracelets. Au sein d’une même collection, les bracelets ont un design identique et la fabrication d’une nouvelle collection implique uniquement le changement de la bobine de bande décorative.The pattern can be uniform all along the strip. For example, the decorative strip may be a natural or synthetic textile strip (non-woven, unidirectional, woven, braided, knitted) made in particular of the following materials: linen, cotton, hemp, wool, polyester, polyamide-polyurethane. The decorative strip may also be a strip of photo paper, a metal sheet, an adhesive strip incorporating mineral particles such as sand, organic particles such as wood fibers, vegetable materials or metallic particles such as gold leaf. The decorative strip may also be a strip of elastomeric thermoplastic such as: a strip of TPU, TPI, TPE-0 (thermoplastic olefins), of TPE-S - (styrenic thermoplastics), of TPE-E (thermoplastic copolyester), of TPE -A (thermoplastic copolyamide) or in TPE-V and TPSi-V (combination of thermoplastic and crosslinked silicone). The decorative strip can also be a PVC, PET, in certain varieties of polycarbonate or PC, natural or synthetic rubber. The strip can be used raw and, in this case, the decor is provided by the material itself with its natural fiber appearance, its metallic luster, etc. The strip can also be decorated by conventional printing methods such as, for example, pad printing, screen printing, offset, flexography, digital printing. In particular, printing on a substrate can make it possible to integrate into the decor colored pigments, compounds having fluorescent, phosphorescent, thermochromic or photochromic properties. The strip can also be decorated by on-line calendering etching processes. From an industrial point of view, this process is well suited to the manufacture of collections of bracelets. Within the same collection, the bracelets have an identical design and the production of a new collection involves only the change of the reel of decorative band.

[0016] Selon une variante de l’invention, le motif est imprimé à la demande sur le substrat vierge en bande. Plusieurs séquences de motifs différents peuvent ainsi être imprimées et/ou gravés à la suite sur une même bande 1 comme illustré à la fig. 2. L’impression est préférentiellement réalisée par impression numérique pour permettre une plus grande flexibilité. Dans ce cas, les bandes en thermoplastique élastomère (TPE-O, TPU, TPI, TPE-S, TPSi-v, TPE-v), en caoutchouc, en PET, les bandes textiles synthétiques ou naturelles, (en particulier les cuirs synthétiques) etc. sont particulièrementAccording to a variant of the invention, the pattern is printed on demand on the virgin strip substrate. Several sequences of different patterns can thus be printed and / or engraved consecutively on the same strip 1 as illustrated in FIG. 2. Printing is preferably carried out by digital printing to allow greater flexibility. In this case, the bands of thermoplastic elastomer (TPE-O, TPU, TPI, TPE-S, TPSi-v, TPE-v), of rubber, of PET, synthetic or natural textile bands, (in particular synthetic leathers ) etc. are particularly

CH 713 313 A2 adaptées. D’un point de vue industriel, ce procédé de masse est particulièrement approprié pour la fabrication de bracelets personnalisés. Le client choisit son design (dessin, photo personnelle, etc.) et, éventuellement le type de substrat, en ligne ou en boutique, son design de préférence sous forme d’un fichier numérique est traité pour s’adapter aux dimensions du substrat, puis le motif 2D ou 3D est imprimé par impression numérique sur une portion de bande de substrat vierge de longueur correspondant à la largeur ou à la longueur d’un brin de bracelet. Ensuite, une fois que la bande décorative est intégralement imprimée avec les différentes séquences de motifs choisis par les clients, elle est revêtue par les deux bandes en matériau synthétique. L’extrudat multicouche ainsi formé est découpé au jet d’eau, au laser, par couteau numérique (par exemple les machines proposées par le fabricant Zünd) ou par étampage pour conduire à un bracelet personnalisé.CH 713 313 A2 adapted. From an industrial point of view, this mass process is particularly suitable for the manufacture of personalized bracelets. The customer chooses his design (drawing, personal photo, etc.) and, possibly the type of substrate, online or in store, his design preferably in the form of a digital file is processed to adapt to the dimensions of the substrate, then the 2D or 3D pattern is printed by digital printing on a portion of blank substrate strip of length corresponding to the width or the length of a bracelet strand. Then, once the decorative strip is fully printed with the different sequences of patterns chosen by customers, it is coated with the two strips of synthetic material. The multilayer extrudate thus formed is cut using a water jet, a laser, a digital knife (for example the machines offered by the manufacturer Zünd) or by stamping to yield a personalized bracelet.

