CH672729A5 - - Google Patents
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- Publication number
- CH672729A5 CH672729A5 CH630/87A CH63087A CH672729A5 CH 672729 A5 CH672729 A5 CH 672729A5 CH 630/87 A CH630/87 A CH 630/87A CH 63087 A CH63087 A CH 63087A CH 672729 A5 CH672729 A5 CH 672729A5
- Authority
- CH
- Switzerland
- Prior art keywords
- dihydroxyindole
- composition containing
- dyeing
- anion
- formula
- Prior art date
Links
- 239000000203 mixture Substances 0.000 claims description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 25
- 238000004043 dyeing Methods 0.000 claims description 23
- 150000001450 anions Chemical class 0.000 claims description 22
- SGNZYJXNUURYCH-UHFFFAOYSA-N 5,6-dihydroxyindole Chemical compound C1=C(O)C(O)=CC2=C1NC=C2 SGNZYJXNUURYCH-UHFFFAOYSA-N 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 21
- 239000000975 dye Substances 0.000 claims description 16
- 239000000835 fiber Substances 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 102000011782 Keratins Human genes 0.000 claims description 12
- 108010076876 Keratins Proteins 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- 239000002609 medium Substances 0.000 claims description 11
- 239000012286 potassium permanganate Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 6
- 239000002671 adjuvant Substances 0.000 claims description 5
- 239000012736 aqueous medium Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- HMTUVSJLXALWIU-UHFFFAOYSA-N 2,3-dimethyl-1h-indole-5,6-diol Chemical compound OC1=C(O)C=C2C(C)=C(C)NC2=C1 HMTUVSJLXALWIU-UHFFFAOYSA-N 0.000 claims description 3
- QGJCWKNNWOVPTJ-UHFFFAOYSA-N 2-methyl-1h-indole-5,6-diol Chemical compound OC1=C(O)C=C2NC(C)=CC2=C1 QGJCWKNNWOVPTJ-UHFFFAOYSA-N 0.000 claims description 3
- ZUTZCXDHPIACCR-UHFFFAOYSA-N 3-methyl-1h-indole-5,6-diol Chemical compound OC1=C(O)C=C2C(C)=CNC2=C1 ZUTZCXDHPIACCR-UHFFFAOYSA-N 0.000 claims description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical class COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 claims description 2
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 claims description 2
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 239000000872 buffer Substances 0.000 claims description 2
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 claims description 2
- 150000002193 fatty amides Chemical class 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 229940057867 methyl lactate Drugs 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 claims description 2
- 239000003352 sequestering agent Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000004604 Blowing Agent Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 235000011149 sulphuric acid Nutrition 0.000 description 6
- 238000011282 treatment Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 4
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 4
- 239000011550 stock solution Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 239000010413 mother solution Substances 0.000 description 3
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000002610 basifying agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000557626 Corvus corax Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920013806 TRITON CG-110 Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000002535 acidifier Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000003113 alkalizing effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000003061 melanogenesis Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- KIEOKOFEPABQKJ-UHFFFAOYSA-N sodium dichromate Chemical compound [Na+].[Na+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KIEOKOFEPABQKJ-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/08—Material containing basic nitrogen containing amide groups using oxidation dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
- A61K8/492—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid having condensed rings, e.g. indol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- Cosmetics (AREA)
- Coloring (AREA)
Description
DESCRIPTION DESCRIPTION
La teinture des fibres kératiniques humaines, et en particulier des cheveux humains, à l'aide du 5,6-dihydroxyindole, est bien connue et a fait l'objet de différents brevets français de la titulaire Nos 1133 594, 1 166172, 2390 158 et de la demande de brevet français 2536993. The dyeing of human keratin fibers, and in particular human hair, using 5,6-dihydroxyindole, is well known and has been the subject of various French patents of the holder Nos 1133 594, 1 166 172, 2390 158 and French patent application 2536993.
Parmi les procédés de teinture des cheveux décrits dans ces différents documents, il a été mentionné la possibilité d'utiliser, à titre de catalyseur d'oxydation, différents sels de métaux tels que les sels de manganèse, de cobalt, de fer, de cuivre, d'argent. La dernière demande de brevet préconise l'utilisation d'ions cupriques en solution alcaline, mais également d'ions de métaux tels que ceux de fer, cobalt, manganèse, argent, titane, zirconium, tantale, chrome, Among the hair dyeing processes described in these various documents, it has been mentioned the possibility of using, as oxidation catalyst, different metal salts such as manganese, cobalt, iron, copper salts , silver. The latest patent application recommends the use of cupric ions in alkaline solution, but also of metal ions such as those of iron, cobalt, manganese, silver, titanium, zirconium, tantalum, chromium,
nickel, palladium, platine, or, mercure, cadmium, zinc, étain, antimoine, plomb et bismuth. nickel, palladium, platinum, gold, mercury, cadmium, zinc, tin, antimony, lead and bismuth.
