CA2909443C - Procede pour separer des sels de metal alcalin d'hydrocarbures ayant reagi avec un metal alcalin - Google Patents

Procede pour separer des sels de metal alcalin d'hydrocarbures ayant reagi avec un metal alcalin Download PDF

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Publication number
CA2909443C
CA2909443C CA2909443A CA2909443A CA2909443C CA 2909443 C CA2909443 C CA 2909443C CA 2909443 A CA2909443 A CA 2909443A CA 2909443 A CA2909443 A CA 2909443A CA 2909443 C CA2909443 C CA 2909443C
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Canada
Prior art keywords
alkali metal
mixture
hydrocarbon feedstock
sodium
process according
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Active
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CA2909443A
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English (en)
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CA2909443A1 (fr
Inventor
John Gordon
Javier Alvare
Dennis Leroy Larsen
Jeff Killpack
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Enlighten Innovations Inc
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Enlighten Innovations Inc
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Publication date
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Publication of CA2909443A1 publication Critical patent/CA2909443A1/fr
Application granted granted Critical
Publication of CA2909443C publication Critical patent/CA2909443C/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/08—Recovery of used refining agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/067—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with molten alkaline material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/073—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with solid alkaline material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/12—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one alkaline treatment step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne un procédé destiné à faciliter la séparation gravimétrique de sels de métal alcalin, par exemple des sulfures et polysulfures de métal alcalin, d'hydrocarbures ayant réagi avec un métal alcalin. Le procédé divulgué fait partie d'un procédé de valorisation d'une charge d'hydrocarbures par suppression d'hétéroatomes et/ou d'un ou plusieurs métaux lourds de la composition de la charge d'hydrocarbures. Ce procédé consiste à faire réagir la charge d'huiles avec un métal alcalin et un hydrocarbure de valorisation. Le métal alcalin réagit avec une partie des hétéroatomes et/ou avec un ou plusieurs métaux lourds pour former une phase inorganique contenant des sels de métal alcalin et des métaux lourds réduits, et une charge d'hydrocarbures valorisée. La phase inorganique peut être séparée par gravimétrie de la charge d'hydrocarbures valorisée après mélangeage à une température comprise entre environ 350 °C et 400 °C pendant un laps de temps compris entre environ 15 minutes et 2 heures.
CA2909443A 2013-04-15 2014-04-15 Procede pour separer des sels de metal alcalin d'hydrocarbures ayant reagi avec un metal alcalin Active CA2909443C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361812057P 2013-04-15 2013-04-15
US61/812,057 2013-04-15
PCT/US2014/034183 WO2014172361A1 (fr) 2013-04-15 2014-04-15 Procédé pour séparer des sels de métal alcalin d'hydrocarbures ayant réagi avec un métal alcalin

Publications (2)

Publication Number Publication Date
CA2909443A1 CA2909443A1 (fr) 2014-10-23
CA2909443C true CA2909443C (fr) 2019-10-01

Family

ID=51731798

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2909443A Active CA2909443C (fr) 2013-04-15 2014-04-15 Procede pour separer des sels de metal alcalin d'hydrocarbures ayant reagi avec un metal alcalin

Country Status (10)

Country Link
EP (1) EP2986691A4 (fr)
JP (1) JP6480914B2 (fr)
KR (1) KR102090358B1 (fr)
CN (1) CN105229120B (fr)
CA (1) CA2909443C (fr)
HK (1) HK1224325A1 (fr)
MX (1) MX2015014348A (fr)
MY (1) MY173980A (fr)
SG (1) SG11201508465WA (fr)
WO (1) WO2014172361A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10113122B2 (en) 2015-08-31 2018-10-30 University Of New Brunswick Process for upgrading heavy hydrocarbon liquids
JP6817656B2 (ja) * 2016-10-04 2021-01-20 エンライテン イノベーションズ インコーポレイテッド 液体炭化水素からアルカリ金属塩を含む粒子を分離するための方法
US11407646B2 (en) * 2016-10-19 2022-08-09 National Institute For Materials Science Method for synthesizing ammonia, and apparatus for said method
KR20230087600A (ko) * 2020-10-19 2023-06-16 차이나 페트로리움 앤드 케미컬 코포레이션 연료유 생산 방법, 시스템 및 그 응용, 연료유 및 그 응용

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3788978A (en) * 1972-05-24 1974-01-29 Exxon Research Engineering Co Process for the desulfurization of petroleum oil stocks
US3787315A (en) * 1972-06-01 1974-01-22 Exxon Research Engineering Co Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen
JPS63295406A (ja) * 1986-07-21 1988-12-01 Sankyo Kasei Kk 結晶硫化ナトリウム水和物の製造法
US7192516B2 (en) * 2003-04-17 2007-03-20 Trans Ionics Corporation Desulfurization of petroleum streams using metallic sodium
US7686948B2 (en) * 2004-12-27 2010-03-30 Exxonmobil Research And Engineering Company Method of removing sulfur from sulfur-containing hydrocarbon streams
US8088270B2 (en) * 2007-11-27 2012-01-03 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
KR101736753B1 (ko) * 2009-11-02 2017-05-17 필드 업그레이딩 리미티드 알칼리 금속과 탄화수소를 사용하여 석유 공급원료를 업그레이드시키는 방법
EP2696954B1 (fr) * 2011-04-15 2021-08-25 Aditya Birla Science and Technology Company Private Limited Procédé de séparation et de purification de sulfure de sodium
KR101920524B1 (ko) * 2011-07-15 2018-11-20 필드 업그레이딩 리미티드 알칼리 금속을 사용한 업그레이드 플랫폼

Also Published As

Publication number Publication date
HK1224325A1 (zh) 2017-08-18
JP6480914B2 (ja) 2019-03-13
CA2909443A1 (fr) 2014-10-23
KR102090358B1 (ko) 2020-03-17
WO2014172361A1 (fr) 2014-10-23
SG11201508465WA (en) 2015-11-27
JP2016521303A (ja) 2016-07-21
KR20150143652A (ko) 2015-12-23
CN105229120B (zh) 2018-09-21
MX2015014348A (es) 2016-10-03
EP2986691A4 (fr) 2017-03-29
MY173980A (en) 2020-03-02
CN105229120A (zh) 2016-01-06
EP2986691A1 (fr) 2016-02-24

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Effective date: 20190410