[0017] Les bandes plastiques enrobantes selon l’invention sont destinées à protéger la bande décorative des agressions extérieures et à fournir un aspect esthétique et/ou visuel particulier, par exemple les bandes plastiques enrobantes peuvent être arranger pour présenter un effet loupe ou un autre effet optique analogue. II y a une bande enrobante intérieure destinée à être en contact avec la peau et une bande enrobante extérieure positionnée sur la face opposée du substrat. Typiquement, ces bandes ont une épaisseur comprise entre 100 pm et 2 mm et, de préférence, entre 100 pm et 1 mm.The plastic wrapping strips according to the invention are intended to protect the decorative strip from external aggressions and to provide a particular aesthetic and / or visual appearance, for example the plastic wrapping strips can be arranged to present a magnifying glass effect or another analogous optical effect. There is an interior coating strip intended to be in contact with the skin and an exterior coating strip positioned on the opposite face of the substrate. Typically, these strips have a thickness of between 100 μm and 2 mm and, preferably, between 100 μm and 1 mm.

[0018] La bande plastique enrobante extérieure est au moins partiellement transparente ou translucide avec un indice de transmission supérieur à 60% selon la norme ASTM D-1003 de façon à laisser apparaître le motif de la bande décorative. Plusieurs configurations peuvent être envisagées. Dans une première variante, la bande extérieure est intégralement transparente ou translucide et laisse par conséquent apparaître le motif sur toute la surface. Dans une deuxième variante, la bande enrobante extérieure est obtenue par co-extrusion de mélanges de matériaux de différentes couleurs ou indices de réfraction, au moins un des mélanges étant transparent pour laisse apparaître le motif de la bande décorative. On peut ainsi, par exemple, réaliser sur la largeur de l’extrudat des lignes de couleur différentes tout en maintenant une zone transparente ou translucide. Cette configuration permet d’obtenir des effets de profondeur différents entre les bords et le centre du bracelet.The outer coating plastic strip is at least partially transparent or translucent with a transmission index greater than 60% according to standard ASTM D-1003 so as to reveal the pattern of the decorative strip. Several configurations can be envisaged. In a first variant, the outer strip is entirely transparent or translucent and therefore lets the pattern appear over the entire surface. In a second variant, the outer wrapping strip is obtained by co-extrusion of mixtures of materials of different colors or refractive indices, at least one of the mixtures being transparent to reveal the pattern of the decorative strip. It is thus possible, for example, to produce across the width of the extrudate different colored lines while maintaining a transparent or translucent zone. This configuration provides different depth effects between the edges and the center of the bracelet.

[0019] La bande plastique enrobante intérieure est choisie pour apporter du confort au client. Elle a une dureté comprise entre 55 et 90 shore A et peut contenir des additifs pour améliorer le confort. Par exemple, elle peut contenir des céramiques de type nitrure de bore hexagonal pour évacuer l’énergie calorifique et diminuer la sudation. Elle peut aussi contenir des fibres textiles ayant un effet capillaire afin d’évacuer la sueur, ou des sels d’aluminium pour limiter la sudation. Elle peut également contenir des agents antibactériens comme des particules d’argent ou de pyrithione de zinc pour un effet anti-odeur. Comme pour la bande extérieure, elle peut être obtenue par co-extrusion de mélanges plastiques de différentes couleurs ou de différents indices de réfraction pour offrir des effets optiques différents entre les bords et le centre du bracelet. De même, la présente invention n’exclut pas que la bande intérieure soit également au moins en partie transparente ou translucide.The interior wrapping plastic band is chosen to provide comfort to the client. It has a hardness between 55 and 90 shore A and may contain additives to improve comfort. For example, it may contain ceramics of the hexagonal boron nitride type to dissipate the heat energy and reduce sweating. It can also contain textile fibers having a capillary effect in order to evacuate sweat, or aluminum salts to limit sweating. It may also contain antibacterial agents such as silver particles or zinc pyrithione for an anti-odor effect. As with the outer band, it can be obtained by co-extrusion of plastic mixtures of different colors or of different refractive indices to provide different optical effects between the edges and the center of the bracelet. Likewise, the present invention does not exclude that the inner strip is also at least partially transparent or translucent.

