CA2864478A1 - Procede de nanofiltration permettant d'ameliorer la recuperation de la saumure et l'elimination des sulfates - Google Patents
Procede de nanofiltration permettant d'ameliorer la recuperation de la saumure et l'elimination des sulfates Download PDFInfo
- Publication number
- CA2864478A1 CA2864478A1 CA2864478A CA2864478A CA2864478A1 CA 2864478 A1 CA2864478 A1 CA 2864478A1 CA 2864478 A CA2864478 A CA 2864478A CA 2864478 A CA2864478 A CA 2864478A CA 2864478 A1 CA2864478 A1 CA 2864478A1
- Authority
- CA
- Canada
- Prior art keywords
- stream
- nanofiltration
- brine
- module
- outlet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 title claims abstract description 135
- 239000012267 brine Substances 0.000 title claims abstract description 127
- 238000001728 nano-filtration Methods 0.000 title claims abstract description 107
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 53
- 230000008569 process Effects 0.000 title claims abstract description 47
- 238000011084 recovery Methods 0.000 title abstract description 10
- 239000012466 permeate Substances 0.000 claims abstract description 46
- 238000010790 dilution Methods 0.000 claims abstract description 44
- 239000012895 dilution Substances 0.000 claims abstract description 44
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000012535 impurity Substances 0.000 claims abstract description 18
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 13
- 239000012528 membrane Substances 0.000 claims description 56
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 37
- 239000011780 sodium chloride Substances 0.000 claims description 18
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 17
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 17
- 235000011152 sodium sulphate Nutrition 0.000 claims description 17
- 239000007832 Na2SO4 Substances 0.000 claims description 11
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000007865 diluting Methods 0.000 abstract description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 150000003839 salts Chemical class 0.000 description 12
- 150000001450 anions Chemical class 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 108091006629 SLC13A2 Proteins 0.000 description 9
- 230000003204 osmotic effect Effects 0.000 description 8
- 235000011121 sodium hydroxide Nutrition 0.000 description 8
- 238000012993 chemical processing Methods 0.000 description 6
- 239000012141 concentrate Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 5
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 3
- -1 S042- Chemical class 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003966 growth inhibitor Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005374 membrane filtration Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000000108 ultra-filtration Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000003843 chloralkali process Methods 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000012994 industrial processing Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/027—Nanofiltration
- B01D61/0271—Nanofiltration comprising multiple nanofiltration steps
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
- B01D61/026—Reverse osmosis; Hyperfiltration comprising multiple reverse osmosis steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/027—Nanofiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/04—Feed pretreatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/04—Chlorides
- C01D3/06—Preparation by working up brines; seawater or spent lyes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/442—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2317/00—Membrane module arrangements within a plant or an apparatus
- B01D2317/02—Elements in series
- B01D2317/022—Reject series
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/101—Sulfur compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261607722P | 2012-03-07 | 2012-03-07 | |
US61/607,722 | 2012-03-07 | ||
PCT/CA2013/050131 WO2013131183A1 (fr) | 2012-03-07 | 2013-02-20 | Procédé de nanofiltration permettant d'améliorer la récupération de la saumure et l'élimination des sulfates |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2864478A1 true CA2864478A1 (fr) | 2013-09-12 |
Family
ID=49115825
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2864478A Abandoned CA2864478A1 (fr) | 2012-03-07 | 2013-02-20 | Procede de nanofiltration permettant d'ameliorer la recuperation de la saumure et l'elimination des sulfates |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2822674A4 (fr) |
CA (1) | CA2864478A1 (fr) |
