CA2904503C - Modified cellulose from chemical kraft fiber and methods of making and using the same - Google Patents
Modified cellulose from chemical kraft fiber and methods of making and using the same Download PDFInfo
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- CA2904503C CA2904503C CA2904503A CA2904503A CA2904503C CA 2904503 C CA2904503 C CA 2904503C CA 2904503 A CA2904503 A CA 2904503A CA 2904503 A CA2904503 A CA 2904503A CA 2904503 C CA2904503 C CA 2904503C
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- Prior art keywords
- fiber
- cellulose
- kraft
- pulp
- stage
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- 239000000835 fiber Substances 0.000 title claims abstract description 657
- 239000002655 kraft paper Substances 0.000 title claims abstract description 251
- 238000000034 method Methods 0.000 title claims abstract description 180
- 229920002678 cellulose Polymers 0.000 title description 138
- 239000001913 cellulose Substances 0.000 title description 127
- 239000000126 substance Substances 0.000 title description 27
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- 150000002978 peroxides Chemical class 0.000 claims abstract description 35
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- 206010021639 Incontinence Diseases 0.000 claims abstract description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 79
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- 230000001965 increasing effect Effects 0.000 claims description 23
- 230000014759 maintenance of location Effects 0.000 claims description 18
- 230000006872 improvement Effects 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 159
- 229910052742 iron Inorganic materials 0.000 abstract description 77
- 238000011282 treatment Methods 0.000 abstract description 56
- 229920003043 Cellulose fiber Polymers 0.000 description 165
- 235000010980 cellulose Nutrition 0.000 description 125
- 239000000047 product Substances 0.000 description 122
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 100
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 70
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- 229910052802 copper Inorganic materials 0.000 description 60
- 238000004519 manufacturing process Methods 0.000 description 54
- 239000010949 copper Substances 0.000 description 52
- 239000000523 sample Substances 0.000 description 52
- 150000001299 aldehydes Chemical group 0.000 description 51
- 238000012360 testing method Methods 0.000 description 39
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 34
- 229910021529 ammonia Inorganic materials 0.000 description 33
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 33
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 31
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- 239000010410 layer Substances 0.000 description 29
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- 235000005018 Pinus echinata Nutrition 0.000 description 26
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- 229920000742 Cotton Polymers 0.000 description 16
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 16
- 239000003205 fragrance Substances 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 15
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- 230000001580 bacterial effect Effects 0.000 description 12
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 12
- 230000002829 reductive effect Effects 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- 239000007844 bleaching agent Substances 0.000 description 11
- 239000001301 oxygen Substances 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 10
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- 239000005751 Copper oxide Substances 0.000 description 9
- -1 Fenton's reagent Chemical class 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229960004643 cupric oxide Drugs 0.000 description 9
- 239000011790 ferrous sulphate Substances 0.000 description 9
- 235000003891 ferrous sulphate Nutrition 0.000 description 9
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 238000004537 pulping Methods 0.000 description 9
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- 239000012028 Fenton's reagent Substances 0.000 description 7
- MGZTXXNFBIUONY-UHFFFAOYSA-N hydrogen peroxide;iron(2+);sulfuric acid Chemical compound [Fe+2].OO.OS(O)(=O)=O MGZTXXNFBIUONY-UHFFFAOYSA-N 0.000 description 7
