CA2857018A1 - Azide crosslinked and physically crosslinked polymers for membrane separation - Google Patents
Azide crosslinked and physically crosslinked polymers for membrane separation Download PDFInfo
- Publication number
- CA2857018A1 CA2857018A1 CA2857018A CA2857018A CA2857018A1 CA 2857018 A1 CA2857018 A1 CA 2857018A1 CA 2857018 A CA2857018 A CA 2857018A CA 2857018 A CA2857018 A CA 2857018A CA 2857018 A1 CA2857018 A1 CA 2857018A1
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- Prior art keywords
- membrane
- formula
- composition according
- independently
- azide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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- 239000012528 membrane Substances 0.000 title claims abstract description 145
- 238000000926 separation method Methods 0.000 title claims abstract description 48
- 150000001540 azides Chemical class 0.000 title claims abstract description 43
- 229920006037 cross link polymer Polymers 0.000 title description 4
- 239000007789 gas Substances 0.000 claims abstract description 98
- 239000000203 mixture Substances 0.000 claims abstract description 62
- 150000001875 compounds Chemical class 0.000 claims abstract description 53
- 239000002253 acid Substances 0.000 claims abstract description 27
- 150000002148 esters Chemical class 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 33
- 239000003431 cross linking reagent Substances 0.000 claims description 30
- 125000003118 aryl group Chemical group 0.000 claims description 28
- 239000004615 ingredient Substances 0.000 claims description 15
- 125000004122 cyclic group Chemical group 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 125000000743 hydrocarbylene group Chemical group 0.000 claims description 10
- 125000003367 polycyclic group Chemical group 0.000 claims description 9
- 125000002947 alkylene group Chemical group 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 238000000746 purification Methods 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 125000005647 linker group Chemical group 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
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- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 239000003546 flue gas Substances 0.000 abstract description 9
- 150000001408 amides Chemical class 0.000 abstract description 8
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 7
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- -1 suffocate Chemical compound 0.000 description 49
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- 229910002092 carbon dioxide Inorganic materials 0.000 description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 21
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 18
- 238000004132 cross linking Methods 0.000 description 15
- 239000000178 monomer Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
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- 238000003491 array Methods 0.000 description 8
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- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
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- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
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- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 229920002677 supramolecular polymer Polymers 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- FRGPKMWIYVTFIQ-UHFFFAOYSA-N triethoxy(3-isocyanatopropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN=C=O FRGPKMWIYVTFIQ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/27—Compounds containing a nitrogen atom bound to two other nitrogen atoms, e.g. diazoamino-compounds
- C08K5/28—Azides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/54—Polyureas; Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/44—Polyester-amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/43—Compounds containing sulfur bound to nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D2053/221—Devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyamides (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161537387P | 2011-09-21 | 2011-09-21 | |
| US61/537,387 | 2011-09-21 | ||
| PCT/US2012/056234 WO2013043807A1 (en) | 2011-09-21 | 2012-09-20 | Azide crosslinked and physically crosslinked polymers for membrane separation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2857018A1 true CA2857018A1 (en) | 2013-03-28 |
Family
ID=47003239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2857018A Abandoned CA2857018A1 (en) | 2011-09-21 | 2012-09-20 | Azide crosslinked and physically crosslinked polymers for membrane separation |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9174175B2 (enExample) |
| JP (1) | JP2015500891A (enExample) |
| CN (1) | CN104220527B (enExample) |
| AU (1) | AU2012312423A1 (enExample) |
| BR (1) | BR112014006503A2 (enExample) |
| CA (1) | CA2857018A1 (enExample) |
| IL (1) | IL231551A0 (enExample) |