WO (1) | WO2013131183A1 (fr) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016005996A2 (fr) * | 2014-07-10 | 2016-01-14 | Geist Research Pvt. Ltd. | Procédé et système de récupération de sulfate de sodium anhydre à partir d'un flux de rejet d'un système d'élimination de sulfates |
US10947143B2 (en) | 2019-04-01 | 2021-03-16 | Saline Water Conversion Corporation | Desalination brine concentration system and method |
WO2021034332A1 (fr) | 2019-08-22 | 2021-02-25 | Saline Water Conversion Corporation | Concentration d'ions multivalents à l'aide d'une nanofiltration à plusieurs étages |
CN115298136A (zh) * | 2020-03-16 | 2022-11-04 | 杜邦安全与建筑公司 | 硫酸的浓缩 |
CN111362471A (zh) * | 2020-04-17 | 2020-07-03 | 莱特莱德(北京)环境技术股份有限公司 | 煤化工副产氯化钠饱和溶液中脱硫酸钠的装置 |
US11806668B2 (en) | 2021-12-14 | 2023-11-07 | Saline Water Conversion Corporation | Method and system for extraction of minerals based on divalent cations from brine |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4586993A (en) * | 1985-05-31 | 1986-05-06 | Stearns Catalytic World Corporation | Control of sulfates in membrane cell chlor-alkali process |
US5587083A (en) * | 1995-04-17 | 1996-12-24 | Chemetics International Company Ltd. | Nanofiltration of concentrated aqueous salt solutions |
EP1586562A1 (fr) * | 2004-03-30 | 2005-10-19 | Council of Scientific and Industrial Research | Récupération de thiocyanate de natrium à partir d'une solution provenant d'un procédé industriel par nanofiltration |
CA2469769A1 (fr) * | 2004-06-04 | 2005-12-04 | Aker Kvaerner Canada Inc. | Appareil et methode pour concentrer une solution d'halogenure de metal alcalin usee au moyen d'une distillation sur membrane osmotique |
US8083942B2 (en) * | 2004-12-06 | 2011-12-27 | Board of Regents of the Nevada System of Higher Education, on Behalf of the Universary of Nevada, Reno | Systems and methods for purification of liquids |
MX2007010061A (es) * | 2005-02-18 | 2007-10-10 | Akzo Nobel Nv | Procedimiento para preparar sal. |
CN201144172Y (zh) * | 2007-12-27 | 2008-11-05 | 张艳 | 纳滤膜脱除盐水中硫酸根的装置 |
US20100163471A1 (en) * | 2008-12-30 | 2010-07-01 | Irving Elyanow | Water desalination plant and system for the production of pure water and salt |
US9561471B2 (en) * | 2009-05-13 | 2017-02-07 | Carollo Engineers, Inc. | Brine treatment scaling control system and method |
WO2011102848A1 (fr) * | 2010-02-17 | 2011-08-25 | Katana Energy Llc | Installation de dessalement de l'eau de mer sans rejets comprenant l'extraction de minéraux intégrée à la production d'une énergie à cycle combiné au gaz naturel |
-
2013
- 2013-02-20 WO PCT/CA2013/050131 patent/WO2013131183A1/fr active Application Filing
- 2013-02-20 EP EP13758618.6A patent/EP2822674A4/fr not_active Withdrawn
- 2013-02-20 CA CA2864478A patent/CA2864478A1/fr not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
EP2822674A4 (fr) | 2015-12-16 |
WO2013131183A1 (fr) | 2013-09-12 |
EP2822674A1 (fr) | 2015-01-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20140299546A1 (en) | Nanofiltration process for enhanced brine recovery and sulfate removal | |
US5587083A (en) | Nanofiltration of concentrated aqueous salt solutions | |
CA2504848C (fr) | Appareil et methode de distillation a membrane d'osmose | |
CA2864478A1 (fr) | Procede de nanofiltration permettant d'ameliorer la recuperation de la saumure et l'elimination des sulfates | |
WO2007132477A1 (fr) | Processus de prétraitement des eaux salées alimentant des usines de dessalement | |
NO341704B1 (no) | Fremgangsmåte for fremstilling av salt | |
JP2008516883A (ja) | 塩水から2価アニオンの可溶性塩を結晶化させる方法 | |
US20150165381A1 (en) | Nanofiltration process for impurity removal | |
DK1848661T3 (en) | PROCEDURE FOR THE PREPARATION OF CHLOR OR SODIUM CHLORATE | |
CN107098360A (zh) | 利用草甘膦废盐水生产离子膜烧碱用原料的方法 | |
US20190023569A1 (en) | High strength, low salt hypochlorite production | |
WO2022173852A1 (fr) | Systèmes et procédés de production directe d'hydroxyde de lithium | |
WO2005092793A1 (fr) | Recuperation de thiocyanate de sodium dans une solution industrielle par une technique de nanofiltration | |
WO2021152356A1 (fr) | Procédé et système de récupération d'eau et de sels à partir de rejet de saumure d'une installation de dessalement conduisant à un système de rejet zéro liquide | |
EP2855355A1 (fr) | Processus de séparation de membrane assisté par cristallisation | |
NO344281B1 (no) | Fremgangsmåte for fremstilling av klorinneholdende forbindelser | |
EP1586562A1 (fr) | Récupération de thiocyanate de natrium à partir d'une solution provenant d'un procédé industriel par nanofiltration |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FZDE | Discontinued |
Effective date: 20170222 |