US3871839A - Method of feeding solid carbonaceous material to a high temperature reaction zone - Google Patents

Method of feeding solid carbonaceous material to a high temperature reaction zone Download PDF

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US3871839A
US3871839A US296959A US29695972A US3871839A US 3871839 A US3871839 A US 3871839A US 296959 A US296959 A US 296959A US 29695972 A US29695972 A US 29695972A US 3871839 A US3871839 A US 3871839A
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slurry
gasifier
solid carbonaceous
gas
carbonaceous material
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Burton E Moody
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Air Products and Chemicals Inc
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Air Products and Chemicals Inc
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Priority to US296959A priority Critical patent/US3871839A/en
Priority to ZA737437*A priority patent/ZA737437B/en
Priority to JP48111879A priority patent/JPS4974203A/ja
Priority to BE136472A priority patent/BE805825A/en
Priority to FR7336219A priority patent/FR2202929B1/fr
Priority to GB4760473A priority patent/GB1407176A/en
Priority to DE19732350953 priority patent/DE2350953A1/en
Priority to PL1973165799A priority patent/PL96935B1/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/485Entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/50Fuel charging devices
    • C10J3/506Fuel charging devices for entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903Feed preparation
    • C10J2300/0906Physical processes, e.g. shredding, comminuting, chopping, sorting
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/094Char
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0943Coke
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846Partial oxidation, i.e. injection of air or oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1884Heat exchange between at least two process streams with one stream being synthesis gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1892Heat exchange between at least two process streams with one stream being water/steam
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S48/00Gas: heating and illuminating
    • Y10S48/07Slurry

Definitions

  • ABSTRACT A method of feeding solid carbonaceous material to a gasifier operating under conditions of high temperature and pressure by forming a slurry of the carbonaceous material and a liquid vehicle, raising the internal pressure of the slurry to the operating level of the gas ifier, drying the carbonaceous material by entraining the carbonaceous material in a hot gas stream, and thereafter separating the carbonaceous material and feeding the carbonaceous material to the gasifier.
  • the method is adaptable to using the gasifier effluent to dry the carbonaceous material and includes using process materials such as char accumulated from the process and condensing steam to provide a portion of the source of carbonaceous materials and vehicle for the slurry.
  • Field of the Invention pertains to the feeding of solid carbonaceous material, e.g. coal, into a high-pressure, hightemperature reaction zone such as a coal gasifier.
  • a coal gasifier In coal gasification, finely pulverized coal is reacted in the presence of steam and air oxygen at elevated temperature and pressure to form an effluent gas. If the product is to be a low BTU content gas, it is subject toremoval of hydrogen sulfide and then used directly.
  • a high methane content gas is to be produced, the effluent gas is then subjected to various process steps including water shift reaction, acid gas removal and methanation thereby yielding a synthetic natural gas.
  • figsuch process is discgasgd in U.S. Pat. No. 2,840,462; another is the process referred to as the; BCR Two-Stage Super-Pressure Gasification Process developed by Bituminous Coal Research Incorporated of Monroeville, PA; and a third pertains to generation fo a synthetic gas by electrothermal hydrogasification developed by the Institute of Gas Technology of Chicago, ILL.
  • the finely divided carbonaceous material is fed to the gasification vessel by a conventional lock hopper feeding system, a piston feeder, and a hydrocarbon liquid slurry respectively after the coal has been ground to size, screened, dewatered, and stored in storage hoppers.
  • U.S. Pat. No. 3,207,102 discloses a slurry feed for a steam generating unit such as is found in a commercial electrical generating plant. Here again the slurry is not dewatered prior to injection into the furnace and the slurry is further comminuted by impingement against a breaker in the furnace zone.
  • U.S. Pat. No. 3,229,651 discloses an alternate slurry feed means for conducting a finely divided solid carbonaceous material into a steam boiler or the like.
  • coal will be fed to the gasifier by a pressurized piston feeder in conjunction with a star-wheel feeder.
  • the coal will be pressurized by the piston feeder and fed into the gasifier by the star-wheel feeder.
  • a number of lock hoppers feed coal into a highpressure surge vessel from which the coal would be fed to the gasifier.
  • the high-pressure gas in the hopper is vented to a series of receivers at different pressure levels down to atmospheric pressure. Gas is vented first to the highest pressure receiver and when pressure equalization is approached the venting is switched to the receiver at the next lower pressure and so on until the final venting is to atmospheric pressure.
  • the lock hopper is then refilled with coal then pressurized in staged from each gas receiver in turn and the receivers are maintained at constant pressure by pumping gas from the receiver at the next lowest pressure.
  • F inal pressurization is made by pumping gas from the highest pressure receiver directly into the lock hopper.
  • the coal is fed into oneof several alternating hoppers, the hopperis pressurized, the coal is injected into the gasifier and the hopper is vented for receiving the next charge.
  • the solid carbonaceous material can be dispersed in a liquid vehicle in the form of a slurry, the slurry can be raised to an elevated pressure by means of a slurry pump, the slurry can be dried using the high-temperature effluents from the gasification vessel and simultaneously entrained in a humidified gas, the solid carbonaceous materials can be separated from the gas into which it has been entrained, and fed at high pressure into the gasifier by means of a stream of hot recycled gas or stream.
  • the separated gas can be sent to the further purification steps without loss of volume of production for the overall gasification process. It is further contemplated that char separated and collected in the gasification process and condensed steam from the process or boiler feed water can be used in making up the initial slurry.
  • FIG. 1 is a schematic drawing of the method of the instant invention.
  • FIG. 2 is a schematic drawing of the method of the instant invention as applied to a process for producing a synthesis gas.
  • FIG. 1 there is shown a slurry tank with an impeller 12 mounted on shaft 14 rotated by a suitable motor or other rotating device not shown.
  • the tank 10 receives the pulverized carbonaceous material from a feed hopper or pipe that is shown by arrow 16.
  • the pulverized carbonaceous material generally is coal but can include coke, char or low grade volatile materials such as lignite.
  • Arrow l8 designates a source of supply of water which can be fresh water from utility, boiler feed water, or condensed steam from the process generally referred to as condensate.
