CA2728540A1

CA2728540A1 - Cushioning device

Info

Publication number: CA2728540A1
Application number: CA2728540A
Authority: CA
Inventors: Philip C. Yang; Charles E. Lundy, Jr.
Original assignee: Schering Plough Healthcare Products Inc
Current assignee: Bayer Consumer Care Holdings LLC
Priority date: 2008-06-27
Filing date: 2009-06-26
Publication date: 2009-12-30
Also published as: AR089933A2; AU2009262057A1; BRPI0913961A2; EP2310467A2; JP2012224868A; WO2009158560A3; AR089932A2; US20090320324A1; US20120060304A1; CO6331356A2; WO2009158560A2; AR072377A1; MX2010014523A; JP5244238B2; JP2011525446A

Abstract

A cushioning device comprising a sticky surface, the device comprising a gel material bound to a thermoplastic film material having a polarity compatible with the gel material, wherein the thermoplastic film material further comprises a pressure sensitive adhesive located on a surface of the film material opposite to the surface that is bonded to the gel material.

Description

CUSHIONING DEVICE
Background of The Invention The subject invention is directed to cushioning devices comprising a pressure sensitive adhesive. In particular, the invention concerns the use of pressure sensitive adhesive materials to improve the hold of soft gel cushioning devices. One of the key attributes of the footwear cushions is to prevent the footwear from rubbing sensitive areas of skin, in particular in the heel area.
5 However, in order to achieve all the desired attributes of the cushion, the cushion needs to stay in place firmly during movement associated with normal use of footwear. Cushioning devices made of soft gels are known in the art and are desirable for their comfort, flexibility, durability and look. The assignee of this invention, Schering-Plough Healthcare Products, Inc., markets a cushioning 2 0 device under the trade name Dr. Scholl'sO Gel Heel Liner, which comprises a thermoplastic polyurethane (TPU) film bonded to a polyurethane (PU) gel, where the PU gel is produced in a way to have a sticky surface. However, no additional adhesive is used in this product. The Heel Liner is packaged with a release film to preserve the tackiness of the PU gel sticky surface, which is then applied to the 25 shoe to hold the liner in place. The TPU film provides a nonstick surface opposite the sticky surface, which nonstick contacts the wearers foot, sock, or hosiery.
It has now been determined, however, that the sticky PU gel does not hold the liner in place for extended periods of use as may be desired for a cushioning element. Pressure sensitive adhesive materials have been used in the art.

30 However, direct modification of a sticky PU gel with a pressure sensitive adhesive did not produce a cushioning element with a stronger hold. Thus, a cushioning device that provides the benefit of a gel and provides for long term hold in the shoe where placed would be desirable. Further, a method of manufacturing a gel cushioning device with a pressure sensitive adhesive would also be desirable.
These and other advantages follow from the invention described and claimed here.

Summary Of The Invention The subject invention provides a cushioning device comprising a layer of polyurethane gel material comprising top and bottom surfaces, at least one layer of thermoplastic polyurethane film material bonded to the one or both of said top and bottom surfaces thereof, and a layer of pressure sensitive adhesive bonded to one of said at least one thermoplastic polyurethane film material, wherein the pressure sensitive adhesive is located on a surface of the thermoplastic polyurethane film opposite to the surface contacting said bottom surface of said polyurethane gel material.
The subject invention also provides a get cushioning device comprising a sticky surface, the device comprising a gel material bound to a thermoplastic film material having good compatibility with the gel material, wherein the thermoplastic film material further comprises a pressure sensitive adhesive located on a surface of the film material opposite to the surface that is bonded to the gel material.
2 W The subject invention further provides gel cushioning device comprising a sticky surface, the device comprising a layer of gel material having an upper and lower surface and two layers of thermoplastic film material, each film material comprising upper and lower surfaces, wherein the upper surface of the gel material is bonded with the lower surface of one of said layers of film material and 25 the lower surface of the gel material is bonded with the upper surface of the other of said layers of film material, wherein at least one of the layers of film material comprises a pressure sensitive adhesive on a surface opposite the surface bonded to the gel material thereby providing the sticky surface of the device.
The subject invention also provides a method of constructing a gel cushioning device comprising a sticky surface, which comprises loading gel material into a mold cavity comprising at least one layer of thermoplastic film material, said at least one layer of thermoplastic film material comprising upper and lower surfaces, and curing the gel material to form a solid gel, such that the cured gel -.3terial is bonded with the fnl material and wherein said at least one of ti on a surface opposite the surface bonded to the gel material thereby providing the sticky surface of the device.