[0020] Selon l’invention, les matières synthétiques utilisées lors du revêtement par co-extrusion sont des mélanges comprenant au moins un élastomère. Les élastomères préférés sont les thermoplastiques élastomères, les silicones, les caoutchoucs et les élastomères fluorés.According to the invention, the synthetic materials used during coating by co-extrusion are mixtures comprising at least one elastomer. The preferred elastomers are thermoplastic elastomers, silicones, rubbers and fluorinated elastomers.

[0021] Plus précisément, pour la bande extérieure, les élastomères sont préférentiellement choisis parmi la liste suivante:More specifically, for the outer band, the elastomers are preferably chosen from the following list:

- TPE-0 - Oléfines thermoplastiques- TPE-0 - Thermoplastic olefins

- TPE-S - Plus particulièrement les composés SBS, SEBS ou SEPS styrénique- TPE-S - More particularly the SBS, SEBS or SEPS styrenic compounds

- TPE-E - Composé de copolyester- TPE-E - Composed of copolyester

- TPE-U - Polyuréthane thermoplastique- TPE-U - Thermoplastic polyurethane

- TPE-A - Polyamide thermoplastique- TPE-A - Thermoplastic polyamide

- Résines ionomères- Ionomer resins

- Silicones et préférentiellement les MVQ (méthylvinylsilicones)- Silicones and preferably MVQs (methylvinylsilicones)

- Elastomères fluorés: FKM.- Fluorinated elastomers: FKM.

[0022] Plus précisément, pour la bande intérieure, les élastomères sont préférentiellement choisis parmi la liste suivante:More specifically, for the inner strip, the elastomers are preferably chosen from the following list:

- TPE-0 - Oléfines thermoplastiques- TPE-0 - Thermoplastic olefins

- TPE-S - Plus particulièrement les composés SBS, SEBS ou SEPS styrénique- TPE-S - More particularly the SBS, SEBS or SEPS styrenic compounds

- TPE-V - Plus particulièrement les composés PP/EPDM ou TPSiV (combinaison de thermoplastique et de silicone réticulé)- TPE-V - More particularly PP / EPDM or TPSiV compounds (combination of thermoplastic and crosslinked silicone)

- TPE-E - Composé de copolyester thermoplastique- TPE-E - Composed of thermoplastic copolyester

- TPE-U - Polyuréthane thermoplastique- TPE-U - Thermoplastic polyurethane

- TPE-A - coPolyamide thermoplastique- TPE-A - thermoplastic coPolyamide

- Résines ionomères- Ionomer resins

- Silicones et préférentiellement les MVQ (méthylvinylsilicones)- Silicones and preferably MVQs (methylvinylsilicones)

- Elastomères fluorés: FKM.- Fluorinated elastomers: FKM.

[0023] De préférence, les matières synthétiques pour la bande intérieure et la bande extérieure sont chimiquement compatibles et de préférence les mêmes pour assurer une bonne cohésion du bracelet.Preferably, the synthetic materials for the inner band and the outer band are chemically compatible and preferably the same to ensure good cohesion of the bracelet.