Ces différents procédés mettent en œuvre des cations métalliques utilisés comme «promoteurs de mélanogenèse» ou «catalyseurs d'oxydation». These different processes use metal cations used as "melanogenesis promoters" or "oxidation catalysts".
On a par ailleurs déjà préconisé l'utilisation, en teinture des cheveux, du permanganate de potassium ou du bichromate de sodium, mais dans des conditions telles que ces dérivés ne pouvaient réagir au niveau des cheveux que sous leur forme réduite, c'est-à-dire de cations métalliques. The use of potassium permanganate or sodium dichromate has already been recommended in hair dyeing, but under conditions such that these derivatives could only react in the hair in their reduced form, ie ie metal cations.
La titulaire a découvert, ce qui fait l'objet de l'invention, qu'il était possible d'améliorer de façon importante la puissance tinctoriale du 5,6-dihydroxyindole ou de certains de ses dérivés en prétraitant les fibres kératiniques avec un anion métallique ayant une bonne affinité pour la kératine et ayant un potentiel d'oxydoréduc-tion supérieur à celui du 5,6-dihydroxyindole ou de ses dérivés. The licensee discovered, which is the subject of the invention, that it was possible to significantly improve the dyeing power of 5,6-dihydroxyindole or certain of its derivatives by pretreating the keratin fibers with an anion metal having a good affinity for keratin and having a redox potential greater than that of 5,6-dihydroxyindole or its derivatives.
Les avantages de ce prétraitement se manifestent en particulier lors de traitements de coloration répétés ou pour la teinture de fibres kératiniques comme les cheveux tels que les cheveux «non naturels», c'est-à-dire déjà sensibilisés par un traitement cosmétique tel que la décoloration ou la permanente. The advantages of this pretreatment are manifested in particular during repeated dyeing treatments or for the dyeing of keratin fibers such as the hair such as "unnatural" hair, that is to say already sensitized by a cosmetic treatment such as the discoloration or perm.
Sans que cette explication soit limitative, la titulaire pense que l'anion, une fois fixé sur la fibre, agit comme oxydant vis-à-vis du 5,6-dihydroxyindole ou de ses dérivés. Without this explanation being limiting, the licensee believes that the anion, once fixed on the fiber, acts as an oxidant vis-à-vis 5,6-dihydroxyindole or its derivatives.
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L'invention a donc pour objet un procédé de teinture des fibres kératiniques, en particulier des cheveux humains, mettant en œuvre un prétraitement avec un anion métallique ayant une bonne affinité pour la kératine, ce prétraitement étant suivi de l'application du 5,6-dihydroxyindole ou de certains de ses dérivés. The subject of the invention is therefore a process for dyeing keratin fibers, in particular human hair, using a pretreatment with a metal anion having a good affinity for keratin, this pretreatment being followed by the application of 5.6 -dihydroxyindole or some of its derivatives.
Un autre objet de l'invention est constitué par un dispositif à plusieurs compartiments, ou kit de teinture, permettant la mise en œuvre du procédé conforme à l'invention. Another object of the invention is constituted by a device with several compartments, or dyeing kit, allowing the implementation of the method according to the invention.
D'autres objets de l'invention apparaîtront à la lecture de la description et des exemples qui suivent. Other objects of the invention will appear on reading the description and the examples which follow.
Le procédé de teinture des fibres kératiniques, et en particulier des cheveux humains, conforme à l'invention est essentiellement caractérisé par le fait que l'on applique successivement: The process for dyeing keratin fibers, and in particular human hair, in accordance with the invention is essentially characterized by the fact that successively:
a) une composition contenant, dans un milieu approprié pour la teinture, à un pH compris entre 2 et 10, un anion d'un métal présentant une affinité pour la kératine et ayant un potentiel d'oxydoré-duction supérieur à celui du 5,6-dihydroxyindole ou de ses dérivés de formule I: a) a composition containing, in a medium suitable for dyeing, at a pH between 2 and 10, an anion of a metal having an affinity for keratin and having an oxidoreduction potential greater than that of 5, 6-dihydroxyindole or its derivatives of formula I:
dans laquelle R, et R2, indépendamment l'un de l'autre, désignent hydrogène, méthyle ou éthyle, in which R, and R2, independently of one another, denote hydrogen, methyl or ethyl,
b) une composition contenant, dans un milieu approprié pour la teinture, à un pH compris entre 7 et 10, un colorant de formule I. b) a composition containing, in a medium suitable for dyeing, at a pH of between 7 and 10, a dye of formula I.
