CH512979A - Degassing plastics during mixing - using mixing srew in housing with - sintered metal lining - Google Patents

Degassing plastics during mixing - using mixing srew in housing with - sintered metal lining

Info

Publication number
CH512979A
CH512979A CH1451169A CH1451169A CH512979A CH 512979 A CH512979 A CH 512979A CH 1451169 A CH1451169 A CH 1451169A CH 1451169 A CH1451169 A CH 1451169A CH 512979 A CH512979 A CH 512979A
Authority
CH
Switzerland
Prior art keywords
mixing
sintered metal
housing
metal lining
degassing
Prior art date
Application number
CH1451169A
Other languages
German (de)
Inventor
Sutter Fritz
Peter Staeheli Hans
Original Assignee
Buss Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Buss Ag filed Critical Buss Ag
Priority to CH1451169A priority Critical patent/CH512979A/en
Priority to AT911069A priority patent/AT307011B/en
Publication of CH512979A publication Critical patent/CH512979A/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/76Venting, drying means; Degassing means
    • B29C48/765Venting, drying means; Degassing means in the extruder apparatus
    • B29C48/766Venting, drying means; Degassing means in the extruder apparatus in screw extruders
    • B29C48/767Venting, drying means; Degassing means in the extruder apparatus in screw extruders through a degassing opening of a barrel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/375Plasticisers, homogenisers or feeders comprising two or more stages
    • B29C48/38Plasticisers, homogenisers or feeders comprising two or more stages using two or more serially arranged screws in the same barrel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/68Barrels or cylinders
    • B29C48/685Barrels or cylinders characterised by their inner surfaces, e.g. having grooves, projections or threads
    • B29C48/687Barrels or cylinders characterised by their inner surfaces, e.g. having grooves, projections or threads having projections with a short length in the barrel direction, e.g. pins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/76Venting, drying means; Degassing means
    • B29C48/763Vent constructions, e.g. venting means avoiding melt escape
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/45Axially movable screws

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

A mixing and kneading apparatus for granulate, esp. an extruder-type machine for PVC or other plastics, comprises a supply screw and a mixing screw which revolves and also moves axially, the barrel for the mixing screw is lined with sintered metal. This lining is connected externally to a vacuum source, for degassing during mixing or alternatively to a pressurised source, for introducing additives.

Description

       

  
 



  Einrichtung zum Behandeln von staub- und pulverförmigen Materialien
Die vorliegende Erfindung bezieht sich auf eine Einrichtung zum Behandeln von staub- und pulverförmigen Materialien, die mittels einer Zufuhrschnecke einer Misch- und Kneteinrichtung mit rotierender und hin und her gehender Welle zugeführt, mit dieser durchmischt, verdichtet, geknetet und gefördert werden.



  Die Einrichtung eignet sich insbesondere zur Behandlung von Kunststoffen, wie PVC, speziell Hart-PVC, mit Lösungsmittel angeriebenen Farbstoffen usw.



   Bei Kunststoff und Gummi verarbeitenden Maschinen liegt eine der Schwierigkeiten darin, dass eine vollständige Homogenisierung der Masse nur durch eine intensive   Durchknetung    und Durchmischung zu erreichen ist. Dies ist jedoch nur dann durchführbar, wenn die in der Masse eingeschlossenen Gase ausgetrieben werden. Zum Entgasen von plastischen Kunststoff- oder Gummi-Massen hat man bereits vorgeschlagen, in der Misch- und Kneteinrichtung Druckgas durchlassende Schichten in Form von Lamellenpaketen anzuordnen.



  Die Verwendung von Lamellen ist jedoch umständlich und teuer, so dass dieser Vorschlag keine grosse Verbreitung fand.



   Ferner ist es bekannt, Entgasungskammern zu verwenden, welche mit einer Vakuumpumpe mit Kondensatabscheider in Verbindung stehen. Eine weitere Lösung zum Freimachen der Gase besteht darin, indem das Produkt einem schroffen Druckabfall unterzogen wird, was mittels eines Stauringes geschehen kann. Zwischen Stauring und Welle tritt das Produkt in dünner Schicht aus und weist eine grosse Oberfläche und damit eine einigermassen gute Entgasung auf. Wenn sich jedoch diese dünne Schicht infolge ihrer Elastizität wieder zusammenzieht, so wird die Entgasung schwierig.



   Zweck der Erfindung ist, die genannten Nachteile zu beheben und eine sehr einfache und wirksame Lösung vorzuschlagen. Dieses Ziel wird durch eine Einrichtung eingangs beschriebener Art erreicht, bei welcher das Gehäuse eine Sintermetallauskleidung aufweist, die aussen an eine Vakuum- oder Druckquelle anschliessbar ist. In dieser Weise wird die Entgasung auf einer relativ grossen Oberfläche durchgeführt, so dass ein schonendes Ausdampfen erfolgt.



