CA3033530C - Apparatus for analyzing the elemental composition of a liquid sample and methods of using the same - Google Patents
Apparatus for analyzing the elemental composition of a liquid sample and methods of using the same Download PDFInfo
- Publication number
- CA3033530C CA3033530C CA3033530A CA3033530A CA3033530C CA 3033530 C CA3033530 C CA 3033530C CA 3033530 A CA3033530 A CA 3033530A CA 3033530 A CA3033530 A CA 3033530A CA 3033530 C CA3033530 C CA 3033530C
- Authority
- CA
- Canada
- Prior art keywords
- liquid
- analyzing
- electrodes
- elemental composition
- pumping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 138
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000005086 pumping Methods 0.000 claims abstract description 64
- 238000004070 electrodeposition Methods 0.000 claims abstract description 44
- 239000012491 analyte Substances 0.000 claims abstract description 14
- 238000004458 analytical method Methods 0.000 claims abstract description 12
- 150000002500 ions Chemical class 0.000 claims abstract description 9
- 238000001228 spectrum Methods 0.000 claims abstract description 9
- 238000001514 detection method Methods 0.000 claims description 35
- 230000003287 optical effect Effects 0.000 claims description 33
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- 239000000835 fiber Substances 0.000 claims description 20
- 238000004140 cleaning Methods 0.000 claims description 13
- 229910002804 graphite Inorganic materials 0.000 claims description 13
- 239000010439 graphite Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- 230000002441 reversible effect Effects 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 10
- 238000012544 monitoring process Methods 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 239000002131 composite material Substances 0.000 claims description 8
- 230000001419 dependent effect Effects 0.000 claims description 6
- 238000001819 mass spectrum Methods 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 4
- 239000002041 carbon nanotube Substances 0.000 claims description 4
- 229910003472 fullerene Inorganic materials 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 4
- 229910052741 iridium Inorganic materials 0.000 claims description 4
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 4
- -1 platinu.m Chemical compound 0.000 claims description 4
- 229910052702 rhenium Inorganic materials 0.000 claims description 4
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 2
- 238000005070 sampling Methods 0.000 claims description 2
- 239000002659 electrodeposit Substances 0.000 claims 4
- 230000003340 mental effect Effects 0.000 claims 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 claims 1
- 238000004094 preconcentration Methods 0.000 abstract description 10
- 239000000523 sample Substances 0.000 description 27
- 239000011651 chromium Substances 0.000 description 15
- 229910052804 chromium Inorganic materials 0.000 description 12
- 229910052793 cadmium Inorganic materials 0.000 description 9
- 229910052745 lead Inorganic materials 0.000 description 9
- 229910052753 mercury Inorganic materials 0.000 description 9
- 235000020188 drinking water Nutrition 0.000 description 8
- 239000003651 drinking water Substances 0.000 description 8
- 238000000835 electrochemical detection Methods 0.000 description 8
- 229910021645 metal ion Inorganic materials 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000000151 deposition Methods 0.000 description 6
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 6
- 239000008399 tap water Substances 0.000 description 6
- 235000020679 tap water Nutrition 0.000 description 6
- 230000008021 deposition Effects 0.000 description 5
- 238000000295 emission spectrum Methods 0.000 description 5
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000003595 spectral effect Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000001636 atomic emission spectroscopy Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000013535 sea water Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000003968 anodic stripping voltammetry Methods 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 238000004752 cathodic stripping voltammetry Methods 0.000 description 2
