CH447444A - Liquid lubricant - Google Patents

Liquid lubricant

Info

Publication number
CH447444A
CH447444A CH1683164A CH1683164A CH447444A CH 447444 A CH447444 A CH 447444A CH 1683164 A CH1683164 A CH 1683164A CH 1683164 A CH1683164 A CH 1683164A CH 447444 A CH447444 A CH 447444A
Authority
CH
Switzerland
Prior art keywords
additives
parts
sep
liquid lubricant
graphite
Prior art date
Application number
CH1683164A
Other languages
French (fr)
Inventor
Billot De Goldlin Alain
Roche Henri
Original Assignee
Antar Petroles Atlantique
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR920382A external-priority patent/FR1352244A/en
Application filed by Antar Petroles Atlantique filed Critical Antar Petroles Atlantique
Publication of CH447444A publication Critical patent/CH447444A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/065Sulfides; Selenides; Tellurides
    • C10M2201/066Molybdenum sulfide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/34Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/028Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/02Bearings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/042Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/044Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/046Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

  

  Lubrifiant     liquide       On a décrit au brevet suisse No 420458 du 30 décem  bre 1963 un lubrifiant liquide pour engrenages, en parti  culier pour transmissions, boîtes de vitesses, ponts d'en  gins à moteur, constitué, pour 100 parties en poids d'une  huile minérale de qualité de 0,5 à 5 parties d'additifs     dis-          persants    et/ou d'additifs de viscosité, de 6 à 10 parties  d'additifs extrême pression, de 0,2 à 15 parties d'additifs  compound, de lubrifiants solides formés de     MoS2    et de  graphite à raison de 0,2 à 1 partie de bisulfure de mo  lybdène et de 0,02 à 0,05 partie de graphite de pureté  synthèse.  



  On a maintenant découvert que la teneur en additifs  dispersants et/ou additifs de viscosité peut être inférieure    Un exemple de     lubrifiant    selon l'invention est donné     ci-après     
EMI0001.0007     
  
     On trouvera dans le brevet précité des renseigne  ments sur les produits de marque     susmentionnés.     



  Des essais systématiques ont été effectués au labora  toire ; ces essais, qui ont été effectués entre autres sur des  machines quatre billes et sur machine     TIMKEN    et sur la  machine d'essais du Service Technique de la Marine,  pour surveiller l'usure (ou diamètre d'empreinte pour la  machine quatre billes), les charges de grippage et les  charges de soudure ont donné des résultats exceptionnels  par leurs qualités.  



  Il a également été procédé à des essais  < c en service    qui ont permis de constater  a) une diminution notable des bruits, sensible  même pour une oreille peu exercée;    à 5 parties et peut même descendre à 0,2 partie, sans  nuire aux propriétés avantageuses du lubrifiant.  



  La présente invention a donc pour objet un lubrifiant  liquide pour engrenages, caractérisé en ce qu'il contient  essentiellement, pour 100 parties en poids d'une huile  minérale de qualité, au moins 0,2 partie, mais moins de  0,5 partie, d'additifs dispersants et/ou d'additifs de visco  sité, de 6 à 10 parties d'additifs extrême pression, de 0,2  à 15 parties d'additifs compound, de lubrifiants solides  formés de     MoS2    et de graphite à raison de 0,2 à 1 partie  de bisulfure de molybdène et de 0,02 à 0,05 partie de  graphite de pureté synthèse.

      b) la disparition du     pitting    (ou formation de trous)  sur certains organes soumis à de fortes charges (notam  ment pont à vis des véhicules ;  c) une grande souplesse de la boîte de vitesses : le  passage des vitesses s'effectuait plus aisément, la diffé  rence étant surtout sensible par grand froid (-200 à  -300 C au cours de l'hiver 1962/1963) ;

    d) la diminution des frottements a été mise en évi  dence  - par la réduction des températures des boîtes de  vitesses mesurées après un service identique (température  ambiante     30     C sur autoroute)    
EMI0002.0001     
  
    huile <SEP> lubrifiant <SEP> liquide
<tb>  extrême <SEP> pression <SEP> suivant
<tb>  classique <SEP> l'invention
<tb>    <SEP> Peugeot <SEP> 404 <SEP> >> <SEP> 125,) <SEP> C <SEP> 1l5  <SEP> C       - par une augmentation du rendement de la boite  de vitesses se traduisant par un gain en vitesse de pointe.  



  Ces divers résultats confirment bien la valeur et les  qualités du lubrifiant selon l'invention.



  Liquid lubricant Swiss Patent No. 420458 of December 30, 1963 describes a liquid lubricant for gears, in particular for transmissions, gearboxes, motor gear bridges, consisting, per 100 parts by weight of an oil quality mineral from 0.5 to 5 parts of dispersant additives and / or viscosity additives, from 6 to 10 parts of extreme pressure additives, from 0.2 to 15 parts of compound additives, lubricants solids formed from MoS2 and graphite in an amount of 0.2 to 1 part of lybdenum disulphide and 0.02 to 0.05 part of synthetic purity graphite.