   Auf beiliegender Zeichnung ist ein Ausführungsbei spiel des Erfindungsgegenstandes dargestellt, und zwar zeigen:
Fig. 1 den linken Teil der Einrichtung mit Zufuhreinrichtung im Vertikalschnitt und
Fig. 2 den anschliessenden Austragteil der Einrichtung, ebenfalls im Vertikalschnitt.



   Die Einrichtung zum Behandeln von staub- und pulverförmigen Materialien weist eine horizontale Misch- und Kneteinrichtung 1 und eine vertikale Zufuhreinrichtung 2 auf. Die Misch- und Kneteinrichtung 1 ist mit einem zylindrischen Gehäuse 3 versehen, in welchem eine rotierende und hin und her gehende Welle 4 angeordnet ist. Die Welle 4 trägt einen Schneckengang 5, welcher im Bereiche der Zufuhreinrichtung 2 ununterbrochen ausgeführt ist und anschliessend aus unterbrochenen Gangteilen 6 besteht. Die unterbrochenen Gangteile 6 arbeiten mit Knetzähnen 7 zusammen, die sich durch die Wand des Gehäuses 1 erstrecken und in den Behandlungsraum 8 des Gehäuses 3 hineinragen.



   Es ist bei dieser Misch- und Kneteinrichtung besonders vorteilhaft, dass das Mischen und Kneten und die Bewegung des Guts vorwiegend zwischen den Gangteilen 6 und den Knetzähnen 7 erfolgt. Daher ist die Knetraumwandung im Vergleich zu einer Maschine mit durchgehender Schnecke viel weniger belastet.



   Zum Antrieb der Welle 4 dient ein Elektromotor mit Getriebe, welche Teile im Gehäuse 9 untergebracht sind. Das Gehäuse 3 weist eine seitliche Eintrittsöffnung 10 für das zu behandelnde Gut und eine zentrale, sich konisch verjüngende Austrittsöffnung 11 mit Schliesseinrichtung 15 auf.



   Die der Austrittsöffnung 11 zugekehrte Hälfte des Gehäuses 3 ist inwendig mit einer Sintmetallauskleidung versehen, welche aus aneinandergereihten Sintermetallringen 12 besteht. Die äussere Oberfläche der   Sinter-    metallringe ist mit je einem Ringkanal 13 ausgerüstet, wobei im Bereiche jedes einzelnen Ringkanals eine nach  aussen führende Entlüftungsbohrung 14 vorhanden ist.



  Die Bohrungen 14 sind über eine nicht gezeigte gemeinsame Leitung an eine Vakuumquelle angeschlossen.



   In der axialen Fortsetzung der Schneckenwelle 4 ist eine Schliesseinrichtung 15 angeordnet, welche einen verschiebbaren und gleichzeitig drehbaren Schliessdorn 16 besitzt, dessen Schliessende gegen die Austrittsöffnung 11 des Behandlungsraumes 8 gerichtet ist. Die Schliesseinrichtung kann so ausgebildet sein, dass der Schliessdorn einerseits mit einem im Öffnungssinne wirkenden   Spann-    organ versehen ist und anderseits unter Wirkung eines Arretierorgans steht, das beim Erreichen eines vorbestimmten Axialdruckes die Verschiebung des   Schliess-    dornes im Öffnungssinne bewirkt. In dieser Weise wird sichergestellt, dass der Behandlungsraum beim Anfahren gut gefüllt wird, so dass die gewünschte Reaktion anspringen kann. Anschliessend erfolgt die plötzliche Freigabe der Austrittsöffnung 11, wodurch ein Abreissen der Reaktion verhindert wird.



   Die Zufuhreinrichtung 2 ist nur teilweise gezeichnet.



  Sie weist ein vertikales Gehäuse 17 auf, welches mit dem Flansch 18 der Eintrittsöffnung 10 verbunden ist.



  Im Gehäuse 17 ist eine Förderschnecke 19 untergebracht, welche von einem nicht gezeigten Motor über ein Winkelgetriebe angetrieben wird. Das untere Ende der Zufuhreinrichtung 2 weist einen Entgasungseinsatz 20 auf, welcher ein zylindrisches Gehäuse 21 mit radialem Stutzen 22 besitzt. Dieser wird an eine Vakuumoder Druckquelle angeschlossen. Im Gehäuse 21 befindet sich ein Filterkörper 23 aus porösem Material.



  In diesem Raum 24 kann eine Vorentgasung erfolgen.



