CA2806188C - Electrically rechargeable, metal-air battery systems and methods - Google Patents

Electrically rechargeable, metal-air battery systems and methods Download PDF

Info

Publication number
CA2806188C
CA2806188C CA2806188A CA2806188A CA2806188C CA 2806188 C CA2806188 C CA 2806188C CA 2806188 A CA2806188 A CA 2806188A CA 2806188 A CA2806188 A CA 2806188A CA 2806188 C CA2806188 C CA 2806188C
Authority
CA
Canada
Prior art keywords
metal
air
electrode
air battery
methods
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2806188A
Other languages
French (fr)
Other versions
CA2806188A1 (en
Inventor
Steven Amendola
Lois Johnson
Michael Binder
Michael Kunz
Phillip J. Black
Michael Oster
Stefanie Sharp-Goldman
Tesia Chciuk
Regan Johnson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eos Energy Technology Holdings LLC
Original Assignee
Eos Energy Storage LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eos Energy Storage LLC filed Critical Eos Energy Storage LLC
Publication of CA2806188A1 publication Critical patent/CA2806188A1/en
Application granted granted Critical
Publication of CA2806188C publication Critical patent/CA2806188C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/42Alloys based on zinc
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/04Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H01M12/065Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode with plate-like electrodes or stacks of plate-like electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/08Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/96Carbon-based electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/70Arrangements for stirring or circulating the electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0002Aqueous electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49108Electric battery cell making

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Hybrid Cells (AREA)
  • Inert Electrodes (AREA)
  • Filling, Topping-Up Batteries (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

The invention provides fully electrically rechargeable metal-air battery systems and methods of achieving such systems. A rechargeable metal air battery cell may comprise a metal electrode, an air electrode, and an aqueous electrolyte separating the metal electrode and the air electrode. In some embodiments, the metal electrode may directly contact the electrolyte and no separator or porous membrane need be provided between the air electrode and the electrolyte. Rechargeable metal air battery cells may be electrically connected to one another through a centrode connection between a metal electrode of a first battery cell and an air electrode of a second battery cell. Air tunnels may be provided between individual metal air battery cells, in some embodiments, an electrolyte flow management system may be provided.
CA2806188A 2010-07-21 2011-07-20 Electrically rechargeable, metal-air battery systems and methods Active CA2806188C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/841,115 2010-07-21
US12/841,115 US20120021303A1 (en) 2010-07-21 2010-07-21 Electrically rechargeable, metal-air battery systems and methods
PCT/US2011/044715 WO2012012558A2 (en) 2010-07-21 2011-07-20 Electrically rechargeable, metal-air battery systems and methods

Publications (2)

Publication Number Publication Date
CA2806188A1 CA2806188A1 (en) 2012-01-26
CA2806188C true CA2806188C (en) 2021-10-19

Family

ID=45493890

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2806188A Active CA2806188C (en) 2010-07-21 2011-07-20 Electrically rechargeable, metal-air battery systems and methods

Country Status (11)

Country Link
US (3) US20120021303A1 (en)
EP (1) EP2596544A4 (en)
JP (1) JP5897006B2 (en)
KR (2) KR20130093094A (en)
CN (1) CN103119780B (en)
AU (1) AU2011282149B2 (en)
BR (1) BR112013001496A2 (en)
CA (1) CA2806188C (en)
MX (1) MX347789B (en)
TW (1) TWI523299B (en)
WO (1) WO2012012558A2 (en)

