CA2647961C - Slit banded paper - Google Patents
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- CA2647961C CA2647961C CA2647961A CA2647961A CA2647961C CA 2647961 C CA2647961 C CA 2647961C CA 2647961 A CA2647961 A CA 2647961A CA 2647961 A CA2647961 A CA 2647961A CA 2647961 C CA2647961 C CA 2647961C
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
- A24D1/025—Cigars; Cigarettes with special covers the covers having material applied to defined areas, e.g. bands for reducing the ignition propensity
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- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Paper (AREA)
Abstract
Wrappers of smoking articles having slit banded regions (10) exhibit both low ignition propensity and reduced rates of self-extinguishment under free burn conditions. In one embodiment, the slit banded regions comprises first (11), second (12) and third (13) zones, with the second zone having greater permeability that the first and third zones, which comprise add-on material. A method of making the wrapper as is also disclosed, as are smoking articles including the wrappers.
Description
=
SLIT BANDED PAPER
Technical Field The invention relates to wrappers for smoking articles.
SUMMARY
In a first embodiment, provided is a wrapper of a smoking article comprising a base web and at least one transverse banded region comprising first, second and third zones. The first and third zones comprise add-on material, which reduces permeability of the wrapper. The first 6 and third zones each have a width such that if either of said first or third zone were applied separately to wrappers of smoking articles, the smoking articles would exhibit statistically = significant occurrences of total burn through and statistically few or no occurrences of self-extinguishment under free burn conditions. The sum of the widths of the first and third zones is such that if the zones were applied to wrappers of smoking articles as a single continuous band (without a slit or other discontinuity), the smoking articles would exhibit statistically few or no 12 occurrences of total burn through and statistically significant occurrences of self-extinguishment under free burn conditions. The first and third zones are separated by the second zone. The wrapper has greater permeability along the second zone than along the first and third zones.
The second zone has a width less than or equal to either width of the first and third zones, so that lit smoking articles comprising the first, second and third zones exhibit statistically reduced occurrences of self-extinguishment under free burn conditions, as compared to smoking articles la comprising wrappers whereon the first and third zones are applied as a single continuous band, while maintaining statistically few or no occurrences of total burn through.
In a second embodiment, provided is an wrapper of a smoking article comprising a base web and a transverse banded region of add-on material. The transverse banded region is sufficient to cause, extinguishment of smoking articles comprising the transverse banded region when left upon a substrate. The wrapper further comprises at least one air permeable, 24 intermediate zone along the transverse banded region such that the occurrences of self-extinguishments of smoking articles comprising the wrapper is statistically reduced over those without the intermediate zone.
In a third embodiment, provided is a wrapper of a smoking article comprising a base web and at least one transverse banded region comprising first, second and third zones on the base web. The at least one transverse banded region is free of fillers. The first and third zones are 30 outward of the second zone, and the second zone has a greater permeability compared to the first and third zones.
In a fourth embodiment, provided is a wrapper of a smoking article comprising a base web and at least one transverse banded region comprising first, second and third zones on the base web. The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third zones, and the second zone and the first 36 and third zones comprise add-on material.
SLIT BANDED PAPER
Technical Field The invention relates to wrappers for smoking articles.
SUMMARY
In a first embodiment, provided is a wrapper of a smoking article comprising a base web and at least one transverse banded region comprising first, second and third zones. The first and third zones comprise add-on material, which reduces permeability of the wrapper. The first 6 and third zones each have a width such that if either of said first or third zone were applied separately to wrappers of smoking articles, the smoking articles would exhibit statistically = significant occurrences of total burn through and statistically few or no occurrences of self-extinguishment under free burn conditions. The sum of the widths of the first and third zones is such that if the zones were applied to wrappers of smoking articles as a single continuous band (without a slit or other discontinuity), the smoking articles would exhibit statistically few or no 12 occurrences of total burn through and statistically significant occurrences of self-extinguishment under free burn conditions. The first and third zones are separated by the second zone. The wrapper has greater permeability along the second zone than along the first and third zones.
The second zone has a width less than or equal to either width of the first and third zones, so that lit smoking articles comprising the first, second and third zones exhibit statistically reduced occurrences of self-extinguishment under free burn conditions, as compared to smoking articles la comprising wrappers whereon the first and third zones are applied as a single continuous band, while maintaining statistically few or no occurrences of total burn through.
In a second embodiment, provided is an wrapper of a smoking article comprising a base web and a transverse banded region of add-on material. The transverse banded region is sufficient to cause, extinguishment of smoking articles comprising the transverse banded region when left upon a substrate. The wrapper further comprises at least one air permeable, 24 intermediate zone along the transverse banded region such that the occurrences of self-extinguishments of smoking articles comprising the wrapper is statistically reduced over those without the intermediate zone.
In a third embodiment, provided is a wrapper of a smoking article comprising a base web and at least one transverse banded region comprising first, second and third zones on the base web. The at least one transverse banded region is free of fillers. The first and third zones are 30 outward of the second zone, and the second zone has a greater permeability compared to the first and third zones.
In a fourth embodiment, provided is a wrapper of a smoking article comprising a base web and at least one transverse banded region comprising first, second and third zones on the base web. The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third zones, and the second zone and the first 36 and third zones comprise add-on material.
In a fifth embodiment, provided is a method of making a banded wrapper of a smoking article comprising supplying a base web and forming at least one transverse banded region comprising first, second and third zones on the base web. The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third zones, and at least the first and third zones are formed from an add-on material free of fillers 6 and optionally at least one of the zones is formed at least in part from an add-on material which includes a filler.
In a sixth embodiment, provided is a method of making a banded wrapper of a smoking article comprising supplying a base web and forming at least one transverse banded region comprising first, second and third zones on the base web. The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third 12 zones, and the second zone and the first and third zones are formed from an add-on material.
BRIEF DESCRIPTION OF THE DRAWINGS
FIGs. 1-3 are illustrations of smoking articles comprising the slit banded paper as described herein.
FIGs. 4-5 illustrate alternate embodiments of smoking articles comprising the split 18 banded paper as described herein.
FIG. 6 is a schematic view of a multiple stage printing apparatus.
DETAILED DESCRIPTION
Preferably, a smoking article extinguishes when placed onto a substrate, and the tendency to do so is referenced herein as a smoking article having "low ignition propensity".
24 Ideally, a low propensity smoking article will continue to burn when freely suspended such as within the holder of an ashtray or when being held in the hand without puffing ("free burn").
Many prior cigarette designs that achieve low ignition propensity requirements exhibit high rates of self-extinguishment under free burn conditions.
The phrase "total burn through" as used herein, refers to testing by American Society of Testing and Materials (ASTM) Standard E2187-04, "Standard Test Method for Measuring the 30 Ignition Strength of Cigarettes", which provides a measure of the capability of a lit banded-papered cigarette, positioned on a combustible substrate, to continue burning without puffing.
Thus, "total burn through" refers to the situation in which the coal proceeds entirely through a banded region on a cigarette wrapper and does not cause extinguishment of the lit cigarette.
Further, the phrases "self-extinguish under free burn conditions" or "self-extinguishment under free burn conditions" as used herein, refer to.the extinguishment of a lit cigarette without puffing, 36 when such cigarette is under free burn conditions.
In a sixth embodiment, provided is a method of making a banded wrapper of a smoking article comprising supplying a base web and forming at least one transverse banded region comprising first, second and third zones on the base web. The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third 12 zones, and the second zone and the first and third zones are formed from an add-on material.
BRIEF DESCRIPTION OF THE DRAWINGS
FIGs. 1-3 are illustrations of smoking articles comprising the slit banded paper as described herein.
FIGs. 4-5 illustrate alternate embodiments of smoking articles comprising the split 18 banded paper as described herein.
FIG. 6 is a schematic view of a multiple stage printing apparatus.
DETAILED DESCRIPTION
Preferably, a smoking article extinguishes when placed onto a substrate, and the tendency to do so is referenced herein as a smoking article having "low ignition propensity".
24 Ideally, a low propensity smoking article will continue to burn when freely suspended such as within the holder of an ashtray or when being held in the hand without puffing ("free burn").
Many prior cigarette designs that achieve low ignition propensity requirements exhibit high rates of self-extinguishment under free burn conditions.
The phrase "total burn through" as used herein, refers to testing by American Society of Testing and Materials (ASTM) Standard E2187-04, "Standard Test Method for Measuring the 30 Ignition Strength of Cigarettes", which provides a measure of the capability of a lit banded-papered cigarette, positioned on a combustible substrate, to continue burning without puffing.
Thus, "total burn through" refers to the situation in which the coal proceeds entirely through a banded region on a cigarette wrapper and does not cause extinguishment of the lit cigarette.
Further, the phrases "self-extinguish under free burn conditions" or "self-extinguishment under free burn conditions" as used herein, refer to.the extinguishment of a lit cigarette without puffing, 36 when such cigarette is under free burn conditions.
The banded regions described herein exhibit both low ignition propensity and reduced rates of self-extinguishment under free burn conditions. The banded regions are preferably formed b printing, specifically gravure printing, as described in detail below. As an alternative to printing, the banded regions may comprise a slurry of highly refined fibrous cellulose (e.g., fibers, fibrils, microfibrils, or combinations thereof) or other add-on material applied using 6 various spray or coating techniques, including application techniques that utilize a moving orifice applicator at the forming section of a paper-making machine as described in commonly owned US 5 997 691 and US 6 596 125.
In another embodiment, the banded region can comprise first, second and third zones of add-on material, which may be applied by any of the methods disclosed herein, wherein the 12 second zone includes perforations which preferably are filled with an occluding material which melts or is evaporated when the burning coal approaches the banded region to thereby provide the second zone with increased permeability.
