CA3207422A1 - Explosifs a emulsion du type eau dans huile - Google Patents
Explosifs a emulsion du type eau dans huile Download PDFInfo
- Publication number
- CA3207422A1 CA3207422A1 CA3207422A CA3207422A CA3207422A1 CA 3207422 A1 CA3207422 A1 CA 3207422A1 CA 3207422 A CA3207422 A CA 3207422A CA 3207422 A CA3207422 A CA 3207422A CA 3207422 A1 CA3207422 A1 CA 3207422A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- oil
- total weight
- view
- explosive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002360 explosive Substances 0.000 title claims abstract description 106
- 239000000203 mixture Substances 0.000 claims abstract description 273
- 239000000839 emulsion Substances 0.000 claims abstract description 173
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims abstract description 146
- 239000003921 oil Substances 0.000 claims abstract description 126
- 235000019198 oils Nutrition 0.000 claims abstract description 120
- 239000000446 fuel Substances 0.000 claims abstract description 112
- 239000007800 oxidant agent Substances 0.000 claims abstract description 109
- 239000012071 phase Substances 0.000 claims abstract description 105
- 239000012074 organic phase Substances 0.000 claims abstract description 87
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 77
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 69
- 239000008158 vegetable oil Substances 0.000 claims abstract description 68
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 53
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000002551 biofuel Substances 0.000 claims description 28
- 235000019737 Animal fat Nutrition 0.000 claims description 15
- 235000012424 soybean oil Nutrition 0.000 claims description 14
- 239000003549 soybean oil Substances 0.000 claims description 13
- 239000003225 biodiesel Substances 0.000 claims description 9
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 7
- 235000005687 corn oil Nutrition 0.000 claims description 6
- 235000019482 Palm oil Nutrition 0.000 claims description 4
- 235000019486 Sunflower oil Nutrition 0.000 claims description 4
- 239000002540 palm oil Substances 0.000 claims description 4
- 239000002600 sunflower oil Substances 0.000 claims description 4
- 239000002285 corn oil Substances 0.000 claims description 3
- 241000221089 Jatropha Species 0.000 claims description 2
- 108010039491 Ricin Proteins 0.000 claims description 2
- 235000019519 canola oil Nutrition 0.000 claims description 2
- 239000000828 canola oil Substances 0.000 claims description 2
- 235000019864 coconut oil Nutrition 0.000 claims description 2
- 239000003240 coconut oil Substances 0.000 claims description 2
- 229940119170 jojoba wax Drugs 0.000 claims description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 abstract description 70
- 235000010344 sodium nitrate Nutrition 0.000 abstract description 35
- 239000004317 sodium nitrate Substances 0.000 abstract description 34
- 239000007762 w/o emulsion Substances 0.000 abstract 1
- 239000000523 sample Substances 0.000 description 71
- 150000003839 salts Chemical group 0.000 description 18
- 244000068988 Glycine max Species 0.000 description 16
- 235000010469 Glycine max Nutrition 0.000 description 14
- 239000003925 fat Substances 0.000 description 14
- 235000019197 fats Nutrition 0.000 description 14
- 229920005652 polyisobutylene succinic anhydride Polymers 0.000 description 11
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 6
- 240000002791 Brassica napus Species 0.000 description 6
- 239000001593 sorbitan monooleate Substances 0.000 description 6
- 229940035049 sorbitan monooleate Drugs 0.000 description 6
- 235000011069 sorbitan monooleate Nutrition 0.000 description 6
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 241001465754 Metazoa Species 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229920002367 Polyisobutene Polymers 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- -1 animal fat (tallow) Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 241000195493 Cryptophyta Species 0.000 description 2
- 235000019483 Peanut oil Nutrition 0.000 description 2
- 244000057114 Sapium sebiferum Species 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 235000014571 nuts Nutrition 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000000312 peanut oil Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000005713 safflower oil Nutrition 0.000 description 2
- 239000003813 safflower oil Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 244000266618 Atriplex confertifolia Species 0.000 description 1
- 235000012137 Atriplex confertifolia Nutrition 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 241000282832 Camelidae Species 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- 235000003301 Ceiba pentandra Nutrition 0.000 description 1
- 244000146553 Ceiba pentandra Species 0.000 description 1