  • the slurry tank 10 isconnected via conduit 10 to a slurry pump 22 which in turn is connected through conduits 24, 26, heat exchanger 28, and valve 30, to a mixing chamber 32.
  • the heat exchanger 28 is included in the process stream and can be bypassed if not needed as by conduit 34. If used, the heat exchanger 28 can be used to heat the slurry by means of heat exchange with steam, hot condensate, hot gas from the gasifier or hog gas from an independent gas heater (not shown).
  • the mixing chamber 32 contains an inlet conduit 36 for receiving hot gas, which in turn is connected to another conduit 38 having disposed therein temperature indicating control valve 40.
  • An outlet conduit 42 is connected to a separator 44, which in turn has an outlet gas conduit 46 and a solids removal device shown as 48. Removal device 48 in turn is connected to a coal feeder 50, which in turn is connected to a conduit 52 to a venturi nozzle 54.
  • a conduit 56 is connected to the venturi nozzle 54 in order to entrain the coal into a reactant gas for injection of the reactant and gas and coal into the gasifier.
  • solid carbonaceous material e.g. coal is fed through conduit 16 and condensate through conduit 18 into the slurry tank 10.
  • the impeller 12 is used to agitate the coal and condensate in tank 10 to form a slurry having approximately 50 percent by weight solids.
  • the slurry is then pumped under pressure to the mixing chamber 32 which chamber is maintained at the pressure of the gasifier vessel as the slurry is sprayed therein.
  • the mixing chamber 32 the slurry is contacted by the hot gasifier effluent entering through conduit 36.
  • the action of the hot gasifier effluent and the spraying of the slurry causes the water to v be driven off and the solid carbonaceous material (coalibecomes dried and entrained in the humidified hot gasifier effluent:
  • the evaporated water humidifies the effluent gas to enhance subsequent reactions in the shift convertor where the gas is used.
  • Steam conduit 38 is included to maintain the temperature of the spray drying chamber and to adjust the humidity of the effluent gas with the entrained solid carbonaceous material which is passed through conduit 42 to a cyclone separator and solid carbonaceous storage vessel 44 wherein the solid carbonaceous material is separated from the gas ans stored for use as needed with the solid carbonaceous material being withdrawn through a solids removal device, e.g., conduit 48, into feeder 50 for feeding into the gasification vessel.
  • the dried carbonaceous material is fed under pressure from conduit 52 into centuri feed nozzle 54 for pneumatic feeding to the reactor or gasifier. It may be advantageous to entrain the coal in a reactnat stream 56 which can be either hot recycled gas or steam used in the gasifier reaction vessel as in U.S. Pat. No.
  • coal can be fed through conduit 52 directly to the gasifier nozzles.
  • the gas separated in separator 44 is conducted through conduit 46 to subsequent processing steps (e.g. water gas shift reactor, acid gas removal, and methanation) in the overall gasification scheme so that none of the gasifier effluent is sacrificed in feeding the coal or other solid carbonaceous material to the gasifier.
  • the foregoing process provides a method for feeding dried preheated coal to a gasifier. It is possible to preheat the coal during drying to a temperature .of approximately 500F therebyachieving overall process economies in the production of synthetic natural gas by reducing oxygen requirements.
  • the foregoing basic method can be modified for application to other gasification schemes.
  • the gasification vessel for such a process requires heated coal at 80 atmospheres pressure for gasifier feed and requires process gasifier effluent temperature of 660F with a 1:1 steam to dry gas ratio for feed to the shift converter, which is the step after the gasifier.
  • the coal slurry is prepared as a 50 percent by weight mixture by adding coal at approximately 60F, hot condensate at approximately 212F and a low pressure steam at 50 psig and 298F into the slurry tank 10.
  • the slurry is pumped at the desired pressure (80 atmospheres) and preheated by hot condensate in heat exchanger 28.
  • the slurry is dried (32) and the coal and process gas separated in the cyclone 44.
  • the first section of the process will encompass multiple train slurry preparation consisting of makedown tanks and mixers, low-pressure, centrifigal slurry pumps, holding tansk with mixers, and circulation pumps.
  • coal sized at approximately percent less than 200 mesh and hot condensate direct from deaerators will be combined to produce a 50 weight percent coal water slurry in the make-down tanks.
  • Each tank will have a 10-minute residence time and be of 16,500 gallon capacity.
  • the slurry mixer will employ an axial flow, constant velocity discharge impeller with the shaft and impeller covered with rubber to minimize erosion. There will be provision in these tanks for steam sparging for heating of the slurry and usual circumstances where the coal may have settled to the bottom of the tank. After the slurry is throughly mixed, it will flow into a manifold from which it will be pumped to the holding tanks.
  • the next section of the process containsof the slurry pumping and hot condensate heat exchangers.
  • the slurry pumps will develop the system pressure of approximately 80 atmospheres using reciprocating singleacting Triplex plunger pumps.
  • the slurry will be discharged from the pumps at 1,200 psi and approximately 230F into a heat exchanger wherein the slurry will be raised to approximately 430F before feeding into the dryer.
  • the temperature of 430F is required in order to obtain the desired gas and coal temperature with a 1 to 1 steam to dry gas ratio in the process gas from the dryer. Care must be taken in constructing special inlet channels and distribution in the heat exchanger to prevent or minimize erosion due to the abrasive characteristics of the slurry.
  • the next section of the overall process will consist of slurry drying wherein there is employed a spray dryer, a cyclone, and a pair of coal receivers.
  • the coal slurry is dried and the water is vaporized in a spray dryer which will operate at approximately 80 atmospheres pressure with exit gas temperatures of 660F.
  • Gas used for heating the slurry will be effluent gas from the gasifier.
  • the effluent gas from the gasifier is at a temperature of 1,750F but before being used is subjected to a char separation in a cyclone separator. The char is then recycled to the gasifier.
  • a second cyclone separation is effected to eliminate the balance of the char from the gaas and lower the gas temperature to approximately 1,100F.
  • a portion of the gas from the first and second cyclone is combined with a net temperature of about 1,600F which gas is used in the spray dryers to content the slurry which is pumped into the dryer and atomized. If required, steam canbe added'to increase the atomization of the slurry or it can be added later to achieve the desired steam to dry gas ratio.