Par exemple, le potentiel d'oxydoréduction, extrapolé à pH 0, du 5,6-dihydroxyindole étant de +0,25 volt/H2, les anions mis en œuvre conformément à l'invention devront donc avoir un potentiel d'oxydoréduction supérieur, dans ces conditions, à celui du colorant. For example, the redox potential, extrapolated to pH 0, of the 5,6-dihydroxyindole being +0.25 volt / H2, the anions used in accordance with the invention must therefore have a higher redox potential, under these conditions, to that of the dye.
Le procédé est appliqué de préférence à la teinture des cheveux et en particulier des cheveux humains vivants. Le milieu approprié à la teinture est dans ce cas cosmétiquement acceptable. The method is preferably applied to dyeing hair and in particular living human hair. The medium suitable for the dye is in this case cosmetically acceptable.
Les colorants préférés de formule I sont le 5,6-dihydroxyindole, le 2-méthyl 5,6-dihydroxyindole, le 3-méthyl 5,6-dihydroxyindole et le 2,3-diméthyl 5,6-dihydroxyindole. The preferred dyes of formula I are 5,6-dihydroxyindole, 2-methyl 5,6-dihydroxyindole, 3-methyl 5,6-dihydroxyindole and 2,3-dimethyl 5,6-dihydroxyindole.
Les anions particulièrement préférés sont constitués par les anions permanganate (MnO^T) et bichromate (Cr2072~) et dérivant plus particulièrement du permanganate de potassium et du bichromate de sodium. The particularly preferred anions consist of the permanganate (MnO 4 T) and bichromate (Cr 2 072 ~) anions and deriving more particularly from potassium permanganate and sodium bichromate.
La composition contenant les anions métalliques a de préférence une molalité en anions supérieure à 10~3 mole/1000 g, et de préférence située entre 10~2 mole/1000 g et 10-' mole/1000 g. Cela correspond, pour Mn04", à une concentration supérieure à 0,012 g % et comprise de préférence entre 0,12 et 1,18 g% et, pour Cr2072-, à une concentration supérieure à 0,022 g % et comprise de préférence entre 0,22 et 2,16 g%. The composition containing the metal anions preferably has an anion molality greater than 10 ~ 3 mole / 1000 g, and preferably situated between 10 ~ 2 mole / 1000 g and 10- 'mole / 1000 g. This corresponds, for Mn04 ", to a concentration greater than 0.012 g% and preferably comprised between 0.12 and 1.18 g% and, for Cr2072-, to a concentration greater than 0.022 g% and preferably comprised between 0, 22 and 2.16 g%.
Le pH de la composition contenant l'anion est ajusté avec des agents acidifiants ou alcalinisants n'ayant aucun effet réducteur sur les anions. The pH of the composition containing the anion is adjusted with acidifying or basifying agents having no reducing effect on the anions.
Dans une forme de réalisation particulièrement préférée, la composition utilisée pour le prétraitement est acide et a un pH de préférence compris entre 2 et 5 et en particulier voisin de 3. Un acide inorganique utilisable peut être par exemple l'acide sulfurique. In a particularly preferred embodiment, the composition used for the pretreatment is acidic and has a pH preferably between 2 and 5 and in particular close to 3. An inorganic acid which can be used can for example be sulfuric acid.
La composition de prétraitement peut également contenir d'autres adjuvants inorganiques. A titre d'exemple, on peut citer les silices ou les argiles, permettant en particulier d'épaissir ou de gonfler cette composition. Elle ne contient pas d'ajuvants susceptibles de réduire l'anion. The pretreatment composition may also contain other inorganic adjuvants. By way of example, mention may be made of silicas or clays, making it possible in particular to thicken or swell this composition. It does not contain adjuvants that can reduce the anion.
Cette composition a de préférence une viscosité suffisante pour une application sur la tête. This composition preferably has a viscosity sufficient for application to the head.
La composition contenant le 5,6-dihydroxyindole oirun dérivé de formule I est ajustée de préférence à un pH compris entre 7 et 10 à l'aide d'un agent alcalinisant, inorganique ou organique, connu en lui-même. A cet effet, on peut citer comme agents alcalinisants l'ammoniaque ou des aminés telles que la monoéthanolamine, la diétha-nolamine, la triéthanolamine, la morpholine, la diéthylamine, l'hy-droxylamine. The composition containing 5,6-dihydroxyindole or a derivative of formula I is preferably adjusted to a pH of between 7 and 10 using an alkalizing agent, inorganic or organic, known in itself. For this purpose, there may be mentioned as basifying agents ammonia or amines such as monoethanolamine, diethanolamine, triethanolamine, morpholine, diethylamine, hy-droxylamine.
La concentration en 5,6-dihydroxyindole ou de ses dérivés, de formule I, peut varier entre 0,5 et 2% en poids, et de préférence entre 1 et 1,5% en poids par rapport au poids total de la composition mise en œuvre dans le deuxième temps du procédé. The concentration of 5,6-dihydroxyindole or its derivatives, of formula I, can vary between 0.5 and 2% by weight, and preferably between 1 and 1.5% by weight relative to the total weight of the composition used. implemented in the second stage of the process.
