CA2756753C - Rendering coal as an environmentally carbon dioxide neutral fuel and a regenerative carbon source - Google Patents

Rendering coal as an environmentally carbon dioxide neutral fuel and a regenerative carbon source Download PDF

Info

Publication number
CA2756753C
CA2756753C CA2756753A CA2756753A CA2756753C CA 2756753 C CA2756753 C CA 2756753C CA 2756753 A CA2756753 A CA 2756753A CA 2756753 A CA2756753 A CA 2756753A CA 2756753 C CA2756753 C CA 2756753C
Authority
CA
Canada
Prior art keywords
carbon dioxide
methanol
catalyst
coal
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2756753A
Other languages
English (en)
French (fr)
Other versions
CA2756753A1 (en
Inventor
George A. Olah
G.K. Surya Prakash
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Southern California
Original Assignee
University of Southern California
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Southern California filed Critical University of Southern California
Publication of CA2756753A1 publication Critical patent/CA2756753A1/en
Application granted granted Critical
Publication of CA2756753C publication Critical patent/CA2756753C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/04—Methanol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)
CA2756753A 2009-04-10 2010-04-07 Rendering coal as an environmentally carbon dioxide neutral fuel and a regenerative carbon source Expired - Fee Related CA2756753C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16829709P 2009-04-10 2009-04-10
US61/168,297 2009-04-10
PCT/US2010/030229 WO2010118127A1 (en) 2009-04-10 2010-04-07 Rendering coal as an environmentally carbon dioxide neutral fuel and a regenerative carbon source

Publications (2)

Publication Number Publication Date
CA2756753A1 CA2756753A1 (en) 2010-10-14
CA2756753C true CA2756753C (en) 2016-11-29

Family

ID=42629525

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2756753A Expired - Fee Related CA2756753C (en) 2009-04-10 2010-04-07 Rendering coal as an environmentally carbon dioxide neutral fuel and a regenerative carbon source

Country Status (8)

Country Link
US (1) US8461215B2 (enExample)
EP (1) EP2417081A1 (enExample)
JP (1) JP2012523420A (enExample)
KR (1) KR20120010232A (enExample)
CN (1) CN102388005B (enExample)
AU (1) AU2010234500B2 (enExample)
CA (1) CA2756753C (enExample)
WO (1) WO2010118127A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109772371A (zh) * 2017-11-14 2019-05-21 中国石油化工股份有限公司 一种复合物及其制备方法和应用
CN109772441A (zh) * 2017-11-14 2019-05-21 中国石油化工股份有限公司 一种壳核结构的催化剂及其制备方法和应用

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3011693C (en) 2009-09-08 2021-03-09 The Ohio State University Research Foundation Synthetic fuels and chemicals production with in-situ co2 capture
DE102010041033A1 (de) * 2010-09-20 2012-03-22 Siemens Aktiengesellschaft Stoffverwertung mit elektropositivem Metall
US8697759B1 (en) * 2012-10-09 2014-04-15 University Of Southern California Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming
EP2953892B1 (en) * 2013-02-05 2023-04-05 Ohio State Innovation Foundation Methods for fuel conversion
JP6302824B2 (ja) * 2014-11-27 2018-03-28 東京瓦斯株式会社 芳香族炭化水素の製造方法
US10040737B2 (en) 2015-07-14 2018-08-07 John E. Stauffer Methanol production from methane and carbon dioxide
AU2017250214B2 (en) 2016-04-12 2021-08-12 Ohio State Innovation Foundation Chemical looping syngas production from carbonaceous fuels
WO2018004992A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Conversion of methane to dimethyl ether
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
DE112016007162A5 (de) * 2016-09-25 2019-05-16 Peter Paul Smolka Treibstoff-Produktionsanlage für Kraftwerke
US11090624B2 (en) 2017-07-31 2021-08-17 Ohio State Innovation Foundation Reactor system with unequal reactor assembly operating pressures
WO2020033500A1 (en) 2018-08-09 2020-02-13 Ohio State Innovation Foundation Systems, methods and materials for hydrogen sulfide conversion
EP3894061B1 (en) 2019-01-17 2023-12-20 Ohio State Innovation Foundation Systems, methods and materials for stable phase syngas generation
CA3129146A1 (en) 2019-04-09 2020-10-15 Liang-Shih Fan Alkene generation using metal sulfide particles
EP4010115A4 (en) 2019-08-19 2023-07-19 Ohio State Innovation Foundation IMMOBILIZED METAL OXIDE NANOPARTICLES ON A MESOPOROUS SUPPORT
EP4021847B1 (en) * 2019-08-26 2025-06-25 ExxonMobil Technology and Engineering Company Process intensification for reverse flow reactors
US12161969B2 (en) 2019-09-03 2024-12-10 Ohio State Innovation Foundation Redox reaction facilitated carbon dioxide capture from flue gas and conversion to carbon monoxide
AU2021301359A1 (en) 2020-06-29 2023-03-02 Ohio State Innovation Foundation Systems and methods for high reactant conversion through multiple reactant flow ratio staging
WO2023230576A2 (en) * 2022-05-25 2023-11-30 Kellogg Brown & Root Llc Integrated carbon capture and olefins production process
WO2025170652A1 (en) * 2024-02-09 2025-08-14 Saudi Arabian Oil Company Co-production of sustainable low-carbon fuels from co2 and h2

