CA2774943C - A method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor - Google Patents

A method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor Download PDF

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Publication number
CA2774943C
CA2774943C CA2774943A CA2774943A CA2774943C CA 2774943 C CA2774943 C CA 2774943C CA 2774943 A CA2774943 A CA 2774943A CA 2774943 A CA2774943 A CA 2774943A CA 2774943 C CA2774943 C CA 2774943C
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CA
Canada
Prior art keywords
steam
methane
reactor
product gas
coal
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Expired - Fee Related
Application number
CA2774943A
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English (en)
French (fr)
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CA2774943A1 (en
Inventor
Arun Sk Raju
Chan Seung Park
Joseph M. Norbeck
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University of California, San Diego
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University of California, San Diego
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Publication of CA2774943A1 publication Critical patent/CA2774943A1/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08—Production of synthetic natural gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84—Energy production
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/092—Wood, cellulose
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0966—Hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Processing Of Solid Wastes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Industrial Gases (AREA)
CA2774943A 2009-09-22 2010-09-22 A method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor Expired - Fee Related CA2774943C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US24483309P 2009-09-22 2009-09-22
US61/244,833 2009-09-22
PCT/US2010/049889 WO2011038046A2 (en) 2009-09-22 2010-09-22 A method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor

Publications (2)

Publication Number Publication Date
CA2774943A1 CA2774943A1 (en) 2011-03-31
CA2774943C true CA2774943C (en) 2018-08-28

Family

ID=43796473

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2774943A Expired - Fee Related CA2774943C (en) 2009-09-22 2010-09-22 A method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor

Country Status (9)

Country Link
US (1) US9493721B2 (enExample)
EP (1) EP2480640A4 (enExample)
CN (1) CN102510894A (enExample)
AU (1) AU2010298335B2 (enExample)
CA (1) CA2774943C (enExample)
EA (1) EA022769B1 (enExample)
IN (1) IN2012DN02366A (enExample)
WO (1) WO2011038046A2 (enExample)
ZA (1) ZA201202013B (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8841495B2 (en) 2011-04-18 2014-09-23 Gas Technology Institute Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor
ITRM20120665A1 (it) * 2012-12-27 2014-06-28 Agenzia Naz Per Le Nuove Tecn Ologie L Ener Processo per la produzione di metano da carbone
JP5999115B2 (ja) * 2014-01-14 2016-09-28 Ｊｆｅスチール株式会社 有機物質の低分子化方法および低分子化システム
CN104531245B (zh) * 2015-01-28 2017-09-26 唐山信德燃气化工程有限公司 一种垃圾生物质燃气的增氢方法及其装置
PL224909B1 (pl) * 2015-03-12 2017-02-28 Jjra Spółka Z Ograniczoną Odpowiedzialnością Sposób i układ do wytwarzania biometanu i ekometanu oraz energii elektrycznej i cieplnej
JP6248987B2 (ja) * 2015-07-03 2017-12-20 Ｊｆｅスチール株式会社 有機物質の低分子化方法
CN105132056B (zh) * 2015-08-25 2018-07-06 中国五环工程有限公司 褐煤蒸汽加氢气化制天然气工艺及其系统
JP7036853B2 (ja) * 2020-03-19 2022-03-15 本田技研工業株式会社 燃料製造システム
US12173238B2 (en) 2020-06-29 2024-12-24 Uop Llc Integrated process for hydrotreating a renewable feedstock with improved carbon monoxide management
RU2754911C1 (ru) * 2020-11-11 2021-09-09 Федеральное государственное бюджетное образовательное учреждение высшего образования "Казанский государственный энергетический университет" (ФГБОУ ВО "КГЭУ") Установка для газификации углеродсодержащих отходов
KR102639730B1 (ko) * 2021-10-13 2024-02-23 울산과학기술원 탄화수소 제조방법 및 이를 이용하여 제조된 탄화수소

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3703052A (en) * 1970-11-12 1972-11-21 Inst Gas Technology Process for production of pipeline quality gas from oil shale
US3779725A (en) 1971-12-06 1973-12-18 Air Prod & Chem Coal gassification
US3871839A (en) * 1972-10-12 1975-03-18 Air Prod & Chem Method of feeding solid carbonaceous material to a high temperature reaction zone
US3854896A (en) * 1973-01-29 1974-12-17 Gilbert Associates Method of converting coal to pipeline quality gas
US3904389A (en) * 1974-08-13 1975-09-09 David L Banquy Process for the production of high BTU methane-containing gas
US4209305A (en) * 1975-12-08 1980-06-24 British Gas Corporation Process for making substitute natural gas
US4152122A (en) * 1977-12-05 1979-05-01 Syngas International, Ltd. Apparatus for the production of methane containing gas by hydrogasification
US4597776A (en) * 1982-10-01 1986-07-01 Rockwell International Corporation Hydropyrolysis process
CA1300885C (en) * 1986-08-26 1992-05-19 Donald S. Scott Hydrogasification of biomass to produce high yields of methane
US6685754B2 (en) * 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
US8603430B2 (en) * 2002-02-05 2013-12-10 The Regents Of The University Of California Controlling the synthesis gas composition of a steam methane reformer
US8236072B2 (en) * 2007-02-08 2012-08-07 Arizona Public Service Company System and method for producing substitute natural gas from coal
GB0715101D0 (en) * 2007-08-03 2007-09-12 Johnson Matthey Plc Process
US8217210B2 (en) * 2007-08-27 2012-07-10 Purdue Research Foundation Integrated gasification—pyrolysis process

Also Published As

Publication number Publication date
US20120222353A1 (en) 2012-09-06
ZA201202013B (en) 2013-06-26
CN102510894A (zh) 2012-06-20
WO2011038046A4 (en) 2011-11-03
EA022769B1 (ru) 2016-02-29
EA201290117A1 (ru) 2012-08-30
AU2010298335A1 (en) 2012-04-12
WO2011038046A8 (en) 2011-06-23
IN2012DN02366A (enExample) 2015-08-21
CA2774943A1 (en) 2011-03-31
EP2480640A2 (en) 2012-08-01
WO2011038046A3 (en) 2011-09-29
AU2010298335B2 (en) 2015-09-17
US9493721B2 (en) 2016-11-15
WO2011038046A2 (en) 2011-03-31
EP2480640A4 (en) 2013-11-20

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Effective date: 20150714

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Effective date: 20200922