Thus, provided is a wrapper of a smoking article comprising a base web and at least one transverse banded region comprising first, second and third zones. The first and third zones comprise add-on material, which reduces permeability of the wrapper. The first and third zones 18 each have a width such that if either of said first or third zone were applied separately to wrappers of smoking articles, the smoking articles would exhibit statistically significant occurrences of total burn through and statistically few or no occurrences of self-extinguishment under free burn conditions (e.g., after testing a batch of 20 to 50 cigarettes). The sum of the widths of the first and third zones is such that if the zones were applied to wrappers of smoking articles as a single continuous band (without a slit or other discontinuity), the smoking articles 24 would exhibit statistically few or no occurrences of total burn through and statistically significant occurrences of self-extinguishment under free burn conditions. The first and third zones are separated by the second zone. The second zone comprises less add-on material than the first and third zones or no add-on material. The wrapper has greater permeability along the second zone than along the first and third zones. The second zone has a width less than either width of the first and third zones (which can have equal or unequal widths), so that lit smoking articles comprising the first, second and third zones exhibit statistically reduced occurrences of self-extinguishment under free burn conditions, as compared to smoking articles comprising wrappers whereon the first and third zones are applied as a single continuous band, while maintaining statistically few or no occurrences of total burn through.
Preferably, the first and third zones are of uniform add-on material across the first and third zones.
Optionally, the second zone may have a width essentially equal to the first and third zones.
36 Total weight of add-on material for the banded region preferably lies in the range of 0.5 grams per square meter (g/m2) to 15g/m2, more preferably in the range of from 0.5g/m2 to 3g/m2, even more preferably in the range of from 0.5g/m2 to 1.5g/m2, approximately.
Conventional cigarette paper is permeable, with the permeability commonly designated in CORESTA, which measures paper permeability in terms of volumetric flow rate (cm3/sec) per unit area (cm2) per unit pressure drop (cm of water). Permeability of the cigarette paper normally exceeds 20 CORESTA and preferably, the cigarette paper has a permeability of about 6 33 to about 60 CORESTA and a basis weight of about 22g/m2 30g/m2.
However, permeability through the banded regions and the underlying cigarette paper preferably lies in the range of 0 to 15 CORESTA. The reduction in permeability preferably restricts air flow needed to support combustion of the cigarette coal in the vicinity of the banded region.
The first and third zones preferably have a greater basis weight in grams per square meter than the intermediate second zone; for example, the basis weight in grams per square 12 meter of the first and third zones may be at least twice the basis weight in grams per square meter of the second zone. The second zone may comprise a gap. As used herein, the term "gap" refers to a discrete area of a banded region, between the first and third zones, lacking any permeability reducing add-on material (L e., containing no layers of permeability reducing add-on material). In order to aid combustion in the second zone, the wrapper may comprise iron oxide at the location of the second zone. The second zone preferably has a greater permeability than 18 the first and third zones.
The at least one transverse banded region preferably comprises a first printed layer contacting the base web and a second printed layer, preferably having an equal or greater basis weight in grams per square meter than the first printed layer, on the first printed layer. However, the second and/or subsequent layers may be less in basis weight than the first layer. For example, the basis weight in grams per square meter of the second printed layer may be at 24 least twice the basis weight in grams per square meter of the first printed layer. In an embodiment, the second zone may comprise a single printed layer and the first and third zones may each comprise at least two printed layers (more preferably three or more layers).
Alternatively, the first and third zones may each comprise at least three or four printed layers, and the second zone may comprise only one or two or no printed layers.
Non-banded areas of the base web preferably do not comprise permeability reducing 30 add-on material. As described below with reference to FIG. 2, the transverse banded region may comprise greater than three zones. For example, the transverse banded region may comprise, for example, five zones, with the second and fourth zones separating the first, third and fifth zones and the wrapper having greater permeability along the second and fourth zones than along the first, third and fifth zones.
Also provided is an wrapper of a smoking article comprising a base web and a 36 transverse banded region of add-on material. The transverse banded region is designed to cause extinguishment of smoking articles comprising the transverse banded region when left upon a substrate. The wrapper further comprises a more permeable, intermediate zone along the transverse banded region such that the occurrences of self-extinguishments of smoking articles comprising the wrapper is statistically reduced over those without the intermediate zone.
In a further embodiment, a wrapper of a smoking article comprises a base web and at least one transverse banded region comprising first, second and third zones on the base web.
6 The at least one transverse banded region cah be free of fillers and optionally at least one of the zones is formed at least in part from an add-on material which includes a filler. The add-on material is preferably uniform across the first and third zones. The first and third zones are outward of the second zone, and the overall wrapper structure at the second zone has a greater permeability compared to the overall wrapper structure at the first and third zones.
Additionally provided is a wrapper of a smoking article comprising a base web and at 12 least one transverse banded region comprising first, second and third zones on the base web.
The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third zones, and the second zone and the first and third zones comprise add-on material.
The wrappers of the invention are preferably supplied on bobbins and it is preferred that the wrapper on the bobbin comprises evenly spaced apart transverse banded regions or a is repeating series of transverse banded regions.
Moreover, provided is a method of making a banded wrapper of a smoking article comprising supplying a base web and forming at least one transverse banded region comprising first, second and third zones on the base web. The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third zones, and at least the first ahd third zones are formed from an add-on material free of fillers.
24 Optionally at least one of the zones is formed at least in part from an add-on material which includes a filler. The add-on material is preferably uniform across the first and third zones.
Furthermore, provided is a method of making a banded wrapper of a smoking article comprising supplying a base web and forming at least one transverse banded region comprising first, second and third zones on the base web. The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third zones, 30 and the second zone and the first and third zones are formed from an add-on material.
Optionally at least one of the zones is formed at least in part from an add-on material which includes a filler. The add-on material is preferably uniform across the first and third zones.
FIGs. 1-3 illustrate smoking articles comprising slit banded paper as described herein.
Specifically, FIG. 1 illustrates a smoking article having two banded regions 10 on a base web 100, each comprising first and third zones of add-on material 11, 13 separated by a second 36 zone 12, which may be in the form of a gap or may be in the form of a zone of reduced add-on material. The first and third zones of add-on material 11, 13 may each be, for example, about 2mm to 5mm, preferably about 2mm to 3mm, wide, and the second zone 12 may be, for example, about 1mm to 2 mm wide. More specifically, the first and third zones of add-on material 11, 13 may each be, for example, about 3mm wide, and the second zone 12 may be, for example, about 1.5mm or 2mm wide. The first and third zones of add-on material 11, 13 preferably comprise multiple layers of add-on material, such as, for example, two, three or four layers of add-on material. The add-on 6 material is preferably uniform across the first and third zones 11, 13.
- FIG. 2 illustrates a smoking article having two banded regions 20 on a base web 100, each comprising first, third and fifth zones of add-on material 21, 23, 25 separated by second and fourth zones 22, 24, which may be in the form of gaps or in the form of reduced levels of add-on material. The first, third and fifth zones of add-on material 21, 23, 25 may each be, for example, about 2mm to 3mm wide, and the second and fourth zones 22, 24 may each be, for example, about 1mrn to 2mm wide. More preferably, the first, third and fifth zones of add-on material 21, 23, 25 may each be, for example, about 2mm wide, and the second and fourth zones 22, 24 may each be, for example, about lmm wide or less. The first, third and fifth zones of add-on material 21, 23, 25 preferably comprise multiple layers of add-on material, such as, for example, two, three or four layers of add-on material. The add-on material is preferably uniform across the first, third and fifth zones 21, 23, 25.
FIG. 3 illustrates a smoking article having two banded regions 30 on a base web 100, each comprising first and third zones of add-on material 31, 33 separated by a second zone of less add-on material 32. The first and third zones of add-on material 31, 33 may each be, for example, about 2mm to 3mm wide, and the second zone of less add-on material 32 may be, for example, about 1mm to 2mm wide. More preferably, the first and third zones of add-on material 31, 33 may each be, kir example, about 3mm wide, and the second zone of less add-on material 32 may be, for example, about 2mm wide or less. The first and third zones of add-on material 31, 33 preferably comprise multiple layers of add-on material, such as, for example, two, three or four layers of add-on material, while the second zone of less add-on material 32 may comprise, for example, one or two layers of add-on material. The add-on material is preferably uniform across the first and third zones 31, 33. Although second zones 32 are operative at a lmm width, the embodiment performs better at a 1.2mm width or greater.
Referring to FIGs. 1-3, slit banded paper facilitates use of wrappers of lower permeability for a given level of CO than prior designs of banded paper. For example, it was found in some circumstances that a tobacco rod comprising paper having a permeability of 33 CORESTA and a CO (FTC) delivery of 11mg would produce 15mg of CO (FTC) if previous versions of bands were applied without further change. In order to counteract his increase, the permeability of the wrapper would have to be raised to about 46 CORESTA. Such changes create a multitude of consequence in cigarette design, such as, for example, impacting puff count, possibly lessening machinability of the paper, and the like. In contrast, the slit banded paper having a permeability of 33 CORESTA provided 12mg CO (FTC). Thus, the slit banded banded technology described herein facilitates application of bands with a lesser impact on CO levels (FTC).
Referring to FIGs. 4 and 5, further embodiments may include banded regions wherein the zones extend longitudinally instead of= circumferentially.
=More specifically, FIG. 4 corresponds to banded region configuration of FIG. 2 with the zones extend longitudinally 6 instead of circumferentially, and FIG. 5 corresponds to banded region configuration of FIG. 3 with the zones extend longitudinally instead of circumferentially.