[0024] Selon l’élastomère sélectionné pour ses propriétés spécifiques, le mélange pourra être complété par les charges et additifs divers désirés pour améliorer le confort du client.Depending on the elastomer selected for its specific properties, the mixture may be supplemented with the various fillers and additives desired to improve customer comfort.

CH 713 313 A2 [0025] Le procédé de revêtement par co-extrusion peut consister à fabriquer un extrudat 3 multicouche ayant une largeur correspondant à la largeur du bracelet comme représenté à la fig. 3. Avantageusement, le substrat 1 présente une largeur inférieure à celle des bandes 2 inférieure et supérieure afin d’être enrobé sur tout le pourtour de sa section transversale par les bandes synthétiques. Le procédé de revêtement par co-extrusion peut également consister à fabriquer un extrudat 3 multicouche ayant une largeur correspondant à la longueur d’un brin ou des deux brins du bracelet comme représenté à la fig. 4. De manière similaire, la section transversale du substrat est entièrement recouverte par la matière synthétique. Selon le mode de réalisation de la fig. 3, la forme du bracelet 5 et les trous 6 désirés sont obtenus par étampage, découpe laser, couteau numérique ou jet d’eau. L’extrudat multicouche obtenu après co-extrusion peut être d’une seule pièce et attaché au boîtier 8 de montre à l’aide de passants 7 disposés de chaque côté du boîtier de montre, il s’agit d’une construction dite NATO illustrée à la fig. 5. Selon le mode de réalisation de la fig. 4, afin de faciliter l’assemblage ultérieur du bracelet au boîtier de montre, il est avantageux de fabriquer un extrudat 3 multicouche comportant aux extrémités latérales une structure tubulaire creuse 9 en saillie destinée à recevoir une barrette permettant respectivement l’accroche à une boîte de montre avec des cornes et à une boucle, la largeur requise pour le bracelet étant préalablement obtenue par découpe laser, couteau numérique, jet d’eau ou étampage. II est également envisageable de fabriquer un extrudat multicouche intégrant sur sa largeur le profil du boîtier encadré par les brins du bracelet, l’évidement du boîtier pouvant ultérieurement être réalisé par étampage.CH 713 313 A2 The coating method by co-extrusion can consist in manufacturing a multilayer extrudate 3 having a width corresponding to the width of the bracelet as shown in FIG. 3. Advantageously, the substrate 1 has a width less than that of the lower and upper strips 2 so as to be coated around the entire periphery of its cross section with the synthetic strips. The co-extrusion coating process can also consist in manufacturing a multilayer extrudate 3 having a width corresponding to the length of one strand or two strands of the bracelet as shown in FIG. 4. Similarly, the cross section of the substrate is completely covered by the synthetic material. According to the embodiment of FIG. 3, the shape of the bracelet 5 and the desired holes 6 are obtained by stamping, laser cutting, digital knife or water jet. The multilayer extrudate obtained after co-extrusion can be in one piece and attached to the watch case 8 using loops 7 disposed on each side of the watch case, it is a so-called NATO construction illustrated in fig. 5. According to the embodiment of FIG. 4, in order to facilitate the subsequent assembly of the strap to the watch case, it is advantageous to manufacture a multilayer extrudate 3 comprising at the lateral ends a hollow tubular structure 9 projecting intended to receive a bar allowing respectively the attachment to a box of watch with horns and a buckle, the width required for the bracelet being obtained beforehand by laser cutting, digital knife, water jet or stamping. It is also conceivable to manufacture a multilayer extrudate integrating over its width the profile of the case framed by the strands of the bracelet, the recess of the case being able to be produced subsequently by stamping.