- 230000002401 inhibitory effect Effects 0.000 description 7
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- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 125000003172 aldehyde group Chemical group 0.000 description 6
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 6
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- 239000012530 fluid Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 6
- 230000035484 reaction time Effects 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- 229920000057 Mannan Polymers 0.000 description 5
- 229920000297 Rayon Polymers 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
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- 239000000825 pharmaceutical preparation Substances 0.000 description 5
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- 229920001503 Glucan Polymers 0.000 description 4
- 229920001131 Pulp (paper) Polymers 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
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- 229920002301 cellulose acetate Polymers 0.000 description 4
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- 229920005610 lignin Polymers 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
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- 239000007858 starting material Substances 0.000 description 4
- 229920001221 xylan Polymers 0.000 description 4
- 150000004823 xylans Chemical class 0.000 description 4
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 239000004155 Chlorine dioxide Substances 0.000 description 3
- 238000010306 acid treatment Methods 0.000 description 3
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- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
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- 239000011230 binding agent Substances 0.000 description 3
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- 235000019398 chlorine dioxide Nutrition 0.000 description 3
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- 239000008367 deionised water Substances 0.000 description 3
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- 235000006040 Prunus persica var persica Nutrition 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
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- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical class C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
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- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 229940007042 proteus vulgaris Drugs 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002601 urease inhibitor Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/28—Polysaccharides or their derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/40—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing ingredients of undetermined constitution or reaction products thereof, e.g. plant or animal extracts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Hematology (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Botany (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Zoology (AREA)
- Paper (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/840,915 | 2013-03-15 | ||
| US13/840,915 US9511167B2 (en) | 2009-05-28 | 2013-03-15 | Modified cellulose from chemical kraft fiber and methods of making and using the same |
| PCT/IB2014/000854 WO2014140819A1 (en) | 2013-03-15 | 2014-03-05 | Modified cellulose from chemical kraft fiber and methods of making and using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2904503A1 CA2904503A1 (en) | 2014-09-18 |
| CA2904503C true CA2904503C (en) | 2021-03-02 |
Family
ID=50972743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2904503A Active CA2904503C (en) | 2013-03-15 | 2014-03-05 | Modified cellulose from chemical kraft fiber and methods of making and using the same |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP2968644A1 (he) |
| JP (2) | JP6341940B2 (he) |
| KR (1) | KR20150141969A (he) |
| CN (1) | CN105209083B (he) |
| AU (1) | AU2014229580B2 (he) |
| BR (1) | BR112015022887A2 (he) |
| CA (1) | CA2904503C (he) |
| IL (1) | IL241057B (he) |
| MX (1) | MX2015012713A (he) |
| RU (1) | RU2662553C2 (he) |
| TW (1) | TWI620847B (he) |
| WO (1) | WO2014140819A1 (he) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6404259B2 (ja) * | 2016-05-13 | 2018-10-10 | ユニ・チャーム株式会社 | 吸収性物品 |