In a preferred embodiment, the first layer of each banded region is preferably formed using an aqueous occlusive composition, which extends completely across the banded region.
The successive layer (or layers) of each banded region may be formed by using the same aqueous film forming composition or different aqueous compositions. For example, multiple 12 layers may all comprise layers containing exclusively starch or multiple layers may comprise one or more layers containing exclusively starch and one or more layers containing calcium carbonate (in any order). During gravure printing, the occlusive composition is preferably heated to a temperature where its viscosity lies within the range of viscosities suitable for gravure printing. When the heated occlusive composition is applied, the occlusive composition is cooled or quenched and may be gelatinized. Thus, a portion of the free water in the occlusive 18 composition becomes bound and unavailable to soak or migrate into underlying fibers of the base web. That binding of free water inhibits formation of waviness, cockling, and/or wrinkling in the base web. Successive layers of the banded regions preferably have increased thickness relative to the first layer. The banded regions provide a reduction in permeability to the underlying base web, which preferably restricts air flow needed to support combustion of the cigarette coal in the vicinity of the banded region.
The occlusive composition used in the occlusive composition may be selected from the group consisting of starch, alginate, carrageenan, guar gum, pectin, and mixtures thereof.
Preferably, the occlusive composition comprises starch, more preferably oxidized starch, such 30 as, for example, tapioca starch, more specifically oxidized tapioca starch. In embodiments, the occlusive composition preferably does not contain fillers, such as, for example, calcium carbonate, which would increase the burn rate through the banded region. In a preferred embodiment, the occlusive composition used for printing comprises water and.
about 20% to about 50%, by weight, of the occlusive composition. At higher concentrations of the occlusive composition in the composition, the composition may experience gelatinization when its 36 temperature is rapidly reduced. Thus, the binding of free water into the printed banded region may occur.
At room temperature (about 23 C), the high-solids-content occlusive composition has a viscosity exceeding about 2mPas (200 centipoise (cP)) and is unsuitable for gravure printing;
however, at a temperature in the range of about 40 C to about 90 C, the viscosity of the occlusive composition is decreased sufficiently for use as a gravure printing composition. For gravure printing, the upper limit of suitable viscosity is about 2mPa.s (200 cP). Most preferably, 6 the occlusive composition has a viscosity of about 1mPas (100 cP) at a temperature in the range of 40 C to 90 C so that the composition can be quenched on contact with the paper after gravure printing at that temperature. The viscosity of the composition at room temperature is also important. The high viscosity at room temperature is needed so that the occlusive composition gels at room temperature.
Preferably, the banded regions are applied to the wrapper using a successive gravure 12 printing process. Gravure printing operations are capable of precise registry of successive printing operations. Accordingly, gravure printing can be used to effectively print not only the first layer of the banded regions, but also the optional successive layers.
In a successive gravure printing process, preferably after the first layer is applied to the base web it is allowed to dry thereon using suiting arrangements, prior to being advanced to a second gravure printing station where a second layer is applied to the first layer using 18 conventional successive-pass gravure printing equipment. Preferably, the second layer is coextensive with the first layer in both width and length; however, the second layer may have a different basis weight in grams per square meter than the first layer. The occlusive composition of the second layer gels on the cooler first layer ¨ and free water does not migrate or become absorbed by the paper. Preferably, the second layer is allowed to dry using suitable arrangements prior to being advanced to successive gravure printing station(s) where 24 successive layer(s) are applied. Preferably, the successive layer(s) are coextensive with the previous layer(s) in both width and length (i.e., the layers do not have a stepped appearance);
however, the successive layer(s) may have different basis weight in grams per square meter than the previous layer(s) or may comprise different add-on compositions.
Preferably, successive layer(s) are preferably allowed to dry after the printing of each successive layer in accordance with well-known gravure printing techniques and conventional gravure printing 30 systems.
The gravure printing process can be used immediately following paper manufacture, e., at a printing station at a location near the end of the paper making machine.
Alternatively, the gravure printing process can be used in connection with reels carrying the wrapper onto which the banded regions are to be printed. For example, a reel of wrapper having a selected permeability and a selected basis weight is mounted so that the wrapper can be unspooled from 36 the reel as a continuous base web.
The base web advances or passes through a first gravure printing station where the first layer of each banded region is printed on the paper. The printing process may be applied to the felt side or the wire side of the paper, or both. Next, the wrapper passes through a second gravure printing station where a second layer of each banded region is printed on the corresponding first layer. Additional layers are applied in a similar manner as described.
6 Finally, the wrapper with the printed banded regions is wound up on a collection reel. The collection reel is then cut into bobbins. The bobbins are then used during manufacture of the desired smoking article in conventional tobacco rod making machines.
The apparatus at each of the gravure printing stations is essentially the same in its material aspects. Accordingly, it will suffice to describe one of the gravure printing stations in detail, it being understood that the other gravure printing stations have common features, unless 12 otherwise noted. A=single pass technique can be used to make the banded paper instead of a multi-pass technique.
At the first gravure printing station, the apparatus includes a gravure cylinder or roller generally mounted for rotation around a horizontal axis. The generally cylindrical surface of the roller is patterned (i.e., with dots, lines, cells, etc.) in a suitable process to define a negative of the first layer of banded regions. Conventional engraving (etching), chemical engraving, 18 electronic engraving, and photo etching can be used to pattern the surface of the gravure cylinder. The circumference of the roller is determined such that it is an integral multiple of the sum of the nominal distance between banded regions plus the banded region width. Thus, for each revolution of the roller, that integral number of first layers of the banded regions is printed on the wrapper.
With gravure printing, while each layer of add-on material may be applied uniformly, 24 each layer of add-on material need not be applied uniformly. For example, a layer of add-on material may be applied such that discrete portions of the layer have differing grams per square meter weights than other areas of the layer. This may be accomplished, for example, by printing a discrete portion of the layer having a differing basis weight than other areas of the layer in a separate printing stage using add-on material having a differing basis weight.
Alternatively, a layer of add-on material may be applied such that discrete portions of the layer 30 have differing depths than other areas of the layer. This may be accomplished, for example, by patterning the gravure cylinder or roller so as to provide a discrete portion of the layer having a differing depth than other areas of the layer.
The multiple zones, for example, first, second and third zones, of the banded regions described herein may be applied in a single printing stage or multiple printing stages. When applied in multiple printing stages, each zone which contains add-on material may be applied in 36 a separate printing stage. For example, for a banded region containing first, second and third zones, wherein only the first and third zones contain add-on material, the first zone may be applied in a first printing stage and the third zone may be applied in a second printing stage.
Alternatively, when applied in a single printing stage, the zones containing add-on material are applied using an appropriately patterned gravure cylinder or roller. For example, for a banded region containing first, second and third zones, wherein only the first and third zones contain add-on material, the gravure cylinder or roller is patterned so as to apply add-on material only in 6 the first and third zones.
An impression cylinder is mounted for counter-rotation on an axis parallel to the axis of the roller. In some applications, the impression cylinder includes a nonmetallic resilient surface.
The impression cylinder is positioned between the roller and a backing roller, which is also mounted for rotation on an axis parallel to the axis of the roller and which counter-rotates relative to the impression cylinder. One of the functions provided by the backing roller is 12 stiffening the central portions of the impression cylinder so that the uniform printing pressure is attained between the roller and the impression cylinder. The gravure cylinder or roller and the impression cylinder cooperate to define a nip through which the base web advances during the printing process. That nip is sized to pinch the base web as it moves between the gravure cylinder and the impression cylinder. The nip pressure on the base web ensures the correct transfer of the composition from the cylinder to the paper.
18 A reservoir contains the occlusive composition discussed above for forming banded regions on the wrapper. The reservoir communicates with a suitable pump which is capable of handling the viscous occlusive composition. The occlusive composition may then flow to a suitable heat exchanger where the temperature of the occlusive composition is elevated so that it lies in the range of about 40 to about 90 C so that the viscosity of the occlusive composition is adjusted to a level which is suitable for gravure printing. As discussed above, viscosity for 24 gravure printing usually needs to be less than about 200 cP. Preferably, the temperature of the occlusive composition is selected so that the viscosity is less than about 100 cP.
While a separate heat exchanger is disclosed, it may be desirable to provide thermal conditioning of the occlusive composition in the reservoir itself. For example, heating elements and stirring apparatus may be included in the reservoir to maintain the elevated temperature for the occlusive composition. Placement of the thermal conditioning in the reservoir has the 30 advantage of making pump selection and operating requirements simpler since the pump need not handle the occlusive composition at the higher viscosity associated with lower temperatures because the occlusive composition would already be heated and, therefore, at the lower viscosity. Whether thermal conditioning occurs in the reservoir or in a separate heat exchanger, it is important that the thermal conditioning step occur at a temperature selected to avoid scorching the occlusive composition. Scorching can cause discoloration of the occlusive 36 composition, and can affect the occlusive characteristics of the composition. Thus, scorching is to be avoided while the occlusive composition is subjected to thermal conditioning.
=
Regardless of where the thermal conditioning step occurs, the heated occlusive composition is delivered to a suitable applicator that spreads the occlusive composition along the length of the gravure cylinder. That spreading step may be effected by pouring or spraying the occlusive composition onto the gravure cylinder, or simply by delivering the liquid occlusive composition to a bath of occlusive composition that collects at the bottom of the gravure 6 cylinder, between the gravure cylinder and a collector. The cylinder may be heated to prevent premature cooling of the composition.