Cette composition peut contenir, en plus de l'eau, différents solvants parmi lesquels on peut citer les alcanols inférieurs en Cx-C4 comme l'éthanol, l'isopropanol, le propanol, l'alcool tertiobutylique, l'éthylèneglycol, les éthers monométhylique, monoéthylique ou mo-nobutylique de l'éthylèneglycol et l'acétate de monoéthyléther de l'éthylèneglycol, le propylèneglycol, les monométhyléthers du propy-lèneglycol ou du dipropylèneglycol et le lactate de méthyle. Les solvants sont utilisés dans des proportions comprises de préférence entre 1 et 30% en poids, et plus particulièrement entre 3 et 20%. This composition can contain, in addition to water, various solvents among which mention may be made of lower Cx-C4 alkanols such as ethanol, isopropanol, propanol, tert-butyl alcohol, ethylene glycol, monomethyl ethers , monoethyl or monobutyl of ethylene glycol and ethylene glycol monoethyl ether acetate, propylene glycol, monomethyl ethers of propylene glycol or dipropylene glycol and methyl lactate. The solvents are used in proportions preferably between 1 and 30% by weight, and more particularly between 3 and 20%.
Cette composition peut contenir également d'autres adjuvants tels que des agents tensioactifs, des électrolytes, des agents antioxydants, des tampons, des parfums, des amides gras, des agents de gonflement de la fibre kératinique tels que l'urée, des séquestrants, des agents filmogènes, des conservateurs, etc. Ces compositions peuvent également être épaissies, notamment avec des agents choisis parmi l'alginate de sodium, la gomme arabique, la gomme de guar, des biopolymères tels que la gomme de xanthanne ou les scléroglu-canes, les dérivés de la cellulose tels que la méthylcellulose, l'hy-droxyéthylcellulose, l'hydroxypropylméthylcellulose, la carboxymé-thylcellulose et des polymères divers ayant des fonctions épaississantes tels que des dérivés d'acide acrylique. Ces compositions peuvent également être épaissies avec des agents épaississants minéraux tels que la bentonite. Les agents épaississants sont présents de préférence dans des proportions comprises entre 0,1 et 5% en poids, et en particulier comprises entre 0,5 et 3% en poids par rapport au poids total de la composition. This composition can also contain other adjuvants such as surfactants, electrolytes, antioxidants, buffers, perfumes, fatty amides, keratinous fiber swelling agents such as urea, sequestrants, film-forming agents, preservatives, etc. These compositions can also be thickened, in particular with agents chosen from sodium alginate, gum arabic, guar gum, biopolymers such as xanthan gum or scleroglu-canes, cellulose derivatives such as methylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose and various polymers having thickening functions such as derivatives of acrylic acid. These compositions can also be thickened with mineral thickening agents such as bentonite. The thickening agents are preferably present in proportions of between 0.1 and 5% by weight, and in particular of between 0.5 and 3% by weight relative to the total weight of the composition.
Une forme de réalisation de l'invention peut également consister à stocker le colorant en milieu anhydre comme décrit dans le brevet français N° 2 390 158 de la titulaire et à mélanger, juste avant l'emploi, cette composition avec un milieu aqueux approprié pour la teinture. Le milieu anhydre peut être constitué par les solvants définis ci-dessus contenant moins de 1 % d'eau. An embodiment of the invention may also consist in storing the dye in an anhydrous medium as described in French patent No. 2,390,158 of the holder and in mixing, just before use, this composition with an aqueous medium suitable for the dye. The anhydrous medium can consist of the solvents defined above containing less than 1% of water.
Le procédé conforme à l'invention consiste essentiellement à appliquer, dans un premier temps et pendant une durée de 3 à 30 minutes, de préférence de 5 à 20 minutes, la composition contenant l'anion définie ci-dessus, à la température ambiante de l'ordre de 25 à 35° C. Il est possible éventuellement d'accélérer le traitement par un léger chauffage jusqu'à environ 40° C. The process according to the invention consists essentially in applying, firstly and for a period of 3 to 30 minutes, preferably from 5 to 20 minutes, the composition containing the anion defined above, at room temperature of around 25 to 35 ° C. It is possible, if necessary, to accelerate the treatment by a slight heating to about 40 ° C.
Les fibres sont rincées. On applique après ce traitement la composition tinctoriale pendant une durée de 2 à 10 minutes, on rince à l'eau et on effectue éventuellement un shampooing et un nouveau rinçage. The fibers are rinsed. After this treatment, the dye composition is applied for a period of 2 to 10 minutes, rinsing with water and optionally shampooing and rinsing again.