Brief Description Of The Drawings Figure 1A depicts a cross section of a prior art cushioning element.

Figure 1 B depicts a cross section of an example embodiment of the cushioning element of the invention.

Figure 2 depicts a cross section of a second example embodiment of the cushioning element of the invention.

Detailed Description As depicted in Figure 1, the products of the invention comprise an advance over prior art TPU/PU molded cushioning elements in that they provide for a means to attach a pressure sensitive adhesive to a gel material to provide extra holding capabilities. Figure 1A shows a cross section of a prior art material comprising gel material (104) bonded to a film material (102). The film material provides an exterior surface that resists friction to allow for smooth contact with skin or articles of clothing. Figure 1 B shows a cross section of an example embodiment of the subject invention wherein a layer of gel material having top and bottom surfaces comprises two layers of film material (102, 103) bonded to each surface of the gel material. In the practice of the invention, the gel material _ may comprise, for example polyurethane gel, styrenic based gels, or silicone gels.
The gel materials useful in the invention may typically have a Shore 00 hardness of between about 10 and about 80, preferably between about 30 and about 60. In certain embodiments of the invention, the polyurethane gel materials are used and may have a Shore 00 hardness of about 50. The gel material may typically 3 have a tN c ess of bet een 0.3 and 3 T e fÃI material may comnurse .. ._ _.. ~- ... I I -.,.. Fps cushion, the film material will likely comprise a thermoplastic polyurethane film material. Likewise, when an SEBS gel material is used in the cushion, the film material will likely comprise SEES thermoplastic film. The film materials may typically have a Shore A hardness of between about 40 to about 95 and may typically have a thickness of between 0.025 mm and 0.25 mm. In certain 1u embodiments according to this invention where more than one layer of film is used, the individual layers of film will have the same thickness. In certain additional embodiments according to this invention, individual layers of film will have different thicknesses. In practice, varying the thickness of the film will affect the softness and flexibility of the film and will likewise affect the softness and flexibility of the final gel cushion product. In certain embodiments, a thermoplastic polyurethane film is used and may be at least 0.025 mm thick.
As used herein polyurethane material will be understood to encompass polymers that contain a plurality of urethane linkages and comprised of either aliphatic or aromatic isocyanate prepolymers, and combinations thereof, both with 200 either di or trifunctional polyol polymers or prepolymers. The polyurethane material may optionally also contain other kinds of chemical linkages formed from the reactions of polyisocyanates, including but not limited to urea linkages, isocyanurate linkages, oxazolidone linkages, biuret linkages, allophanate linkages, combinations of these, and the like. Polyurethane gel materials are typically formed by reacting polyisocyanates with polyols. Examples of poly isocyanates include those formed from aliphatic or aromatic isocyanate prepolymers or combinations thereof. Examples of polyols include di or trifunctional polyol polymers or prepolymers Examples of polyols used include polyether polyols such as poly ethylene oxide) and poly(propylene oxide), modified poiyether polyols, polytetram.ethylene glycol, co;- ler:sation polyester polyols produced by reacting dicarboxylic acids with diols, lactone-type polyester polyols produced by ring opening polymerization of epsilon-caprolactone or the like, and polycarbonate polyols, vinyl polymers into which hydroxyl groups are introduced s ch ac ;nlyols having pcYsobu r ylene as tho aft chain, high levels of damping when tested by dynamic mechanical analysis performed in the range of -50 degree Celsius to 100 degrees Celsius. Gels material can include, but not limited to, the Kraton family of styrene-olefin-rubber block copolymers, thermoplastic polyurethanes, thermoset polyurethanes, thermoplastic poly olefins, polyamides, polyureas, polyesters and other polymer materials that ILO reversibly soften as a function of temperature. The preferred elastomers are a Kraton block copolymer of styrene/ethylene-co-butylene/styrene (SEES) or styrene/butadiene/styrene (SBS) with mineral oil incorporated into the matrix as a plasticizer.
As used herein, pressure sensitive adhesives (also known as contact 5 adhesives) are those that form viscoelastic bonds that are aggressively and permanently tacky, adhere without the need of more than slight pressure, and require no activation by water, solvent or heat. Pressure sensitive adhesives are typically available in solvent and latex or water based forms and are often based on non-crosslinked rubber adhesives, acrylics or polyurethanes.