  • the dried coal and humidified gas is then taken over into a cyclone where the coal is separated and conducted into a pair of receivers, which will operate on a switching cycle to eliminate back surging through the cyclone.
  • the separated gas will be taken and fed to the carbon monoxide shift converters for further processing into the required pipeline gas. At this stage, the coal can be withdrawn from the storage hoppers under pressure and fed to the gasifier for reacting.
  • FIG. 2 There is shown in FIG. 2 a method of using a slurry feed in conjunction with a commercial partial oxidation unit.
  • the partial oxidation unit is shown in U.S. Pat. No. 2,595,234 and is used to produce a synthesis gas consisting mainly of water vapor, hydrogen, carbon dito free the mixer and impeller for start up under u'n- I oxide, and carbon monoxide, which can be subsequently shift converted to carbon dioxide and hydrogen.
  • the hydrogen is then separatedout and used for various processesincluding gasification of crude oil or as product hydrogen for other manufacturing operations.
  • the partial oxidation reactor is shown as60 in FIG. 2 and has an inlet conduit 62 for receiving the solid carbonaceous material to be reacted, a second inlet conduit 64 for receiving oxygen that reacts with the solid carbonaceous material and outlet conduit 66 for conduiting the synthesis gas out of the reactor and a bottom clean out 68 for removing slag and/or ash from the gasifier.
  • the product gas is conducted from conduit 66 to a separator 70 and from separator 70 through conduit 72 to a waste heat boiler 74, from waste heat boiler 74 through conduit 76 to a dryer 78, from dryer 78 to separator 80 and from separator 80 through to purification (shift) through conduit 81.
  • Coal is fed to the reactor 60 through conduit 82 which is in turn connected to a pneumatic injectionm device 84 which receives the coal feed from conduit 86 and carries the coal into the reactor 60 by means of steam shown by arrow 88.
  • Conduit 86 is connected in turn in reverse order to separator 80 and dryer 78.
  • a conduit 90 is connected to preheater 92 which in turn is connected to slurry pump 94 through conduit 95-for receiving the coal slurry.
  • Slurry pump 94 is connected to the slurry tank 96 by conduit 98.
  • Slurry tank 96 include'san impeller 100 and a drive shaft 102, which are connected to a suitable source of power such as a motor (not shown).
  • the slurry can be made as the result of wet grinding of the carbonaceous material in which event tank 96 is bypassed through conduit 104 directly to the slurry pump 94.
  • char, coke, or combinations thereof are introduced into the slurry tank 96 and are designated as arrow 106.
  • Condensate is added to tank 96 as indicated by arrow 108, e.g., condensate from the process in the form of boiler feed water, condensed steam, or fresh water.
  • the impeller is activated to provide the proper mixing of the solid carbonaceous material and condensate to form the slurry.
  • the slurry can be formed as the coal is wet ground to size and passed directly to the slurry pump 94 through conduit 104.
  • the preferably slurry is one that consists of 40 to 60 percent by weight water with the rest solid carbonaceous material.
  • the slurry is passed to the slurry pump 94 where its pressure is raised to that above the operating pressure of the gasifier 60 and is then preheated in heat exchanger 92 if the overall heat balance of the system requires additional heat into the system.
  • the slurry is then injected into the dryer 78 where it is contacted by the hot effluent from the waste heat boiler 74 and the water is driven off and the solid carbonaceous material is raised in temperature and entrained in a gas.
  • a source of steam can be provided through conduit 77 to control the humidity and temperature of the effluent in conduit 79 from dryer 78.
  • Waste heat boiler 74 is included in'this system to recover heat and-at the same time-to produce high-pressure steam for the overall reaction and for injecting into the gasifier itself.
  • the process provides a dry preheated carbonaceous solid fuel to the gasifier thereby increasing gasifier efficiency.-.
  • the water is evaporated without the use of additional oxygen and simultaneously provides steam required for subsequent shift operations of the effluent.
  • the process provides a method for utilizing a high-.
  • sulfur fuel such as coal, petroleum, coke or the like by producing sulfur as hydrogen sulfide because of the overall reducing atmosphere.
  • a method of feeding carbonaceous particles to a gasifier-operating at elevated temperature and pressure comprising the steps of:
  • a method of feeding solid carbonaceous particles to a gasifier operating at high temperature and high pressure comprising the steps of:
  • drying chamber introducing-the pressurized feed stream to a drying chamber, said drying chamber being separated from said gasifier, wherein it is contacted by hot gaseous effluent from the gasifier without substantial reaction so that, the water is evaporated, and the dried solid carbonaceous particles are entrained in the gaseous effluent;
  • gaseous effluent separated from the solid carbonaceous particles consists "essentially of-water vapor, carbon monoxide, and hydrogen, and issubjected to a subsequent shift step wherein carbon dioxide and hydrogen .LILAUAJU ILLA la. .1 M

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Treatment Of Sludge (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

A method of feeding solid carbonaceous material to a gasifier operating under conditions of high temperature and pressure by forming a slurry of the carbonaceous material and a liquid vehicle, raising the internal pressure of the slurry to the operating level of the gasifier, drying the carbonaceous material by entraining the carbonaceous material in a hot gas stream, and thereafter separating the carbonaceous material and feeding the carbonaceous material to the gasifier. The method is adaptable to using the gasifier effluent to dry the carbonaceous material and includes using process materials such as char accumulated from the process and condensing steam to provide a portion of the source of carbonaceous materials and vehicle for the slurry.

Description

United States Patent [1 1 Moody 1 Mar. 18, 1975 METHOD OF FEEDING SOLID CARBONACEOUS MATERIAL TO A HIGH TEMPERATURE REACTION ZONE [75] Inventor: Burton E. Moody, Allentown, Pa.
[73] Assignee: Air Products and Chemicals, Inc.,
Allentown, Pa.