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 description 2
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 238000001287 electrothermal atomic absorption spectrometry Methods 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 230000008520 organization Effects 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 238000001391 atomic fluorescence spectroscopy Methods 0.000 description 1
- 238000000559 atomic spectroscopy Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 238000003891 environmental analysis Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000004186 food analysis Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
- G01N1/14—Suction devices, e.g. pumps; Ejector devices
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/40—Concentrating samples
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/66—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light electrically excited, e.g. electroluminescence
- G01N21/67—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light electrically excited, e.g. electroluminescence using electric arcs or discharges
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/66—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light electrically excited, e.g. electroluminescence
- G01N21/69—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light electrically excited, e.g. electroluminescence specially adapted for fluids, e.g. molten metal
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/02—Details
- H01J49/04—Arrangements for introducing or extracting samples to be analysed, e.g. vacuum locks; Arrangements for external adjustment of electron- or ion-optical components
- H01J49/0431—Arrangements for introducing or extracting samples to be analysed, e.g. vacuum locks; Arrangements for external adjustment of electron- or ion-optical components for liquid samples
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/02—Details
- H01J49/10—Ion sources; Ion guns
- H01J49/12—Ion sources; Ion guns using an arc discharge, e.g. of the duoplasmatron type
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/40—Concentrating samples
- G01N2001/4038—Concentrating samples electric methods, e.g. electromigration, electrophoresis, ionisation
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Immunology (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Biochemistry (AREA)
- Pathology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Hydrology & Water Resources (AREA)
- Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Electron Tubes For Measurement (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662384799P | 2016-09-08 | 2016-09-08 | |
| US62/384,799 | 2016-09-08 | ||
| PCT/CA2017/051032 WO2018045455A1 (en) | 2016-09-08 | 2017-08-31 | Apparatus for analyzing the elemental composition of a liquid sample and methods of using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3033530A1 CA3033530A1 (en) | 2018-03-15 |
| CA3033530C true CA3033530C (en) | 2023-03-07 |
Family
ID=61561311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3033530A Active CA3033530C (en) | 2016-09-08 | 2017-08-31 | Apparatus for analyzing the elemental composition of a liquid sample and methods of using the same |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11474042B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP3510383B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6990455B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN109690296B (cg-RX-API-DMAC7.html) |
| CA (1) | CA3033530C (cg-RX-API-DMAC7.html) |
| WO (1) | WO2018045455A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7019505B2 (ja) * | 2018-04-26 | 2022-02-15 | アークレイ株式会社 | プラズマ分光分析方法 |
| CN111063604B (zh) * | 2020-01-13 | 2025-04-22 | 华南师范大学 | 加热毛细管液体阴极辉光放电电离装置 |
| CN111739783B (zh) * | 2020-05-28 | 2021-10-29 | 清华大学 | 用于小型质谱仪的大气压电弧离子源及其检测方法 |
| US20240162024A1 (en) * | 2021-03-16 | 2024-05-16 | Quadrocore Corp. | A system for production of high yield of ions in rf only confinement field for use in mass spectrometry |
| CN113720811B (zh) * | 2021-08-19 | 2022-12-30 | 中国地质大学（武汉） | 一种基于超声雾化进样的微等离子体激发源及激发方法 |