In certain embodiments of the invention, the pressure sensitive adhesives may comprise acrylic and methacrylate adhesives, rubber-based pressure sensitive adhesives, styrene copolymers such as styrene-isoprene-styrene (SIS) and styrene-butadiene-styrene (SBS) copolymers with at least one tackifier, and silicones. Acrylic adhesives often use an acrylate system such as ethylene ethyl 25- acrylate (EEA) or ethylene methyl acrylate (EMA) copolymers, which are used to form hot melt PSA adhesives. Natural rubber, synthetic rubber or elastomer adhesives may typically comprise a variety of materials such as silicone, polyurethane, chloroprene, butyl, polybutadiene, isoprene or neoprene. Rubber and elastomers are characterized by their high degree of ""'ex'.Oility and elasticity.

33 In certain embodiments, the pressure sensitive adhesive material may comprise acrylate-based adhesive materials. The thickness of the layer of the pressure sensitive adhesive material may be varied by those of ordinary skill in the art according to the adhesive material used and :rye desired tack. in the p + of of the s s~ t' e o. ce : r _ y:.. ib fit . b tE 1.

An additional aspect of the invention comprises a method of manufacturing a cushioning element comprising a polyurethane gel material, which method comprises the step of bonding a polyurethane gel and a thermoplastic film material, wherein the thermoplastic film material comprises a pressure sensitive adhesive. In preparation of one embodiment of the invention it was discovered that the pressure sensitive adhesive layer cannot bond directly to the soft polyurethane gel during the molding process. To overcome this limitation, a layer of thermoplastic film material comprising the pressure sensitive adhesive layer was added to the mold and bonded to the polyurethane gel.

In certain embodiments of the invention, the cushioning element is prepared by a direct molding process where the gel material is applied directly to the mold, for example by injecting the gel prepolymer into the mold cavity.
During a direct molding process, before the gel material is injected, the film material layer comprising the pressure sensitive adhesive is applied to the mold cavity with the adhesive on the side of the film material closest to the mold and then the PU
gel 2 material is injected into the mold over the film material. The mold can be treated to resist bonding of the pressure sensitive adhesive or a release liner material can be applied in the mold first before the film material is applied to the mold.
In certain embodiments of the invention, the mold may be preheated to the desired curing temperature prior to injecting the gel material or heated after all materials 25 are loaded into the mold. For example, when using polyurethane gel materials according to the invention the mold temperature is typically between 85 -95C
and the cycle time is approximately 8 min. The pressure is typically low and not critical for this type of operation provided that the pressure is high enough to fill the cavity-mold with polyurethane prepolymer.

As depicted in Figure 2, a release liner 106 is shown contacting the exposed surface of the PSA layer depicted in Figure 1 S. In this example embodiment of the invention, the gel cushion can be manufactured by direct molding process. In this manner, the thin release liner laminate comprises the C~ '7 film comprises the cover layer of the liner during the molding process. The release liner can be kept on the product when packaged for sale and discarded before applying the gel cushioning element to a surface, such as a shoe or other article of footwear. In certain embodiments the cushioning device may further comprise a synthetic rubber foam, a woven cotton fabric, a synthetic fiber, a knit s fabric, a polyvinyl chloride film, and/or a synthetic non-woven fabric.
The products of the invention can be formed into any shape suitable for use as a cushioning device, for example for insertion into footwear to prevent rubbing between sensitive skin and hard or exposed surfaces of the footwear.
The cushioning elements can also be applied to other garments e.g., hats, - = helmets, protective sporting gear such as elbow and knee pads and other garments requiring extra padding for comfort, sizing and/or safety. Cushioning elements according to the invention may also be applied to surfaces which come in contact with body parts to provide protection from injury such as, e.g., chairs, desks, cabinets, tables, doors and door frames, among others. Depending on the 2 0 size and shape of the object to which the cushioning element is applied, certain shapes will better protect different areas of the body from contact with the object.
In certain example embodiments the products are molded in the shape of, e.g., circles, parabolas, stars, squares, rectangles, rounded rectangles, half-moon, among others. The appropriate shape of the cushioning element can be 25 determined based on the size and surface of the object to which the cushioning element will be applied. In alternative example embodiments, the cushioning element can be provided as a sheet of material that the user can cut to a desired shape. The sheet of material can also be provided with preformed shapes that can be removed as desired for the appropriate protection from contact with the 30 object.