[22] Filed: Oct. 12, 1972 [21] Appl. No.: 296,959
[52] US. Cl 48/197 R, 48/210, 48/DlG. 7 [51] Int. Cl. C10j 3/06 [58] Field of Search..... 48/197 R, 202, 210, DIG. 7, 48/206; 34/12, 22, 33; 110/7 R, 7 A, 7 S; 159/16 R, 29; 201/20; 252/373 STEAM HOT GASlFlER EFFLUENT 36 CARBONACEOUS MATERIAL CONDENSATE REACTANT STR EAM 3,715,195 2/1973 Tassoney et a1. 48/197 R Primary ExaminerS. Leon Bashore Assistant ExaminerPeter F. Kratz Attorney, Agent, or Firm-James C. Simmons; Barry Moyerman [5 7 ABSTRACT A method of feeding solid carbonaceous material to a gasifier operating under conditions of high temperature and pressure by forming a slurry of the carbonaceous material and a liquid vehicle, raising the internal pressure of the slurry to the operating level of the gas ifier, drying the carbonaceous material by entraining the carbonaceous material in a hot gas stream, and thereafter separating the carbonaceous material and feeding the carbonaceous material to the gasifier. The method is adaptable to using the gasifier effluent to dry the carbonaceous material and includes using process materials such as char accumulated from the process and condensing steam to provide a portion of the source of carbonaceous materials and vehicle for the slurry.
7 Claims, 2 Drawing Figures GAS TO PROCESS TO GASIFIER FEED NOZZLES METHOD OF FEEDING SOLID CARBONACEOUS MATERIAL TO A HIGH TEMPERATURE REACTION ZONE BACKGROUND OF THE INVENTION 1. Field of the Invention This invention pertains to the feeding of solid carbonaceous material, e.g. coal, into a high-pressure, hightemperature reaction zone such as a coal gasifier. In coal gasification, finely pulverized coal is reacted in the presence of steam and air oxygen at elevated temperature and pressure to form an effluent gas. If the product is to be a low BTU content gas, it is subject toremoval of hydrogen sulfide and then used directly. If a high methane content gas is to be produced, the effluent gas is then subjected to various process steps including water shift reaction, acid gas removal and methanation thereby yielding a synthetic natural gas. figsuch process is discgasgd in U.S. Pat. No. 2,840,462; another is the process referred to as the; BCR Two-Stage Super-Pressure Gasification Process developed by Bituminous Coal Research Incorporated of Monroeville, PA; and a third pertains to generation fo a synthetic gas by electrothermal hydrogasification developed by the Institute of Gas Technology of Chicago, ILL.
In the above processes, the finely divided carbonaceous material (coal) is fed to the gasification vessel by a conventional lock hopper feeding system, a piston feeder, and a hydrocarbon liquid slurry respectively after the coal has been ground to size, screened, dewatered, and stored in storage hoppers.
2. Prior Art.
Although use of a water slurry feed system for feeding solid carbonaceous materials to a hydrogasification vessel has not been shown in the prior art, slurry feed systems for use with other high-temperature reaction vessels for. finely divided solid carbonaceous material is known. For example, U.S. Pat. No. 3,116,143 discloses a slurry feeding system wherein a coal slurry is injected directly into the hot zone of a blast furnace for manufacturing iron. The Patentee discloses injecting the slurry directly into the blast furnace without dewatering or otherwise removing the moisture.
Another feed system for feeding dried coal to a blast furnace as shown in U.S. Pat. No. 3,250,016 wherein the Patentee discloses a fluidized bef for drying the coal by using blast furnace off gas prior to injection into the blast furnace.
U.S. Pat. No. 3,207,102 discloses a slurry feed for a steam generating unit such as is found in a commercial electrical generating plant. Here again the slurry is not dewatered prior to injection into the furnace and the slurry is further comminuted by impingement against a breaker in the furnace zone. U.S. Pat. No. 3,229,651 discloses an alternate slurry feed means for conducting a finely divided solid carbonaceous material into a steam boiler or the like.
In a two-stage, super-pressure gasifier as developed by Bituminous Coal Research Incorporated, it is contemplated that coal will be fed to the gasifier by a pressurized piston feeder in conjunction with a star-wheel feeder. The coal will be pressurized by the piston feeder and fed into the gasifier by the star-wheel feeder.
As an alternative system of feeding the gasifier, it has been suggested to use-a lock hopper system with and without staged pressure letdownlln the staged pressure system, a number of lock hoppers feed coal into a highpressure surge vessel from which the coal would be fed to the gasifier. After the coal is transferred from a hopper into the surge vessel, the high-pressure gas in the hopper is vented to a series of receivers at different pressure levels down to atmospheric pressure. Gas is vented first to the highest pressure receiver and when pressure equalization is approached the venting is switched to the receiver at the next lower pressure and so on until the final venting is to atmospheric pressure. The lock hopper is then refilled with coal then pressurized in staged from each gas receiver in turn and the receivers are maintained at constant pressure by pumping gas from the receiver at the next lowest pressure. F inal pressurization is made by pumping gas from the highest pressure receiver directly into the lock hopper.
In the non-staged lock hopper system, the coal is fed into oneof several alternating hoppers, the hopperis pressurized, the coal is injected into the gasifier and the hopper is vented for receiving the next charge.
In each of the above systems, the cost of compressing the gas increases significantly with increases in operating pressure. The staged system while being more expensive to install operates at lower cost because of a lower required volume of pressuring gas and lower compressing costs.
SUMMARY OF THE INVENTION In order to avoid the foregoing problems and to provide an improved method of feeding solid carbonaceous material to a high-temperature, high-pressure reaction vessel, it has been discovered that the solid carbonaceous material can be dispersed in a liquid vehicle in the form of a slurry, the slurry can be raised to an elevated pressure by means of a slurry pump, the slurry can be dried using the high-temperature effluents from the gasification vessel and simultaneously entrained in a humidified gas, the solid carbonaceous materials can be separated from the gas into which it has been entrained, and fed at high pressure into the gasifier by means of a stream of hot recycled gas or stream. In addition, the separated gas can be sent to the further purification steps without loss of volume of production for the overall gasification process. It is further contemplated that char separated and collected in the gasification process and condensed steam from the process or boiler feed water can be used in making up the initial slurry.