Families Citing this family (115)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7820321B2 (en) * 2008-07-07 2010-10-26 Enervault Corporation Redox flow battery system for distributed energy storage
US8785023B2 (en) * 2008-07-07 2014-07-22 Enervault Corparation Cascade redox flow battery systems
US8802304B2 (en) 2010-08-10 2014-08-12 Eos Energy Storage, Llc Bifunctional (rechargeable) air electrodes comprising a corrosion-resistant outer layer and conductive inner layer
US9385531B2 (en) * 2010-08-24 2016-07-05 Bennett Hill Branscomb System and method for optimizing returns of power feedstock producers
US8980484B2 (en) 2011-03-29 2015-03-17 Enervault Corporation Monitoring electrolyte concentrations in redox flow battery systems
US8916281B2 (en) 2011-03-29 2014-12-23 Enervault Corporation Rebalancing electrolytes in redox flow battery systems
US9711830B2 (en) * 2011-09-02 2017-07-18 Panisolar Inc. Electrochemically rechargeable metal-air cell with a replaceable metal anode
WO2013090680A2 (en) * 2011-12-14 2013-06-20 Eos Energy Storage, Llc Electrically rechargeable, metal anode cell and battery systems and methods
WO2013111426A1 (en) * 2012-01-24 2013-08-01 日本碍子株式会社 Power storage apparatus and method of operating power storage apparatus
JP6056496B2 (en) * 2012-01-25 2017-01-11 日産自動車株式会社 Air battery and battery pack using the same
JP6011799B2 (en) * 2012-01-27 2016-10-19 日産自動車株式会社 Assembled battery
JP6070239B2 (en) * 2012-02-22 2017-02-01 日産自動車株式会社 Air battery
US9166218B2 (en) * 2012-02-24 2015-10-20 Ford Global Technologies, Llc Electrolyte replenishing system and method
WO2013133029A1 (en) * 2012-03-09 2013-09-12 日産自動車株式会社 Air cell
KR102032245B1 (en) * 2012-04-03 2019-10-16 삼성전자주식회사 Lithium air battery module
US20150056523A1 (en) 2012-04-04 2015-02-26 Phinergy Ltd. Electrolyte system and method of preparation thereof
JP5904854B2 (en) * 2012-04-17 2016-04-20 日立造船株式会社 Metal air battery
JP6229994B2 (en) * 2012-04-18 2017-11-15 日産自動車株式会社 Positive electrode for air battery and method for producing the same
AU2012382382A1 (en) 2012-06-12 2015-01-15 Aquahydrex Pty Ltd Breathable electrode and method for use in water splitting
CN104602935B (en) 2012-07-09 2017-07-07 斐源有限公司 Systems and methods of controlling operation of metal-air batteries
JP6051650B2 (en) * 2012-07-23 2016-12-27 日産自動車株式会社 Air battery
US9774066B2 (en) 2012-08-01 2017-09-26 Sharp Laboratories Of America, Inc. Large-scale metal-air battery with slurry anode
US9608264B2 (en) 2012-08-01 2017-03-28 Sharp Laboratories Of America, Inc. Air cathode battery using zinc slurry anode with carbon additive
US20140072886A1 (en) * 2012-09-07 2014-03-13 Basf Se Rechargeable electrochemical zinc-oxygen cells
WO2014037851A2 (en) * 2012-09-07 2014-03-13 Basf Se Rechargeable electrochemical zinc-oxygen cells
WO2014047137A1 (en) 2012-09-24 2014-03-27 Cornell University Methods, systems, and applications for solar-thermal microfluidic pcr
WO2014074504A1 (en) 2012-11-06 2014-05-15 Cornell University Carbon dioxide assisted metal-oxygen battery and related method
FR2998719B1 (en) * 2012-11-29 2016-05-06 Electricite De France METAL-AIR BATTERY WITH DEVICE FOR CONTROLLING THE POTENTIAL OF THE NEGATIVE ELECTRODE
WO2014106027A1 (en) * 2012-12-27 2014-07-03 Robert Bosch Gmbh AQUEOUS Li/O2 BATTERY WITH WATER STORAGE
US20160093904A1 (en) * 2013-02-21 2016-03-31 Robert Bosch Gmbh Secondary battery recuperator system
CN103199285B (en) * 2013-04-10 2016-01-13 大连融科储能技术发展有限公司 A flow battery shutdown protection method and a flow battery system
CN103296338A (en) * 2013-06-20 2013-09-11 北京西区码头商贸有限公司 Aluminum air fuel cell system
KR20160040614A (en) 2013-07-31 2016-04-14 아쿠아하이드렉스 프로프라이어터리 리미티드 Electro-synthetic or electro-energy cell with gas diffusion electrode(s)
US10056636B1 (en) * 2013-10-03 2018-08-21 Primus Power Corporation Electrolyte compositions for use in a metal-halogen flow battery
EP3086400B1 (en) * 2013-12-19 2019-08-28 Nissan Motor Co., Ltd Electrode structure, air cell, and air cell stack
CN104733785B (en) * 2013-12-20 2017-11-07 苏州宝时得电动工具有限公司 Battery
JP6255423B2 (en) * 2014-01-29 2017-12-27 シャープ株式会社 Metal air battery
FR3018141B1 (en) * 2014-03-03 2016-05-06 Commissariat Energie Atomique ASSEMBLY MODULE COMPRISING ELECTROCHEMICAL CELLS RECEIVED BY TERMINALS AND CONNECTING CLAMPS