Ce procédé peut être utilisé pour teindre les cheveux naturels ou déjà teints, permanentés ou non, ou défrisés, ou des cheveux fortement ou légèrement décolorés et éventuellement permanentés. This process can be used to dye natural or already dyed hair, permed or not, or straightened, or strongly or slightly discolored and possibly permed hair.
Il est également possible de le mettre en œuvre pour teindre des fourrures. It is also possible to use it to dye furs.
Un autre objet de l'invention est constitué par un dispositif à plusieurs compartiments, ou kit, de teinture, comportant dans une présentation unique une pluralité de conteneurs dont l'un contient la composition colorante, l'autre l'anion, et éventuellement un troisième contenant le milieu aqueux lorsque le colorant est conservé sous forme anhydre. Another object of the invention is constituted by a device with several compartments, or kit, for dyeing, comprising in a single presentation a plurality of containers, one of which contains the coloring composition, the other the anion, and optionally a third containing the aqueous medium when the dye is stored in anhydrous form.
La composition de prétraitement peut être conditionnée en deux parties, l'une renfermant l'anion sous forme de solution aqueuse, l'autre renfermant une solution aqueuse épaissie. Il est bien entendu que ces différents compartiments sont destinés à être mélangés juste avant l'emploi. The pretreatment composition can be packaged in two parts, one containing the anion in the form of an aqueous solution, the other containing a thickened aqueous solution. It is understood that these different compartments are intended to be mixed just before use.
Lorsque le procédé de coloration conforme à l'invention s'applique à la'teinture des cheveux, il peut éventuellement encore être When the dyeing process according to the invention applies to hair dyeing, it can optionally still be
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précédé ou suivi d'autres traitements cosmétiques connus en eux-mêmes. preceded or followed by other cosmetic treatments known in themselves.
Les exemples suivants sont destinés à illustrer l'invention sans pour autant présenter un caractère limitatif. The following examples are intended to illustrate the invention without, however, being limiting in nature.
Exemple 1 Example 1
Une solution mère de permanganate de potassium stable est préparée en dissolvant 1,58 g de KMn04 dans 100 ml d'eau (volume final) ajustée à pH 3 avec H2S04. Cette solution est maintenue dans un flacon à l'abri de la lumière. A stock solution of stable potassium permanganate is prepared by dissolving 1.58 g of KMnO4 in 100 ml of water (final volume) adjusted to pH 3 with H2SO4. This solution is kept in a bottle protected from light.
A un gel préparé en malaxant 7 g de silice, Aerosil 200 (Degussa), avec 85 g d'eau amenée à pH 3 avec H2S04, on incorpore intimement, sous agitation, 9 g de la solution mère de permanganate de potassium. Into a gel prepared by mixing 7 g of silica, Aerosil 200 (Degussa), with 85 g of water brought to pH 3 with H2SO4, 9 g of the mother solution of potassium permanganate are intimately incorporated, with stirring.
Le cheveu est recouvert du gel ainsi préparé à l'aide d'une spatule ou d'un pinceau. The hair is covered with the gel thus prepared using a spatula or a brush.
La pose dure 10 minutes. The pose lasts 10 minutes.
Le cheveu est rincé à l'eau pour éliminer le gel. The hair is rinsed with water to remove the gel.
On prépare avant l'emploi une solution épaissie contenant: Before use, a thickened solution containing:
— NH4C1 5,0 g - NH4C1 5.0 g
— Cellosize WP03H 5,0 g - Cellosize WP03H 5.0 g
— NH4OH q.s. pH 9,0 - NH4OH q.s. pH 9.0
— Eau q.s. 80 g - Water q.s. 80g
On incorpore, juste avant l'emploi et très rapidement, 1 g de 5,6-dihydroxyindole préalablement solubilisé dans 20 g d'éthanol anhydre. 1 g of 5,6-dihydroxyindole, dissolved beforehand in 20 g of anhydrous ethanol, is incorporated just before use and very quickly.
Le cheveu prétraité est recouvert de cette solution. The pretreated hair is covered with this solution.
La pose dure 5 minutes. The pose lasts 5 minutes.
Le cheveu est abondamment rincé à l'eau. Un shampooing au laurylsulfate de sodium est appliqué sur la tête. The hair is abundantly rinsed with water. A sodium lauryl sulfate shampoo is applied to the head.
Le cheveu initialement gris, à 90% blanc, est devenu noir. The initially gray hair, 90% white, has become black.
Exemple 2 Example 2
Le prétraitement est identique à celui de l'exemple 1. The pretreatment is identical to that of Example 1.
