CA2711234A1 - Environmentally friendly ternary transportation flex-fuel of gasoline, methanol and bioethanol - Google Patents

Environmentally friendly ternary transportation flex-fuel of gasoline, methanol and bioethanol Download PDF

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Publication number
CA2711234A1
CA2711234A1 CA2711234A CA2711234A CA2711234A1 CA 2711234 A1 CA2711234 A1 CA 2711234A1 CA 2711234 A CA2711234 A CA 2711234A CA 2711234 A CA2711234 A CA 2711234A CA 2711234 A1 CA2711234 A1 CA 2711234A1
Authority
CA
Canada
Prior art keywords
methanol
bioethanol
mixture
gasoline
flex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2711234A
Other languages
French (fr)
Inventor
George A. Olah
G. K. Surya Prakash
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Southern California USC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2711234A1 publication Critical patent/CA2711234A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1233Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/125Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition

Abstract

An efficient and economic ternary flex-fuel mixture that includes at least 10%
gasoline, at least 10% bioethanol and at least 45% methanol, with the amount of gasoline, bioethanol and methanol totaling 100%, wherein the flex-fuel mixture has an octane rating of at least 90 and remains homogeneous in the presence of up to 10% water therein. Preferred flex-fuel mixtures include 10-15 to 30% gasoline, 50 to 75-80% methanol, and 10 to 25% of bioethanol and having an octane rating of 90 to 98. Also, methods of making these flex-fuel mixtures and to improvements in methods for preparing a flex-fuel mixture of gasoline and bioethanol by adding methanol in an amount sufficient to enable the mixture to remain homogeneous in the presence of up to 10% water to thus allow handling, transportation, dispensing and use of the mixture in the same manner as conventional gasoline fuels.

Claims (20)

1. An efficient and environmentally friendly ternary transportation flex-fuel mixture comprising at least 10% gasoline, at least 10% bioethanol and at least 45% methanol, with the amount of gasoline, bioethanol and methanol totaling 100%, wherein the flex-fuel mixture has an octane rating of at least 90 and remains homogeneous in the presence of up to 10% water therein.
2. The flex-fuel mixture of claim 1 wherein the gasoline is present in an amount of less than 33% of the mixture and the methanol is present in an amount of at least 50% of the mixture.
3. The flex-fuel mixture of claim 1 wherein the bioethanol is present in an amount of less than 33% of the mixture and the methanol is present in an amount of at least 50% of the mixture.
4. The flex-fuel mixture of claim 1 wherein the methanol is present in an amount of less than 75% of the mixture.
5. The flex-fuel mixture of claim 1 comprising 10 to 30% gasoline, 50 to 80%
methanol, and 10 to 25% of bioethanol and having an octane rating of 90 to 98.
6. The flex-fuel mixture of claim 1 comprising 15 to 30% gasoline, 50 to 75%
methanol, and 10 to 25% of bioethanol and having an octane rating of 90 to 98.
7. A method of making the flex-fuel mixture of claim 1 which comprises mixing the gasoline, bioethanol and methanol together in the amounts recited and under mixing conditions sufficient to form a homogenous mixture.
8. The method of claim 7 wherein the mixing is conducted by first mixing the gasoline with the methanol to form a binary mixture and subsequently adding the bioethanol.
9. The method of claim 7 wherein the mixing is conducted by first mixing the methanol with bioethanol to form a binary mixture and subsequently adding the gasoline.
10. The method of claim 7, wherein the methanol is made from carbon dioxide that is generated by an industrial plant to avoid emitting carbon dioxide into the atmosphere where it can contribute to further global warming.
11. The method of claim 7, wherein the methanol is made from carbon dioxide that is removed from the atmosphere to reduce the contribution of the carbon dioxide to global warming.
12. A method of storing, handling, transporting or dispensing a bioethanol containing fuel using existing infrastructure without the need to render and keep the fuel anhydrous which comprises formulating the fuel with at least 10% gasoline, at least 10%
bioethanol and at least 45% methanol, with the amount of gasoline, bioethanol and methanol totaling 100%, wherein the flex-fuel mixture has an octane rating of at least 90 and remains homogeneous in the presence of up to 10% water therein.
13. In a method for preparing a flex-fuel mixture of gasoline and bioethanol, the improvement which comprises adding methanol in an amount sufficient to enable the mixture to remain homogeneous in the presence of up to 10% water to thus allow handling, transportation, dispensing and use of the mixture in the same manner as conventional gasoline fuels without first having to treat the bioethanol to remove associated water or without having to be rendered anhydrous.
14. The method of claim 13 wherein the flex-fuel mixture comprises at least 10%
gasoline, at least 10% bioethanol and at least 45% methanol, with the amount of gasoline, bioethanol and methanol totaling 100%.
15. The method of claim 13 wherein the flex-fuel mixture has an octane rating of at least 90.
16. The method of claim 13 wherein the gasoline is present in an amount of less than 33% of the mixture and the methanol is present in an amount of at least 50% of the mixture.
17. The method of claim 13 wherein the bioethanol is present in an amount of less than 33% of the mixture and the methanol is present in an amount of at least 50% of the mixture.
18. The method of claim 13 wherein the methanol is present in an amount of less than 75% of the mixture.
19. The method of claim 13 wherein the flex-fuel mixture comprises 10 to 30%
gasoline, 50 to 80% methanol, and 10 to 25% of bioethanol and has an octane rating of 90 to 98.
20. The method of claim 13 wherein the flex-fuel mixture comprises 15 to 30%
gasoline, 50 to 75% methanol, and 10 to 25% of bioethanol and has an octane rating of 90 to 98.
CA2711234A 2008-01-04 2008-12-30 Environmentally friendly ternary transportation flex-fuel of gasoline, methanol and bioethanol Abandoned CA2711234A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US1893308P 2008-01-04 2008-01-04
US61/018,933 2008-01-04
PCT/US2008/088539 WO2009088861A1 (en) 2008-01-04 2008-12-30 Environmentally friendly ternary transportation flex-fuel of gasoline, methanol and bioethanol