Experimental A human wear test was conducted to compare the unmodified ply 4. \r~-jesw~. -ac J i a .:'..1 - ..

invention would provide appropriate adhesion performance when compared to the unmodified polyurethane gel heel liner. Prior to the wear test, a probe tack test was conducted on both devices according to ASTM D 2979-01 to measure the force required to separate an adhesive and adherend shortly after they have been contacted under a defined load of known duration and at a specified temperature.
The devices were also tested for shear hold according to PSTC-107 A, which measures the adhesive material's ability to remain adhered under a constant load applied parallel to the surface of the material and substrate, in particular measuring the shear adhesion when applied to a vertical standard steel panel.
The two devices were determined to have the following adhesion tack and shear hold:

PU got without PSA PU gel with PSA. vW
Probe Tack (g) 449 +/- 9 422 +/- 39 Shear Hold (min) 445 +/- 220 325 +/- 173 Based on the results of the probe tack test and the shear hold test, those of ordinary skill in the art would recognize that the two heel liner devices have essentially the same adhesion tack and shear hold, and would be expected to have the same adhesion performance in use, i.e., the ability to stay in place in a shoe under normal wear.
The adhesion performance of heel liner cushions formed according to the invention was then evaluated in a wear test by volunteers who inserted the devices into their shoes and wore them for three days of normal use. The test L i subjects were divided such that 23 subjects evaluated the unmodified heel e-s while 22 subjects evaluated the heel liner modified with PSA. Both the unmodified heel liners and the modified heel liners were similar in appearance so the test subjects did not know which device they were wearing. After three days, the test subjects were asked to rate their agreement or disagreement with whether the c f.-`hion stayed in place n normal use. rating acct to a sever; p6nt Answer Rating agree extremely 1 i - - ----- - ------ - - -------- - ---------- -agree moderately 2 agree slightly 3 neither agree or disagree 4 - - ------- - ------- - - -------- --------disagree slightly 5 disagree moderately 6 disagree extremely 7 The sum of the top three rating answers indicated a positive feedback of the performance of the heel liner cushion adhesion and the sum of the bottom three rating answers indicated the negative feedback to the performance of the heel liner cushion. The results were as follows:

Unmodified Modified Top3box 13 21 Bottom 3 box 10 1 As shown, the modified heel liners produced according to the subject invention containing the PSA produced an overwhelmingly positive feed back from users. Conversely, the unmodified heel liners showed equivocal results of 15 positive and negative feed back. The statistical analysis (p of 0.0041) of the wear test results indicated that the liners modified with PSA according to the invention provide a better adhesion performance during wear than the unmodified version, which result was unexpected based on the probe tack and shear hold tests on the cushions.
%.
Several embodiments of the present invention are specifically described herein. However, it wii. be appreciated that modifications and va,5ations of the appended c1a, s cep ai õtn fruffÃ Ua i cx Ã ate ScOpe of the invention.

Claims

1. A cushioning device comprising a layer of polyurethane gel material comprising top and bottom surfaces, at least one layer of thermoplastic polyurethane film material bonded to the one or both of said top and bottom surfaces thereof, and a layer of pressure sensitive adhesive bonded to one of said at least one thermoplastic polyurethane film material, wherein the pressure sensitive adhesive is located on a surface of the thermoplastic polyurethane film opposite to the surface contacting said bottom surface of said polyurethane gel material.