Therefore, it is the primary object of this invention to provide an improved method for feeding solid carbonaceous material to a high-pressure, high-temperature reaction zone.
It is another object of this invention to provide a method for feeding solid carbonaceous material to a gasification vessel.
It is still another object of this invention to provide a method for feeding pulverized coal to a gasification vessel.
It is yet another object of this invention to provide a method for feeding solid carbonaceous material to a partial oxidation reactor.
BRIEF DESCRIPTION OF THE DRAWING FIG. 1 is a schematic drawing of the method of the instant invention.
FIG. 2 is a schematic drawing of the method of the instant invention as applied to a process for producing a synthesis gas.
DETAILED DESCRIPTION OF THE INVENTION so that the end product is a gas substantially methane that is suitable for pipeline use.
Referring now to FIG. 1, there is shown a slurry tank with an impeller 12 mounted on shaft 14 rotated by a suitable motor or other rotating device not shown. The tank 10 receives the pulverized carbonaceous material from a feed hopper or pipe that is shown by arrow 16. The pulverized carbonaceous material generally is coal but can include coke, char or low grade volatile materials such as lignite. Arrow l8 designates a source of supply of water which can be fresh water from utility, boiler feed water, or condensed steam from the process generally referred to as condensate. The slurry tank 10 isconnected via conduit 10 to a slurry pump 22 which in turn is connected through conduits 24, 26, heat exchanger 28, and valve 30, to a mixing chamber 32. The heat exchanger 28 is included in the process stream and can be bypassed if not needed as by conduit 34. If used, the heat exchanger 28 can be used to heat the slurry by means of heat exchange with steam, hot condensate, hot gas from the gasifier or hog gas from an independent gas heater (not shown). The mixing chamber 32 contains an inlet conduit 36 for receiving hot gas, which in turn is connected to another conduit 38 having disposed therein temperature indicating control valve 40. An outlet conduit 42 is connected to a separator 44, which in turn has an outlet gas conduit 46 and a solids removal device shown as 48. Removal device 48 in turn is connected to a coal feeder 50, which in turn is connected to a conduit 52 to a venturi nozzle 54. A conduit 56 is connected to the venturi nozzle 54 in order to entrain the coal into a reactant gas for injection of the reactant and gas and coal into the gasifier.
In the above process shceme, solid carbonaceous material, e.g. coal is fed through conduit 16 and condensate through conduit 18 into the slurry tank 10. The impeller 12 is used to agitate the coal and condensate in tank 10 to form a slurry having approximately 50 percent by weight solids. The slurry is then pumped under pressure to the mixing chamber 32 which chamber is maintained at the pressure of the gasifier vessel as the slurry is sprayed therein. In the mixing chamber 32, the slurry is contacted by the hot gasifier effluent entering through conduit 36. The action of the hot gasifier effluent and the spraying of the slurry causes the water to v be driven off and the solid carbonaceous material (coalibecomes dried and entrained in the humidified hot gasifier effluent: The evaporated water humidifies the effluent gas to enhance subsequent reactions in the shift convertor where the gas is used. Steam conduit 38 is included to maintain the temperature of the spray drying chamber and to adjust the humidity of the effluent gas with the entrained solid carbonaceous material which is passed through conduit 42 to a cyclone separator and solid carbonaceous storage vessel 44 wherein the solid carbonaceous material is separated from the gas ans stored for use as needed with the solid carbonaceous material being withdrawn through a solids removal device, e.g., conduit 48, into feeder 50 for feeding into the gasification vessel. The dried carbonaceous material is fed under pressure from conduit 52 into centuri feed nozzle 54 for pneumatic feeding to the reactor or gasifier. It may be advantageous to entrain the coal in a reactnat stream 56 which can be either hot recycled gas or steam used in the gasifier reaction vessel as in U.S. Pat. No. 2,840,462. Alternatively, the coal can be fed through conduit 52 directly to the gasifier nozzles. The gas separated in separator 44 is conducted through conduit 46 to subsequent processing steps (e.g. water gas shift reactor, acid gas removal, and methanation) in the overall gasification scheme so that none of the gasifier effluent is sacrificed in feeding the coal or other solid carbonaceous material to the gasifier.
The foregoing process provides a method for feeding dried preheated coal to a gasifier. It is possible to preheat the coal during drying to a temperature .of approximately 500F therebyachieving overall process economies in the production of synthetic natural gas by reducing oxygen requirements.
The foregoing basic method can be modified for application to other gasification schemes. For example. there is a proposed coal gasification process developed by Bituminous Coal Research Incorporated wherein a synthetic natural gas will be produced at the rate of 250 MM SCF/SD. The gasification vessel for such a process requires heated coal at 80 atmospheres pressure for gasifier feed and requires process gasifier effluent temperature of 660F with a 1:1 steam to dry gas ratio for feed to the shift converter, which is the step after the gasifier.
For such a gasification vessel, the coal slurry is prepared as a 50 percent by weight mixture by adding coal at approximately 60F, hot condensate at approximately 212F and a low pressure steam at 50 psig and 298F into the slurry tank 10. The slurry is pumped at the desired pressure (80 atmospheres) and preheated by hot condensate in heat exchanger 28. Finally, the slurry is dried (32) and the coal and process gas separated in the cyclone 44. In order to accomplish this, it is proposed that the overall system will appear as follows. The first section of the process will encompass multiple train slurry preparation consisting of makedown tanks and mixers, low-pressure, centrifigal slurry pumps, holding tansk with mixers, and circulation pumps. In this section, coal sized at approximately percent less than 200 mesh and hot condensate direct from deaerators will be combined to produce a 50 weight percent coal water slurry in the make-down tanks. Each tank will have a 10-minute residence time and be of 16,500 gallon capacity. The slurry mixer will employ an axial flow, constant velocity discharge impeller with the shaft and impeller covered with rubber to minimize erosion. There will be provision in these tanks for steam sparging for heating of the slurry and usual circumstances where the coal may have settled to the bottom of the tank. After the slurry is throughly mixed, it will flow into a manifold from which it will be pumped to the holding tanks. Low pressure centrifugal pumps each rated at 50 percent of plant capacity will be used to pump the slurry into the holding tanks which will each have a capacity of approximately 65,000 gallons and will provide 40-minute residence time for the slurry. As with the make-down tanks, the mixers will require protection from erosion; however, the horse power needed will be less since they will only be required to agitate the slurry enough to maintain the coal in the form of a slurry. Circulating pumps will be provided to circulate the slurry through a manifold and return it to the pressurized slurry tanks in order to maintain the stability of the slurry.