| CN117907562B (zh) * | 2024-03-19 | 2024-06-04 | 张家港扬子江冷轧板有限公司 | 一种同时检测镀层中多种元素含量的方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62225932A (ja) * | 1986-03-27 | 1987-10-03 | Toshiba Corp | トリウムの分析方法 |
| EP0569908B1 (en) * | 1992-05-11 | 2002-02-13 | Nippon Telegraph And Telephone Corporation | Electrochemical detection method and apparatus therefor |
| US5481110A (en) * | 1993-09-22 | 1996-01-02 | Westinghouse Electric Corp | Thin film preconcentrator array |
| US5641686A (en) * | 1995-03-28 | 1997-06-24 | The United States Of America As Represented By The United States Department Of Energy | Flow injection trace gas analysis method for on-site determination of organoarsenicals |
| US6686998B2 (en) * | 2001-11-30 | 2004-02-03 | Wisconsin Alumni Research Foundation | Method and apparatus for glow discharges with liquid microelectrodes |
| US20040118348A1 (en) | 2002-03-07 | 2004-06-24 | Mills Randell L.. | Microwave power cell, chemical reactor, and power converter |
| US20040129579A1 (en) * | 2002-07-23 | 2004-07-08 | Crooks Richard M. | Photonic signal reporting of electrochemical events |
| US7460225B2 (en) * | 2004-03-05 | 2008-12-02 | Vassili Karanassios | Miniaturized source devices for optical and mass spectrometry |
| US7929138B1 (en) | 2008-02-15 | 2011-04-19 | The United States Of America As Represented By The United States Department Of Energy | Ambient-atmosphere glow discharge for determination of elemental concentration in solutions in a high-throughput or transient fashion |
| FR2953927B1 (fr) * | 2009-12-14 | 2012-02-03 | Commissariat Energie Atomique | Dispositif et procede de fabrication d'echantillon a partir d'un liquide |
| CN102263006B (zh) * | 2011-06-28 | 2013-07-31 | 中国科学院化学研究所 | 一种基于热辅助辉光放电的质谱离子源装置及其离子化分析方法 |
| JP5817372B2 (ja) | 2011-09-15 | 2015-11-18 | 国立大学法人群馬大学 | 重金属分析装置及び重金属の分析方法 |
| JP5785851B2 (ja) * | 2011-11-04 | 2015-09-30 | 株式会社日立製作所 | 有機発光装置 |
| RU2487342C1 (ru) * | 2012-01-12 | 2013-07-10 | Открытое Акционерное Общество "Научно-Производственное Предприятие "Буревестник" | Способ эмиссионного анализа элементного состава жидких сред |
| US9500621B2 (en) * | 2012-06-04 | 2016-11-22 | Beckman Coulter, Inc. | Leakage current sense circuit for error detection in an improved capillary electrophoresis-electrospray ionization-mass spectrometry system |
| US9536725B2 (en) * | 2013-02-05 | 2017-01-03 | Clemson University | Means of introducing an analyte into liquid sampling atmospheric pressure glow discharge |
| IL292835A (en) | 2013-11-20 | 2022-07-01 | Brilliant Light Power Inc | Electricity production systems and methods relating thereto |
| CN104155276B (zh) * | 2014-08-22 | 2016-08-17 | 哈尔滨工业大学 | 一种饮用水高风险污染物监测预警系统及其使用方法 |
| CN104458872B (zh) * | 2014-12-17 | 2019-06-07 | 中国计量学院 | 一种测量水中重金属离子的装置 |
| CN104483423B (zh) * | 2014-12-31 | 2016-03-09 | 同方威视技术股份有限公司 | 样品采集和热解析进样装置和方法以及痕量检测设备 |
| WO2017040359A1 (en) * | 2015-08-28 | 2017-03-09 | Indiana University Research And Technology Corporation | Atmospheric-pressure ionization and fragmentation of molecules for structural elucidation |
| JP2018534553A (ja) * | 2015-09-24 | 2018-11-22 | イノテック・アルバータ・インコーポレイテッドＩｎｎｏＴｅｃｈ Ａｌｂｅｒｔａ Ｉｎｃ． | 溶液カソードグロー放電元素分析 |
| CN105842230B (zh) * | 2016-03-29 | 2018-06-22 | 中国科学院上海硅酸盐研究所 | 一种用于重金属元素检测的装置及方法 |
-
2017
- 2017-08-31 CA CA3033530A patent/CA3033530C/en active Active
- 2017-08-31 EP EP17847843.4A patent/EP3510383B1/en active Active
- 2017-08-31 US US16/326,595 patent/US11474042B2/en active Active
- 2017-08-31 WO PCT/CA2017/051032 patent/WO2018045455A1/en not_active Ceased
- 2017-08-31 CN CN201780054081.5A patent/CN109690296B/zh active Active
- 2017-08-31 JP JP2019513058A patent/JP6990455B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP6990455B2 (ja) | 2022-01-12 |
| CA3033530A1 (en) | 2018-03-15 |
| US11474042B2 (en) | 2022-10-18 |
| EP3510383A1 (en) | 2019-07-17 |
| EP3510383B1 (en) | 2022-06-01 |
| US20210131971A1 (en) | 2021-05-06 |
| JP2019535002A (ja) | 2019-12-05 |
| EP3510383A4 (en) | 2020-06-10 |
| CN109690296A (zh) | 2019-04-26 |
| WO2018045455A1 (en) | 2018-03-15 |
| CN109690296B (zh) | 2021-10-08 |
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