2. The cushioning device of claim 1 wherein the pressure sensitive adhesive comprises acrylic adhesives, methacrylate adhesives, rubber-based adhesives,

3. The cushioning device of claim 1 wherein the pressure sensitive adhesive is an adhesive based on styrene copolymers or silicones and combinations thereof.

4. The cushioning device of claim 3, wherein the styrene copolymers comprise styrene-isoprene-styrene (SIS), styrene-ethylene-butylene-styrene (SEBS), styrene-butadiene-styrene (SBS) copolymers with at least one tackifier, or combinations thereof.

5. The cushioning device of claim 2, wherein the acrylic adhesive comprises ethylene ethyl acrylate (EEA), ethylene methyl acrylate (EMA) copolymers or combinations thereof.

6. The cushioning device of claim 1, wherein the layer of pressure sensitive adhesive has a thickness of between about 0.0125 mm and about 0.25 mm.

7. The cushioning device of claim 1, wherein the polyurethane gel material has a Shore 00 hardness of between about 10 and about 80

8. The cushioning device of claim 1, wherein the polyurethane gel material has a Shore 00 hardness of between about 30 and about 60.

9. The cushioning device of claim 1, wherein the polyurethane gel material has a Shore 00 hardness of Shore 00 hardness of about 54.

10. The cushioning device of claim 1, wherein the polyurethane gel material has a thickness of between 0.3 and 3 mm.

11. The cushioning device of claim 1, wherein the thermoplastic polyurethane film material has a Shore A hardness of between about 40 to about 95.

12. The cushioning device of claim 1, wherein the thermoplastic polyurethane film material has a thickness of between 0.025 mm and 0.25 mm.

13. The cushioning device of claim 1, wherein a layer of thermoplastic polyurethane film material is bonded to both of said top and bottom surfaces of polyurethane gel materials.

14. The cushioning device of claim 13, wherein the individual layers of thermoplastic polyurethane film have the same thickness.

15. The cushioning device of claim 13, wherein the individual layers of thermoplastic polyurethane film have different thicknesses.

16. The cushioning device of claim 1, wherein at least one layer of the thermoplastic polyurethane film has a thickness of at least 0.025 mm.

17. A gel cushioning device comprising a sticky surface, the device comprising a gel material bound to a thermoplastic film material having good compatibility with the gel material, wherein the thermoplastic film material further comprises a pressure sensitive adhesive located on a surface of the film material opposite to the surface that is bonded to the gel material.

18. The cushioning device of claim 17, wherein the gel material is a polyurethane gel material.

19. The cushioning device of claim 17, wherein the thermoplastic film material is a polyurethane material.

20. The cushioning device of claim 17, wherein the gel material is SEBS gel material.

21. The cushioning device of claim 17, wherein the thermoplastic film material is SEBS material.

22. The cushioning device of claim 17, wherein the pressure sensitive adhesive comprises acrylic adhesives, methacrylate adhesives, rubber-based adhesives,

23. The cushioning device of claim 17, wherein the pressure sensitive adhesive is an adhesive based on styrene copolymers or silicones and combinations thereof.

24. The cushioning device of claim 23, wherein the styrene copolymers comprise styrene-isoprene-styrene (SIS), styrene-ethylene-butylene-styrene (SEBS), styrene-butadiene-styrene (SBS) copolymers with at least one tackifier, or combinations thereof.

25. The cushioning device of claim 23, wherein the acrylic adhesive comprises ethylene ethyl acrylate (EEA), ethylene methyl acrylate (EMA) copolymers, or combinations thereof.

26. The cushioning device of claim 17, wherein the pressure sensitive adhesive has a thickness of between about 0.0125 mm and about 0.25 mm.

27. The cushioning device of claim 17, wherein the gel material has a Shore 00 hardness of between about 10 and about 80

28. The cushioning device of claim 17, wherein the material has a Shore 00 hardness of between about 30 and about 60.

29. The cushioning device of claim 17, wherein the material has a Shore 00 hardness of Shore 00 hardness of about 50.

30. The cushioning device of claim 17, wherein the gel material has a thickness of between 0.3 and 3 mm.

31. The cushioning device of claim 17, wherein the thermoplastic film material has a Shore A hardness of between about 40 to about 95.