Generally, the collector extends vertically around the gravure roller to a height sufficient to collect the bath, but to a height well below the top of the gravure cylinder. When the bath reaches the top of the collector, occlusive composition can flow through a drain at the bottom of the apparatus back into the reservoir. Thus, the occlusive composition circulates through the 12 printing station and can be maintained at suitable printing viscosity by the thermal conditioning apparatus discussed above.
As the gravure cylinder rotates through the applicator and/or the bath, the occlusive composition adheres to the surface of the gravure cylinder, including in the impressions provided therein to define the banded regions. Further rotation of the gravure cylinder toward the nip moves the cylinder surface past a suitable doctor blade. The doctor blade extends along 18 the length of the gravure cylinder and is.positioned so that is wipes the surface of the gravure cylinder. In this way, those portions of the gravure cylinder that define the nominal spacing between adjacent banded regions is essentially wiped clean of the occlusive composition, while engraved portions of the gravure cylinder that define the banded regions themselves advance toward the nip full of the occlusive composition.
As the wrapper and the surface of the gravure cylinder move through the nip, the 24 occlusive composition is transferred to the surface of the wrapper. The linear speed or velocity of the wrapper matches the tangential surface speed of both the gravure cylinder and the impression cylinder as the wrapper passes through the nip. In that way, slippage and/or smearing of the occlusive composition on the wrapper are avoided.
The thickness of the multilayer banded regions preferably is less than about 20% of the thickness of the base web, and may be less than 5% of the thickness of the base web. The 30 thickness of the first layer of the banded region applied in the first gravure printing station, preferably is less than 4% of the base web thickness, and may be less than 1%
of the base web thickness. Thus, it is seen that the thickness of the first layer is small in relation to the thickness of the underlying base web.
FIG. 6 is a schematic view of a multiple stage printing apparatus. With reference to the above-description for multiple stage printing, FIG. 6 illustrates a reel 40, first gravure printing 36 station 42, second gravure printing station 44, third gravure printing station 46, collection reel 48, rollers 50, impression cylinder 52, backing roller 54, nips 56, reservoir 58, pump 60, heat exchanger 62, applicator 64, bath 66, collector 67, drain 68, doctor blade 70, adjustment cylinders 72, and idler roller 74. In FIG. 6, features of the first gravure printing station 42 contain reference numerals with the suffix "a", corresponding features of the second gravure printing station 44 contain the same reference numeral with the suffix "b", and corresponding features of the third gravure printing station 46 contain the same reference numeral with the suffix "c".
EXAMPLES =
The following examples are intended to be non-limiting and merely illustrative.
Cigarettes with five different wrappers (i.e., wrappers with five different banded region configurations), were tested for ignition propensity ("IP") and self-extinguishment ("SE") at 00 (horizontal). The base web of each of the wrappers had a permeability of 33 CORESTA and 12 basis weight of 25g/m2. As used herein ="IP" refers to total burn through of a cigarette.
Accordingly, an IP value of 0% indicates that 0% of the cigarettes tested exhibited total burn through, an IP value of 2.5% indicates that 2.5% of the cigarettes tested exhibited total burn through, and an IP value of 5% indicates that 5% of the cigarettes tested exhibited total burn through. As used herein "SE" refers to self-extinguishment under free burn conditions. Thus, for example, an SE value of 95% indicates that 95% of the cigarettes tested exhibited self-18 extinguishment under free burn conditions, while an SE value of 20%
indicates that 20% of the cigarettes tested exhibited self-extinguishment uhder free burn conditions.
Table 1 = Wrapper Banded Total IP Run IP Run IP Run IP SE @ 00 Region Banded 1 2 3 Avg.
Configuration* Region = Width A Control 6 mm 0% 0% 0% 0% 95%
3-1-3 7 mm 0% 2.5% 0% 0.8% 60%
3-2-3 8 mm 0% 0% 5% 1.7% 25%
2-2-2 6 mm 2.5% 0% 0% 0.8% 45%
_ 2-1-2-1-2 8 mm 2.5% 2.5% 2.5% 2.5% 20%
* Numbers refer to zone widths in mm (see Tables 2-5, below) Referring to Table 1, wrapper A was a control, comprising a continuous, solid 6mm printed banded region, having an add-on rate of 5.5x. As used herein, an add-on rate of 5.5x 24 results in 8g/m2 to 9g/m2 of add-on material on a dry weight basis, and a basis weight of 26.5g/m2 for 6mm banded regions with a 27mm phase (i.e., the spacing from the leading edge of a banded region to the leading edge of the next banded region) applied to a base web with a basis weight of 25g/m2.
Table 2 ¨ Details of Wrapper B
Zone 1 Zone 2 Zone 3 Width 3mm 1mm 3mm Layers of Add-on Material 2 1 2 Add-on Rate Per Layer 1.5x/4x 1.5x/0 1.5x/4x Total Add-on Material 5.5x 1.5x 5.5x Table 3 ¨ Details of Wrapper C
Zone 1 Zone 2 Zone 3 Width 3mm 2mm 3mm Layers of Add-on Material 2 1 2 Add-on Rate Per Layer 1.5x/4x 1.5x/0 1.5x/4x Total Add-on Material 5.5x 1.5x 5.5x Table 4 ¨ Details of Wrapper D
Zone 1 Zone 2 Zone 3 Width 2mm 2mm 2mm Layers of Add-on-Material 2 2 2 Add-on Rate Per Layer 1.5x/4x 1.5x/2x 1.5x/4x Total Add-on Material 5.5x 3.5x 5.5x Table 5 ¨ Details of Wrapper E
Zone 1 Zone 2 Zone 3 Zone 4 Zone 5 Width 2 mm 1 mm 2 mm 1 mm 2 mm Layers of Add-on Material 2 1 2 1 2 Add-on Rate Per Layer 1.5x/4x 1.5x/0 1.5x/4x 1.5x/0 1.5x/4x Total Add-on Material 5.5x 1.5x 5.5x 1.5x 5.5x As compared to control wrapper A, wrappers B-E exhibited the desired reduction in SE
while maintaining IP (i.e., without significantly increasing IP). In particular, wrapper B exhibited an improvement over control wrapper A, as evidenced by the decrease in SE
average from 95%
12 to 60%. Further, comparing wrappers B and D, it can be seen that by increasing the width of the second zone from 1mm to 2mm, the SE average decreased from 60% to 25%
(while approximately maintaining the IP value). Thus, the width of the second zone is preferably greater than 1mm, preferably about 1.5mm or about 2mm. While good results were also shown by wrapper C, which exhibited an SE average of 45%, the best results were shown by wrapper E, which exhibited an SE average of 20%.
It should be noted that wrapper E, having a banded region comprising first, second, third, fourth and fifth zones and which showed the best results, had 1mm second and fourth zones of greater permeability. In contrast, wrapper B, having a banded region comprising just 6 first, second and third zones, with a 1mm second zone of a greater permeability, did not perform as well. Thus, wrappers having banded regions comprising just first, second and third zones preferably have wider zones of greater permeability (i.e., about 1.5mm or about 2mm) than the zones of greater permeability of wrappers having banded regions comprising first, second, third, fourth and fifth zones.
The terms and phases used herein are not to be interpreted with mathematical or 12 geometric precision, rather geometric terminology is to be interpreted as meaning approximating or similar to the geometric terms and concepts. Terms such as "generally" are intended to encompass both precise meanings of the associated terms and concepts as well as to provide reasonable latitude which is consistent with form, function, and/or meaning.
While various embodiments have been described, it is to be understood that variations and modifications may be resorted to as will be apparent to those skilled in the art. For 18 example, the embodiments are described as having slits preferably 1mm to 2mm wide; other embodiments could be constructed with slits 1mm to 3mm wide. Such variations and modifications are to be considered within the purview and scope of the claims appended hereto.
In another embodiment, the banded region can comprise first, second and third zones of add-on material, which may be applied by any of the methods disclosed herein, wherein the 12 second zone includes perforations which preferably are filled with an occluding material which melts or is evaporated when the burning coal approaches the banded region to thereby provide the second zone with increased permeability.
Thus, provided is a wrapper of a smoking article comprising a base web and at least one transverse banded region comprising first, second and third zones. The first and third zones comprise add-on material, which reduces permeability of the wrapper. The first and third zones 18 each have a width such that if either of said first or third zone were applied separately to wrappers of smoking articles, the smoking articles would exhibit statistically significant occurrences of total burn through and statistically few or no occurrences of self-extinguishment under free burn conditions (e.g., after testing a batch of 20 to 50 cigarettes). The sum of the widths of the first and third zones is such that if the zones were applied to wrappers of smoking articles as a single continuous band (without a slit or other discontinuity), the smoking articles 24 would exhibit statistically few or no occurrences of total burn through and statistically significant occurrences of self-extinguishment under free burn conditions. The first and third zones are separated by the second zone. The second zone comprises less add-on material than the first and third zones or no add-on material. The wrapper has greater permeability along the second zone than along the first and third zones. The second zone has a width less than either width of the first and third zones (which can have equal or unequal widths), so that lit smoking articles comprising the first, second and third zones exhibit statistically reduced occurrences of self-extinguishment under free burn conditions, as compared to smoking articles comprising wrappers whereon the first and third zones are applied as a single continuous band, while maintaining statistically few or no occurrences of total burn through.
Preferably, the first and third zones are of uniform add-on material across the first and third zones.
Optionally, the second zone may have a width essentially equal to the first and third zones.
36 Total weight of add-on material for the banded region preferably lies in the range of 0.5 grams per square meter (g/m2) to 15g/m2, more preferably in the range of from 0.5g/m2 to 3g/m2, even more preferably in the range of from 0.5g/m2 to 1.5g/m2, approximately.
