CA2827635C - Valuable metal extraction agent and valuable metal extraction method using said extraction agent - Google Patents

Valuable metal extraction agent and valuable metal extraction method using said extraction agent Download PDF

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Publication number
CA2827635C
CA2827635C CA 2827635 CA2827635A CA2827635C CA 2827635 C CA2827635 C CA 2827635C CA 2827635 CA2827635 CA 2827635 CA 2827635 A CA2827635 A CA 2827635A CA 2827635 C CA2827635 C CA 2827635C
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CA
Canada
Prior art keywords
unit
extraction agent
valuable metal
rare earth
inclusive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA 2827635
Other languages
French (fr)
Other versions
CA2827635A1 (en
Inventor
Masahiro Goto
Fukiko KUBOTA
Yuzo BABA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Metal Mining Co Ltd
Kyushu University NUC
Original Assignee
Sumitomo Metal Mining Co Ltd
Kyushu University NUC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Mining Co Ltd, Kyushu University NUC filed Critical Sumitomo Metal Mining Co Ltd
Publication of CA2827635A1 publication Critical patent/CA2827635A1/en
Application granted granted Critical
Publication of CA2827635C publication Critical patent/CA2827635C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/20—Compounds containing only rare earth metals as the metal element
    • C01F17/276—Nitrates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/10—Preparation or treatment, e.g. separation or purification
    • C01F17/17—Preparation or treatment, e.g. separation or purification involving a liquid-liquid extraction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C237/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C237/06—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/20—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D233/26—Radicals substituted by carbon atoms having three bonds to hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/40—Mixtures
    • C22B3/402—Mixtures of acyclic or carbocyclic compounds of different types
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B59/00—Obtaining rare earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/54—Reclaiming serviceable parts of waste accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/008—Disposal or recycling of fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The objective of the present invention is to selectively extract light rare earth metals, and by extension, europium, from an acidic solution containing a plurality of types of rare earth metal. This valuable metal extraction agent is represented by the general formula. In the formula: R1 and R2 each indicate the same or different alkyl group; R3 indicates a hydrogen atom or an alkyl group; and R4 indicates a hydrogen atom or any given group other than an amino group bonded to the a carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, when extracting europium using the extraction agent, the pH is adjusted into the range of 2.0-3.0 inclusive, and when selectively extracting light rare earth metals, the pH is adjusted to 1.7-2.7 inclusive. (see above formula)
CA 2827635 2011-11-09 2012-11-02 Valuable metal extraction agent and valuable metal extraction method using said extraction agent Active CA2827635C (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP2011-245981 2011-11-09
JP2011245981 2011-11-09
JP2012-056143 2012-03-13
JP2012056143 2012-03-13
JP2012178293A JP5279938B1 (en) 2011-11-09 2012-08-10 Valuable metal extractant and method for extracting valuable metal using the extractant
JP2012-178293 2012-08-10
PCT/JP2012/078445 WO2013069562A1 (en) 2011-11-09 2012-11-02 Valuable metal extraction agent and valuable metal extraction method using said extraction agent

Publications (2)

Publication Number Publication Date
CA2827635A1 CA2827635A1 (en) 2013-05-16
CA2827635C true CA2827635C (en) 2014-10-14

Family

ID=48289938

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2827635 Active CA2827635C (en) 2011-11-09 2012-11-02 Valuable metal extraction agent and valuable metal extraction method using said extraction agent

Country Status (8)

