CA2613698C - Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2) - Google Patents

Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2) Download PDF

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Publication number
CA2613698C
CA2613698C CA2613698A CA2613698A CA2613698C CA 2613698 C CA2613698 C CA 2613698C CA 2613698 A CA2613698 A CA 2613698A CA 2613698 A CA2613698 A CA 2613698A CA 2613698 C CA2613698 C CA 2613698C
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Prior art keywords
sorbent
cao
gas
calcination
carbonation
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CA2613698A
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CA2613698A1 (fr
Inventor
Liang-Shih Fan
Himanshu Gupta
Mahesh V. Iyer
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Ohio State University
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Ohio State University
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Priority claimed from US11/255,099 external-priority patent/US7618606B2/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0277—Carbonates of compounds other than those provided for in B01J20/043
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B01J20/3466—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase with steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3491—Regenerating or reactivating by pressure treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/50—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/18—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/602—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

La présente invention concerne un processus à base de réaction qui a été développé de façon à retirer de manière sélective du dioxyde de carbone (CO2) d'un mélange de gaz multicomposant de façon à obtenir un flux gazeux épuisé en CO2 comparé à la concentration de CO2 d'entrée de ce flux. Le processus proposé effectue la séparation du CO2 du mélange de gaz (tel qu'un gaz de combustion/gaz de combustible) par sa réaction avec des oxydes métalliques (tels que l'oxyde de calcium). Cette séparation par réaction à base de calcium du processus de CO2 (CaRS-CO2) consiste à mettre en contact un gaz chargé de CO2 avec un oxyde de calcium (CaO) dans un réacteur de sorte que le CaO capture le CO2 par formation de carbonate de calcium (CaCOa). Une fois consommé, le CaCO3 est régénéré par sa calcination conduisant à la formation de nouveau sorbant CaO et à l'évolution d'un flux concentré de CO2. Le cycle carbonation/calcination forme la base du processus CaRS-CO2. Ce processus identifie aussi l'application d'une structure CaCO3 mésoporeuse élaboré par un processus détaillé ailleurs, qui atteint une conversion supérieure à 90 % sur de multiples cycles de carbonation et de calcination. Enfin, la régénération thermique (calcination) sous vide fournit une meilleure structure de sorbant qui maintient des niveaux de réactivité reproductibles sur de multiples cycles.
CA2613698A 2005-06-28 2006-06-28 Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2) Active CA2613698C (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US69459405P 2005-06-28 2005-06-28
US60/694,594 2005-06-28
US11/255,099 US7618606B2 (en) 2003-02-06 2005-10-20 Separation of carbon dioxide (CO2) from gas mixtures
US11/255,099 2005-10-20
PCT/US2006/025266 WO2007002792A2 (fr) 2005-06-28 2006-06-28 Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2)

Publications (2)

Publication Number Publication Date
CA2613698A1 CA2613698A1 (fr) 2007-01-04
CA2613698C true CA2613698C (fr) 2013-02-05

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2613698A Active CA2613698C (fr) 2005-06-28 2006-06-28 Separation de dioxyde de carbone (co2) de melange de gaz par processus de separation par reaction a base de calcium ( cars-co2)

Country Status (3)

Country Link
EP (1) EP1899049A4 (fr)
CA (1) CA2613698C (fr)
WO (1) WO2007002792A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11718558B2 (en) 2019-08-13 2023-08-08 California Institute Of Technology Process to make calcium oxide or ordinary Portland cement from calcium bearing rocks and minerals

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7618606B2 (en) * 2003-02-06 2009-11-17 The Ohio State University Separation of carbon dioxide (CO2) from gas mixtures
US7678351B2 (en) 2005-03-17 2010-03-16 The Ohio State University High temperature CO2 capture using engineered eggshells: a route to carbon management
CA2664674C (fr) 2006-09-25 2014-09-23 The Ohio State University Production d'hydrogene haute pression haute purete avec capture sur place de co2 et de soufre dans un reacteur a une seule etape
AU2009246062B2 (en) * 2008-05-15 2014-07-17 Calix Limited System and method for processing flue gas
EP2296786A4 (fr) 2008-06-05 2012-09-19 Ind Res Ltd Procédé de séparation de gaz
DE102008050816B4 (de) * 2008-10-08 2013-09-05 Alstom Technology Ltd. Verfahren und Anordnung zur Abscheidung von CO2 aus Verbrennungsabgas
CN102438941A (zh) * 2008-10-13 2012-05-02 俄亥俄州立大学研究基金会 结合二氧化碳、硫和卤化物捕获的用于生产高纯度氢气的钙循环工艺
WO2011082448A1 (fr) * 2010-01-08 2011-07-14 The University Of Queensland Régénération de sorbant
CA3097188A1 (fr) * 2018-05-18 2019-11-21 California Institute Of Technology Procede de conversion d'especes de soufre reduit et d'eau en hydrogene et en acide sulfurique
CN111085101B (zh) * 2019-12-25 2021-03-09 华北电力大学 一种二氧化碳矿化封存及固化飞灰中重金属的系统及方法
EP3862067A1 (fr) * 2020-02-10 2021-08-11 Clariant Catalysts (Japan) K.K. Éliminateur de co2 et d'o2
US11717802B2 (en) 2021-03-04 2023-08-08 Energy And Environmental Research Center Foundation Methods of treating metal carbonate salts
US11858819B2 (en) 2021-03-04 2024-01-02 Energy And Environmental Research Center Foundation Methods of producing a syngas composition
FR3125817A1 (fr) 2021-07-30 2023-02-03 Welya Procédé de formation d’un produit final à partir de carbonate de calcium et d’une autre espèce
CN115282922B (zh) * 2022-08-01 2024-01-09 合肥工业大学 一种垃圾焚烧飞灰改性处理方法及其在二氧化碳高温吸附中的应用

Family Cites Families (7)

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Publication number Priority date Publication date Assignee Title
US4748010A (en) * 1985-03-11 1988-05-31 Chemstar, Inc. Energy conserving limestone calcining system
NL9201179A (nl) * 1992-07-02 1994-02-01 Tno Werkwijze voor het regeneratief verwijderen van kooldioxide uit gasstromen.
US6755892B2 (en) * 2000-08-17 2004-06-29 Hamilton Sundstrand Carbon dioxide scrubber for fuel and gas emissions
US20030113239A1 (en) * 2001-08-01 2003-06-19 Pahlman John E. Systems and processes for removal of pollutants from a gas stream
ES2192994B1 (es) * 2002-03-22 2005-02-16 Consejo Superior Investig. Cientificas Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion.
US6942719B2 (en) * 2003-06-30 2005-09-13 The Boeing Company Methods and systems for pressure swing regeneration for hydrogen generation
CA2543984C (fr) * 2003-11-14 2011-08-09 Her Majesty The Queen In Right Of Canada As Represented By The Ministeof Natural Resources Reactivation de sorbants a base de chaux par choc de co2

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11718558B2 (en) 2019-08-13 2023-08-08 California Institute Of Technology Process to make calcium oxide or ordinary Portland cement from calcium bearing rocks and minerals

Also Published As

Publication number Publication date
EP1899049A4 (fr) 2010-12-08
WO2007002792A2 (fr) 2007-01-04
CA2613698A1 (fr) 2007-01-04
WO2007002792A3 (fr) 2007-03-29
EP1899049A2 (fr) 2008-03-19

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