The next section of the process containsof the slurry pumping and hot condensate heat exchangers. The slurry pumps will develop the system pressure of approximately 80 atmospheres using reciprocating singleacting Triplex plunger pumps. The slurry will be discharged from the pumps at 1,200 psi and approximately 230F into a heat exchanger wherein the slurry will be raised to approximately 430F before feeding into the dryer. The temperature of 430F is required in order to obtain the desired gas and coal temperature with a 1 to 1 steam to dry gas ratio in the process gas from the dryer. Care must be taken in constructing special inlet channels and distribution in the heat exchanger to prevent or minimize erosion due to the abrasive characteristics of the slurry.
The next section of the overall process will consist of slurry drying wherein there is employed a spray dryer, a cyclone, and a pair of coal receivers. The coal slurry is dried and the water is vaporized in a spray dryer which will operate at approximately 80 atmospheres pressure with exit gas temperatures of 660F. Gas used for heating the slurry will be effluent gas from the gasifier. In the BCR Process, the effluent gas from the gasifier is at a temperature of 1,750F but before being used is subjected to a char separation in a cyclone separator. The char is then recycled to the gasifier. In the BCR Process, a second cyclone separation is effected to eliminate the balance of the char from the gaas and lower the gas temperature to approximately 1,100F. A portion of the gas from the first and second cyclone is combined with a net temperature of about 1,600F which gas is used in the spray dryers to content the slurry which is pumped into the dryer and atomized. If required, steam canbe added'to increase the atomization of the slurry or it can be added later to achieve the desired steam to dry gas ratio. The dried coal and humidified gas is then taken over into a cyclone where the coal is separated and conducted into a pair of receivers, which will operate on a switching cycle to eliminate back surging through the cyclone. The separated gas will be taken and fed to the carbon monoxide shift converters for further processing into the required pipeline gas. At this stage, the coal can be withdrawn from the storage hoppers under pressure and fed to the gasifier for reacting.
There is shown in FIG. 2 a method of using a slurry feed in conjunction with a commercial partial oxidation unit. The partial oxidation unit is shown in U.S. Pat. No. 2,595,234 and is used to produce a synthesis gas consisting mainly of water vapor, hydrogen, carbon dito free the mixer and impeller for start up under u'n- I oxide, and carbon monoxide, which can be subsequently shift converted to carbon dioxide and hydrogen. The hydrogen is then separatedout and used for various processesincluding gasification of crude oil or as product hydrogen for other manufacturing operations.
The partial oxidation reactoris shown as60 in FIG. 2 and has an inlet conduit 62 for receiving the solid carbonaceous material to be reacted, a second inlet conduit 64 for receiving oxygen that reacts with the solid carbonaceous material and outlet conduit 66 for conduiting the synthesis gas out of the reactor and a bottom clean out 68 for removing slag and/or ash from the gasifier. The product gas is conducted from conduit 66 to a separator 70 and from separator 70 through conduit 72 to a waste heat boiler 74, from waste heat boiler 74 through conduit 76 to a dryer 78, from dryer 78 to separator 80 and from separator 80 through to purification (shift) through conduit 81. Coal is fed to the reactor 60 through conduit 82 which is in turn connected to a pneumatic injectionm device 84 which receives the coal feed from conduit 86 and carries the coal into the reactor 60 by means of steam shown by arrow 88. Conduit 86 is connected in turn in reverse order to separator 80 and dryer 78. From dryer 78 a conduit 90 is connected to preheater 92 which in turn is connected to slurry pump 94 through conduit 95-for receiving the coal slurry. Slurry pump 94 is connected to the slurry tank 96 by conduit 98. Slurry tank 96 include'san impeller 100 and a drive shaft 102, which are connected to a suitable source of power such as a motor (not shown). Alternatively, the slurry can be made as the result of wet grinding of the carbonaceous material in which event tank 96 is bypassed through conduit 104 directly to the slurry pump 94. y
In operating the method of FIG. 2 in the one alternative solid carbonaceous material in the form of coal, char, coke, or combinations thereof are introduced into the slurry tank 96 and are designated as arrow 106. Condensate is added to tank 96 as indicated by arrow 108, e.g., condensate from the process in the form of boiler feed water, condensed steam, or fresh water. The impeller is activated to provide the proper mixing of the solid carbonaceous material and condensate to form the slurry. Alternatively as shown by arrow 104, the slurry can be formed as the coal is wet ground to size and passed directly to the slurry pump 94 through conduit 104. The preferably slurry is one that consists of 40 to 60 percent by weight water with the rest solid carbonaceous material. The slurry is passed to the slurry pump 94 where its pressure is raised to that above the operating pressure of the gasifier 60 and is then preheated in heat exchanger 92 if the overall heat balance of the system requires additional heat into the system. The slurry is then injected into the dryer 78 where it is contacted by the hot effluent from the waste heat boiler 74 and the water is driven off and the solid carbonaceous material is raised in temperature and entrained in a gas. As described in connection with FIG. 1, a source of steam can be provided through conduit 77 to control the humidity and temperature of the effluent in conduit 79 from dryer 78. The gas solid mixture is then conducted to the cyclone separator 80 wherein the coal and gas are separated, the gas going from conduit 81 on to further purification and the coal being conducted through conduit 86 into the gasification vessel by means of the injection nozzle 84. Waste heat boiler 74 is included in'this system to recover heat and-at the same time-to produce high-pressure steam for the overall reaction and for injecting into the gasifier itself.
The foregoing method of feeding a partial oxidation unit accomplishes the following:
1. The process provides a dry preheated carbonaceous solid fuel to the gasifier thereby increasing gasifier efficiency.-.
