CA2817726A1 - Low gwp heat transfer compositions - Google Patents
Low gwp heat transfer compositions Download PDFInfo
- Publication number
- CA2817726A1 CA2817726A1 CA2817726A CA2817726A CA2817726A1 CA 2817726 A1 CA2817726 A1 CA 2817726A1 CA 2817726 A CA2817726 A CA 2817726A CA 2817726 A CA2817726 A CA 2817726A CA 2817726 A1 CA2817726 A1 CA 2817726A1
- Authority
- CA
- Canada
- Prior art keywords
- weight
- composition
- hfc
- less
- heat transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 138
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims abstract description 44
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims abstract description 33
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- 238000010792 warming Methods 0.000 claims abstract description 13
- 125000004805 propylene group Chemical class [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 7
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims abstract description 6
- 238000005057 refrigeration Methods 0.000 claims description 42
- 238000001816 cooling Methods 0.000 claims description 17
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 claims description 7
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 abstract description 17
- 239000003507 refrigerant Substances 0.000 description 43
- 239000000314 lubricant Substances 0.000 description 9
- 239000000460 chlorine Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000004378 air conditioning Methods 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229920001515 polyalkylene glycol Polymers 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 2
- CDOOAUSHHFGWSA-UHFFFAOYSA-N 1,3,3,3-tetrafluoropropene Chemical compound FC=CC(F)(F)F CDOOAUSHHFGWSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 229920013639 polyalphaolefin Polymers 0.000 description 2
- 238000009420 retrofitting Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- AHSZBZTYLKTYJI-UHFFFAOYSA-N (2,2-dimethyl-3-nonanoyloxypropyl) nonanoate Chemical compound CCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCC AHSZBZTYLKTYJI-UHFFFAOYSA-N 0.000 description 1
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 description 1
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 description 1
- -1 Polyol Esters Chemical class 0.000 description 1
- 101100214695 Staphylococcus aureus aacA-aphD gene Proteins 0.000 description 1
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/34—The mixture being non-azeotropic
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41300010P | 2010-11-12 | 2010-11-12 | |
| US61/413,000 | 2010-11-12 | ||
| US13/292,374 US20120119136A1 (en) | 2010-11-12 | 2011-11-09 | Low gwp heat transfer compositions |
| US13/292,374 | 2011-11-09 | ||
| PCT/US2011/060308 WO2012065026A2 (en) | 2010-11-12 | 2011-11-11 | Low gwp heat transfer compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2817726A1 true CA2817726A1 (en) | 2012-05-18 |
Family
ID=46046960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2817726A Abandoned CA2817726A1 (en) | 2010-11-12 | 2011-11-11 | Low gwp heat transfer compositions |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20120119136A1 (enExample) |
| EP (1) | EP2638124A4 (enExample) |
| JP (2) | JP6017437B2 (enExample) |
| KR (1) | KR20130102617A (enExample) |
| CN (2) | CN103282461A (enExample) |
| BR (1) | BR112013011704A2 (enExample) |
| CA (1) | CA2817726A1 (enExample) |
| MX (1) | MX2013005230A (enExample) |