| KR102381597B1 (ko) * | 2018-06-29 | 2022-04-01 | 유니챰 가부시키가이샤 | 흡수성 물품 |
| CN114134747B (zh) * | 2021-11-02 | 2023-01-06 | 天津科技大学 | 芬顿氧化高效降解纸浆残余木素短序漂白方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL113985C (he) | 1957-01-28 | |||
| US5346589A (en) | 1991-02-21 | 1994-09-13 | Genencor International, Inc. | Crystalline cellulose production |
| US5223096A (en) | 1991-11-01 | 1993-06-29 | Procter & Gamble Company | Soft absorbent tissue paper with high permanent wet strength |
| US5264082A (en) | 1992-04-09 | 1993-11-23 | Procter & Gamble Company | Soft absorbent tissue paper containing a biodegradable quaternized amine-ester softening compound and a permanent wet strength resin |
| US5262007A (en) | 1992-04-09 | 1993-11-16 | Procter & Gamble Company | Soft absorbent tissue paper containing a biodegradable quaternized amine-ester softening compound and a temporary wet strength resin |
| US5312522A (en) | 1993-01-14 | 1994-05-17 | Procter & Gamble Company | Paper products containing a biodegradable chemical softening composition |
| US6074527A (en) * | 1994-06-29 | 2000-06-13 | Kimberly-Clark Worldwide, Inc. | Production of soft paper products from coarse cellulosic fibers |
| US5415737A (en) | 1994-09-20 | 1995-05-16 | The Procter & Gamble Company | Paper products containing a biodegradable vegetable oil based chemical softening composition |
| EP0889997B1 (en) | 1996-03-28 | 2002-07-10 | The Procter & Gamble Company | Paper products having wet strength from aldehyde-functionalized cellulosic fibers and polymers |
| US6310268B1 (en) * | 1999-09-29 | 2001-10-30 | Rayonier Products And Financial Services Company | Non-ionic plasticizer additives for wood pulps and absorbent cores |
| US6582559B2 (en) | 2000-05-04 | 2003-06-24 | Sca Hygiene Products Zeist B.V. | Aldehyde-containing polymers as wet strength additives |
| AU2003229743A1 (en) * | 2002-05-01 | 2003-11-17 | Basf Aktiengesellschaft | Plasticized superabsorbent polymer sheets and use thereof in hygienic articles |
| US7019191B2 (en) | 2003-03-25 | 2006-03-28 | Ethicon, Inc. | Hemostatic wound dressings and methods of making same |
| US6844066B2 (en) * | 2003-05-19 | 2005-01-18 | Rayonier Products And Financial Services Company | Superabsorbent cellulosic fiber and method of making same |
| ES2974916T3 (es) * | 2005-05-02 | 2024-07-02 | Int Paper Co | Materiales lignocelulósicos y los productos fabricados a partir de los mismos |
| RU2419456C2 (ru) * | 2006-11-17 | 2011-05-27 | Ска Хайджин Продактс Аб | Абсорбирующее изделие |
| CA2949518C (en) * | 2009-05-28 | 2019-01-08 | Gp Cellulose Gmbh | Modified cellulose from chemical kraft fiber and methods of making and using the same |
-
2014
- 2014-03-05 CA CA2904503A patent/CA2904503C/en active Active
- 2014-03-05 MX MX2015012713A patent/MX2015012713A/es unknown
- 2014-03-05 EP EP14730987.6A patent/EP2968644A1/en not_active Withdrawn
- 2014-03-05 WO PCT/IB2014/000854 patent/WO2014140819A1/en active Application Filing
- 2014-03-05 JP JP2015562380A patent/JP6341940B2/ja active Active
- 2014-03-05 KR KR1020157029626A patent/KR20150141969A/ko not_active Application Discontinuation
- 2014-03-05 RU RU2015144199A patent/RU2662553C2/ru active
- 2014-03-05 AU AU2014229580A patent/AU2014229580B2/en active Active
- 2014-03-05 CN CN201480026854.5A patent/CN105209083B/zh active Active
- 2014-03-05 BR BR112015022887A patent/BR112015022887A2/pt not_active Application Discontinuation
- 2014-03-14 TW TW103109524A patent/TWI620847B/zh active
-
2015
- 2015-09-02 IL IL241057A patent/IL241057B/he active IP Right Grant
-
2018
- 2018-02-13 JP JP2018022933A patent/JP2018075495A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| TWI620847B (zh) | 2018-04-11 |
| AU2014229580A1 (en) | 2015-09-17 |
| AU2014229580B2 (en) | 2017-05-04 |
| WO2014140819A1 (en) | 2014-09-18 |
| IL241057A0 (he) | 2015-11-30 |
| CN105209083A (zh) | 2015-12-30 |
| RU2015144199A (ru) | 2017-04-24 |
| CN105209083B (zh) | 2018-08-10 |
| JP6341940B2 (ja) | 2018-06-13 |
| CA2904503A1 (en) | 2014-09-18 |
| RU2662553C2 (ru) | 2018-07-26 |
| TW201443314A (zh) | 2014-11-16 |
| EP2968644A1 (en) | 2016-01-20 |
| BR112015022887A2 (pt) | 2017-07-18 |
| MX2015012713A (es) | 2016-10-21 |
| JP2016512061A (ja) | 2016-04-25 |
| KR20150141969A (ko) | 2015-12-21 |
| IL241057B (he) | 2020-02-27 |
| JP2018075495A (ja) | 2018-05-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20190225 |