   Es soll betont werden, dass mittels der beschriebenen Einrichtung nicht nur ein Entgasen, sondern auch ein Entwässern der zu behandelnden Materialien erfolgen kann. Ferner kann die beschriebene Einrichtung auch in umgekehrter Weise zur Zuführung einer Gasphase in die zu behandelnden Materialien oder zum Zuführen einer Flüssigkeit in feinster Verteilung dienen. Es ist immer eine relativ grosse wirksame Oberfläche zum Entgasen bzw. zur Zuführung einer Gas- oder Flüssigkeitsphase vorhanden. Da die Sintermetallringe in einfacher Weise gewechselt werden können, ergibt sich die Möglichkeit der einfachen Reinigung derselben. Je nach zu behandelnden Materialien werden   Sintermetaliringe    von verschiedener Porosität gebraucht, so dass in jedem Falle eine optimale Wirkung erzielt werden kann.



   Die beschriebene Einrichtung ist ausserordentlich einfach und wirkungsvoll, wobei insbesondere auf die schonendste Behandlung der Materialien Wert gelegt wurde. 



  
 



  Device for handling dusty and powdery materials
The present invention relates to a device for treating dusty and powdery materials, which are fed by means of a feed screw to a mixing and kneading device with a rotating and reciprocating shaft, mixed with it, compacted, kneaded and conveyed.



  The device is particularly suitable for the treatment of plastics such as PVC, especially rigid PVC, dyes rubbed with solvents, etc.



   One of the difficulties with plastic and rubber processing machines is that a complete homogenization of the mass can only be achieved through intensive kneading and mixing. However, this is only feasible if the gases enclosed in the mass are expelled. For degassing plastic or rubber masses, it has already been proposed to arrange layers permeable to compressed gas in the form of lamellar stacks in the mixing and kneading device.



  However, the use of lamellas is laborious and expensive, so that this proposal was not widely used.



   It is also known to use degassing chambers which are connected to a vacuum pump with a condensate separator. Another solution for releasing the gases consists in subjecting the product to a sharp drop in pressure, which can be done by means of a dam ring. The product emerges in a thin layer between the dam ring and the shaft and has a large surface area and therefore reasonably good degassing. However, when this thin layer contracts again due to its elasticity, degassing becomes difficult.



   The purpose of the invention is to remedy the disadvantages mentioned and to propose a very simple and effective solution. This goal is achieved by a device of the type described at the outset, in which the housing has a sintered metal lining that can be connected to a vacuum or pressure source on the outside. In this way, the degassing is carried out on a relatively large surface, so that a gentle evaporation takes place.



   In the accompanying drawing, an exemplary embodiment of the subject matter of the invention is shown, namely show:
Fig. 1 shows the left part of the device with feed device in vertical section and
2 the subsequent discharge part of the device, also in vertical section.



   The device for treating dusty and powdery materials has a horizontal mixing and kneading device 1 and a vertical feed device 2. The mixing and kneading device 1 is provided with a cylindrical housing 3 in which a rotating and reciprocating shaft 4 is arranged. The shaft 4 carries a worm thread 5, which is designed to be uninterrupted in the region of the feed device 2 and then consists of interrupted thread parts 6. The interrupted passage parts 6 work together with kneading teeth 7, which extend through the wall of the housing 1 and protrude into the treatment space 8 of the housing 3.



   With this mixing and kneading device, it is particularly advantageous that the mixing and kneading and the movement of the material take place predominantly between the gear parts 6 and the kneading teeth 7. The wall of the kneading chamber is therefore much less stressed than in a machine with a continuous screw.



   An electric motor with gear, which parts are housed in the housing 9, is used to drive the shaft 4. The housing 3 has a lateral inlet opening 10 for the material to be treated and a central, conically tapering outlet opening 11 with a closing device 15.



   The half of the housing 3 facing the outlet opening 11 is internally provided with a sintered metal lining, which consists of sintered metal rings 12 arranged in a row. The outer surface of the sintered metal rings is each equipped with an annular channel 13, a vent hole 14 leading to the outside being present in the area of each individual annular channel.



  The bores 14 are connected to a vacuum source via a common line (not shown).



   In the axial continuation of the worm shaft 4 a closing device 15 is arranged which has a displaceable and at the same time rotatable closing mandrel 16, the closing end of which is directed towards the outlet opening 11 of the treatment room 8. The locking device can be designed in such a way that the locking pin is on the one hand provided with a tensioning element acting in the opening direction and on the other hand is under the action of a locking element which causes the locking pin to be displaced in the opening direction when a predetermined axial pressure is reached. This ensures that the treatment room is well filled when it starts up so that the desired reaction can start. This is followed by the sudden release of the outlet opening 11, which prevents the reaction from breaking off.



   The feed device 2 is only partially drawn.



  It has a vertical housing 17 which is connected to the flange 18 of the inlet opening 10.



  A screw conveyor 19 is accommodated in the housing 17 and is driven by a motor, not shown, via an angular gear. The lower end of the feed device 2 has a degassing insert 20 which has a cylindrical housing 21 with a radial connection 22. This is connected to a vacuum or pressure source. In the housing 21 there is a filter body 23 made of porous material.