- 241000283153 Cetacea Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 240000000528 Ricinus communis Species 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 235000005128 Sapium sebiferum Nutrition 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 244000000231 Sesamum indicum Species 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 229910001964 alkaline earth metal nitrate Inorganic materials 0.000 description 1
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 1
- 239000010828 animal waste Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 235000013367 dietary fats Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000010520 ghee Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 239000010460 hemp oil Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002646 long chain fatty acid esters Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 235000019508 mustard seed Nutrition 0.000 description 1
- 239000010491 poppyseed oil Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000010463 virgin olive oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
- C06B47/145—Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Colloid Chemistry (AREA)
- Lubricants (AREA)
- Edible Oils And Fats (AREA)
Abstract
La présente invention concerne de manière générale une composition explosive en émulsion eau dans huile, comprenant une phase organique et une phase oxydante comprenant au moins du nitrate d'ammonium, au moins 50 % en poids de l'huile non renouvelable normalement utilisée dans la phase organique étant remplacée par une ou plusieurs huiles renouvelables, en particulier une huile végétale droite. La présente invention concerne une composition d'émulsion explosive du type eau dans huile, comprenant entre 80 % en poids et 95 % en poids d'une phase oxydant compte tenu du poids total de la composition d'émulsion ; au moins 40 % en poids de nitrate d'ammonium (AN), et au moins un ou plusieurs sels de nitrate secondaire ; notamment au moins 15 % en poids de nitrate de calcium, ou au moins 20 % en poids de nitrate de calcium et/ou de nitrate de sodium, compte tenu du poids total de la composition de phase d'oxydant ; entre 5 % en poids et 20 % en poids d'une phase organique compte tenu du poids total de la composition d'émulsion. La phase organique comprend entre 12 % en poids et 50 % en poids d'un ou plusieurs émulsifiants, entre 50 % en poids et 88 % en poids d'une composition de carburant, compte tenu du poids total de la composition de phase organique. La composition de carburant comprend entre 20 % en poids et 100 % en poids d'une huile végétale brute (HVB), compte tenu du poids total de la composition de carburant.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP21161191.8A EP4056545A1 (fr) | 2021-03-08 | 2021-03-08 | Explosifs à émulsion de type eau dans huile |
| EP21161191.8 | 2021-03-08 | ||
| PCT/EP2022/055797 WO2022189381A1 (fr) | 2021-03-08 | 2022-03-08 | Explosifs à émulsion du type eau dans huile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA3207422A1 true CA3207422A1 (fr) | 2022-09-15 |
Family
ID=74859760
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3207422A Pending CA3207422A1 (fr) | 2021-03-08 | 2022-03-08 | Explosifs a emulsion du type eau dans huile |
Country Status (5)
| Country | Link |
|---|---|
| EP (2) | EP4056545A1 (fr) |
| AU (1) | AU2022233004A1 (fr) |
| BR (1) | BR112023017507A2 (fr) |
| CA (1) | CA3207422A1 (fr) |
| WO (1) | WO2022189381A1 (fr) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR241896A1 (es) * | 1982-05-12 | 1993-01-29 | Union Explosivos Rio Tinto | Composicion y procedimiento para la obtencion de explosivos en emulsion. |
| US4931110A (en) * | 1989-03-03 | 1990-06-05 | Ireco Incorporated | Emulsion explosives containing a polymeric emulsifier |
| CA2049628C (fr) * | 1991-08-21 | 2002-02-26 | Clare T. Aitken | Explosif a emulsion a l'huile vegetale |
| AUPR054800A0 (en) * | 2000-10-04 | 2000-10-26 | Orica Explosives Technology Pty Ltd | Emulsion explosive |
| WO2002076912A2 (fr) * | 2001-02-27 | 2002-10-03 | Dynaenergetics Gmbh & Co Kg | Explosif a emulsion biodegradable |
-
2021
- 2021-03-08 EP EP21161191.8A patent/EP4056545A1/fr not_active Withdrawn
-
2022
- 2022-03-08 EP EP22711522.7A patent/EP4305007A1/fr active Pending
- 2022-03-08 AU AU2022233004A patent/AU2022233004A1/en active Pending
- 2022-03-08 BR BR112023017507A patent/BR112023017507A2/pt unknown
- 2022-03-08 CA CA3207422A patent/CA3207422A1/fr active Pending
- 2022-03-08 WO PCT/EP2022/055797 patent/WO2022189381A1/fr active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| US20240132421A1 (en) | 2024-04-25 |
| BR112023017507A2 (pt) | 2023-10-10 |
| EP4305007A1 (fr) | 2024-01-17 |
| EP4056545A1 (fr) | 2022-09-14 |
| AU2022233004A1 (en) | 2023-09-07 |
| WO2022189381A1 (fr) | 2022-09-15 |
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