On prépare, avant l'emploi, une solution épaissie contenant: Before use, a thickened solution is prepared containing:
— Hydrogénophosphate de dipotassium 5,6 g - Dipotassium hydrogen phosphate 5.6 g
— Dihydrogénophosphate de potassium 2,2 g - Potassium dihydrogen phosphate 2.2 g
— Cellosize WP03H 5,0 g - Cellosize WP03H 5.0 g
— HCl ou NaOH q.s. pH 7,0 - HCl or NaOH q.s. pH 7.0
— Eau q.s. 80 g - Water q.s. 80g
On incorpore, juste avant l'emploi et très rapidement, 1 g de 5,6-dihydroxyindole préalablement solubilisé dans 20 g d'éthanol anhydre. 1 g of 5,6-dihydroxyindole, dissolved beforehand in 20 g of anhydrous ethanol, is incorporated just before use and very quickly.
Le cheveu prétraité et rincé est recouvert de cette solution. La pose dure 5 minutes. The pretreated and rinsed hair is covered with this solution. The pose lasts 5 minutes.
Le cheveu est abondamment rincé à l'eau. Un shampooing au laurylsulfate de sodium est appliqué sur la tête. The hair is abundantly rinsed with water. A sodium lauryl sulfate shampoo is applied to the head.
Le cheveu initialement gris, à 90% blanc, a pris une teinte grise très intense. The initially gray hair, 90% white, has taken on a very intense gray hue.
Exemple 3 Example 3
La solution mère de permanganate de potassium est celle décrite à l'exemple 1. The mother solution of potassium permanganate is that described in Example 1.
On prépare un gel en malaxant 7 g de silice, Aerosil 200 (Degussa), avec 76 g d'eau amenée à pH 3 avec H2S04; on incorpore intimement sous agitation 18 g de la solution mère de permanganate de potassium. A gel is prepared by kneading 7 g of silica, Aerosil 200 (Degussa), with 76 g of water brought to pH 3 with H2SO4; 18 g of the potassium permanganate stock solution are incorporated intimately with stirring.
Le cheveu est recouvert du gel et la pose dure 5 minutes. Le cheveu est rincé à l'eau. The hair is covered with gel and the installation lasts 5 minutes. The hair is rinsed with water.
On utilise pour teindre ce cheveu la même composition tinctoriale et le même procédé que ceux décrits à l'exemple 1. The same dye composition and the same process as those described in Example 1 are used to dye this hair.
Le cheveu initialement gris, à 90% blanc, est devenu noir. The initially gray hair, 90% white, has become black.
Exemple 4 Example 4
La solution mère de permanganate de potassium est celle décrite à l'exemple 1. The mother solution of potassium permanganate is that described in Example 1.
On prépare une solution épaissie en mélangeant 15 g d'argile Gel White H/USP à 70 g d'eau. On ajuste le pH à 3 avec un minimum d'acide sulfurique. On incorpore alors 11,5 g de solution mère de permanganate de potassium. A thickened solution is prepared by mixing 15 g of Gel White H / USP clay with 70 g of water. The pH is adjusted to 3 with a minimum of sulfuric acid. 11.5 g of potassium permanganate stock solution are then incorporated.
Le poids final est ajusté à 100 g avec un peu d'eau à pH 3 (H2S04). The final weight is adjusted to 100 g with a little water at pH 3 (H2SO4).
Le cheveu est recouvert de cette solution épaissie. The hair is covered with this thickened solution.
La pose dure 5 minutes. The pose lasts 5 minutes.
Le cheveu est rincé à l'eau. The hair is rinsed with water.
On prépare, avant l'emploi, une solution épaissie contenant: Before use, a thickened solution is prepared containing:
— NH4C1 5,0 g - NH4C1 5.0 g
— Carbopol 940 0,7 g - Carbopol 940 0.7 g
— NH4OH q.s. pH 9,0 - NH4OH q.s. pH 9.0
— Eau q.s. 80 g - Water q.s. 80g
On incorpore, juste avant l'emploi et très rapidement, 1,2 g de 5,6-dihydroxyindole préalablement solubilisé dans 20 g d'éthanol. 1.2 g of 5,6-dihydroxyindole, previously dissolved in 20 g of ethanol, are incorporated just before use and very quickly.
Le cheveu prétraité est recouvert de cette solution. The pretreated hair is covered with this solution.
La pose dure 5 minutes. The pose lasts 5 minutes.
Le cheveu est abondamment rincé à l'eau. Un shampooing au laurylsulfate de sodium est appliqué sur la tête. The hair is abundantly rinsed with water. A sodium lauryl sulfate shampoo is applied to the head.
Le cheveu initialement gris, à 90% blanc, est devenu noir. The initially gray hair, 90% white, has become black.
Exemple 5 Example 5
Une solution de bichromate de potassium est préparée en dissolvant 2,94 g de K2Cr207 dans 100 ml d'eau (volume final), ajustée à pH 3 avec H2S04. Cette solution est maintenue dans un flacon à l'abri de la lumière. A solution of potassium dichromate is prepared by dissolving 2.94 g of K2Cr207 in 100 ml of water (final volume), adjusted to pH 3 with H2SO4. This solution is kept in a bottle protected from light.