[0026] On précisera en outre que la filière de co-extrusion peut présenter un profil original permettant d’extruder des bandes enrobantes avec des zones en saillie ou, de manière plus générale, présentant un relief particulier. La fig. 6 illustre par exemple le profil qui pourrait être obtenu pour la bande extérieure du bracelet. II est aussi possible sans sortir du cadre de l’invention, de profiter en plus des autres avantages du procédé d’extrusion, comme combiner plusieurs matières afin de modifier localement les propriétés mécaniques du bracelet, notamment au niveau des attaches, par exemple.It will further be specified that the co-extrusion die may have an original profile making it possible to extrude encapsulating strips with projecting zones or, more generally, having a particular relief. Fig. 6 illustrates for example the profile which could be obtained for the outer band of the bracelet. It is also possible without departing from the scope of the invention to take advantage of the other advantages of the extrusion process, such as combining several materials in order to locally modify the mechanical properties of the bracelet, in particular at the level of the fasteners, for example.

[0027] Les bracelets ainsi réalisés par co-extrusion présentent de nombreux avantages.The bracelets thus produced by co-extrusion have many advantages.

[0028] Le procédé selon l’invention est un procédé de masse peu coûteux qui permet d’obtenir des bracelets personnalisés avec un design choisi par le client, voire un bracelet unique. On se différencie ainsi des procédés de moulage pièce par pièce peu adaptés pour une production de masse avec des cadences élevées.The method according to the invention is an inexpensive mass method which makes it possible to obtain personalized bracelets with a design chosen by the customer, or even a unique bracelet. One thus differs from the molding processes piece by piece little adapted for mass production with high rates.

[0029] Des designs très différents peuvent être obtenus sans modification de la ligne industrielle.Very different designs can be obtained without modification of the industrial line.

[0030] Les bracelets présentent une esthétique particulière avec un effet de profondeur et un effet tridimensionnel générés par la couche épaisse et transparente de matière synthétique.The bracelets have a particular aesthetic with a depth effect and a three-dimensional effect generated by the thick and transparent layer of synthetic material.

[0031] Le motif complexe se situe à l’intérieur du bracelet. II est donc protégé des agressions extérieures (usure mécanique, agressions chimiques, UV, ...) par la bande synthétique. Le motif est imprimé sur un substrat plat et non pas sur un bracelet tridimensionnel, ce qui simplifie également fortement le procédé d’impression.The complex pattern is located inside the bracelet. It is therefore protected from external aggressions (mechanical wear, chemical aggressions, UV, ...) by the synthetic band. The pattern is printed on a flat substrate and not on a three-dimensional bracelet, which also greatly simplifies the printing process.

[0032] Contrairement au procédé de moulage par injection, le procédé selon l’invention permet de positionner avec précision la bande décorative au sein du matériau synthétique.Unlike the injection molding process, the process according to the invention makes it possible to precisely position the decorative strip within the synthetic material.

[0033] La nature de la bande décorative peut être choisie pour assurer une bonne adhésion de l’encre indépendamment de la formulation de base du bracelet.The nature of the decorative strip can be chosen to ensure good adhesion of the ink regardless of the basic formulation of the bracelet.

[0034] De plus, l’intégrité du bracelet est assurée par l’adhésion entre la bande supérieure et la bande inférieure sans devoir se soucier des propriétés d’adhérence entre la bande décorative et les bandes enrobantes. Ces caractéristiques permettent d’intégrer tout type de support au sein de la pièce d’habillage, y compris des textiles.In addition, the integrity of the bracelet is ensured by the adhesion between the upper strip and the lower strip without having to worry about the adhesion properties between the decorative strip and the wrapping strips. These characteristics make it possible to integrate any type of support within the dressing part, including textiles.

Légende [0035] (1) Substrat, aussi appelé bande décorative (2) Bande extérieure et bande intérieure (3) Extrudat (4) Imprimante (5) Bracelet (6) Trou (7) Passant (8) Boîtier (9) Structure tubulaire creuseLegend [1] (1) Substrate, also called decorative strip (2) Outer strip and inner strip (3) Extrudate (4) Printer (5) Bracelet (6) Hole (7) Loop (8) Housing (9) Tubular structure dig

CH 713 313 A2 (10) MontreCH 713 313 A2 (10) Watch

Claims (15)