Conventional cigarette paper is permeable, with the permeability commonly designated in CORESTA, which measures paper permeability in terms of volumetric flow rate (cm3/sec) per unit area (cm2) per unit pressure drop (cm of water). Permeability of the cigarette paper normally exceeds 20 CORESTA and preferably, the cigarette paper has a permeability of about 6 33 to about 60 CORESTA and a basis weight of about 22g/m2 30g/m2.
However, permeability through the banded regions and the underlying cigarette paper preferably lies in the range of 0 to 15 CORESTA. The reduction in permeability preferably restricts air flow needed to support combustion of the cigarette coal in the vicinity of the banded region.
The first and third zones preferably have a greater basis weight in grams per square meter than the intermediate second zone; for example, the basis weight in grams per square 12 meter of the first and third zones may be at least twice the basis weight in grams per square meter of the second zone. The second zone may comprise a gap. As used herein, the term "gap" refers to a discrete area of a banded region, between the first and third zones, lacking any permeability reducing add-on material (L e., containing no layers of permeability reducing add-on material). In order to aid combustion in the second zone, the wrapper may comprise iron oxide at the location of the second zone. The second zone preferably has a greater permeability than 18 the first and third zones.
The at least one transverse banded region preferably comprises a first printed layer contacting the base web and a second printed layer, preferably having an equal or greater basis weight in grams per square meter than the first printed layer, on the first printed layer. However, the second and/or subsequent layers may be less in basis weight than the first layer. For example, the basis weight in grams per square meter of the second printed layer may be at 24 least twice the basis weight in grams per square meter of the first printed layer. In an embodiment, the second zone may comprise a single printed layer and the first and third zones may each comprise at least two printed layers (more preferably three or more layers).
Alternatively, the first and third zones may each comprise at least three or four printed layers, and the second zone may comprise only one or two or no printed layers.
Non-banded areas of the base web preferably do not comprise permeability reducing 30 add-on material. As described below with reference to FIG. 2, the transverse banded region may comprise greater than three zones. For example, the transverse banded region may comprise, for example, five zones, with the second and fourth zones separating the first, third and fifth zones and the wrapper having greater permeability along the second and fourth zones than along the first, third and fifth zones.
Also provided is an wrapper of a smoking article comprising a base web and a 36 transverse banded region of add-on material. The transverse banded region is designed to cause extinguishment of smoking articles comprising the transverse banded region when left upon a substrate. The wrapper further comprises a more permeable, intermediate zone along the transverse banded region such that the occurrences of self-extinguishments of smoking articles comprising the wrapper is statistically reduced over those without the intermediate zone.
In a further embodiment, a wrapper of a smoking article comprises a base web and at least one transverse banded region comprising first, second and third zones on the base web.
6 The at least one transverse banded region cah be free of fillers and optionally at least one of the zones is formed at least in part from an add-on material which includes a filler. The add-on material is preferably uniform across the first and third zones. The first and third zones are outward of the second zone, and the overall wrapper structure at the second zone has a greater permeability compared to the overall wrapper structure at the first and third zones.
Additionally provided is a wrapper of a smoking article comprising a base web and at 12 least one transverse banded region comprising first, second and third zones on the base web.
The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third zones, and the second zone and the first and third zones comprise add-on material.
The wrappers of the invention are preferably supplied on bobbins and it is preferred that the wrapper on the bobbin comprises evenly spaced apart transverse banded regions or a is repeating series of transverse banded regions.
Moreover, provided is a method of making a banded wrapper of a smoking article comprising supplying a base web and forming at least one transverse banded region comprising first, second and third zones on the base web. The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third zones, and at least the first ahd third zones are formed from an add-on material free of fillers.
24 Optionally at least one of the zones is formed at least in part from an add-on material which includes a filler. The add-on material is preferably uniform across the first and third zones.
Furthermore, provided is a method of making a banded wrapper of a smoking article comprising supplying a base web and forming at least one transverse banded region comprising first, second and third zones on the base web. The first and third zones are outward of the second zone, the second zone has a greater permeability compared to the first and third zones, 30 and the second zone and the first and third zones are formed from an add-on material.
Optionally at least one of the zones is formed at least in part from an add-on material which includes a filler. The add-on material is preferably uniform across the first and third zones.
FIGs. 1-3 illustrate smoking articles comprising slit banded paper as described herein.
Specifically, FIG. 1 illustrates a smoking article having two banded regions 10 on a base web 100, each comprising first and third zones of add-on material 11, 13 separated by a second 36 zone 12, which may be in the form of a gap or may be in the form of a zone of reduced add-on material. The first and third zones of add-on material 11, 13 may each be, for example, about 2mm to 5mm, preferably about 2mm to 3mm, wide, and the second zone 12 may be, for example, about 1mm to 2 mm wide. More specifically, the first and third zones of add-on material 11, 13 may each be, for example, about 3mm wide, and the second zone 12 may be, for example, about 1.5mm or 2mm wide. The first and third zones of add-on material 11, 13 preferably comprise multiple layers of add-on material, such as, for example, two, three or four layers of add-on material. The add-on 6 material is preferably uniform across the first and third zones 11, 13.
- FIG. 2 illustrates a smoking article having two banded regions 20 on a base web 100, each comprising first, third and fifth zones of add-on material 21, 23, 25 separated by second and fourth zones 22, 24, which may be in the form of gaps or in the form of reduced levels of add-on material. The first, third and fifth zones of add-on material 21, 23, 25 may each be, for example, about 2mm to 3mm wide, and the second and fourth zones 22, 24 may each be, for example, about 1mrn to 2mm wide. More preferably, the first, third and fifth zones of add-on material 21, 23, 25 may each be, for example, about 2mm wide, and the second and fourth zones 22, 24 may each be, for example, about lmm wide or less. The first, third and fifth zones of add-on material 21, 23, 25 preferably comprise multiple layers of add-on material, such as, for example, two, three or four layers of add-on material. The add-on material is preferably uniform across the first, third and fifth zones 21, 23, 25.
FIG. 3 illustrates a smoking article having two banded regions 30 on a base web 100, each comprising first and third zones of add-on material 31, 33 separated by a second zone of less add-on material 32. The first and third zones of add-on material 31, 33 may each be, for example, about 2mm to 3mm wide, and the second zone of less add-on material 32 may be, for example, about 1mm to 2mm wide. More preferably, the first and third zones of add-on material 31, 33 may each be, kir example, about 3mm wide, and the second zone of less add-on material 32 may be, for example, about 2mm wide or less. The first and third zones of add-on material 31, 33 preferably comprise multiple layers of add-on material, such as, for example, two, three or four layers of add-on material, while the second zone of less add-on material 32 may comprise, for example, one or two layers of add-on material. The add-on material is preferably uniform across the first and third zones 31, 33. Although second zones 32 are operative at a lmm width, the embodiment performs better at a 1.2mm width or greater.
Referring to FIGs. 1-3, slit banded paper facilitates use of wrappers of lower permeability for a given level of CO than prior designs of banded paper. For example, it was found in some circumstances that a tobacco rod comprising paper having a permeability of 33 CORESTA and a CO (FTC) delivery of 11mg would produce 15mg of CO (FTC) if previous versions of bands were applied without further change. In order to counteract his increase, the permeability of the wrapper would have to be raised to about 46 CORESTA. Such changes create a multitude of consequence in cigarette design, such as, for example, impacting puff count, possibly lessening machinability of the paper, and the like. In contrast, the slit banded paper having a permeability of 33 CORESTA provided 12mg CO (FTC). Thus, the slit banded banded technology described herein facilitates application of bands with a lesser impact on CO levels (FTC).
Referring to FIGs. 4 and 5, further embodiments may include banded regions wherein the zones extend longitudinally instead of= circumferentially.
=More specifically, FIG. 4 corresponds to banded region configuration of FIG. 2 with the zones extend longitudinally 6 instead of circumferentially, and FIG. 5 corresponds to banded region configuration of FIG. 3 with the zones extend longitudinally instead of circumferentially.
In a preferred embodiment, the first layer of each banded region is preferably formed using an aqueous occlusive composition, which extends completely across the banded region.
The successive layer (or layers) of each banded region may be formed by using the same aqueous film forming composition or different aqueous compositions. For example, multiple 12 layers may all comprise layers containing exclusively starch or multiple layers may comprise one or more layers containing exclusively starch and one or more layers containing calcium carbonate (in any order). During gravure printing, the occlusive composition is preferably heated to a temperature where its viscosity lies within the range of viscosities suitable for gravure printing. When the heated occlusive composition is applied, the occlusive composition is cooled or quenched and may be gelatinized. Thus, a portion of the free water in the occlusive 18 composition becomes bound and unavailable to soak or migrate into underlying fibers of the base web. That binding of free water inhibits formation of waviness, cockling, and/or wrinkling in the base web. Successive layers of the banded regions preferably have increased thickness relative to the first layer. The banded regions provide a reduction in permeability to the underlying base web, which preferably restricts air flow needed to support combustion of the cigarette coal in the vicinity of the banded region.
The occlusive composition used in the occlusive composition may be selected from the group consisting of starch, alginate, carrageenan, guar gum, pectin, and mixtures thereof.
Preferably, the occlusive composition comprises starch, more preferably oxidized starch, such 30 as, for example, tapioca starch, more specifically oxidized tapioca starch. In embodiments, the occlusive composition preferably does not contain fillers, such as, for example, calcium carbonate, which would increase the burn rate through the banded region. In a preferred embodiment, the occlusive composition used for printing comprises water and.
about 20% to about 50%, by weight, of the occlusive composition. At higher concentrations of the occlusive composition in the composition, the composition may experience gelatinization when its 36 temperature is rapidly reduced. Thus, the binding of free water into the printed banded region may occur.
At room temperature (about 23 C), the high-solids-content occlusive composition has a viscosity exceeding about 2mPas (200 centipoise (cP)) and is unsuitable for gravure printing;
however, at a temperature in the range of about 40 C to about 90 C, the viscosity of the occlusive composition is decreased sufficiently for use as a gravure printing composition. For gravure printing, the upper limit of suitable viscosity is about 2mPa.s (200 cP). Most preferably, 6 the occlusive composition has a viscosity of about 1mPas (100 cP) at a temperature in the range of 40 C to 90 C so that the composition can be quenched on contact with the paper after gravure printing at that temperature. The viscosity of the composition at room temperature is also important. The high viscosity at room temperature is needed so that the occlusive composition gels at room temperature.
Preferably, the banded regions are applied to the wrapper using a successive gravure 12 printing process. Gravure printing operations are capable of precise registry of successive printing operations. Accordingly, gravure printing can be used to effectively print not only the first layer of the banded regions, but also the optional successive layers.
In a successive gravure printing process, preferably after the first layer is applied to the base web it is allowed to dry thereon using suiting arrangements, prior to being advanced to a second gravure printing station where a second layer is applied to the first layer using 18 conventional successive-pass gravure printing equipment. Preferably, the second layer is coextensive with the first layer in both width and length; however, the second layer may have a different basis weight in grams per square meter than the first layer. The occlusive composition of the second layer gels on the cooler first layer ¨ and free water does not migrate or become absorbed by the paper. Preferably, the second layer is allowed to dry using suitable arrangements prior to being advanced to successive gravure printing station(s) where 24 successive layer(s) are applied. Preferably, the successive layer(s) are coextensive with the previous layer(s) in both width and length (i.e., the layers do not have a stepped appearance);
however, the successive layer(s) may have different basis weight in grams per square meter than the previous layer(s) or may comprise different add-on compositions.
Preferably, successive layer(s) are preferably allowed to dry after the printing of each successive layer in accordance with well-known gravure printing techniques and conventional gravure printing 30 systems.
The gravure printing process can be used immediately following paper manufacture, e., at a printing station at a location near the end of the paper making machine.
Alternatively, the gravure printing process can be used in connection with reels carrying the wrapper onto which the banded regions are to be printed. For example, a reel of wrapper having a selected permeability and a selected basis weight is mounted so that the wrapper can be unspooled from 36 the reel as a continuous base web.
The base web advances or passes through a first gravure printing station where the first layer of each banded region is printed on the paper. The printing process may be applied to the felt side or the wire side of the paper, or both. Next, the wrapper passes through a second gravure printing station where a second layer of each banded region is printed on the corresponding first layer. Additional layers are applied in a similar manner as described.
6 Finally, the wrapper with the printed banded regions is wound up on a collection reel. The collection reel is then cut into bobbins. The bobbins are then used during manufacture of the desired smoking article in conventional tobacco rod making machines.
The apparatus at each of the gravure printing stations is essentially the same in its material aspects. Accordingly, it will suffice to describe one of the gravure printing stations in detail, it being understood that the other gravure printing stations have common features, unless 12 otherwise noted. A=single pass technique can be used to make the banded paper instead of a multi-pass technique.
At the first gravure printing station, the apparatus includes a gravure cylinder or roller generally mounted for rotation around a horizontal axis. The generally cylindrical surface of the roller is patterned (i.e., with dots, lines, cells, etc.) in a suitable process to define a negative of the first layer of banded regions. Conventional engraving (etching), chemical engraving, 18 electronic engraving, and photo etching can be used to pattern the surface of the gravure cylinder. The circumference of the roller is determined such that it is an integral multiple of the sum of the nominal distance between banded regions plus the banded region width. Thus, for each revolution of the roller, that integral number of first layers of the banded regions is printed on the wrapper.
With gravure printing, while each layer of add-on material may be applied uniformly, 24 each layer of add-on material need not be applied uniformly. For example, a layer of add-on material may be applied such that discrete portions of the layer have differing grams per square meter weights than other areas of the layer. This may be accomplished, for example, by printing a discrete portion of the layer having a differing basis weight than other areas of the layer in a separate printing stage using add-on material having a differing basis weight.
Alternatively, a layer of add-on material may be applied such that discrete portions of the layer 30 have differing depths than other areas of the layer. This may be accomplished, for example, by patterning the gravure cylinder or roller so as to provide a discrete portion of the layer having a differing depth than other areas of the layer.
The multiple zones, for example, first, second and third zones, of the banded regions described herein may be applied in a single printing stage or multiple printing stages. When applied in multiple printing stages, each zone which contains add-on material may be applied in 36 a separate printing stage. For example, for a banded region containing first, second and third zones, wherein only the first and third zones contain add-on material, the first zone may be applied in a first printing stage and the third zone may be applied in a second printing stage.
Alternatively, when applied in a single printing stage, the zones containing add-on material are applied using an appropriately patterned gravure cylinder or roller. For example, for a banded region containing first, second and third zones, wherein only the first and third zones contain add-on material, the gravure cylinder or roller is patterned so as to apply add-on material only in 6 the first and third zones.
An impression cylinder is mounted for counter-rotation on an axis parallel to the axis of the roller. In some applications, the impression cylinder includes a nonmetallic resilient surface.
The impression cylinder is positioned between the roller and a backing roller, which is also mounted for rotation on an axis parallel to the axis of the roller and which counter-rotates relative to the impression cylinder. One of the functions provided by the backing roller is 12 stiffening the central portions of the impression cylinder so that the uniform printing pressure is attained between the roller and the impression cylinder. The gravure cylinder or roller and the impression cylinder cooperate to define a nip through which the base web advances during the printing process. That nip is sized to pinch the base web as it moves between the gravure cylinder and the impression cylinder. The nip pressure on the base web ensures the correct transfer of the composition from the cylinder to the paper.
18 A reservoir contains the occlusive composition discussed above for forming banded regions on the wrapper. The reservoir communicates with a suitable pump which is capable of handling the viscous occlusive composition. The occlusive composition may then flow to a suitable heat exchanger where the temperature of the occlusive composition is elevated so that it lies in the range of about 40 to about 90 C so that the viscosity of the occlusive composition is adjusted to a level which is suitable for gravure printing. As discussed above, viscosity for 24 gravure printing usually needs to be less than about 200 cP. Preferably, the temperature of the occlusive composition is selected so that the viscosity is less than about 100 cP.
While a separate heat exchanger is disclosed, it may be desirable to provide thermal conditioning of the occlusive composition in the reservoir itself. For example, heating elements and stirring apparatus may be included in the reservoir to maintain the elevated temperature for the occlusive composition. Placement of the thermal conditioning in the reservoir has the 30 advantage of making pump selection and operating requirements simpler since the pump need not handle the occlusive composition at the higher viscosity associated with lower temperatures because the occlusive composition would already be heated and, therefore, at the lower viscosity. Whether thermal conditioning occurs in the reservoir or in a separate heat exchanger, it is important that the thermal conditioning step occur at a temperature selected to avoid scorching the occlusive composition. Scorching can cause discoloration of the occlusive 36 composition, and can affect the occlusive characteristics of the composition. Thus, scorching is to be avoided while the occlusive composition is subjected to thermal conditioning.
=
Regardless of where the thermal conditioning step occurs, the heated occlusive composition is delivered to a suitable applicator that spreads the occlusive composition along the length of the gravure cylinder. That spreading step may be effected by pouring or spraying the occlusive composition onto the gravure cylinder, or simply by delivering the liquid occlusive composition to a bath of occlusive composition that collects at the bottom of the gravure 6 cylinder, between the gravure cylinder and a collector. The cylinder may be heated to prevent premature cooling of the composition.
Generally, the collector extends vertically around the gravure roller to a height sufficient to collect the bath, but to a height well below the top of the gravure cylinder. When the bath reaches the top of the collector, occlusive composition can flow through a drain at the bottom of the apparatus back into the reservoir. Thus, the occlusive composition circulates through the 12 printing station and can be maintained at suitable printing viscosity by the thermal conditioning apparatus discussed above.
As the gravure cylinder rotates through the applicator and/or the bath, the occlusive composition adheres to the surface of the gravure cylinder, including in the impressions provided therein to define the banded regions. Further rotation of the gravure cylinder toward the nip moves the cylinder surface past a suitable doctor blade. The doctor blade extends along 18 the length of the gravure cylinder and is.positioned so that is wipes the surface of the gravure cylinder. In this way, those portions of the gravure cylinder that define the nominal spacing between adjacent banded regions is essentially wiped clean of the occlusive composition, while engraved portions of the gravure cylinder that define the banded regions themselves advance toward the nip full of the occlusive composition.
As the wrapper and the surface of the gravure cylinder move through the nip, the 24 occlusive composition is transferred to the surface of the wrapper. The linear speed or velocity of the wrapper matches the tangential surface speed of both the gravure cylinder and the impression cylinder as the wrapper passes through the nip. In that way, slippage and/or smearing of the occlusive composition on the wrapper are avoided.
The thickness of the multilayer banded regions preferably is less than about 20% of the thickness of the base web, and may be less than 5% of the thickness of the base web. The 30 thickness of the first layer of the banded region applied in the first gravure printing station, preferably is less than 4% of the base web thickness, and may be less than 1%
of the base web thickness. Thus, it is seen that the thickness of the first layer is small in relation to the thickness of the underlying base web.