  Pre-degassing can take place in this space 24.



   It should be emphasized that not only degassing, but also dewatering of the materials to be treated can take place by means of the device described. Furthermore, the device described can also be used in reverse for feeding a gas phase into the materials to be treated or for feeding a liquid in extremely fine distribution. There is always a relatively large effective surface for degassing or for supplying a gas or liquid phase. Since the sintered metal rings can be changed in a simple manner, there is the possibility of simple cleaning of the same. Depending on the materials to be treated, sintered metal rings of different porosity are required so that an optimal effect can be achieved in each case.



   The device described is extremely simple and effective, with particular emphasis on the most gentle treatment of the materials.


    

Claims (1)

PATENTANSPRUCH PATENT CLAIM Einrichtung zum Behandeln von staub- und pulver- förmigen Materialien, die mittels einer Zufuhrschnecke, einer Misch- und Kneteinrichtung mit rotierender und hin und her gehender Welle zugeführt, in dieser durchmischt, verdichtet, geknetet und gefördert werden, dadurch gekennzeichnet, dass das Gehäuse (3) der Mischund Kneteinrichtung (1) eine Sintermetallauskleidung aufweist, welche aussen an eine Vakuum- oder Druckquelle anschliessbar ist. Device for treating dusty and powdery materials, which are fed by means of a feed screw, a mixing and kneading device with a rotating and reciprocating shaft, mixed, compressed, kneaded and conveyed in this, characterized in that the housing ( 3) the mixing and kneading device (1) has a sintered metal lining which can be connected externally to a vacuum or pressure source. UNTERANSPRÜCHE 1. Einrichtung nach Patentanspruch, dadurch gekennzeichnet, dass die Sintermetallauskleidung aus gleich- achsig aneinandergereihten Sintermetallringen (12) besteht. SUBCLAIMS 1. Device according to claim, characterized in that the sintered metal lining consists of sintered metal rings (12) lined up on the same axis. 2. Einrichtung nach Patentanspruch und Unteranspruch 1, dadurch gekennzeichnet, dass die äussere Oberfläche der Sintermetallringe mit je einem Ringkanal (13) ausgerüstet ist, wobei im Bereiche jedes einzelnen Ringkanals eine nach aussen führende Entlüftungsbohrung (14) im Gehäuse (13) vorhanden ist. 2. Device according to claim and dependent claim 1, characterized in that the outer surface of the sintered metal rings is each equipped with an annular channel (13), with an outwardly leading vent hole (14) in the housing (13) in the area of each individual annular channel.
CH1451169A 1969-09-23 1969-09-23 Degassing plastics during mixing - using mixing srew in housing with - sintered metal lining CH512979A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CH1451169A CH512979A (en) 1969-09-23 1969-09-23 Degassing plastics during mixing - using mixing srew in housing with - sintered metal lining
AT911069A AT307011B (en) 1969-09-23 1969-09-26 Mixing and kneading device for processing dusty and powdery materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH1451169A CH512979A (en) 1969-09-23 1969-09-23 Degassing plastics during mixing - using mixing srew in housing with - sintered metal lining
AT911069A AT307011B (en) 1969-09-23 1969-09-26 Mixing and kneading device for processing dusty and powdery materials

Publications (1)

Publication Number Publication Date
CH512979A true CH512979A (en) 1971-09-30

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ID=25605305

Family Applications (1)

Application Number Title Priority Date Filing Date
CH1451169A CH512979A (en) 1969-09-23 1969-09-23 Degassing plastics during mixing - using mixing srew in housing with - sintered metal lining

Country Status (2)

Country Link
AT (1) AT307011B (en)
CH (1) CH512979A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1556203A1 (en) * 2002-09-20 2005-07-27 Basf Aktiengesellschaft Device for extruding thermoplasts
US9656408B2 (en) 2013-07-11 2017-05-23 Ineos Styrolution Group Gmbh Method for producing thermoplastic molding compounds, and thermoplastic molding compounds produced according thereto

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110901010A (en) * 2019-12-10 2020-03-24 湖南工业大学 Intermittent type natural exhaust port flash returning device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1556203A1 (en) * 2002-09-20 2005-07-27 Basf Aktiengesellschaft Device for extruding thermoplasts
EP1400337B1 (en) * 2002-09-20 2007-08-22 Basf Aktiengesellschaft Apparatus and method for extrusion of thermoplastics and use thereof
US9656408B2 (en) 2013-07-11 2017-05-23 Ineos Styrolution Group Gmbh Method for producing thermoplastic molding compounds, and thermoplastic molding compounds produced according thereto

Also Published As

Publication number Publication date
AT307011B (en) 1973-05-10

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