Une solution épaissie est préparée en mélangeant 15 g d'argile Gel White H/USP à 50 g d'eau. On ajuste le pH à 3 avec de l'acide sulfurique. On incorpore alors 30 g de solution mère de bichromate de potassium. A thickened solution is prepared by mixing 15 g of Gel White H / USP clay with 50 g of water. The pH is adjusted to 3 with sulfuric acid. 30 g of potassium dichromate stock solution are then incorporated.
Le poids final est ajusté à 100 g avec un peu d'eau à pH 3 par H2S04. The final weight is adjusted to 100 g with a little water at pH 3 with H2SO4.
Le cheveu est recouvert de cette solution épaissie. The hair is covered with this thickened solution.
La pose dure 10 minutes. The pose lasts 10 minutes.
Le cheveu est rincé à l'eau. The hair is rinsed with water.
On prépare avant l'emploi une solution épaissie de 5,6-dihydroxyindole, comme dans l'exemple 4. A thickened solution of 5,6-dihydroxyindole is prepared before use, as in Example 4.
Le cheveu prétraité est recouvert de cette solution. The pretreated hair is covered with this solution.
La pose dure 5 minutes. The pose lasts 5 minutes.
Le cheveu est abondamment rincé à l'eau. Un shampooing au laurylsulfate de sodium est appliqué. The hair is abundantly rinsed with water. A sodium lauryl sulfate shampoo is applied.
Le cheveu initialement gris, à 90% blanc, est devenu noir. The initially gray hair, 90% white, has become black.
Exemple 6 Example 6
On prépare un gel de permanganate comme décrit à l'exemple 1. A permanganate gel is prepared as described in Example 1.
On traite une mèche de cheveux décolorés par le gel susmentionné, pendant 10 minutes à température ambiante, puis les cheveux sont rincés à l'eau pour éliminer le gel. A lock of bleached hair is treated with the above-mentioned gel for 10 minutes at room temperature, then the hair is rinsed with water to remove the gel.
On incorpore, juste avant l'emploi, 1,2 g de 5,6-dihydroxyindole dans une solution épaissie contenant: 1.2 g of 5,6-dihydroxyindole are incorporated, just before use, in a thickened solution containing:
— Alkyléther de glycoside (Triton CG 110) 5,0 g - Glycoside alkyl ether (Triton CG 110) 5.0 g
— Gomme de guar (Jaguar HP 60) 1,0 g - Guar gum (Jaguar HP 60) 1.0 g
— Chlorure d'ammonium 5,0 g - Ammonium chloride 5.0 g
— Ammoniaque q.s.p. pH 9 - Ammonia q.s.p. pH 9
— Eau q.s.p. 80 g - Water q.s.p. 80g
On applique cette solution épaissie pendant 10 minutes sur cette mèche, on rince à l'eau, on lave et l'on sèche. Les cheveux sont teints en noir corbeau. This thickened solution is applied to this lock for 10 minutes, rinsed with water, washed and dried. The hair is dyed in raven black.
Exemple 7 Example 7
On prépare les mêmes solutions que dans l'exemple 6, mais en remplaçant le 5,6-dihydroxyindole: The same solutions are prepared as in Example 6, but by replacing the 5,6-dihydroxyindole:
— soit par 1,3 g de 2-méthyl 5,6-dihydroxyindole, - either with 1.3 g of 2-methyl 5,6-dihydroxyindole,
— soit par 1,4 g de 2,3-diméthyl 5,6-dihydroxyindole, - either with 1.4 g of 2,3-dimethyl 5,6-dihydroxyindole,
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— soit par 1,2 g de 3-méthyl 5,6-dihydroxyindole, - either with 1.2 g of 3-methyl 5,6-dihydroxyindole,
et en remplaçant également la mèche de cheveux décolorés par une mèche de cheveux gris naturels à 90% blancs. and also replacing the lock of bleached hair with a lock of 90% natural gray hair.
On obtient respectivement les colorations suivantes : The following colors are obtained respectively:
— gris-marron foncé, - dark gray-brown,
— gris-vert foncé, - dark gray-green,
— gris-bleu foncé. - dark gray-blue.
Exemple 8 Example 8
On reprend l'exemple 1 et on remplace les cheveux naturels par 5 des cheveux permanentés et l'on obtient une coloration noire intense. Example 1 is repeated and the natural hair is replaced by 5 permed hair and an intense black coloring is obtained.