| IN (1) | IN2014CN02124A (enExample) |
| RU (1) | RU2014115675A (enExample) |
| WO (1) | WO2013043807A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014047174A1 (en) * | 2012-09-20 | 2014-03-27 | Dow Global Technologies Llc | Radiation cured membranes derived from polymers that are co-reactive with azide crosslinking agent(s) |
| US9238202B2 (en) * | 2013-12-12 | 2016-01-19 | Uop Llc | Gas separation membranes from chemically and UV treated polymers of intrinsic microporosity |
| US10137406B2 (en) | 2015-06-11 | 2018-11-27 | Hamilton Sundstrand Corporation | Temperature controlled nitrogen generation system |
| CN109906113B (zh) * | 2016-10-28 | 2021-08-31 | 东丽株式会社 | 气体分离膜、气体分离膜元件及气体分离方法 |
| US11717787B2 (en) * | 2021-01-04 | 2023-08-08 | Saudi Arabian Oil Company | High free volume membrane for gas separation |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB816680A (en) * | 1955-11-30 | 1959-07-15 | Ici Ltd | Polymeric foamed materials |
| GB1006140A (en) | 1963-07-26 | 1965-09-29 | Gevaert Photo Prod Nv | Magnetic recording medium |
| US3714194A (en) | 1971-06-09 | 1973-01-30 | Upjohn Co | Di(azidosulfonyl)xanthones |
| US4197133A (en) * | 1977-10-14 | 1980-04-08 | Ciba-Geigy Corporation | Photo-curable compositions of matter containing bis-azidophthalimidyl derivatives |
| NL1003459C2 (nl) | 1996-06-28 | 1998-01-07 | Univ Twente | Copoly(ester-amides) en copoly(ester-urethanen). |
| US7297394B2 (en) | 2002-03-01 | 2007-11-20 | Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg | Biodegradable films and sheets suitable for use as coatings, wraps and packaging materials |
| US20030126990A1 (en) | 2001-12-20 | 2003-07-10 | Koros William J. | Crosslinked and crosslinkable hollow fiber membrane and method of making same |
| JP2008507405A (ja) | 2004-07-26 | 2008-03-13 | ダウ グローバル テクノロジーズ インコーポレイティド | 改良された煤用触媒フィルター |
| JP5107908B2 (ja) | 2005-06-16 | 2012-12-26 | ダウ グローバル テクノロジーズ エルエルシー | 脂肪族ポリエステルアミド組成物およびその製法 |
| CN101258215A (zh) | 2005-09-08 | 2008-09-03 | 陶氏环球技术公司 | 聚酯-酰胺基热熔粘合剂 |
| US7410525B1 (en) | 2005-09-12 | 2008-08-12 | Uop Llc | Mixed matrix membranes incorporating microporous polymers as fillers |
| US8030436B2 (en) * | 2006-07-13 | 2011-10-04 | Advanced Cardiovascular Systems, Inc. | Poly(ester-amide) elastomers and their use with implantable medical devices |
| WO2008064857A1 (en) | 2006-12-01 | 2008-06-05 | Stichting Dutch Polymer Institute | Block-copolymer elastomer |
| WO2008101051A2 (en) | 2007-02-14 | 2008-08-21 | Dow Global Technologies Inc. | Polymer or oligomer fibers by solvent-free electrospinning |
| JP5498778B2 (ja) * | 2007-02-22 | 2014-05-21 | 三井化学株式会社 | アルコキシシラン含有樹脂およびその製造方法 |
| WO2008112833A1 (en) | 2007-03-14 | 2008-09-18 | Dow Global Technologies Inc. | Copolyesteramides with decreased perfection of the amide sequence |
| EP2370196A2 (en) | 2008-11-25 | 2011-10-05 | Dow Global Technologies LLC | Polymer pi-bond-philic filler composites |
| US8268042B2 (en) | 2008-11-25 | 2012-09-18 | Dow Global Technologies Llc | Polymer inorganic clay composites |
| RU2534772C2 (ru) * | 2010-02-12 | 2014-12-10 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Отделение кислых компонентов с помощью мембран из самоорганизующегося полимера |
| BR112013015542A2 (pt) * | 2010-12-20 | 2016-09-13 | Dow Global Technologies Llc | artigo manufaturado curado, método de separação para separar um gas ácido de uma mistura separável, processo de cura e material de msa modificado com silano reticulado |
| AU2011349383A1 (en) * | 2010-12-20 | 2013-06-27 | Dow Global Technologies Llc | Reactive functional group-modified molecularly self-assembling material |
-
2012
- 2012-09-20 CN CN201280056130.6A patent/CN104220527B/zh active Active
- 2012-09-20 WO PCT/US2012/056234 patent/WO2013043807A1/en not_active Ceased
- 2012-09-20 RU RU2014115675/05A patent/RU2014115675A/ru not_active Application Discontinuation
- 2012-09-20 AU AU2012312423A patent/AU2012312423A1/en not_active Abandoned
- 2012-09-20 US US14/345,343 patent/US9174175B2/en active Active
- 2012-09-20 IN IN2124CHN2014 patent/IN2014CN02124A/en unknown
- 2012-09-20 CA CA2857018A patent/CA2857018A1/en not_active Abandoned
- 2012-09-20 JP JP2014531946A patent/JP2015500891A/ja active Pending
- 2012-09-20 BR BR112014006503A patent/BR112014006503A2/pt not_active IP Right Cessation
-
2014
- 2014-03-17 IL IL231551A patent/IL231551A0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20140360366A1 (en) | 2014-12-11 |
| CN104220527A (zh) | 2014-12-17 |
| AU2012312423A8 (en) | 2014-04-24 |
| US9174175B2 (en) | 2015-11-03 |
| BR112014006503A2 (pt) | 2017-03-28 |
| IL231551A0 (en) | 2014-04-30 |
| IN2014CN02124A (enExample) | 2015-05-29 |
| WO2013043807A1 (en) | 2013-03-28 |
| AU2012312423A1 (en) | 2014-04-03 |
| CN104220527B (zh) | 2016-08-24 |
| JP2015500891A (ja) | 2015-01-08 |
| RU2014115675A (ru) | 2015-10-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |
Effective date: 20160921 |