FIG. 6 is a schematic view of a multiple stage printing apparatus. With reference to the above-description for multiple stage printing, FIG. 6 illustrates a reel 40, first gravure printing 36 station 42, second gravure printing station 44, third gravure printing station 46, collection reel 48, rollers 50, impression cylinder 52, backing roller 54, nips 56, reservoir 58, pump 60, heat exchanger 62, applicator 64, bath 66, collector 67, drain 68, doctor blade 70, adjustment cylinders 72, and idler roller 74. In FIG. 6, features of the first gravure printing station 42 contain reference numerals with the suffix "a", corresponding features of the second gravure printing station 44 contain the same reference numeral with the suffix "b", and corresponding features of the third gravure printing station 46 contain the same reference numeral with the suffix "c".
EXAMPLES =
The following examples are intended to be non-limiting and merely illustrative.
Cigarettes with five different wrappers (i.e., wrappers with five different banded region configurations), were tested for ignition propensity ("IP") and self-extinguishment ("SE") at 00 (horizontal). The base web of each of the wrappers had a permeability of 33 CORESTA and 12 basis weight of 25g/m2. As used herein ="IP" refers to total burn through of a cigarette.
Accordingly, an IP value of 0% indicates that 0% of the cigarettes tested exhibited total burn through, an IP value of 2.5% indicates that 2.5% of the cigarettes tested exhibited total burn through, and an IP value of 5% indicates that 5% of the cigarettes tested exhibited total burn through. As used herein "SE" refers to self-extinguishment under free burn conditions. Thus, for example, an SE value of 95% indicates that 95% of the cigarettes tested exhibited self-18 extinguishment under free burn conditions, while an SE value of 20%
indicates that 20% of the cigarettes tested exhibited self-extinguishment uhder free burn conditions.
Table 1 = Wrapper Banded Total IP Run IP Run IP Run IP SE @ 00 Region Banded 1 2 3 Avg.
Configuration* Region = Width A Control 6 mm 0% 0% 0% 0% 95%
3-1-3 7 mm 0% 2.5% 0% 0.8% 60%
3-2-3 8 mm 0% 0% 5% 1.7% 25%
2-2-2 6 mm 2.5% 0% 0% 0.8% 45%
_ 2-1-2-1-2 8 mm 2.5% 2.5% 2.5% 2.5% 20%
* Numbers refer to zone widths in mm (see Tables 2-5, below) Referring to Table 1, wrapper A was a control, comprising a continuous, solid 6mm printed banded region, having an add-on rate of 5.5x. As used herein, an add-on rate of 5.5x 24 results in 8g/m2 to 9g/m2 of add-on material on a dry weight basis, and a basis weight of 26.5g/m2 for 6mm banded regions with a 27mm phase (i.e., the spacing from the leading edge of a banded region to the leading edge of the next banded region) applied to a base web with a basis weight of 25g/m2.
Table 2 ¨ Details of Wrapper B
Zone 1 Zone 2 Zone 3 Width 3mm 1mm 3mm Layers of Add-on Material 2 1 2 Add-on Rate Per Layer 1.5x/4x 1.5x/0 1.5x/4x Total Add-on Material 5.5x 1.5x 5.5x Table 3 ¨ Details of Wrapper C
Zone 1 Zone 2 Zone 3 Width 3mm 2mm 3mm Layers of Add-on Material 2 1 2 Add-on Rate Per Layer 1.5x/4x 1.5x/0 1.5x/4x Total Add-on Material 5.5x 1.5x 5.5x Table 4 ¨ Details of Wrapper D
Zone 1 Zone 2 Zone 3 Width 2mm 2mm 2mm Layers of Add-on-Material 2 2 2 Add-on Rate Per Layer 1.5x/4x 1.5x/2x 1.5x/4x Total Add-on Material 5.5x 3.5x 5.5x Table 5 ¨ Details of Wrapper E
Zone 1 Zone 2 Zone 3 Zone 4 Zone 5 Width 2 mm 1 mm 2 mm 1 mm 2 mm Layers of Add-on Material 2 1 2 1 2 Add-on Rate Per Layer 1.5x/4x 1.5x/0 1.5x/4x 1.5x/0 1.5x/4x Total Add-on Material 5.5x 1.5x 5.5x 1.5x 5.5x As compared to control wrapper A, wrappers B-E exhibited the desired reduction in SE
while maintaining IP (i.e., without significantly increasing IP). In particular, wrapper B exhibited an improvement over control wrapper A, as evidenced by the decrease in SE
average from 95%
12 to 60%. Further, comparing wrappers B and D, it can be seen that by increasing the width of the second zone from 1mm to 2mm, the SE average decreased from 60% to 25%
(while approximately maintaining the IP value). Thus, the width of the second zone is preferably greater than 1mm, preferably about 1.5mm or about 2mm. While good results were also shown by wrapper C, which exhibited an SE average of 45%, the best results were shown by wrapper E, which exhibited an SE average of 20%.
It should be noted that wrapper E, having a banded region comprising first, second, third, fourth and fifth zones and which showed the best results, had 1mm second and fourth zones of greater permeability. In contrast, wrapper B, having a banded region comprising just 6 first, second and third zones, with a 1mm second zone of a greater permeability, did not perform as well. Thus, wrappers having banded regions comprising just first, second and third zones preferably have wider zones of greater permeability (i.e., about 1.5mm or about 2mm) than the zones of greater permeability of wrappers having banded regions comprising first, second, third, fourth and fifth zones.
The terms and phases used herein are not to be interpreted with mathematical or 12 geometric precision, rather geometric terminology is to be interpreted as meaning approximating or similar to the geometric terms and concepts. Terms such as "generally" are intended to encompass both precise meanings of the associated terms and concepts as well as to provide reasonable latitude which is consistent with form, function, and/or meaning.
While various embodiments have been described, it is to be understood that variations and modifications may be resorted to as will be apparent to those skilled in the art. For 18 example, the embodiments are described as having slits preferably 1mm to 2mm wide; other embodiments could be constructed with slits 1mm to 3mm wide. Such variations and modifications are to be considered within the purview and scope of the claims appended hereto.
Claims (29)
1. A wrapper of a smoking article, comprising:
a base web; and at least one transverse banded region comprising first, second and third zones, said first and third zones comprising add-on material, which reduces permeability of said wrapper, said first and third zones being separated by said second zone;
said wrapper having greater permeability along said second zone than along said first and third zones, said second zone having a width less than the width of either of the said first and third zone, the add-on material being uniform across each of the first and third zones, said first and third zones each having a width of 2 mm to 5 mm such that were either of said first or third zone applied separately to wrappers of smoking articles the smoking articles would exhibit total burn through and substantially no occurrences of self-extinguishment under free burn conditions;
the sum of said widths of said first and third zones being such that were the first and third zones applied to wrappers of smoking articles as a single continuous band, the smoking articles would exhibit substantially no occurrences of total burn through and self-extinguishment under free burn conditions, so that lit smoking articles comprising said first, second and third zones exhibit reduced occurrences of self-extinguishment under free burn conditions, as compared to smoking articles comprising wrappers whereon the first and third zones are applied as a single continuous band, while maintaining substantially no occurrences of total burn through.
a base web; and at least one transverse banded region comprising first, second and third zones, said first and third zones comprising add-on material, which reduces permeability of said wrapper, said first and third zones being separated by said second zone;
said wrapper having greater permeability along said second zone than along said first and third zones, said second zone having a width less than the width of either of the said first and third zone, the add-on material being uniform across each of the first and third zones, said first and third zones each having a width of 2 mm to 5 mm such that were either of said first or third zone applied separately to wrappers of smoking articles the smoking articles would exhibit total burn through and substantially no occurrences of self-extinguishment under free burn conditions;
the sum of said widths of said first and third zones being such that were the first and third zones applied to wrappers of smoking articles as a single continuous band, the smoking articles would exhibit substantially no occurrences of total burn through and self-extinguishment under free burn conditions, so that lit smoking articles comprising said first, second and third zones exhibit reduced occurrences of self-extinguishment under free burn conditions, as compared to smoking articles comprising wrappers whereon the first and third zones are applied as a single continuous band, while maintaining substantially no occurrences of total burn through.
2. A wrapper according to claim 1 wherein the first and third zones of add-on material are each 2 mm to 3 mm.
3. A wrapper according to claim 2 in which the first and third zones of add-on material are about 3 mm wide.
4. A wrapper according to any one of claims 1, 2 and 3 wherein the said second zone is 1 mm to 2 mm wide.
5. A wrapper according to claim 4 wherein the said second zone is about 1 mm or 1.5 mm wide.
6. A wrapper according to any one of claims 1-5 wherein the first and third zones have a greater basis weight in grams per square meter than the second zone.
7. A wrapper according to any one of claims 1-6 wherein the basis weight in grams per square meter of the first and third zones is at least twice the basis weight in grams per square meter of the second zone.
8. A wrapper according to any one of claims 1-7 wherein the second zone comprises no add-on material.
9. A wrapper according to any one of claims 1-8 wherein the at least one transverse banded region comprises a first printed layer contacting the base web and a second printed layer on the first printed layer.
10. A wrapper according to any one of claims 1-9 wherein the at least one transverse banded region is a high-solids-content occlusive composition.
11. A wrapper according to claim 10 wherein the said high-solids-content occlusive composition has a viscosity at about 23 °C exceeding about 2 mPa.cndot.s (200 centipoise) and the viscosity at 40 °C
to 90 °C is decreased sufficiently for use of the said composition as a gravure printing composition.
to 90 °C is decreased sufficiently for use of the said composition as a gravure printing composition.