2. In the drying preheating step, the water is evaporated without the use of additional oxygen and simultaneously provides steam required for subsequent shift operations of the effluent.
3. The process provides a method for utilizing a high-.
sulfur fuel such as coal, petroleum, coke or the like by producing sulfur as hydrogen sulfide because of the overall reducing atmosphere.
Having thus described my invention, what is desired to be secured by Letters Patent of the United States is contained in the following claims.
I claim: 1. A method of feeding carbonaceous particles to a gasifier-operating at elevated temperature and pressure comprising the steps of:
forming a slurry of solid carbonaceous particles with water as a liquid vehicle; pumping the slurry into a drying chamber, said drying chamber being separated from said gasifier, maintained at approximately the operating pressure of the gasifier wherein the slurry is mixed with hot effluent gases from the gasifier so that the carbonaceous particles without substantial reaction are dried and heated and entrained in the effluent gas;
substantially immediately separating the entrained carbonaceous particles from the effluent gas which effluent gas includes evaporated water vehicle in the form of steam; and injecting the separated carbonaceous particles into the gasifier.
2. A method according to claim 1 wherein the slurry I is preheated by indirect heat exchange with a hot gas prior to entering the drying chamber.
3. A method. according to claim 1 wherein steam is added to the drying chambercontaining the slurry and gasifier effluent gas to adjust'the temperature of the effluent gas thereby controlling the humidity ofthe effluent gas.
4. A method of feeding solid carbonaceous particles to a gasifier operating at high temperature and high pressure comprising the steps of:
providing a feed stream of solid carbonaceous particles suspended in water; g
raising the internal pressure of the feed stream to a pressure above the operating pressure of the gasifier;
introducing-the pressurized feed stream to a drying chamber, said drying chamber being separated from said gasifier, wherein it is contacted by hot gaseous effluent from the gasifier without substantial reaction so that, the water is evaporated, and the dried solid carbonaceous particles are entrained in the gaseous effluent;
substantially immediately separating the dried solid carbonaceous particles from the gaseous effluent; and entraining the separated solid carbonaceous particles in a stream of reactant being fed into the gasifier.
5. A method according to claim 4 wherein the feed stream is a slurry of 40% by weight solid carbonaceous particles selected from the group consisting of. coal, coke, char or mixtures thereof in water prepared in a mixing tank.
6. A method according to claim 4 wherein the slurry is preheated prior to being introduced into the drying chamber.
7. A method according to claim 4 wherein the gaseous effluent separated from the solid carbonaceous particles consists "essentially of-water vapor, carbon monoxide, and hydrogen, and issubjected to a subsequent shift step wherein carbon dioxide and hydrogen .LILAUAJU ILLA la. .1 M
mm: r I est-141cm; OF contraction Patent 3,871,839 Dated March 18 1975 Inventoflx) Burton E. Moody It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
Column 1, line 26, "f0" shouldbe -of- 0 I Column 1, line 48, "bef" should be--bed-- Column 2, line 15, "staged" should be--stages Colunm 3, line 34, after "conduit" "10" should be-20- Column 3, line 41, meg" should be-hot- Column 3, line 54, shceme" should bescheme Column 4 line 10, "ans" should beand-- Column 4, 1ine 15, "centuri" should be-venturi-- Column 4, line 17, "reactnat" should be-re a ct ant- Column 4, line 57, after "down" de1etequotation marks-- Column 4, line 58, "tansk" should be--tanks Column 5, line 18, "contains" should be--consists- Column 5, line 45, "gaas" should begas-- Column 5, line 49, "content" 514511161 be-contact-- Column 6, lines 11-12, "con-duiting" should beconducting nmmv' frn .I QMMMQE conmewon Patent No. 3,871,839 Dated March 18 1975 .Invent fls) Burton E. Moodv (CONTINUED) It is certified that error appears in the above-identified patent and that said Letters Patent: are hereby corrected as shown below:
m I Page 2 of 2 4 r O I v Column 6 line 2]., after "injection" d elet e' m Column '6, line 48, "preferably" should be-preferable- Q Column 7, lines 34-35,; after "entrained" and before "carbonaceous" insert-dried Signed and Scaled this second Day of December 1975 [SEAL] Attest:
. RUTH c. MASON c. MARSHALL mum Arresting Officer Commissioner ofParems and Trldenlarks in m UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION PatentNo 3,871,839 Dated March 18, 1975 Burton E. Moody Inventor(s) It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
Column 2, line 47, "stream" should read steam Column 5, line 3, "throughly" should read thoroughly Signed and Scaled this sixth D y of January 1976 [SEAL] A ttest:
RUTH C. MASON C. MARSHALL DANN Arresting Officer (mnmissioner nfPatents and Trademarks

Claims (7)

1. A METHOD OF FEEDING CARBONACEOUS PARTICLES TO A GASIFIER OPERATING AT ELEVATED TEMPERATURE AND PRESSURE COMPRISING THE STEPS OF: FORMING A SLURRY OF SOLID CARBONACEOUS PARTICLES WITH WATER AS A LIQUID VEHICLE; PUMPING THE SLURRY INTO A DRYING CHAMBER, SAID DRYING CHAMBER BEING SEPARATED FROM SAID GASIFIER, MAINTAINED AT APPROXIMATELY THE OPERATING PRESSURE OF THE GASIFIER WHEREIN THE SLURRY IS MIXED WITH HOT EFFLUENT GASES FROM THE GASIFIER SO THAT THE CARBONACEOUS PARTICLES WITHOUT SUBSTANTIAL REACTION ARE DRIED AND HEATED AND ENTRAINED IN THE EFFLUENT GAS;
2. A method according to claim 1 wherein the slurry is preheated by indirect heat exchange with a hot gas prior to entering the drying chamber.
3. A method according to claim 1 wherein steam is added to the drying chamber containing the slurry and gasifier effluent gas to adjust the temperature of the effluent gas thereby controlling the humidity of the effluent gas.