CA2942132A1 (en) * 2014-03-05 2015-09-11 Phinergy Ltd. Pit stop for and method of replacement of electrolyte
DE102014208575A1 (en) 2014-05-07 2015-11-12 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Gas diffusion electrode and its use
US10403947B1 (en) * 2014-05-19 2019-09-03 Dan Curfew Metallic electrochemical cells and methods for producing on-demand electricity
JP6414798B2 (en) * 2014-06-25 2018-10-31 日産自動車株式会社 Air battery unit
JP6410078B2 (en) * 2014-06-25 2018-10-24 日産自動車株式会社 Air battery unit
DE102014212144A1 (en) * 2014-06-25 2015-12-31 Robert Bosch Gmbh Apparatus and method for the regeneration of a metal-air battery, and metal-air battery and vehicle
DE102014216371B4 (en) 2014-08-19 2025-04-30 Bayerische Motoren Werke Aktiengesellschaft Charging device and system for charging a motor vehicle
KR102290282B1 (en) 2014-09-15 2021-08-17 삼성전자주식회사 Metal-air battery
US11043679B2 (en) * 2014-12-30 2021-06-22 Ess Tech, Inc. Alternative low cost electrodes for hybrid flow batteries
TWI553279B (en) * 2015-01-09 2016-10-11 Cycle dehumidification device
EP3353844B1 (en) 2015-03-27 2022-05-11 Mason K. Harrup All-inorganic solvents for electrolytes
CN105140593B (en) * 2015-07-14 2018-05-01 北京航空航天大学 A kind of adjustable oxygen-metal battery of environmental protection environment
KR102409388B1 (en) * 2015-07-28 2022-06-15 삼성전자주식회사 Metal air battery, vehicle system comprising the metal air battery and operation method of the vehicle system
US10594008B2 (en) 2015-07-31 2020-03-17 Dan Curfew Electrochemical cell
KR101719685B1 (en) * 2015-08-12 2017-03-24 롯데케미칼 주식회사 Method for charge and discharge of redox flow battery
KR102364851B1 (en) * 2015-08-26 2022-02-18 삼성전자주식회사 Metal air battery including thermal management structure
KR101836836B1 (en) * 2015-10-14 2018-03-09 주식회사 이엠따블유에너지 Zinc-air cell assembly
RU2618440C2 (en) * 2015-10-28 2017-05-05 Федеральное государственное бюджетное учреждение науки Институт теплофизики им. С.С. Кутателадзе Сибирского отделения Российской академии наук (ИТ СО РАН) Method of usage of aluminium-air galvanic element
CN105356011A (en) * 2015-12-03 2016-02-24 黄亮国 Liquid flow zinc-air battery
AU2016403177B2 (en) * 2016-04-21 2021-08-05 Sumitomo Electric Industries, Ltd. Container-type battery
CN105932312B (en) * 2016-05-13 2019-12-31 刘建纯 A carbon battery with low gas evolution and its preparation method
JP2019521497A (en) 2016-07-22 2019-07-25 ナントエナジー,インク. Water and carbon dioxide management system in the electrochemical cell
US11228066B2 (en) 2016-07-22 2022-01-18 Form Energy, Inc. Mist elimination system for electrochemical cells
JP2019530405A (en) 2016-09-15 2019-10-17 ナントエナジー,インク. Hybrid battery system
US10707531B1 (en) 2016-09-27 2020-07-07 New Dominion Enterprises Inc. All-inorganic solvents for electrolytes
BR112019008041A2 (en) 2016-10-21 2019-07-02 Nantenergy Inc corrugated fuel electrode
WO2018187561A1 (en) 2017-04-06 2018-10-11 Jaramillo Mateo Cristian Refuelable battery for the electric grid and method of using thereof
US20230299618A1 (en) * 2017-05-16 2023-09-21 Wireless Electrical Grid Lan, Wigl Inc. Wireless communication device and method of using
CN107579291B (en) * 2017-08-30 2020-05-26 中国科学院宁波材料技术与工程研究所 Aqueous electrolyte and water-based metal ion battery
US11515594B2 (en) 2017-09-29 2022-11-29 Maxell, Ltd. Waterproof device with air cell power source
CN108091931A (en) * 2017-11-03 2018-05-29 湖南望隆企业管理咨询有限公司 A kind of lithium-ion battery electrolytes
CA3082064C (en) * 2017-11-13 2024-10-29 Phinergy Ltd. Aluminum-air battery units and stacks
CN109904566B (en) * 2017-12-11 2021-06-01 中国科学院大连化学物理研究所 A metal/air battery system
CN109975706A (en) * 2017-12-14 2019-07-05 中国科学院大连化学物理研究所 A kind of test method in oxygen reduction cathode service life
WO2019133702A1 (en) 2017-12-29 2019-07-04 Staq Energy, Inc. Long life sealed alkaline secondary batteries
JP7022316B2 (en) * 2018-02-05 2022-02-18 トヨタ自動車株式会社 Sealed battery
US10547059B2 (en) 2018-02-21 2020-01-28 Duracell U.S. Operations, Inc. Sulfate and sulfonate based surfactants for alkaline battery anode
CN108461680B (en) * 2018-03-26 2024-07-05 沈阳航天新光集团有限公司 Large-scale modularized seawater battery
CN112805868A (en) 2018-06-29 2021-05-14 福恩能源公司 Metal air electrochemical cell frame
EP3815167A4 (en) 2018-06-29 2022-03-16 Form Energy, Inc. AQUEOUS POYLSULFIDE BASED ELECTROCHEMICAL CELL
