CA2975919C - Water splitting catalyst containing mn4cao4 core structure, preparation process and application thereof - Google Patents

Water splitting catalyst containing mn4cao4 core structure, preparation process and application thereof Download PDF

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Publication number
CA2975919C
CA2975919C CA2975919A CA2975919A CA2975919C CA 2975919 C CA2975919 C CA 2975919C CA 2975919 A CA2975919 A CA 2975919A CA 2975919 A CA2975919 A CA 2975919A CA 2975919 C CA2975919 C CA 2975919C
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acid
compound
formula
carboxylic acid
butyl
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French (fr)
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CA2975919A1 (en
Inventor
Chunxi Zhang
Changhui Chen
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Institute of Chemistry CAS
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Institute of Chemistry CAS
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C07F13/005—Compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/23—Calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
CA2975919A 2015-02-06 2016-02-02 Water splitting catalyst containing mn4cao4 core structure, preparation process and application thereof Active CA2975919C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201510065238.7A CN104761591B (zh) 2015-02-06 2015-02-06 一种含有Mn4CaO4核心结构的水裂解催化剂，其制备方法及其应用
CN201510065238.7 2015-02-06
PCT/CN2016/073203 WO2016124133A1 (zh) 2015-02-06 2016-02-02 一种含有Mn4CaO4核心结构的水裂解催化剂，其制备方法及其应用

Publications (2)

Publication Number Publication Date
CA2975919A1 CA2975919A1 (en) 2016-08-11
CA2975919C true CA2975919C (en) 2022-07-05

Family

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Family Applications (1)

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CA2975919A Active CA2975919C (en) 2015-02-06 2016-02-02 Water splitting catalyst containing mn4cao4 core structure, preparation process and application thereof

Country Status (8)

Country Link
US (1) US10421065B2 (https=)
EP (1) EP3255053B1 (https=)
JP (1) JP6795508B2 (https=)
KR (1) KR101991755B1 (https=)
CN (1) CN104761591B (https=)
AU (1) AU2016214806B2 (https=)
CA (1) CA2975919C (https=)
WO (1) WO2016124133A1 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104761591B (zh) 2015-02-06 2017-07-21 中国科学院化学研究所 一种含有Mn4CaO4核心结构的水裂解催化剂，其制备方法及其应用
US11511266B2 (en) 2017-11-01 2022-11-29 Institute Of Chemistry, Chinese Academy Of Sciences Cluster compounds containing [Mn3SrO4] and [Mn4SrO4] core structures, preparation method and application thereof
CN109748939B (zh) * 2017-11-01 2020-07-14 中国科学院化学研究所 含有[Mn3SrO4]和[Mn4SrO4]核心结构的簇合物及其制备方法和应用
CN110219015A (zh) * 2019-05-05 2019-09-10 南京航空航天大学 仿生锰核立方烷催化剂复合钒酸铋光电极及其制备方法
TWI794836B (zh) * 2021-06-16 2023-03-01 國立成功大學 高熵複合甘油酸酯及其製法和包含其的電催化劑
CN115710292B (zh) * 2021-08-23 2025-10-24 中国科学院化学研究所 含稀土离子的仿生水裂解催化剂及其制备方法和应用
WO2023023898A1 (zh) * 2021-08-23 2023-03-02 中国科学院化学研究所 含稀土离子的仿生水裂解催化剂及其制备方法和应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101134723A (zh) * 2006-08-29 2008-03-05 惠州市昆泰精细化工有限公司 没食子酸与二价金属离子的复合物及其制备方法与应用
US9365600B2 (en) * 2011-05-06 2016-06-14 University Of Florida Research Foundation, Inc. Polynuclear metal clusters, methods of making, and methods of use thereof
CN104761591B (zh) * 2015-02-06 2017-07-21 中国科学院化学研究所 一种含有Mn4CaO4核心结构的水裂解催化剂，其制备方法及其应用

Also Published As

Publication number Publication date
US20180008969A1 (en) 2018-01-11
AU2016214806A1 (en) 2017-09-07
CA2975919A1 (en) 2016-08-11
JP6795508B2 (ja) 2020-12-02
KR20170102946A (ko) 2017-09-12
CN104761591B (zh) 2017-07-21
EP3255053B1 (en) 2019-09-18
US10421065B2 (en) 2019-09-24
WO2016124133A1 (zh) 2016-08-11
JP2018507843A (ja) 2018-03-22
CN104761591A (zh) 2015-07-08
AU2016214806B2 (en) 2020-03-19
KR101991755B1 (ko) 2019-06-21
EP3255053A1 (en) 2017-12-13
EP3255053A4 (en) 2018-08-01

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