  It has now been discovered that the content of dispersant additives and / or viscosity additives can be lower. An example of a lubricant according to the invention is given below
EMI0001.0007
  
     Information on the aforementioned brand products can be found in the aforementioned patent.



  Systematic tests have been carried out in the laboratory; these tests, which were carried out, among others, on four ball machines and on a TIMKEN machine and on the Marine Technical Service test machine, to monitor wear (or cavity diameter for the four ball machine), seizure loads and welding loads have given exceptional results by their qualities.



  In-service tests have also been carried out which have made it possible to observe a) a noticeable reduction in noise, noticeable even for a little exercised ear; to 5 parts and can even go down to 0.2 part, without harming the advantageous properties of the lubricant.



  The present invention therefore relates to a liquid lubricant for gears, characterized in that it essentially contains, for 100 parts by weight of a quality mineral oil, at least 0.2 part, but less than 0.5 part, dispersant additives and / or viscosity additives, 6 to 10 parts of extreme pressure additives, 0.2 to 15 parts of compound additives, solid lubricants formed from MoS2 and graphite at a rate of 0 , 2 to 1 part of molybdenum disulphide and 0.02 to 0.05 part of synthetic purity graphite.

      b) the disappearance of pitting (or the formation of holes) on certain components subjected to heavy loads (in particular screw-type vehicle axles; c) great flexibility of the gearbox: gear change was made more easily, the difference being especially noticeable in extreme cold (-200 to -300 C during the winter of 1962/1963);

    d) the reduction in friction has been demonstrated - by the reduction in the temperatures of the gearboxes measured after identical service (ambient temperature 30 C on the motorway)
EMI0002.0001
  
    oil <SEP> lubricant <SEP> liquid
<tb> extreme <SEP> pressure <SEP> next
<tb> classic <SEP> invention
<tb> <SEP> Peugeot <SEP> 404 <SEP> >> <SEP> 125,) <SEP> C <SEP> 1l5 <SEP> C - by an increase in the efficiency of the gearbox resulting in a gain at top speed.



  These various results clearly confirm the value and the qualities of the lubricant according to the invention.

 

Claims (1)

REVENDICATION Lubrifiant liquide pour engrenages, caractérisé en ce qu'il contient essentiellement, pour 100 parties en poids d'une huile minérale de qualité au moins 0,2 partie, mais moins de 0,5 partie d'additifs dispersants et/ou d'additifs de viscosité, de 6 à 10 parties d'additifs extrême pression, de 0,2 à 15 parties d'additifs compound, de lubrifiants solides formés de MoS2 et de graphite à raison de 0,2 à 1 partie de bisulfure de molybdène et de 0,02 et 0,05 par tie de graphite de pureté synthèse. CLAIM Liquid lubricant for gears, characterized in that it contains essentially, per 100 parts by weight of a quality mineral oil at least 0.2 part, but less than 0.5 part of dispersant additives and / or viscosity additives, from 6 to 10 parts of extreme pressure additives, from 0.2 to 15 parts of compound additives, solid lubricants formed from MoS2 and graphite in a proportion of 0.2 to 1 part of molybdenum disulphide and 0.02 and 0.05 part of synthetic purity graphite.
CH1683164A 1963-01-03 1964-12-30 Liquid lubricant CH447444A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR920382A FR1352244A (en) 1963-01-03 1963-01-03 Liquid lubricant
FR959269A FR85058E (en) 1963-01-03 1964-01-03 Liquid lubricant

Publications (1)

Publication Number Publication Date
CH447444A true CH447444A (en) 1967-11-30

Family

ID=26199219

Family Applications (2)

Application Number Title Priority Date Filing Date
CH1600763A CH420458A (en) 1963-01-03 1963-12-30 Liquid lubricant
CH1683164A CH447444A (en) 1963-01-03 1964-12-30 Liquid lubricant

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CH1600763A CH420458A (en) 1963-01-03 1963-12-30 Liquid lubricant

Country Status (9)

Country Link
BE (2) BE642024A (en)
CH (2) CH420458A (en)
DE (2) DE1594328A1 (en)
DK (1) DK116952B (en)
FR (1) FR85058E (en)
GB (2) GB1053041A (en)
LU (2) LU45145A1 (en)
MC (1) MC445A1 (en)
NL (2) NL145596B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4164475A (en) * 1975-05-09 1979-08-14 The Standard Oil Company Multi-grade 80W-140 gear oil

Also Published As

Publication number Publication date
DE1594329A1 (en) 1970-10-15
DE1594328A1 (en) 1970-07-23
LU47681A1 (en) 1965-03-02
NL145596B (en) 1975-04-15
LU45145A1 (en) 1964-03-02
GB1053041A (en)
BE657847A (en) 1965-06-30
CH420458A (en) 1966-09-15
BE642024A (en) 1964-06-30
MC445A1 (en) 1964-09-08
DK116952B (en) 1970-03-02
FR85058E (en) 1965-06-04
GB1054501A (en)
NL302930A (en)

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