CH148686A - Process for the preparation of a dye of the anthraquinone series. - Google Patents

Process for the preparation of a dye of the anthraquinone series.

Info

Publication number
CH148686A
CH148686A CH148686DA CH148686A CH 148686 A CH148686 A CH 148686A CH 148686D A CH148686D A CH 148686DA CH 148686 A CH148686 A CH 148686A
Authority
CH
Switzerland
Prior art keywords
dye
preparation
anthraquinone series
series
condensation product
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH148686A publication Critical patent/CH148686A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/28—Dyes with amino groups substituted by hydrocarbon radicals substituted by alkyl, aralkyl or cyclo alkyl groups
    • C09B1/30—Dyes with amino groups substituted by hydrocarbon radicals substituted by alkyl, aralkyl or cyclo alkyl groups sulfonated
    • C09B1/303—Dyes with amino groups substituted by hydrocarbon radicals substituted by alkyl, aralkyl or cyclo alkyl groups sulfonated only sulfonated in the anthracene nucleus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

  Zusatzpatent zum Hauptpatent Nr. 142743.         y    Verfahren zur Herstellung eines Farbstoffes der     Anthrachinonreihe.       Es wurde gefunden, dass man einen     ent-          sulfierten    Farbstoff der     Anthrachinonreihe     erhält, wenn man die     Leukoverbindung     des     1.5-dioxy-4.8-dimethyldiaminoanthra-          chinon-2.        6-disulfosauren    Natriums in     wäs-          serigem    Medium mit Ammoniak erhitzt,

    wobei sehr wahrscheinlich 2     Mol    Ammoniak  mit einem     Mol    des obigen     Anthrachinon-          derivates    kondensieren, und das so erhaltene  Kondensationsprodukt zum     Anthrachinon-          derivat    oxydiert.  



  Der so erhaltene Farbstoff stellt ein dunk  les Pulver dar und löst sich in organischen       Lösungsmitteln    mit blauer Farbe auf. Er  färbt     Aceta,tseide    nach geeigneter     Verpastung     in blauen Tönen an.    <I>Beispiel:</I>    5,2 Teile des     1.5-dioxy-4.8-dimethyl-          diaminoanthrachinon-2.6-disulfosauren    Na  triums werden mit 6 Teilen Natriumhydro-         sulfit    in 25     Volumteilen    wässeriger 24 %     iger          Ammoniaklösung    fünf Stunden auf 100   im  geschlossenen Gefäss erhitzt.

   Man filtriert,  wäscht. heiss aus und erhält. beim Trocknen  ein     Kondensationsprodukt,    welches durch  Erhitzen an der Luft     oxydiert    wird, sich  dann in Schwefelsäure mit gelber und in       E        ssigsäureäthylester    mit blauer Farbe löst.  



       ieses    Kondensationsprodukt     entsprichl     D     f          %-vahrscheinlich    dem     1-Oxy-4-methylamino--          5.        8-diaminoanthrachinon.  



  Additional patent to main patent no. 142743. y Process for the production of a dye of the anthraquinone series. It has been found that a desulfurized dye of the anthraquinone series is obtained if the leuco compound of 1,5-dioxy-4,8-dimethyldiaminoanthraquinone-2. 6-disulfonate of sodium heated in an aqueous medium with ammonia,

    2 moles of ammonia very likely condense with one mole of the above anthraquinone derivative, and the condensation product thus obtained is oxidized to the anthraquinone derivative.



  The dye thus obtained is a dark powder and dissolves in organic solvents with a blue color. It stains Aceta silk in blue tones after suitable pasting. <I> Example: </I> 5.2 parts of 1.5-dioxy-4.8-dimethyl-diaminoanthraquinone-2.6-disulfonic acid sodium are mixed with 6 parts of sodium hydrosulfite in 25 parts by volume of aqueous 24% ammonia solution for five hours to 100 in the closed Vessel heated.

   It is filtered, washed. hot off and receives. on drying, a condensation product which is oxidized by heating in air, then dissolves in sulfuric acid with a yellow color and in ethyl acetate with a blue color.



       This condensation product corresponds to D f% - probably 1-oxy-4-methylamino-- 5, 8-diaminoanthraquinone.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines Farb stoffes der Anthrach@nonreihe, dadurch ge kennzeichnet, dass man die Leukoverbindung des 1.5-dioxy-4.8-dimethyldiaminoanthra-- chinon-2.6-disulfosauren Natriums in wäs serigem Medium mit Ammoniak erhitzt und das so erhaltene Kondensationsprodukt zum Anthrachinonderivat oxydiert. Der so erhaltene Farbstoff stellt ein dunk les Pulver dar und löst sieh in organisehen Lösungsmitteln mit blauer Farbe auf. Er färbt Aeetatseide naeh geeigneter Verpastung in blauen Tönen an. PATENT CLAIM: A process for the production of a dye of the Anthrach @ non series, characterized in that the leuco compound of 1.5-dioxy-4.8-dimethyldiaminoanthra-- quinone-2.6-disulfonic acid sodium is heated in an aqueous medium with ammonia and the condensation product obtained in this way Anthraquinone derivative oxidized. The dye thus obtained is a dark powder and dissolves in organic solvents with a blue color. He dyes acetate silk in blue tones after suitable pasting.
CH148686D 1930-04-17 1930-04-17 Process for the preparation of a dye of the anthraquinone series. CH148686A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH148686T 1930-04-17
CH142743T 1930-04-17

Publications (1)

Publication Number Publication Date
CH148686A true CH148686A (en) 1931-07-31

Family

ID=25714120

Family Applications (1)

Application Number Title Priority Date Filing Date
CH148686D CH148686A (en) 1930-04-17 1930-04-17 Process for the preparation of a dye of the anthraquinone series.

Country Status (1)

Country Link
CH (1) CH148686A (en)

Similar Documents

Publication Publication Date Title
CH148686A (en) Process for the preparation of a dye of the anthraquinone series.
CH150800A (en) Process for the preparation of a dye of the anthraquinone series.
CH150799A (en) Process for the preparation of a dye of the anthraquinone series.
CH150798A (en) Process for the preparation of a dye of the anthraquinone series.
CH148684A (en) Process for the preparation of a dye of the anthraquinone series.
CH150796A (en) Process for the preparation of a dye of the anthraquinone series.
CH150797A (en) Process for the preparation of a dye of the anthraquinone series.
CH150801A (en) Process for the preparation of a dye of the anthraquinone series.
CH150795A (en) Process for the preparation of a dye of the anthraquinone series.
CH148683A (en) Process for the preparation of a dye of the anthraquinone series.
CH146775A (en) Process for the preparation of a dye of the anthraquinone series.
CH146772A (en) Process for the preparation of a dye of the anthraquinone series.
CH146774A (en) Process for the preparation of a dye of the anthraquinone series.
CH146773A (en) Process for the preparation of a dye of the anthraquinone series.
CH148685A (en) Process for the preparation of a dye of the anthraquinone series.
CH106440A (en) Process for the production of a new indigoid dye.
CH150794A (en) Process for the preparation of a dye of the anthraquinone series.
CH155339A (en) Process for the production of a nitrogenous vat dye.
CH142657A (en) Process for the production of a brown vat dye of the benzanthrone series.
CH165055A (en) Process for the production of a new vat dye.
CH121500A (en) Process for the production of a new vat dye.
CH109620A (en) Process for the production of an indigoid dye of the anthracene series.
CH131500A (en) Process for the preparation of a dye intermediate of the benzanthrone series.
CH127783A (en) Process for the preparation of a new vat dye.
CH161229A (en) Process for the preparation of a dye.