4. A method of feeding solid carbonaceous particles to a gasifier operating at high temperature and high pressure comprising the steps of: providing a feed stream of solid carbonaceous particles suspended in water; raising the internal pressure of the feed stream to a pressure above the operating pressure of the gasifier; introducing the pressurized feed stream to a drying chamber, said drying chamber being separated from said gasifier, wherein it is contacted by hot gaseous effluent from the gasifier without substantial reaction so that, the water is evaporated, and the dried solid carbonaceous particles are entrained in the gaseous effluent; substantially immediately separating the dried solid carbonaceous particles from the gaseous effluent; and entraining the separated solid carbonaceous particles in a stream of reactant being fed into the gasifier.
5. A method according to claim 4 wherein the feed stream is a slurry of 40% by weight solid carbonaceous particles selected from the group consisting of coal, coke, char or mixtures thereof in water prepared in a mixing tank.
6. A method according to claim 4 wherein the slurry is preheated prior to being introduced into the drying chamber.
7. A method according to claim 4 wherein the gaseous effluent separated from the solid carbonaceous particles consists essentially of water vapor, carbon monoxide, and hydrogen, and is subjected to a subsequent shift step wherein carbon dioxide and hydrogen are produced.
US296959A 1972-10-12 1972-10-12 Method of feeding solid carbonaceous material to a high temperature reaction zone Expired - Lifetime US3871839A (en)

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JP48111879A JPS4974203A (en) 1972-10-12 1973-10-04
BE136472A BE805825A (en) 1972-10-12 1973-10-09 PROCESS FOR BRINGING A SOLID CARBONY MATERIAL INTO A HIGH TEMPERATURE REACTION ZONE
FR7336219A FR2202929B1 (en) 1972-10-12 1973-10-10
GB4760473A GB1407176A (en) 1972-10-12 1973-10-11 Method of feeding solid carbonaceous material to a high temperature reaction zone
DE19732350953 DE2350953A1 (en) 1972-10-12 1973-10-11 METHOD OF FEING CARBURETOR INTO A CARBURETOR
PL1973165799A PL96935B1 (en) 1972-10-12 1973-10-12 METHOD OF PUTTING THE STEEL COAL MATERIAL TO THE GAS GENERATOR

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US3963426A (en) * 1974-07-22 1976-06-15 Cameron Engineers, Incorporated Process for gasifying carbonaceous matter
US4158552A (en) * 1977-08-29 1979-06-19 Combustion Engineering, Inc. Entrained flow coal gasifier
US4153427A (en) * 1978-02-23 1979-05-08 The United States Of America As Represented By The United States Department Of Energy Apparatus and method for feeding coal into a coal gasifier
US4284416A (en) * 1979-12-14 1981-08-18 Exxon Research & Engineering Co. Integrated coal drying and steam gasification process
US4624684A (en) * 1985-09-03 1986-11-25 Texaco Inc. Process for feeding and gasifying solid carbonaceous fuel
EP0639220A1 (en) * 1992-05-08 1995-02-22 State Electricity Commission Of Victoria Integrated carbonaceous fuel drying and gasification process and apparatus
EP0639220A4 (en) * 1992-05-08 1995-05-10 Victoria Elect Commission Integrated carbonaceous fuel drying and gasification process and apparatus.
US5695532A (en) * 1992-05-08 1997-12-09 State Electricity Commission Of Victoria Integrated carbonaceous fuel drying and gasification process and apparatus
CN1039653C (en) * 1992-05-08 1998-09-02 维多利亚州电力委员会 Integrated carbonaceous fuel drying and gasification process and apparatus
US20010054256A1 (en) * 2000-05-09 2001-12-27 Yukuo Katayama Method for the gasification of coal
US6997965B2 (en) 2000-05-09 2006-02-14 Toyo Engineering Corporation Method for the gasification of coal
US20120222353A1 (en) * 2002-02-05 2012-09-06 The Regents Of The University Of California Method to Produce Methane Rich Fuel Gas from Carbonaceous Feedstocks Using a Steam Hydrogasification Reactor and a Water Gas Shift Reactor
US9493721B2 (en) * 2002-02-05 2016-11-15 The Regents Of The University Of California Method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor
US20080216406A1 (en) * 2007-02-14 2008-09-11 Xin Wang Method of gasification burner online feeding
US7976595B2 (en) * 2007-02-14 2011-07-12 Yankuang Group Corporation Limited Method of gasification burner online feeding
US9074150B2 (en) * 2007-12-26 2015-07-07 Total Raffinage Marketing Treatment chain and process for the thermochemical conversion of a wet feed of biological material by gasification
US20110314736A1 (en) * 2007-12-26 2011-12-29 Total Raffinage Marketing Treatment chain and process for the thermochemical conversion of a wet feed of biological material by gasification
CN102021040A (en) * 2009-09-14 2011-04-20 通用电气公司 Method and apparatus for drying solid feedstock using steam
CN102021040B (en) * 2009-09-14 2014-11-26 通用电气公司 Method and apparatus for drying solid feedstock using steam
US9057030B2 (en) 2010-10-30 2015-06-16 General Electric Company System and method for protecting gasifier quench ring
US8999018B2 (en) * 2012-08-22 2015-04-07 Korea Institute Of Energy Research Apparatus and method for rapidly producing synthetic gas from bio-diesel by-product using microwave plasma
US20140054504A1 (en) * 2012-08-22 2014-02-27 Korea Institute Of Energy Research Apparatus and method for rapidly producing synthetic gas from bio-diesel by-product using microwave plasma
WO2021011020A1 (en) * 2019-07-16 2021-01-21 Infiniforce, Inc. Petroleum sludge or other wastes recycle treatment system
US20210017022A1 (en) * 2019-07-16 2021-01-21 Infiniforce, Inc. Petroleum sludge or other wastes recycle treatment system
US11667525B2 (en) * 2019-07-16 2023-06-06 Infiniforce, Inc. Petroleum sludge or other wastes recycle treatment system

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DE2350953A1 (en) 1974-04-18
FR2202929B1 (en) 1977-05-27
ZA737437B (en) 1974-08-28
BE805825A (en) 1974-02-01
PL96935B1 (en) 1978-01-31
GB1407176A (en) 1975-09-24
JPS4974203A (en) 1974-07-17
FR2202929A1 (en) 1974-05-10

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