CA2833964C - Process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor - Google Patents

Process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor Download PDF

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Publication number
CA2833964C
CA2833964C CA2833964A CA2833964A CA2833964C CA 2833964 C CA2833964 C CA 2833964C CA 2833964 A CA2833964 A CA 2833964A CA 2833964 A CA2833964 A CA 2833964A CA 2833964 C CA2833964 C CA 2833964C
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CA
Canada
Prior art keywords
catalyst
cobalt
precursor
catalyst support
calcination
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Application number
CA2833964A
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English (en)
French (fr)
Other versions
CA2833964A1 (en
Inventor
Cornelia Carolina Eloff
Jan Van De Loosdrecht
Jacobus Lucas Visagie
Hendrik Van Rensburg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sasol Technology Pty Ltd
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Sasol Technology Pty Ltd
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Publication of CA2833964A1 publication Critical patent/CA2833964A1/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Crystallography & Structural Chemistry (AREA)
CA2833964A 2011-05-06 2012-04-25 Process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor Active CA2833964C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA2011/03330 2011-05-06
ZA201103330 2011-05-06
PCT/IB2012/052070 WO2012153218A1 (en) 2011-05-06 2012-04-25 Process for preparing a cobalt - containing hydrocarbon synthesis catalyst precursor

Publications (2)

Publication Number Publication Date
CA2833964A1 CA2833964A1 (en) 2012-11-15
CA2833964C true CA2833964C (en) 2019-07-02

Family

ID=46124582

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2833964A Active CA2833964C (en) 2011-05-06 2012-04-25 Process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor

Country Status (14)

Country Link
US (1) US9205409B2 (https=)
EP (1) EP2704828B1 (https=)
JP (1) JP5956562B2 (https=)
CN (1) CN103501898B (https=)
AP (1) AP3921A (https=)
AR (1) AR086275A1 (https=)
AU (1) AU2012252073B2 (https=)
BR (1) BR112013028495B1 (https=)
CA (1) CA2833964C (https=)
MY (1) MY165448A (https=)
PE (1) PE20140449A1 (https=)
RU (1) RU2591702C2 (https=)
WO (1) WO2012153218A1 (https=)
ZA (1) ZA201308535B (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AP3921A (en) 2011-05-06 2016-12-03 Sasol Tech Pty Ltd Process for preparing a cobalt - containing hydrocarbon synthesis catalyst precursor
JP6824168B2 (ja) * 2014-12-19 2021-02-03 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイＳｈｅｌｌ Ｉｎｔｅｒｎａｔｉｏｎａｌｅ Ｒｅｓｅａｒｃｈ Ｍａａｔｓｃｈａｐｐｉｊ Ｂｅｓｌｏｔｅｎ Ｖｅｎｎｏｏｔｓｈａｐ 触媒の調製方法
AU2016225128C1 (en) 2015-02-25 2019-11-14 Sasol Technology (Pty) Limited Hydrocarbon synthesis catalyst, its preparation process and its use
WO2020121076A1 (en) 2018-12-10 2020-06-18 Sasol South Africa Limited Process for preparing a cobalt-containing catalyst precursor and process for hydrocarbon synthesis
GB201903502D0 (en) * 2019-03-14 2019-05-01 Johnson Matthey Plc Cobalt catalysts and precursors therefor
GB202014184D0 (en) * 2020-09-09 2020-10-21 Johnson Matthey Plc Modifed catalyst supports and catalysts supported thereon

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4605676A (en) 1981-10-13 1986-08-12 Chevron Research Company Synthesis gas conversion using ROR-activated catalyst
DE3839580C1 (https=) 1988-11-24 1990-07-05 Condea Chemie Gmbh, 2212 Brunsbuettel, De
US5292705A (en) * 1992-09-24 1994-03-08 Exxon Research & Engineering Co. Activation of hydrocarbon synthesis catalyst
BR0016078B1 (pt) * 1999-12-01 2014-04-01 Sasol Tech Pty Ltd Processo para preparar um precursor de catalisador de cobalto de fischer-tropsch.
ITMI20010478A1 (it) * 2001-03-08 2002-09-08 Inst Francais Du Petrole Catalizzatore a base di cobalto e suo utilizzo nel processo di fischer-tropsch
DE102005019103B4 (de) 2004-04-26 2023-09-21 Sasol Technology (Proprietary) Ltd. Verfahren zur Herstellung eines auf Cobalt basierenden Katalysators für die Fischer-Tropsch-Synthese und Verfahren zur Herstellung eines Fischer-Tropsch-Kohlenwasserstoffproduktes
GB0704003D0 (en) * 2007-03-01 2007-04-11 Oxford Catalysts Promoted carbide-based fischer-tropsch catalyst, method for its preparation and uses thereof
WO2008135941A2 (en) * 2007-05-04 2008-11-13 Sasol Technology (Proprietary) Limited Catalysts
WO2009127990A1 (en) * 2008-04-15 2009-10-22 Sasol Technology (Proprietary) Limited Catalysts
US8148292B2 (en) 2008-07-25 2012-04-03 Exxonmobil Research And Engineering Company Preparation of high activity cobalt catalysts, the catalysts and their use
EP2401080B8 (en) * 2009-02-26 2015-01-28 Sasol Technology (Proprietary) Limited Process for the preparation of fischer-tropsch catalysts and their use
AP3921A (en) 2011-05-06 2016-12-03 Sasol Tech Pty Ltd Process for preparing a cobalt - containing hydrocarbon synthesis catalyst precursor

Also Published As

Publication number Publication date
BR112013028495A2 (pt) 2018-04-03
JP2014514153A (ja) 2014-06-19
JP5956562B2 (ja) 2016-07-27
EP2704828A1 (en) 2014-03-12
EP2704828B1 (en) 2021-05-26
RU2013154310A (ru) 2015-06-20
PE20140449A1 (es) 2014-04-15
US9205409B2 (en) 2015-12-08
BR112013028495B1 (pt) 2019-12-03
AR086275A1 (es) 2013-12-04
NZ617768A (en) 2015-03-27
CN103501898B (zh) 2016-01-20
AU2012252073B2 (en) 2016-07-14
CN103501898A (zh) 2014-01-08
AP3921A (en) 2016-12-03
US20140080929A1 (en) 2014-03-20
MY165448A (en) 2018-03-22
WO2012153218A1 (en) 2012-11-15
AU2012252073A1 (en) 2013-12-05
RU2591702C2 (ru) 2016-07-20
CA2833964A1 (en) 2012-11-15
AP2013007246A0 (en) 2013-11-30
ZA201308535B (en) 2015-01-28

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