CN119481486A (en) * 2018-06-29 2025-02-18 福恩能源公司 Rolling diaphragm seal
CN108987857A (en) * 2018-07-18 2018-12-11 北京化工大学 A kind of zinc air flow battery based on faintly acid electrolyte
MA53343A (en) 2018-07-27 2022-03-23 Form Energy Inc NEGATIVE ELECTRODES FOR ELECTROCHEMICAL CELLS
CN109167124A (en) * 2018-08-06 2019-01-08 北京理工大学 Floating marine formula longitudinal direction strong-force exhaust metal-air power generation monomer
CN109449544B (en) * 2018-11-06 2024-05-10 广东工业大学 Aluminum air battery system and control method
CN111326831B (en) * 2018-12-14 2021-09-28 中国科学院大连化学物理研究所 Metal-air battery pack or single battery
CN109638309B (en) * 2018-12-14 2022-03-29 北京工业大学 Gas-phase countercurrent diaphragm-free metal-oxygen-containing gas flow battery
KR20210097805A (en) * 2018-12-15 2021-08-09 로그 9 머터리얼즈 사이언티픽 프라이빗 리미티드 System and method for hybrid power backup using graphene-based metal-air battery
CA3127358A1 (en) 2019-02-01 2020-08-06 Aquahydrex, Inc. Electrochemical system with confined electrolyte
IT201900009459A1 (en) 2019-06-19 2020-12-19 Freebatt S R L RECHARGEABLE BATTERY
CN114207915A (en) * 2019-06-28 2022-03-18 福恩能源公司 Device architecture for metal-air battery
US12294086B2 (en) 2019-07-26 2025-05-06 Form Energy, Inc. Low cost metal electrodes
WO2021080687A2 (en) * 2019-08-26 2021-04-29 Massachusetts Institute Of Technology A high-energy rechargeable al-co2 battery for co2 capture/conversion and electric power generation/storage
US11949129B2 (en) 2019-10-04 2024-04-02 Form Energy, Inc. Refuelable battery for the electric grid and method of using thereof
CN112787048B (en) 2019-10-23 2022-08-09 比亚迪股份有限公司 Lithium ion battery, battery module, battery pack and automobile
JP7727966B2 (en) * 2019-11-05 2025-08-22 国立大学法人九州大学 electrolyte
US20210178334A1 (en) * 2019-12-16 2021-06-17 Dionex Corporation Electrolytic eluent generators with stabilized operating voltages
CN111024295B (en) * 2019-12-30 2021-06-25 中国科学院理化技术研究所 Resistance type microfluid pressure sensor
WO2021226399A1 (en) * 2020-05-06 2021-11-11 Form Energy, Inc. Decoupled electrode electrochemical energy storage system
CN111653835A (en) * 2020-06-18 2020-09-11 中国科学院上海应用物理研究所 A high-power high-temperature molten salt battery
TWM635873U (en) * 2021-01-14 2023-01-01 三鈦工業有限公司 Zinc-air fuel cell with multiple electric connectors and a battery pack capable of performing both charging and discharging functions
US11374209B1 (en) * 2021-02-12 2022-06-28 WATTRII, Inc. High-energy cathodes, batteries, and methods of making the same
US11804592B2 (en) 2021-02-12 2023-10-31 WATTRII, Inc. High-energy cathodes, batteries, and methods of making the same
US11955618B2 (en) 2021-03-16 2024-04-09 Worcester Polytechnic Institute Metal-air battery
EP4080647A1 (en) * 2021-04-22 2022-10-26 HILABS GmbH Electrode module, electrochemical cell, battery, and manufacture and use thereof
CN113690477B (en) * 2021-07-20 2022-11-08 浙江天能氢能源科技有限公司 Air cooling type fuel cell stack
CN113471577B (en) * 2021-07-27 2022-10-28 烟台浩忆生物科技有限公司 Soft package metal-air battery and using method thereof
US12002941B2 (en) * 2021-11-08 2024-06-04 Hunt Energy Enterprises, L.L.C. Control of electrolyte inside battery
JP7111321B1 (en) * 2022-05-23 2022-08-02 ineova株式会社 can type metal air battery
EP4544629A1 (en) * 2022-06-23 2025-04-30 E-Zinc Inc. Electrochemical cell with electrolyte management
US12087909B2 (en) 2022-06-27 2024-09-10 WATTRII, Inc. High energy batteries and methods of making the same
CN116111239A (en) * 2023-02-22 2023-05-12 江苏大学 A kind of high specific capacity, high power alkaline aluminum-air battery electrolyte and preparation method thereof
US20250038286A1 (en) * 2023-07-24 2025-01-30 Toyota Motor Engineering & Manufacturing North America, Inc. Systems for removing discharge products from metal-air battery cathodes and metal-air batteries containing the same
KR20250079954A (en) * 2023-11-27 2025-06-05 스탠다드에너지(주) Cell Layer Quality Control for Aqueous Battery and Manufacturing Cell Block using the Same
WO2026035091A1 (en) * 2024-08-08 2026-02-12 성균관대학교산학협력단 Metal-air battery system and method for operating same
CN120453419B (en) * 2025-07-11 2025-09-19 绍兴文理学院 A modular electrolyte circulating air battery pack with fault isolation function
CN121726612A (en) * 2026-02-12 2026-03-24 黄山学院 A bifunctional thiourea-based electrolyte for zinc-air batteries and its application