| WO (1) | WO2012065026A2 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9157018B2 (en) | 2010-11-25 | 2015-10-13 | Arkema France | Compositions of chloro-trifluoropropene and hexafluorobutene |
| FR2968009B1 (fr) | 2010-11-25 | 2012-11-16 | Arkema France | Fluides frigorigenes contenant du (e)-1,1,1,4,4,4-hexafluorobut-2-ene |
| FR2968310B1 (fr) | 2010-12-03 | 2012-12-07 | Arkema France | Compositions a base de 1,1,1,4,4,4-hexafluorobut-2-ene et de 3,3,4,4,4-pentafluorobut-1-ene |
| FR2977256B1 (fr) | 2011-07-01 | 2013-06-21 | Arkema France | Compositions de 2,4,4,4-tetrafluorobut-1-ene et de cis-1,1,1,4,4,4-hexafluorobut-2-ene |
| FR2989084B1 (fr) | 2012-04-04 | 2015-04-10 | Arkema France | Compositions a base de 2,3,3,4,4,4-hexafluorobut-1-ene |
| US9783721B2 (en) | 2012-08-20 | 2017-10-10 | Honeywell International Inc. | Low GWP heat transfer compositions |
| CN104797677A (zh) * | 2012-08-20 | 2015-07-22 | 霍尼韦尔国际公司 | 低gwp传热组合物 |
| TW201410856A (zh) * | 2012-08-23 | 2014-03-16 | Du Pont | 含四氟丙烯及二氟甲烷的冷媒混合物及其運用 |
| TW201412965A (zh) | 2012-08-23 | 2014-04-01 | Du Pont | 含四氟丙烯、二氟甲烷、及可選擇地含二氟乙烷的冷媒混合物及其運用 |
| US8940180B2 (en) | 2012-11-21 | 2015-01-27 | Honeywell International Inc. | Low GWP heat transfer compositions |
| US9982180B2 (en) | 2013-02-13 | 2018-05-29 | Honeywell International Inc. | Heat transfer compositions and methods |
| CN105189689A (zh) * | 2013-02-25 | 2015-12-23 | 霍尼韦尔国际公司 | 含有二氟甲烷和氟代烯烃的组合物 |
| EP2972014A4 (en) * | 2013-03-15 | 2016-10-26 | Honeywell Int Inc | LOW GWP CALOPOROUS COMPOSITIONS |
| US9234123B2 (en) * | 2013-03-21 | 2016-01-12 | Hsi Fire & Safety Group, Llc | Compositions for totally non-flammable aerosol dusters |
| CN105358916A (zh) * | 2013-07-15 | 2016-02-24 | 开利公司 | 用于与hvac/r系统一起使用的阻火器 |
| CN107429150A (zh) * | 2015-02-18 | 2017-12-01 | 霍尼韦尔国际公司 | 低gwp传热组合物 |
| WO2016182030A1 (ja) * | 2015-05-14 | 2016-11-17 | 旭硝子株式会社 | 流体組成物、冷媒組成物および空気調和機 |
| CN108351137B (zh) * | 2015-11-09 | 2021-12-03 | 开利公司 | 并联回路联运集装箱 |
| US11105521B2 (en) * | 2016-03-28 | 2021-08-31 | Mitsubishi Electric Corporation | Outdoor unit |
| JP6443576B2 (ja) * | 2017-05-19 | 2018-12-26 | ダイキン工業株式会社 | 冷媒を含有する組成物、その使用、それを用いた冷凍方法、及びそれを含む冷凍機 |
| CN109280541B (zh) * | 2017-07-19 | 2021-02-12 | 浙江省化工研究院有限公司 | 一种环保型组合物 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090253820A1 (en) * | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
| US9499729B2 (en) * | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
| US7569170B2 (en) * | 2005-03-04 | 2009-08-04 | E.I. Du Pont De Nemours And Company | Compositions comprising a fluoroolefin |
| CN110003859A (zh) * | 2005-03-04 | 2019-07-12 | 科慕埃弗西有限公司 | 包含氟代烯烃的组合物 |
| CN103627019A (zh) * | 2006-03-21 | 2014-03-12 | 霍尼韦尔国际公司 | 含有氟取代不饱和烯烃的发泡剂 |
| ES2982776T3 (es) * | 2007-01-31 | 2024-10-17 | Chemours Co Fc Llc | Un sistema de transferencia de calor por compresión de vapor |
| CN101688817A (zh) * | 2007-06-21 | 2010-03-31 | 纳幕尔杜邦公司 | 用于热传递系统的渗漏检测的方法 |
| GB2457345B (en) * | 2007-10-12 | 2012-02-08 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
| GB201002625D0 (en) * | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
| JP5546726B2 (ja) * | 2007-12-26 | 2014-07-09 | Ｊｘ日鉱日石エネルギー株式会社 | 冷凍機油および冷凍機用作動流体組成物 |
| EP2164917B1 (en) * | 2008-03-07 | 2019-04-24 | Arkema Inc. | Halogenated alkene heat transfer compositions with improved oil return |
| FR2932493B1 (fr) * | 2008-06-11 | 2010-07-30 | Arkema France | Compositions a base d'hydrofluoroolefines |
| MX2021005417A (es) * | 2008-07-30 | 2022-05-18 | Honeywell Int Inc | Composiciones que contienen difluorometano y olefinas sustituidas con fluor. |