Revendicationsclaims 1. Procédé de fabrication d’une pièce d’habillage pour montre ou bijou, notamment d’un bracelet (5), comportant les étapes de:1. Method for manufacturing a piece of clothing for a watch or jewelry, in particular a bracelet (5), comprising the steps of: - mise à disposition d’un substrat (1) comportant une première face opposée à une seconde face,- provision of a substrate (1) comprising a first face opposite to a second face, - revêtement par co-extrusion sur la première face et sur la seconde face dudit substrat (1) avec respectivement une première et une seconde bandes (2) en matériau synthétique; la première bande (2) formant sur la première face une couche transparente ou translucide permettant de maintenir en tout ou en partie le substrat (1) visible.- Co-extrusion coating on the first face and on the second face of said substrate (1) with respectively a first and a second strip (2) of synthetic material; the first strip (2) forming on the first face a transparent or translucent layer making it possible to keep all or part of the substrate (1) visible. 2. Procédé de fabrication selon la revendication 1, caractérisé en ce qu’il comporte, avant l’étape de revêtement par co-extrusion, une étape d’impression et/ou gravure d’un décor sur la première face du substrat (1).2. Manufacturing method according to claim 1, characterized in that it comprises, before the step of coating by co-extrusion, a step of printing and / or etching a decoration on the first face of the substrate (1 ). 3. Procédé selon la revendication 2, caractérisé en ce qu’une pluralité de décors distincts sont imprimés et/ou gravés l’un à la suite de l’autre sur la première face du substrat (1).3. Method according to claim 2, characterized in that a plurality of distinct decorations are printed and / or engraved one after the other on the first face of the substrate (1). 4. Procédé de fabrication selon la revendication 3, caractérisé en ce qu’il comporte avant impression une étape de mise à disposition de fichiers 2D ou 3D comprenant les données personnalisées relatives à l’impression ou au gravage de chaque décor.4. The manufacturing method according to claim 3, characterized in that it comprises before printing a step of making available 2D or 3D files comprising the personalized data relating to the printing or engraving of each decoration. 5. Procédé selon l’une quelconque des revendications précédentes, caractérisé en ce que le substrat (1) est formé d’une bande textile naturelle ou synthétique, d’une bande de papier photo, d’une bande métallique, d’une bande thermoplastique élastomère, d’une bande caoutchouc, ou d’une bande adhésive.5. Method according to any one of the preceding claims, characterized in that the substrate (1) is formed from a natural or synthetic textile strip, from a strip of photo paper, from a metallic strip, from a strip thermoplastic elastomer, a rubber band, or an adhesive band. 6. Procédé selon l’une quelconque des revendications précédentes, caractérisé en ce que le substrat (1) comprend un matériau choisi parmi la liste constituée du lin, du coton, du chanvre, de la laine, du cuir synthétique, du polyester, du polyamide, du polyuréthanne, de thermoplastique oléfine (TPE-O), de thermoplastique polyimide (TPI) de thermoplastique uréthane (TPU), styrénique (TPE-S) ou copolyester (TPE-E) ou polyamide copolyester (TPE-A), de caoutchouc, de polychlorure de vinyl, de PET.6. Method according to any one of the preceding claims, characterized in that the substrate (1) comprises a material chosen from the list consisting of linen, cotton, hemp, wool, synthetic leather, polyester, polyamide, polyurethane, olefin thermoplastic (TPE-O), polyimide thermoplastic (TPI) urethane thermoplastic (TPU), styrenic (TPE-S) or copolyester (TPE-E) or polyamide copolyester (TPE-A), rubber, polyvinyl chloride, PET. 7. Procédé selon la revendication 5, caractérisé en ce que la bande adhésive comprend des particules minérales, des particules organiques ou des particules métalliques.7. Method according to claim 5, characterized in that the adhesive strip comprises mineral particles, organic particles or metallic particles. 8. Procédé selon l’une quelconque des revendications 2 à 7, caractérisé en ce que l’impression permet d’intégrer dans le décor des pigments colorés, des composés luminescents, des composés thermochromes, des composés photochromes ou un mélange de ceux-ci.8. Method according to any one of claims 2 to 7, characterized in that the printing makes it possible to integrate into the decor colored pigments, luminescent compounds, thermochromic compounds, photochromic compounds or a mixture of these . 