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3043898A (en) * 1956-04-24 1962-07-10 Aerojet General Co Gas depolarized battery
US3306774A (en) * 1962-06-21 1967-02-28 Exxon Research Engineering Co Fuel cell with horizontal electrodes
JPS5547003Y2 (en) * 1974-07-24 1980-11-05
FR2298195A1 (en) * 1975-01-14 1976-08-13 Comp Generale Electricite AIR-ZINC ELECTROCHEMICAL GENERATOR
JPS5722383Y2 (en) * 1976-12-28 1982-05-14
US4168349A (en) * 1978-04-27 1979-09-18 Westinghouse Electric Corp. Iron/air battery system having circulating electrolyte and a horizontal cell configuration
US4246324A (en) * 1979-04-09 1981-01-20 Diamond Shamrock Technologies S.A. Consumable replaceable anodes for batteries
YU122483A (en) * 1983-06-02 1986-02-28 Aleksandar Despic Bipolar element of a chemical current source
US4927717A (en) * 1987-06-01 1990-05-22 Eltech Systems Corporation Bipolar metal/air battery
US5049457A (en) * 1989-04-07 1991-09-17 Eltech Systems Corporation Electrolyte for an aluminum air-battery comprising an anti-foaming agent and corrosion exhibitor
US4988581A (en) * 1989-07-19 1991-01-29 Alcan International Limited Metal-air bipolar cell unit
US5232798A (en) * 1990-12-31 1993-08-03 Electric Fuel (E.F.L.) Ltd. Method for inhibiting corrosion in particulate zinc
CA2110097C (en) * 1992-11-30 2002-07-09 Soichiro Kawakami Secondary battery
US5716726A (en) * 1994-12-22 1998-02-10 Dreisbach Electromotive, Inc. Electrolyte starved metal-air battery
US5506067A (en) * 1995-04-04 1996-04-09 Aer Energy Resources, Inc. Rechargeable electrochemical cell and cell case therefor with vent for use in internal recombination of hydrogen and oxygen
US5891589A (en) * 1997-05-19 1999-04-06 Aer Energy Resources, Inc. Method and apparatus for joining metal-air cells
US6068944A (en) * 1997-10-24 2000-05-30 Aer Energy Resources, Inc. Air distributors for metal-air cells
US6235418B1 (en) * 1998-12-18 2001-05-22 Aer Energy Resources, Inc. Uniform shell for a metal-air battery stack
US6689711B2 (en) * 2001-10-09 2004-02-10 Metallic Power, Inc. Methods of producing oxygen reduction catalyst
AU2003256251A1 (en) * 2002-04-24 2003-11-10 The Regents Of The University Of California Planar electrochemical device assembly
DK1516376T3 (en) * 2002-06-25 2009-11-16 Applied Intellectual Capital L Zinc-air battery with acid electrolyte
FR2843235B1 (en) * 2002-07-30 2006-07-28 Conseil Et De Prospective Scie OXIDATION-CONDUCTIVE CONDUCTIVE CERAMIC FOR ZINC ANODE OF ALKALI SECONDARY ELECTROCHEMICAL GENERATORS
US7887956B2 (en) * 2005-03-30 2011-02-15 High Tech Battery Inc. Air cathode having multilayer structure and manufacture method thereof
MX2008014300A (en) * 2006-05-08 2008-11-26 Siemens Water Tech Corp Electrolytic apparatus with polymeric electrode and methods of preparation and use.
US20080096061A1 (en) * 2006-06-12 2008-04-24 Revolt Technology Ltd Metal-Air Battery or Fuel Cell
US20090239131A1 (en) * 2007-01-16 2009-09-24 Richard Otto Winter Electrochemical energy cell system