Publications (1)

Publication Number Publication Date
CA2711234A1 true CA2711234A1 (en) 2009-07-16

Family

ID=40843469

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2711234A Abandoned CA2711234A1 (en) 2008-01-04 2008-12-30 Environmentally friendly ternary transportation flex-fuel of gasoline, methanol and bioethanol

Country Status (8)

Country Link
US (1) US20090172997A1 (en)
EP (1) EP2231834A1 (en)
JP (1) JP2011509326A (en)
KR (1) KR20100100940A (en)
CN (1) CN101918518A (en)
AU (1) AU2008347306B2 (en)
CA (1) CA2711234A1 (en)
WO (1) WO2009088861A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102161917A (en) * 2011-03-11 2011-08-24 雷菊花 Biomass clean gasoline
CN103087785B (en) * 2011-11-03 2015-05-20 平凉市中力新能源科技研究院 Clean fuel for vehicles and preparation method thereof
CN104830378A (en) * 2014-02-10 2015-08-12 四川欧瑞迪能源有限公司 Renewable clean fuel
WO2016134009A1 (en) 2015-02-18 2016-08-25 University Of Southern California Methanol fuels for internal combustion engines
DE102022105802A1 (en) * 2022-03-11 2023-09-14 Obrist Technologies Gmbh Method for producing a liquid fuel mixture using a carbon reducing process

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4384872A (en) * 1979-03-05 1983-05-24 Institute Of Gas Technology Stabilized gasoline-alcohol fuel compositions
IT1193555B (en) * 1980-09-15 1988-07-08 Snam Progetti PROCEDURE FOR THE PRODUCTION OF METHANOL MIXTURES AND HIGHER ALCOHOLS AND MIXTURES OBTAINED BY THAT PROCEDURE
JPS606988B2 (en) * 1981-03-31 1985-02-21 繁信 藤本 Method for producing stable and homogeneous engine fuel composition
FR2508483A1 (en) * 1981-06-30 1982-12-31 Inst Francais Du Petrole PROCESS FOR THE VALORISATION OF VERY RICH CYCLOPARAFFIN CUTTINGS
CN85104713B (en) * 1984-06-28 1987-12-23 发动机燃料联合有限公司 Engine fuel
US4705532A (en) * 1985-07-15 1987-11-10 The Standard Oil Company Alcohol compositions for blending with gasoline
DE3711985A1 (en) * 1987-04-09 1988-10-20 Union Rheinische Braunkohlen USE OF POLYOLETHERS TO PREVENT OR REDUCE DEPOSITS IN MIXTURE PROCESSING SYSTEMS
JPH06108066A (en) * 1992-01-31 1994-04-19 Mitsubishi Oil Co Ltd Gasoline/methanol-blended fuel for internal combustion engine
JP2002080867A (en) * 2000-06-23 2002-03-22 Minoru Nakahama Gasoline substitute fuel
US6858048B1 (en) * 2001-04-18 2005-02-22 Standard Alcohol Company Of America, Inc. Fuels for internal combustion engines
US7559961B2 (en) * 2001-04-18 2009-07-14 Standard Alcohol Company Of America, Inc. Mixed alcohol fuels for internal combustion engines, furnaces, boilers, kilns and gasifiers
JP4450618B2 (en) * 2003-12-24 2010-04-14 コスモ石油株式会社 Ethanol-containing gasoline
JP4626954B2 (en) * 2004-09-03 2011-02-09 Jx日鉱日石エネルギー株式会社 Gasoline composition
CA2604569C (en) * 2005-04-15 2014-08-26 University Of Southern California Efficient and selective conversion of carbon dioxide to methanol, dimethyl ether and derived products
KR100655101B1 (en) * 2006-06-09 2006-12-08 이용만 Fuel composition containing bioethanol and biodiesel for internal combustion engine
WO2007061903A1 (en) * 2005-11-17 2007-05-31 Cps Biofuels, Inc. Alternative fuel and fuel additive compositions

Also Published As

Publication number Publication date
JP2011509326A (en) 2011-03-24
EP2231834A1 (en) 2010-09-29
KR20100100940A (en) 2010-09-15
AU2008347306B2 (en) 2012-08-30
AU2008347306A1 (en) 2009-07-16
US20090172997A1 (en) 2009-07-09
CN101918518A (en) 2010-12-15
WO2009088861A1 (en) 2009-07-16

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Effective date: 20131231