9. Procédé selon l’une quelconque des revendications précédentes, caractérisé en ce que le substrat (1) présente une largeur inférieure à celle des première et seconde bandes (2) afin d’être enrobé par ces dernières lors de l’étape de revêtement par co-extrusion.9. Method according to any one of the preceding claims, characterized in that the substrate (1) has a width less than that of the first and second strips (2) so as to be coated by the latter during the coating step by co-extrusion. 10. Procédé selon l’une quelconque des revendications précédentes, caractérisé en ce que la première bande et/ou la seconde bande (2) en matériau synthétique sont obtenues par co-extrusion de plusieurs mélanges de matériaux synthétiques se distinguant par leurs couleurs et/ou leurs indices de réfraction et/ou leurs propriétés mécaniques.10. Method according to any one of the preceding claims, characterized in that the first strip and / or the second strip (2) made of synthetic material are obtained by co-extrusion of several mixtures of synthetic materials distinguished by their colors and / or their refractive indices and / or their mechanical properties. 11. Procédé selon l’une quelconque des revendications précédentes, caractérisé en ce que les matériaux synthétiques de la première et de la seconde bandes (2) sont choisis parmi les thermoplastiques élastomères, les silicones, les caoutchoucs et les élastomères fluorés.11. Method according to any one of the preceding claims, characterized in that the synthetic materials of the first and of the second strips (2) are chosen from thermoplastic elastomers, silicones, rubbers and fluorinated elastomers. 12. Procédé selon l’une quelconque des revendications précédentes, caractérisé en ce que le matériau synthétique de la seconde bande (2) comporte une charge améliorant le confort de la pièce d’habillage.12. Method according to any one of the preceding claims, characterized in that the synthetic material of the second strip (2) comprises a filler improving the comfort of the covering piece. 13. Procédé selon l’une quelconque des revendications précédentes, caractérisé en ce que l’extrudat (3) issu du revêtement par co-extrusion a une largeur correspondant à la largeur du bracelet (5) ou à la longueur d’un ou deux brins du bracelet (5).13. Method according to any one of the preceding claims, characterized in that the extrudate (3) coming from the coating by co-extrusion has a width corresponding to the width of the bracelet (5) or to the length of one or two bracelet strands (5). 14. Pièce d’habillage pour l’horlogerie ou la bijouterie, en particulier bracelet (5), comportant un substrat (1) plan enrobé sur tout le pourtour de sa section transversale par un ou plusieurs matériaux synthétiques, le ou les matériaux synthétiques formant au moins partiellement un revêtement transparent ou translucide.14. Dressing piece for watchmaking or jewelry, in particular bracelet (5), comprising a flat substrate (1) coated around the entire periphery of its cross section with one or more synthetic materials, the synthetic material or materials forming at least partially a transparent or translucent coating. 15. Pièce d’habillage selon la revendication 14, caractérisée en ce que le substrat (1) comporte sur une face en regard du revêtement transparent ou translucide un décor imprimé ou gravé.15. Dressing piece according to claim 14, characterized in that the substrate (1) comprises on a face opposite the transparent or translucent coating a printed or engraved decoration. CH 713 313 A2CH 713 313 A2 CH 713 313 A2CH 713 313 A2
CH01666/16A 2016-12-16 2016-12-16 Dressing room with decor for a watch or jewel and its manufacturing process. CH713313A2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111978601A (en) * 2019-05-23 2020-11-24 斯沃奇集团研究及开发有限公司 Jewellery made of natural elastomer material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111978601A (en) * 2019-05-23 2020-11-24 斯沃奇集团研究及开发有限公司 Jewellery made of natural elastomer material
US11672313B2 (en) 2019-05-23 2023-06-13 The Swatch Group Research And Development Ltd Piece of jewellery made of natural elastomer material

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