Also Published As

Publication number Publication date
AU2011282149A1 (en) 2013-02-07
TWI523299B (en) 2016-02-21
CN103119780B (en) 2016-03-30
TW201222927A (en) 2012-06-01
EP2596544A4 (en) 2015-08-05
US20180366799A1 (en) 2018-12-20
WO2012012558A2 (en) 2012-01-26
RU2013107587A (en) 2014-08-27
KR20180050431A (en) 2018-05-14
AU2011282149B2 (en) 2014-10-23
EP2596544A2 (en) 2013-05-29
US20120021303A1 (en) 2012-01-26
CA2806188A1 (en) 2012-01-26
BR112013001496A2 (en) 2016-05-31
US20130115531A1 (en) 2013-05-09
JP2013537686A (en) 2013-10-03
JP5897006B2 (en) 2016-03-30
CN103119780A (en) 2013-05-22
KR20130093094A (en) 2013-08-21
AU2011282149A8 (en) 2013-02-14
MX2013000862A (en) 2013-06-03
MX347789B (en) 2017-05-12
WO2012012558A3 (en) 2012-04-26

Similar Documents

Publication Publication Date Title
CA2806188C (en) Electrically rechargeable, metal-air battery systems and methods
WO2013090680A3 (en) Electrically rechargeable, metal anode cell and battery systems and methods
WO2009036444A3 (en) Lithium rechargeable cell with reference electrode for state of health monitoring
EP4668405A3 (en) Single pouch battery cells and methods of manufacture
WO2017176936A8 (en) Lithium metal electrodes and batteries thereof
WO2015074037A3 (en) Separator enclosures for electrodes and electrochemical cells
WO2009148971A3 (en) Electrochemical cells with ionic liquid electrolyte
EP2439810A3 (en) Battery pack
MX2010001809A (en) Electrochemical cell with improved internal contact.
WO2009013629A8 (en) Air battery system and methods for using and controlling air battery system
WO2007134091A3 (en) Secondary electrochemical cell with increased current collecting efficiency
WO2012122353A3 (en) Metal free aqueous electrolyte energy storage device
EP4300666A3 (en) Electrochemical cells having semi-solid electrodes and methods of manufacturing the same
WO2008002626A3 (en) Lithium reservoir system and method for rechargeable lithium ion batteries
EP2337137A3 (en) Rechargeable battery
WO2011085327A3 (en) Variable capacity cell assembly
WO2014183028A3 (en) Rechargeable nanoelectrofuel electrodes and devices for high energy density flow batteries
WO2007014081A3 (en) Polyelectrolyte membranes as separator for battery and fuel cell applications
WO2009111744A3 (en) Electrochemical cells with tabs
WO2013062990A3 (en) Polyurethane based membranes and/or separators for electrochemical cells
WO2006078472A3 (en) Electrochemically self assembled batteries
WO2009031107A3 (en) Lithium ion prismatic cells
EP2450980A3 (en) Battery module
WO2012121505A3 (en) Battery pack provided with stable measurement means
SG10201901001YA (en) A battery system

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20160719

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 13TH ANNIV.) - STANDARD

Year of fee payment: 13

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20240827

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT DETERMINED COMPLIANT

Effective date: 20240827

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20240827

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 14TH ANNIV.) - STANDARD

Year of fee payment: 14

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250527

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250527