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03200734A (ja) * 1989-12-28 1991-09-02 Mitsubishi Heavy Ind Ltd メタノールの合成方法
JPH0565237A (ja) * 1991-09-10 1993-03-19 Mitsubishi Heavy Ind Ltd メタノールを媒体としたエネルギ供給方法
JP2902216B2 (ja) * 1992-06-29 1999-06-07 三菱重工業株式会社 エネルギ源材料の循環方法
JPH10195459A (ja) * 1996-12-30 1998-07-28 Nkk Corp ジメチルエーテル合成用原料ガス製造装置
AU2006236802B2 (en) * 2005-04-15 2011-09-01 University Of Southern California Selective oxidative conversion of methane to methanol, dimethyl ether and derived products
US7608743B2 (en) * 2005-04-15 2009-10-27 University Of Southern California Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products
KR100732784B1 (ko) * 2005-06-17 2007-06-27 한국가스공사 탄화수소로부터 디메틸에테르를 제조하는 방법
US20090264543A1 (en) * 2005-08-01 2009-10-22 Bp, P.L.C. Integrated Process for the Co-Production of Methanol and Demethyl Ether From Syngas Containing Nitrogen
US8198338B2 (en) * 2006-03-20 2012-06-12 Cri Ehf Process for producing liquid fuel from carbon dioxide and water
US7795175B2 (en) 2006-08-10 2010-09-14 University Of Southern California Nano-structure supported solid regenerative polyamine and polyamine polyol absorbents for the separation of carbon dioxide from gas mixtures including the air
US7378561B2 (en) * 2006-08-10 2008-05-27 University Of Southern California Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material
CN100427443C (zh) * 2006-10-11 2008-10-22 太原理工天成科技股份有限公司 一种同时生产甲醇、尿素和人工燃气的方法
US7906559B2 (en) * 2007-06-21 2011-03-15 University Of Southern California Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas
US7704369B2 (en) * 2007-07-13 2010-04-27 University Of Southern California Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109772371A (zh) * 2017-11-14 2019-05-21 中国石油化工股份有限公司 一种复合物及其制备方法和应用
CN109772441A (zh) * 2017-11-14 2019-05-21 中国石油化工股份有限公司 一种壳核结构的催化剂及其制备方法和应用

Also Published As

Publication number Publication date
EP2417081A1 (en) 2012-02-15
CN102388005A (zh) 2012-03-21
AU2010234500B2 (en) 2015-02-19
US20100261125A1 (en) 2010-10-14
KR20120010232A (ko) 2012-02-02
US8461215B2 (en) 2013-06-11
AU2010234500A1 (en) 2011-10-13
JP2012523420A (ja) 2012-10-04
WO2010118127A1 (en) 2010-10-14
CA2756753A1 (en) 2010-10-14
CN102388005B (zh) 2015-09-23

Similar Documents

Publication Publication Date Title
CA2756416C (en) Rendering natural gas as an environmentally carbon dioxide neutral fuel and a regenerative carbon source
US8461215B2 (en) Rendering coal as an environmentally carbon dioxide neutral fuel and a regenerative carbon source
US8461218B2 (en) Rendering petroleum oil as an environmentally carbon dioxide neutral source material for fuels, derived products and as a regenerative carbon source
Goeppert et al. Recycling of carbon dioxide to methanol and derived products–closing the loop
Dalena et al. Methanol production and applications: an overview
CN101743343B (zh) 水性介质中二氧化碳至用于甲醇制备的一氧化碳和氢的电解
JP5145213B2 (ja) 二酸化炭素のメタノール、ジメチルエーテルおよび派生生成物への効率的且つ選択的変換法
US8212088B2 (en) Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products
CA2728322A1 (en) Stockpiling methanol and/or dimethyl ether for fuel and energy reserves
Herrero Conversion of Carbon Dioxide and Crude Glycerine Into Value-added Products
CN101747203B (zh) 沼气直接制取碳酸二甲酯副产制液体燃料甲醇的方法

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20141222

MKLA Lapsed

Effective date: 20220301

MKLA Lapsed

Effective date: 20200831