32. The cushioning device of claim 17, wherein the thermoplastic film material has a thickness of between 0.025 mm and 0.25 mm.

33. The cushioning device of claim 17, wherein the thermoplastic film material has a thickness of at least 0.025 mm.

34. A gel cushioning device comprising a sticky surface, the device comprising a layer of gel material having an upper and lower surface and two layers of thermoplastic film material, each film material comprising upper and lower surfaces, wherein the upper surface of the gel material is bonded with the lower surface of one of said layers of film material and the lower surface of the gel material is bonded with the upper surface of the other of said layers of film material, wherein at least one of the layers of film material comprises a pressure sensitive adhesive o a surface opposite the surface bonded to the gel material thereby providing the sticky surface of the device.

35. The cushioning device of claim 34, wherein the gel material is a polyurethane gel material.

36. The cushioning device of claim 34, wherein the thermoplastic film material is a polyurethane material.

37. The cushioning device of claim 34, wherein the gel material is SEBS gel material.

38. The cushioning device of claim 34, wherein the thermoplastic film material is SEBS material.

39. The cushioning device of claim 34 wherein the pressure sensitive adhesive comprises acrylic adhesives, methacrylate adhesives, rubber-based adhesives,

40. The cushioning device of claim 34 wherein the pressure sensitive adhesive is an adhesive based on styrene copolymers or silicones and combinations thereof.

41. The cushioning device of claim 40, wherein the styrene copolymers comprise styrene-isoprene-styrene (SIS), styrene-ethylene-butylene-styrene (SEBS), styrene-butadiene-styrene (SBS) copolymers with at least one tackifier, or combinations thereof.

42. The cushioning device of claim 40, wherein the acrylic adhesive comprises ethylene ethyl acrylate (EEA), ethylene methyl acrylate (EMA) copolymers, or combinations thereof.

43. The cushioning device of claim 34, wherein the pressure sensitive adhesive has a thickness of between about 0.0125 mm and about 0.25 mm.

44. the cushioning device of claim 34, wherein the gel material has a Shore 00 hardness of between about 10 and about 80

45. The cushioning device of claim 34, wherein the gel material has a Shore 00 hardness of between about 30 and about 60.

46. The cushioning device of claim 34, wherein the gel material has a Shore 00 hardness of Shore 00 hardness of about 50.

47. The cushioning device of claim 34, wherein the gel material has a thickness of between 0.3 and 3 mm.

48. The cushioning device of claim 34, wherein the thermoplastic film material has a Shore A hardness of between about 40 to about 95.

49. The cushioning device of claim 34, wherein the thermoplastic film material has a thickness of between 0.025 mm and 0.25 mm.

50. The cushioning device of claim 34, wherein said thermoplastic film material has a thickness of at least 0.025 mm.

51. A method of constructing a gel cushioning device comprising a sticky surface, which comprises loading gel material into a mold cavity comprising at least one layer of thermoplastic film material, said at least one layer of thermoplastic film material comprising upper and lower surfaces, and curing the gel material to form a solid gel, such that the cured gel material is bonded with the film material and wherein said at least one of the layer of thermoplastic film material comprises a pressure sensitive adhesive on a surface opposite the surface bonded to the gel material thereby providing the sticky surface of the device.

52. The method of claim 51, wherein the mold cavity comprises two layers of thermoplastic film material such that when cured the gel material is bonded with the lower surface of one of said layers of film material and the upper surface of the other of said layers of film material.

53. The method of claim 51, wherein said loading comprises injecting gel material into a mold cavity comprising said thermoplastic film material, at least one of said thermoplastic film materials comprising a pressure sensitive adhesive on a surface opposite the surface contacting the injected gel material.

54. The method of claim 51, wherein said mold cavity further comprises a release liner material positioned between said pressure sensitive adhesive and said mold form.

55. The method of claim 51, wherein said mold form further comprises a surface treatment that resists bonding of the pressure sensitive adhesive to the mold form.

56. The method of claim 51, wherein the gel material is a polyurethane gel material.

57. The method of claim 51, wherein the gel material is SEBS gel material.

58. The method of claim 51, further comprising the steps of removing the cured gel material from the mold cavity and die cutting the material to a desired shape.