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Claims (16)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU86314A LU86314A1 (en) | 1986-02-20 | 1986-02-20 | PROCESS FOR DYEING HUMAN KERATINIC FIBERS WITH 5,6-DIHYDROXYINDOLE AND A METAL ANION |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH672729A5 true CH672729A5 (en) | 1989-12-29 |
Family
ID=19730641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH630/87A CH672729A5 (en) | 1986-02-20 | 1987-02-19 |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS62246510A (en) |
| BE (1) | BE1000115A3 (en) |
| CA (1) | CA1298042C (en) |
| CH (1) | CH672729A5 (en) |
| DE (1) | DE3705453A1 (en) |
| ES (1) | ES2003225A6 (en) |
| FR (1) | FR2594331B1 (en) |
| GB (1) | GB2187210B (en) |
| IT (1) | IT1207356B (en) |
| LU (1) | LU86314A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH679150A5 (en) * | 1986-11-07 | 1991-12-31 | Oreal | |
| LU87097A1 (en) * | 1987-12-30 | 1989-07-07 | Oreal | KERATINIC FIBER DYEING PROCESS AND DYEING COMPOSITION USING 5,6-DIHYDROXYINDOLE, NITER DIRECT DYE AND IODIDE |
| LU87113A1 (en) * | 1988-01-26 | 1989-08-30 | Oreal | KERATINIC FIBER DYEING PROCESS AND DYEING COMPOSITION USING 5,6-DIHYDROXYINDOLE, A QUINONIC AND IODIDE DYE |
| LU87338A1 (en) * | 1988-09-12 | 1990-04-06 | Oreal | USE OF INDOLE DERIVATIVES FOR DYEING KERATINIC MATERIALS, DYE COMPOSITIONS, NOVEL COMPOUNDS AND DYEING METHOD |
| DE4323123A1 (en) * | 1993-07-10 | 1995-01-12 | Hoechst Ag | Process for dyeing fur skins with oxidation dyes |
| FR2757386B1 (en) * | 1996-12-23 | 1999-01-29 | Oreal | TWO-STAGE OXIDATION DYEING PROCESS FOR KERATINIC FIBERS WITH MANGANESE SALT OR COMPLEX AND A 4-SUBSTITUTED 1-NAPHTOL AND DYEING KIT |
| DE19713510A1 (en) * | 1997-04-01 | 1998-10-08 | Henkel Kgaa | Hair dye |
| DE102006031502A1 (en) * | 2006-07-06 | 2008-01-17 | Henkel Kgaa | Oxidation colorant for coloring keratin-containing fibers with atmospheric oxygen as the sole oxidant |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2101696A (en) * | 1934-12-15 | 1937-12-07 | Gen Aniline Works Inc | Process for producing two-color effects on skins or furs |
| DE694310C (en) * | 1937-08-15 | 1940-07-29 | I G Farbenindustrie Akt Ges | Process for the production of oxidation stains as stain |
| FR860591A (en) * | 1939-08-09 | 1941-01-18 | Improvements in hair, hair and textile dyeing processes | |
| NL107681C (en) * | 1957-02-02 | |||
| FR2390158A1 (en) * | 1977-05-10 | 1978-12-08 | Oreal | LIQUID COMPOSITIONS OF DYES FROM THE INDOLES FAMILY FOR HAIR DYEING |
| FI842959A (en) * | 1983-07-28 | 1985-01-29 | Secta Lab Cosmetol | FOERFARANDE OCH KOMPOSITIONER FOER FAERGNING AV HAOR. |
-
1986
- 1986-02-20 LU LU86314A patent/LU86314A1/en unknown
-
1987
- 1987-02-19 CA CA000530134A patent/CA1298042C/en not_active Expired - Fee Related
- 1987-02-19 IT IT8767119A patent/IT1207356B/en active
- 1987-02-19 ES ES8700417A patent/ES2003225A6/en not_active Expired
- 1987-02-19 GB GB8703842A patent/GB2187210B/en not_active Expired - Fee Related
- 1987-02-19 CH CH630/87A patent/CH672729A5/fr not_active IP Right Cessation
- 1987-02-19 FR FR878702162A patent/FR2594331B1/en not_active Expired - Fee Related
- 1987-02-19 BE BE8700145A patent/BE1000115A3/en not_active IP Right Cessation
- 1987-02-20 JP JP62035985A patent/JPS62246510A/en active Pending
- 1987-02-20 DE DE19873705453 patent/DE3705453A1/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| IT1207356B (en) | 1989-05-17 |
| JPS62246510A (en) | 1987-10-27 |
| FR2594331B1 (en) | 1990-10-05 |
| FR2594331A1 (en) | 1987-08-21 |
| DE3705453A1 (en) | 1987-08-27 |
| BE1000115A3 (en) | 1988-04-05 |
| CA1298042C (en) | 1992-03-31 |
| LU86314A1 (en) | 1987-09-10 |
| GB8703842D0 (en) | 1987-03-25 |
| GB2187210A (en) | 1987-09-03 |
| IT8767119A0 (en) | 1987-02-19 |
| GB2187210B (en) | 1990-03-28 |
| ES2003225A6 (en) | 1988-10-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |