CA2687452C

CA2687452C - Brass alloy

Info

Publication number: CA2687452C
Application number: CA 2687452
Authority: CA
Inventors: Wenlin Lo; Xiaoming Peng
Original assignee: Globe Union Industrial Corp
Current assignee: Globe Union Industrial Corp
Priority date: 2009-11-24
Filing date: 2009-11-24
Publication date: 2014-05-27
Anticipated expiration: 2029-11-24
Also published as: CA2687452A1

Abstract

The present invention provides an environmental friendly brass alloy, including 0.4 to 0.8 wt% of aluminum; 0.6 to 1.6 wt% of nickel; 0.8 to 2.0 wt% of tin; more than 95.6 wt% of copper and zinc; and less than 0.1 wt% of iron, lead, phosphorous and impurities, wherein the copper is present in an amount ranging from 60 to 68 wt%.

Description

BRASS ALLOY
BACKGROUND OF THE INVENTION
1. Field of the Invention The present invention relates to copper alloys, and more particularly, to an environment friendly brass alloy.

2. Description of Related Art A brass includes copper and zinc, as major ingredients, usually in a ratio of about 7:3 or 6:4. In addition, a brass usually includes a small amount of impurities. In order to improve the properties of a brass, a conventional brass contains lead (mostly in the range of 1 to 3 wt%) to achieve the desired mechanical properties for use in the industry, thereby becoming an important industrial material that is widely applicable to metallic devices and valves for use in pipelines, faucets and water supply and discharge systems.
However, as awareness of the importance of environmental protection increases and the impact of heavy metals on human health becomes better understood, it is a trend to restrict the use of lead-containing alloys. Various countries, such as Japan and the United States, have progressively amended relevant regulations in an intensive effort to lower the lead content in the environment by particularly requiring that no lead shall leach from lead-containing alloys used in products ranging from household appliances and automobiles to residential water pipes and municipal water systems, while also requiring that lead contamination shall be avoided during processing. Hence, there is a need to develop lead-free brass with good properties for casting, cutting, corrosion-resisting and mechanical processing.
Currently, there are many formulations of lead-free copper alloy. For example, Taiwanese Patent No. 421674, US Patent No. 7354489, and US Patent Application Publication Nos. 20070062615, 20060078458 and 2004023441 disclose adding silicon (Si) in a brass alloy instead of lead. However, the alloys made from these formulations have poor property for cutting. In addition, Chinese Patent Application Publication No. 10144045 discloses aluminum, silicon and phosphorous as main components of a lead-free copper alloy. This lead-free copper alloy can be used for casting, but has poor property for cutting and much lower processing efficiency than lead-containing brass. Chinese Patent Application Publication Nos.
101285138 and 101285137 disclose phosphorous as main component in an alloy;
however, cracks are easily formed while casting this alloy.
In addition, US Patent Nos. 7,297,215, 6,974,509, 6,955,378, 6,149,739, 5,942,056, 5,637,160, 5,653,827, 5,487,867 and 5,330,712, and US Patent Application Publication Nos.
20060005901, 20040094243 and 20070039667, disclose lead-free or low-lead bismuth-containing brass alloy formulations, wherein the bismuth content of the formulations ranges from 0.5 wt% to 7 wt%. Further, US Patent No. 6413330 discloses a lead-free copper alloy containing bismuth, silicon and other components. Chinese Patent Application Publication No.
101440444 also discloses a lead-free brass alloy having high content of zinc and silicon, but this brass alloy has high content of silicon and low content of copper, such that the fluidity of the melt alloy is poor to fill the cavity while casting, resulting in disadvantages such as misnm, etc. Chinese Patent Application Publication No. 101403056 discloses bismuth and manganese in a lead-free brass alloy instead of lead. However, high bismuth content is likely to cause defects like cracks and slag inclusions, leading to low processing efficiencies. On the other hand, low bismuth content and high manganese content cause less cracks, but have poor cutting property.
Due to rare resource and expensive cost, high bismuth content instead of lead results in high fabrication cost of a lead-free brass. Further, the above-mentioned brass alloys have drawbacks such as poor casting property, easily forming cracks, etc.
Moreover, there are literatures disclosing the improvement of a fabrication of a lead-free copper alloy or a lead removal process. For example, US Patent No.
5904783 discloses treating a brass alloy with the sodium and potassium solution at a high temperature for reducing lead leaching into a fluid supply. Taiwanese Patent No.
491897 discloses a method for fabricating a brass alloy having 1-2.6 wt% of bismuth.
However, the conventional lead removal process is used for reducing lead, which is in contact with water, leaching when the lead-containing product is immersed in water, but fails to reduce the lead content to less than 0.3 wt% in a material.
SUMMARY OF THE INVENTION
The present invention provides an environmental friendly brass alloy.
The environmental friendly brass alloy includes 0.4 to 0.8 wt% of aluminum;
0.6 to 1.6 wt% of nickel; 0.8 to 2.0 wt% of tin; more than 95.6 wt% of copper and zinc;
and less than 0.1 wt% of iron, lead, phosphorous and impurities, wherein the copper is in an amount ranging from 60 to 68 wt%.
According to an aspect of the invention, there is provided a brass alloy, consisting of: 0.4 to 0.8 wt% of aluminum; 0.6 to 1.6 wt% of nickel; 0.8 to 2.0 wt% of 3a tin; more than 95.6 wt% of copper and zinc, wherein the copper is present in an amount ranging from 60 to 68 wt%; and the remainder being iron, lead, phosphorous and impurities; and wherein the lead is present in an amount ranging from 0.05 to 0.003 wt%.
In the environmental friendly brass alloy of the present invention, the copper and zinc are present in an amount more than 95.6 wt%. In an aspect, the copper is present in an amount ranging from 60 to 68 wt% of the environmental friendly brass alloy, so as to provide toughness and to facilitate subsequent processes. In a preferred embodiment, the copper is in an amount ranging from 61 to 64 wt%.

In the environmental friendly brass alloy of the present invention, the aluminum is present in an amount ranging from 0.4 to 0.8 wt%. In a preferred embodiment, the aluminum is present in an amount ranging from 0.5 to 0.6 wt%, in which the addition of aluminum increases the fluidity of melt copper and improves casting property of the brass alloy.
In the environmental friendly brass alloy of the present invention, the nickel is present in an amount ranging from 0.6 to 1.6 wt%. In a preferred embodiment, the nickel is present in an amount ranging from 0.8 to 1.4 wt%, in which the addition of nickel improves the mechanical property and corrosion-resistance of the brass alloy.
In the environmental friendly brass alloy of the present invention, the tin is present in an amount ranging from 0.8 to 2.0 wt%. In a preferred embodiment, the tin is present in an amount ranging from 1.2 to 1.6 wt%, in which the addition of tin increases the corrosion-resistance of the brass alloy to the environment with high chloride (such as sea water) and increases the strength of the brass alloy.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG 1A shows a metallographic structural distribution of a specimen of an environmental friendly brass alloy according to the present invention;
FIG 1B shows a metallographic structural distribution of a specimen of a lead-free bismuth brass alloy;
FIG. 1C shows a metallographic structural distribution of a specimen of an lead brass;
FIG. 2A shows a crack of a lead-free bismuth brass alloy;
FIG 2B shows a microscopic image of the cracks of the lead-free bismuth brass alloy;

FIG 3A shows cuttings of a lead-free bismuth brass alloy;
FIG 3B shows cuttings of an C85710 lead brass; and FIG 3C shows cuttings of the environmental friendly brass alloy according to the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
The detailed description of the present invention is illustrated by the following specific examples. Persons skilled in the art can conceive the other advantages and effects of the present invention based on the disclosure contained in the specification of the present invention.
Unless otherwise specified, the ingredients comprised in the environmental friendly brass alloy of the present invention, as discussed herein, are all based on the total weight of the brass alloy, and are expressed in weight percentages (wt%).
The environmental friendly brass alloy according to the present invention has the lead content less than 0.05 wt%, to comply with the international standards for lead content in pipeline materials in contact with water. Therefore, the environmental friendly brass alloy of the present invention is suitable for applications to faucets and lavatory components, pipelines for tap water, water supply systems, etc.
The environmental friendly brass alloy of the present invention includes 0.4 to 0.8 wt% of aluminum; 0.6 to 1.6 wt% of nickel; 0.8 to 2.0 wt% of tin; more than 95.6 wt%
of copper and zinc; and less than 0.1 wt% of iron, lead, phosphorous and impurities, wherein the copper is present in an amount ranging from 60 to 68 wt%.
In the environmental friendly brass alloy of the present invention, the copper and zinc are present in an amount more than 95.6 wt%, wherein the copper is present in an amount ranging from 60 to 68 wt% of the environmental friendly brass alloy.

Preferably, the copper is in an amount ranging from 61 to 64 wt%.
In the environmental friendly brass alloy of the present invention, the aluminum is present in an amount ranging from 0.4 to 0.8 wt%. In a preferred embodiment, the aluminum is present in an amount ranging from 0.5 to 0.6 wt%. The addition of aluminum increases the fluidity of melt copper and improves casting property of the brass alloy. Further, in the environmental friendly brass alloy of the present invention, the nickel is present in an amount ranging from 0.6 to 1.6 wt%. In a preferred embodiment, the nickel is present in an amount ranging from 0.8 to 1.4 wt%.
The addition of nickel improves the mechanical property, corrosion-resistance and dezincification-resistance of the brass alloy. In the environmental friendly brass alloy of the present invention, the tin is present in an amount ranging from 0.8 to 2.0 wt%. In a preferred embodiment, the tin is present in an amount ranging from 1.2 to 1.6 wt%.
The addition of tin increases the corrosion-resistance of the brass alloy to the enviromnent with high chloride (such as sea water) and increases the strength of the brass alloy.
The present invention provides the detailed illustrations in the following examples.
The ingredients of the environmental brass alloy of the present invention used in the following test examples are described as follows, wherein each ingredient is added at a proportion based on the total weight of the brass alloy.
Example 1 of the environmental friendly brass alloy:
Cu: 61.37 wt% Ni: 0.815 wt%
Al: 0.537 wt% Sn: 1.246 wt%
Pb: 0.0103 wt%

Zn, trace elements and impurities: in balance Example 2 of the environmental friendly brass alloy:
Cu: 62.45 wt% Ni: 0.989 wt%
Al: 0.578 wt% Sn: 1.423 wt%
Pb: 0.078 wt%
Zn, trace elements and impurities: in balance Example 3 of the environmental friendly brass alloy:
Cu: 63.34 wt% Ni: 1.167 wt%
Al: 0.564 wt% Sn: 1.548 wt%
Pb: 0.0036 wt%
Zn, trace elements and impurities: in balance Test Example 1:
The environmental friendly brass alloy (Embodiments 1-3), lead-free bismuth brass (Comparative examples 1-3) and C85710 lead brass (Comparative examples 4-5) are used for casting under the same process and operation condition. The processing characteristics and yields of these brass alloys are shown in Table 1. The overall production yield was calculated by the following equation:
0. P. Yield = Number of Non-Defective Products/Total Number of Products x 100%
The overall production yield (0. P. Yield) reflects the qualitative stability of production processes. High qualitative stability of production processes ensures normal production.
Table 1 Environmental friendly brass alloy of Lead-free bismuth brass C85710 lead brass the present invention Item ComparativeComparative Comparative Comparative Comparative Embodiment Embodiment Embodiment example 1 example 2 example 3 example 4 example 5 1 2 3 Measured Cu content 61.92 62.57 63.01 62.3 61.5 61.37 62.45 63.64 (wt%) Measured Al content 0.541 0.581 0.513 0.548 0.554 0.537 0.578 0.564 (wt%) Measured Pb content 0.0016 0.0073 0.0054 1.89 1.67 0.0103 0.0078 0.0036 (wt%) Measured Ni content 0.263 0.449 0.851 0.0076 0.0042 0.815 0.989 1.167 (wt%) Measured Sn content 0.0054 0.0008 0.0023 0.0007 0.0005 1.246 1.423 1.548 (wt%) Number of total products Number of non-defective 583 612 679 891 885 856 873 882 products Yield 58.3% 61.2% 67.9% 89.1% 88.5% 85.6%
87.3% 88.2%
As shown in Table 1, the products made of the lead-free bismuth brass alloy have more defects, and have the yield less than 70%, wherein more bismuth content results in the fewer yield. The casting product of the lead-free bismuth brass has the drawbacks such pores, cracks, slag entrapment, misrun and loose.
Specifically, the melt copper of the lead-free bismuth brass has poor fluidity and poor filling in a mold, resulting in the misrun. Further, the casting products easily form crack, which are usually found while polishing. Moreover, the casting products easily form slag entrapment and pores.
As shown in Table 1, the products made from the environmental friendly brass alloy in the present invention had the best yield (more than 85%), and had the fluidity close to the conventional C85710 lead brass. Further, upon optimization of the casting products, the casting product formed the isometric crystal structures after solidification, so as to eliminate the formation of cracks and to meet the requirement of production.
Test Example 2:

It is shown in FIGS. IA, 1B and IC that the structural distributions of the environmental friendly brass alloy of the present invention, the lead-free bismuth brass and C85710 lead brass were examined under an optical metallographic microscope at 100X magnification.
In Embodiment 3 of the present invention, the environmental friendly brass alloy included 63.64 wt% of Cu, 0.564 wt% of Al, 0.0036 wt% of Pb, 1.167 wt% of Ni and 1.548 wt% of Sn, and has the structural distribution as shown in FIG. IA. As shown in FIG. LA, smaller grains were formed so as to provide excellent material toughness, and thus defects like cracks were not likely to occur.
FIG. 1B shows the structural distribution of the lead-free bismuth brass in Comparative example 3. In Comparative example 3, the lead-free bismuth brass included 63.01 wt% of Cu, 0.513 wt% of Al, 0.0054 wt% of Pb, 0.851 wt% of Bi and 0.0023 wt% of P. The high bismuth content caused more heterogeneous nucleation, quick nucleation and the increased a phase undercooling, resulting in more dendritic forms rather than blocks of grains. Therefore, the continuous pieces of bismuth were formed due to the grain boundary segregation, so as to make the mechanical strength decreased and to increase the hot shortness and cold shortness, such that cracks were easily formed.
FIG. 1C shows the structural distribution of the C85710 lead brass in Comparative example 5. In Comparative example 5, the C85710 lead brass included 61.5 wt% of Cu, 0.554 wt% of Al, 1.67 wt% of Pb, 0.0042 wt% of Bi and 0.0005 wt%
of P. The C85710 lead brass had the a phase of the globular grains and good roughness, such that cracks were not likely to occur.
Upon casting, the lead-free high bismuth brass in Comparative example 1 had the crack as shown in FIG. 2A, and the image under the microscope was shown in FIG.

2B. The product made from the lead-free high bismuth brass was destroyed by the crack.
Test Example 3:
The tests on the mechanical properties of the brass alloys in Embodiment 3 and Comparative example 5 were performed according to the standard set forth in 1S06998-1998, "Tensile experiments on metallic materials at room temperature."
The results are shown in Table 2.
Table 2:
Mechanical properties Material Tensile Strength (Mpa) Elongation (%) 1 2 3 4 5 Avg. 1 2 3 4 5 Avg.
Embodiment 3 424 411 438 417 424 422.8 12 11 11 11 10 11 Comparative 377 368 352 361 374 366.4 10 11 12 10 11 10.8 example 5 As shown in Table 2, the environmental friendly brass alloy in the present invention had the tensile strength higher than the conventional C85710 lead brass, and had the elongation comparable to the conventional C85710 lead brass. Hence, the environmental friendly brass alloy in the present invention has the mechanical properties comparable to the C85710 lead brass, and can indeed substitute for the C85710 lead brass in manufacturing of products.
Test Example 4:
The tests were performed according to the standard set forth in NSF 61-2007a SPAC for the allowable precipitation amounts of metals in products, to examine the .11 amounts of the metal precipitations of the brass alloys in an aqueous environment in Embodiment 3 and Comparative example 5. The results are shown in Table 3.
Table 3 Comparative example Upper Limit Comparative 5 Element of Standard Embodiment 3 example 5 (after a lead- stripping Value (14(L) treatment) Pb 5.0 14.452 0.561 0.364 Bi 50.0 0.026 0.015 0.017 Al 5.0 0.087 0.032 0.093 As shown in Table 3, the precipitation amounts of metals from the environmental friendly brass alloy in the present invention were all much lower than the upper limit of the standard values, so as to meet the requirement of NSF 61-2007a SPAC.
Moreover, the amounts of heavy metal precipitations from the environmental friendly brass alloy in the present invention were significantly lower than the C85710 lead brass and significantly lower than the a lead-stripping treated C85710 lead brass.
Hence, the brass alloy of the present invention is more environmentally friendly and has less risk to human health.
The environmental friendly brass alloy of the present invention has the mechanical properties (such as cutting properties) comparable to the C85710 lead brass, and even better properties (such as tensile strength) than the C85710 lead brass.
The casting products made from the environmental friendly brass alloy of the present invention have great yield, and also the yield of mechanical processing is excellent.
Furthermore, the environmental friendly brass alloy of the present invention reduces the amount of lead precipitations, and can substitute for the conventional brass.

Claims

1. A brass alloy, consisting of:
0.4 to 0.8 wt% of aluminum;
0.6 to 1.6 wt% of nickel;
0.8 to 2.0 wt% of tin;
more than 95.6 wt% of copper and zinc, wherein the copper is present in an amount ranging from 60 to 68 wt%; and the remainder being iron, lead, phosphorous and impurities; and wherein the lead is present in an amount ranging from 0.05 to 0.003 wt%.

2. The brass alloy of claim 1, wherein the aluminum is present in an amount ranging from 0.5 to 0.6 wt%.

3. The brass alloy of claim 1, wherein the nickel is present in an amount ranging from 0.8 to 1.4 wt%.

4. The brass alloy of claim 1, wherein the tin is present in an amount ranging from 1.2 to 1.6 wt%.

5. The brass alloy of claim 1, wherein the copper is present in an amount ranging from 61 to 64 wt%.