| FR2936806B1 (fr) * | 2008-10-08 | 2012-08-31 | Arkema France | Fluide refrigerant |
| JP5012757B2 (ja) * | 2008-10-22 | 2012-08-29 | パナソニック株式会社 | 冷却サイクル装置 |
| US20100122545A1 (en) * | 2008-11-19 | 2010-05-20 | E. I. Du Pont De Nemours And Company | Tetrafluoropropene compositions and uses thereof |
| BR122013002802A2 (pt) * | 2008-11-19 | 2016-01-05 | Du Pont | composição, processo para produzir resfriamento, processo para produzir aquecimento, método, aparelhos e sistema de refrigeração estacionário |
| BRPI0922124A2 (pt) * | 2008-12-02 | 2016-01-05 | Mexichem Amanco Holding Sa | composição e dispositivo de tranferência de calor, uso de uma composição, agente de sopro, composição espumável, espuma, composição pulverizável, métodos para resfriar e para aquecer um artigo, para extrair uma substância da biomassa, um material de uma solução aquosa, e um material de uma matriz sólida particulada, para limpar um artigo, para reequipar um dispositivo de transferência de calor, para reduzir o impacto ambiental que surge da operação de um produto, e para gerar crédito de emissão de gás de estufa, e, dispositivo de geração de energia mecânica. |
| JP2010203759A (ja) * | 2009-02-04 | 2010-09-16 | Panasonic Corp | 冷凍装置 |
| GB0906547D0 (en) * | 2009-04-16 | 2009-05-20 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
| FR2950067B1 (fr) * | 2009-09-11 | 2011-10-28 | Arkema France | Fluide de transfert de chaleur en remplacement du r-410a |
| FR2950068B1 (fr) * | 2009-09-11 | 2012-05-18 | Arkema France | Procede de transfert de chaleur |
| FR2959999B1 (fr) * | 2010-05-11 | 2012-07-20 | Arkema France | Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant |
| CN101864276A (zh) * | 2010-06-03 | 2010-10-20 | 集美大学 | 环保型制冷剂 |
| US9169427B2 (en) * | 2011-07-13 | 2015-10-27 | Honeywell International Inc. | Low GWP heat transfer compositions containing difluoromethane, a fluorinated ethane and 1,3,3,3-tetrafluoropropene |
| JP2014081119A (ja) * | 2012-10-16 | 2014-05-08 | Panasonic Corp | 冷凍装置 |
-
2011
- 2011-11-09 US US13/292,374 patent/US20120119136A1/en not_active Abandoned
- 2011-11-11 WO PCT/US2011/060308 patent/WO2012065026A2/en not_active Ceased
- 2011-11-11 MX MX2013005230A patent/MX2013005230A/es unknown
- 2011-11-11 JP JP2013538925A patent/JP6017437B2/ja not_active Expired - Fee Related
- 2011-11-11 KR KR1020137014375A patent/KR20130102617A/ko not_active Ceased
- 2011-11-11 CN CN2011800647552A patent/CN103282461A/zh active Pending
- 2011-11-11 CN CN201611176528.XA patent/CN107083235A/zh active Pending
- 2011-11-11 EP EP11839053.3A patent/EP2638124A4/en not_active Withdrawn
- 2011-11-11 CA CA2817726A patent/CA2817726A1/en not_active Abandoned
- 2011-11-11 BR BR112013011704A patent/BR112013011704A2/pt not_active IP Right Cessation
-
2016
- 2016-08-09 JP JP2016156227A patent/JP2017025321A/ja not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| BR112013011704A2 (pt) | 2016-08-16 |
| JP2017025321A (ja) | 2017-02-02 |
| KR20130102617A (ko) | 2013-09-17 |
| EP2638124A4 (en) | 2017-10-18 |
| WO2012065026A3 (en) | 2012-07-19 |
| CN103282461A (zh) | 2013-09-04 |
| WO2012065026A2 (en) | 2012-05-18 |
| MX2013005230A (es) | 2013-06-28 |
| JP6017437B2 (ja) | 2016-11-02 |
| EP2638124A2 (en) | 2013-09-18 |
| JP2013542312A (ja) | 2013-11-21 |
| US20120119136A1 (en) | 2012-05-17 |
| CN107083235A (zh) | 2017-08-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20161104 |
|
| FZDE | Discontinued |
Effective date: 20190508 |