Country Link
US (2) US9011804B2 (en)
EP (2) EP2679693B1 (en)
JP (1) JP5279938B1 (en)
CN (2) CN103620065B (en)
AU (1) AU2012336969B2 (en)
CA (1) CA2827635C (en)
PH (1) PH12013501712A1 (en)
WO (1) WO2013069562A1 (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5279938B1 (en) 2011-11-09 2013-09-04 国立大学法人九州大学 Valuable metal extractant and method for extracting valuable metal using the extractant
JP5367862B2 (en) * 2012-03-13 2013-12-11 国立大学法人九州大学 Scandium extractant and method for extracting scandium using the extractant
JP5398885B1 (en) * 2012-08-20 2014-01-29 国立大学法人九州大学 Gallium extraction method
JP5420033B1 (en) * 2012-08-20 2014-02-19 国立大学法人九州大学 Indium extractant and method for extracting indium using the extractant
JP5734268B2 (en) 2012-12-12 2015-06-17 国立大学法人九州大学 Nickel extraction method
JP5595543B1 (en) * 2013-03-18 2014-09-24 国立大学法人九州大学 Valuable metal extraction method
JP5595554B1 (en) 2013-03-18 2014-09-24 国立大学法人九州大学 Method for separating impurities from an acidic solution containing nickel, cobalt and / or scandium
EP2960349B1 (en) * 2013-04-15 2017-10-04 Kyushu University, National University Corporation Extraction agent for precious metals and rhenium, and extraction method for precious metals and rhenium using same
CA2903182C (en) 2013-04-15 2016-10-04 Kyushu University, National University Corporation Extraction agent for precious metals and rhenium, and extraction method for precious metals and rhenium using same
JP5619238B1 (en) * 2013-08-22 2014-11-05 住友金属鉱山株式会社 Scandium recovery method
JP6167915B2 (en) * 2014-01-22 2017-07-26 住友金属鉱山株式会社 Method for separating yttrium and zinc
JP6053724B2 (en) * 2014-06-26 2016-12-27 国立大学法人九州大学 Ion exchange resin and metal adsorption separation method
JP6314730B2 (en) * 2014-07-30 2018-04-25 住友金属鉱山株式会社 Method for recovering valuable metals from waste nickel metal hydride batteries
JP5940688B1 (en) * 2015-01-20 2016-06-29 国立大学法人九州大学 Zirconium extractant and zirconium extraction method
US10689727B2 (en) * 2015-04-23 2020-06-23 Ut-Battelle, Llc Methods for liquid extraction of rare earth metals using ionic liquids
JP6614654B2 (en) * 2015-11-25 2019-12-04 国立研究開発法人日本原子力研究開発機構 Nitriloacetic acid diacetamide compound, extractant, and extraction method
GB2560871B (en) * 2016-12-16 2020-06-03 Univ Belfast Separation of rare earth matals
JP7496594B2 (en) * 2020-05-14 2024-06-07 国立大学法人 宮崎大学 Extractant for rare earth metals or iron
JP7485769B2 (en) * 2021-06-24 2024-05-16 福建省金龍稀土股分有限公司 N,N-dihydrocarbyl amido carboxylic acids and methods for their preparation and use
CN115677528B (en) * 2022-11-03 2025-02-25 厦门稀土材料研究所 A method for separating rhenium and technetium

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1034818C (en) * 1993-07-23 1997-05-07 中国科学院上海有机化学研究所 Extractant for separating rare-earth metal
EP0834581A1 (en) 1996-09-30 1998-04-08 Basf Aktiengesellschaft Use of hydrocarbon-soluble aminomethylenephosphonic acid derivatives for the solvent extraction of metal ions from aqueous solutions
JP3385997B2 (en) 1999-02-12 2003-03-10 大平洋金属株式会社 Method of recovering valuable metals from oxide ore
JP5035788B2 (en) * 2006-06-06 2012-09-26 独立行政法人日本原子力研究開発機構 Rare earth metal extractant and extraction method
CN101519427B (en) 2008-02-29 2015-02-25 中国人民解放军军事医学科学院毒物药物研究所 Peptide derivative with endothelin receptor antagonizing activity, drug composition and application thereof
CN100582264C (en) * 2008-03-18 2010-01-20 贵研铂业股份有限公司 Method for extracting metallic nickel cobalt from irony nickel mine
CN101270417B (en) * 2008-04-30 2010-11-03 江西稀有稀土金属钨业集团有限公司 Method for extracting nickel and/or cobalt
JP5326610B2 (en) 2009-02-02 2013-10-30 住友金属鉱山株式会社 Method for recovering metals from used nickel metal hydride batteries
JP5279938B1 (en) 2011-11-09 2013-09-04 国立大学法人九州大学 Valuable metal extractant and method for extracting valuable metal using the extractant
JP5279942B1 (en) 2011-11-09 2013-09-04 国立大学法人九州大学 Cobalt extraction method

Also Published As

Publication number Publication date
US9011804B2 (en) 2015-04-21
CN103620065A (en) 2014-03-05
US20140234187A1 (en) 2014-08-21
US20140328737A1 (en) 2014-11-06
JP2013216966A (en) 2013-10-24
EP2682486A1 (en) 2014-01-08
AU2012336969B2 (en) 2015-06-18
EP2682486A4 (en) 2014-03-12
CA2827635A1 (en) 2013-05-16
PH12013501712A1 (en) 2013-10-07
CN103582711A (en) 2014-02-12
CN103582711B (en) 2015-03-25
US8951486B2 (en) 2015-02-10
EP2679693A1 (en) 2014-01-01
WO2013069562A1 (en) 2013-05-16
JP5279938B1 (en) 2013-09-04
EP2679693B1 (en) 2016-03-16
EP2682486B1 (en) 2016-03-16
CN103620065B (en) 2015-04-29
AU2012336969A1 (en) 2013-09-05
EP2679693A4 (en) 2014-02-19

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