12. A wrapper according to claim 11 wherein the viscosity at 40 °C
to 90 °C is about 1 mPa.cndot.s (100 cP).
to 90 °C is about 1 mPa.cndot.s (100 cP).
13. A wrapper according to any one of claims 1-12 wherein the transverse banded regions comprise first, third and fifth zones of add-on material separated by second and fourth zones of no or lower levels of add-on material.
14. A wrapper according to claim 13 wherein the first, third and fifth zones are from 2 mm to 3 mm wide.
15. A wrapper according to claim 14 wherein the first, third and fifth zones are 2 mm, wide.
16. A wrapper according to any one of claims 13 to 15 wherein the second and fourth zones are up to 2 mm wide.
17. A wrapper according to claim 16 wherein the second and fourth zones are 1 mm, wide.
18. A wrapper according to any one of claims 1-17 wherein the total weight of add-on material for the said transverse banded region is 0.5 g/m2 to 15 g/m2.
19. A wrapper according to claim 18 wherein the total weight of add-on material for the said transverse banded region is 0.5 g/m2 to 3 g/m2.
20. A wrapper according to claim 19 wherein the total weight of add-on material for the said transverse banded region is 0.5 g/m2 to 1.5 g/m2.
21. A wrapper according to any one of claims 1-20 wherein the permeability of the base web exceeds 20 CORESTA.
22. A wrapper according to claim 21 wherein the permeability of the base web is 33 CORESTA
to 60 CORESTA.
to 60 CORESTA.
23. A wrapper according to any one of claims 1-22 wherein the basis weight of the base web is 22 g/m2 to 30 g/m2.
24. A wrapper according to any one of claims 1-23 wherein the permeability of the transverse banded regions and the underlying cigarette paper is 0 to 15 CORESTA.
25. A method of making a banded wrapper of a smoking article, comprising:
supplying a base web; and forming at least one transverse banded region comprising first, second and third zones on the base web;
wherein the first and third zones are outward of the second zone, wherein the second zone has a greater permeability compared to the first and third zones, wherein the width of the second zone is less than those of the first and third zones, the first and third zones being formed so that the add-on material is uniform across each of the first and third zones and in that the first and third zones are formed so that each of the first and third zones has a width of 2 mm to 5 mm such that were either of said first or third zone applied separately to wrappers of smoking articles the smoking articles would exhibit total burn through and substantially no occurrences of self-extinguishment under free burn conditions.
supplying a base web; and forming at least one transverse banded region comprising first, second and third zones on the base web;
wherein the first and third zones are outward of the second zone, wherein the second zone has a greater permeability compared to the first and third zones, wherein the width of the second zone is less than those of the first and third zones, the first and third zones being formed so that the add-on material is uniform across each of the first and third zones and in that the first and third zones are formed so that each of the first and third zones has a width of 2 mm to 5 mm such that were either of said first or third zone applied separately to wrappers of smoking articles the smoking articles would exhibit total burn through and substantially no occurrences of self-extinguishment under free burn conditions.
26. A method according to claim 25 comprising forming at least the first and third zones by printing a first printed layer of add-on material on the base web.
27. A method according to claim 26 wherein the printing comprises:
heating the occlusive material;
applying the heated occlusive material to a patterned gravure cylinder;
contacting the advancing wrapper with the patterned gravure cylinder; and gelling the occlusive material by contact with the wrapper surface so that the occlusive material does not disrupt planarity of the wrapper.
heating the occlusive material;
applying the heated occlusive material to a patterned gravure cylinder;
contacting the advancing wrapper with the patterned gravure cylinder; and gelling the occlusive material by contact with the wrapper surface so that the occlusive material does not disrupt planarity of the wrapper.
28. A method according to any one of claims 26 and 27 wherein the at least one transverse banded region is formed by printing an occlusive material on the base web.
29. A method according to any one of claims 25 to 28 wherein at least the first (11)(21)(31) and third (13)(23)(33) zones are formed from an add-on material free of fillers.
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| US60/787,540 | 2006-03-31 | ||
| PCT/IB2007/002118 WO2007113693A2 (en) | 2006-03-31 | 2007-04-02 | Slit banded paper |
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| JP (1) | JP5676098B2 (en) |
| KR (1) | KR101564780B1 (en) |
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| US8925556B2 (en) | 2006-03-31 | 2015-01-06 | Philip Morris Usa Inc. | Banded papers, smoking articles and methods |
| EP2150139A2 (en) * | 2007-05-24 | 2010-02-10 | Philip Morris Products S.A. | Smoking article with novel wrappe |
| US8701682B2 (en) | 2009-07-30 | 2014-04-22 | Philip Morris Usa Inc. | Banded paper, smoking article and method |
| US9220297B2 (en) | 2009-08-07 | 2015-12-29 | R. J. Reynolds Tobacco Company | Materials, equipment, and methods for manufacturing cigarettes |
| US20110108042A1 (en) * | 2009-11-10 | 2011-05-12 | Philip Morris Usa Inc. | Registered banded cigarette paper, cigarettes, and method of manufacture |
| GB201018310D0 (en) | 2010-10-29 | 2010-12-15 | British American Tobacco Co | Ventilated smoking article |
| KR20140018213A (en) | 2010-12-13 | 2014-02-12 | 알트리아 클라이언트 서비시스 인코포레이티드 | Process of preparing printing solution and making patterened cigarette wrappers |
| US10375988B2 (en) | 2010-12-13 | 2019-08-13 | Altria Client Services Llc | Cigarette wrapper with novel pattern |
| US11707082B2 (en) | 2010-12-13 | 2023-07-25 | Altria Client Services Llc | Process of preparing printing solution and making patterned cigarette wrapper |
| FR2970153B1 (en) * | 2011-01-07 | 2014-04-25 | Republic Technologies Na Llc | CIGARETTE PAPER WITH ENHANCED NATURAL COMBUSTION |
| CA2833971A1 (en) | 2011-05-16 | 2012-11-22 | Altria Client Services Inc. | Alternating patterns in cigarette wrapper, smoking article and method |
| KR101382650B1 (en) * | 2011-10-25 | 2014-04-08 | 주식회사 케이티앤지 | Coating composition of low ignition propensity cigarette paper and cigarette using the same |
| JP6193363B2 (en) | 2012-05-16 | 2017-09-06 | アルトリア クライアント サービシーズ エルエルシー | Cigarette wrapper with a band having a band with an open area |
| US11064729B2 (en) | 2012-05-16 | 2021-07-20 | Altria Client Services Llc | Cigarette wrapper with novel pattern |
| KR101404139B1 (en) | 2012-07-26 | 2014-06-05 | 주식회사 케이티앤지 | Low ignition propensity cigarette paper and cigarette using the same |
| DE102015105882B4 (en) * | 2015-04-17 | 2017-06-08 | Delfortgroup Ag | Wrapping paper with high short fiber content and smoking article |
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| GB1524211A (en) * | 1975-01-09 | 1978-09-06 | British American Tobacco Co | Smoking articles |
| DE3802645A1 (en) * | 1988-01-29 | 1989-08-10 | Reemtsma H F & Ph | QUICK OR SELF-EXTINGUISHING CIGARETTE |
| US5997691A (en) | 1996-07-09 | 1999-12-07 | Philip Morris Incorporated | Method and apparatus for applying a material to a web |
| US5878754A (en) | 1997-03-10 | 1999-03-09 | Schweitzer-Mauduit International, Inc. | Smoking article wrapper for controlling ignition proclivity of a smoking article |
| PT2127544E (en) † | 2000-11-13 | 2012-09-24 | Schweitzer Mauduit Internat | Paper wrapper and smoking article with reduced ignition proclivity characteristics |
| US20020179105A1 (en) * | 2001-02-26 | 2002-12-05 | Zawadzki Michael A. | Reduced ignition propensity smoking article |
| CN2478371Y (en) * | 2001-03-05 | 2002-02-27 | 胡湘克 | Cigarette with self-extinguishing cigarette end |
| US6596125B2 (en) * | 2001-09-21 | 2003-07-22 | Philip Morris Incorporated | Method and apparatus for applying a material to a web |
| US6779530B2 (en) * | 2002-01-23 | 2004-08-24 | Schweitzer-Mauduit International, Inc. | Smoking articles with reduced ignition proclivity characteristics |
| US20040261805A1 (en) * | 2002-04-30 | 2004-12-30 | Brown & Williamson Tobacco Corporation | Smoking article |
| US6997190B2 (en) * | 2002-11-25 | 2006-02-14 | R.J. Reynolds Tobacco Company | Wrapping materials for smoking articles |
| WO2004110189A2 (en) * | 2003-06-13 | 2004-12-23 | Philip Morris Products S.A. | Cigarette wrapper with catalytic filler and methods of making same |
| US20050172977A1 (en) * | 2004-02-10 | 2005-08-11 | Paul Jadot | Low ignition propensity (lip) paper smoking articles |
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- 2007-04-02 EP EP12156227A patent/EP2457453A1/en not_active Withdrawn
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| KR101564780B1 (en) | 2015-10-30 |
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| UA92520C2 (en) | 2010-11-10 |
| EA200870397A1 (en) | 2009-04-28 |
| IL194178A (en) | 2014-03-31 |
| ES2464279T3 (en) | 2014-06-02 |
| EP2007232B2 (en) | 2024-02-14 |
| EP2007232A2 (en) | 2008-12-31 |
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| DK2007232T3 (en) | 2014-06-16 |
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