CA2606307A1 - Precursor infiltration and coating method - Google Patents
Precursor infiltration and coating method Download PDFInfo
- Publication number
- CA2606307A1 CA2606307A1 CA002606307A CA2606307A CA2606307A1 CA 2606307 A1 CA2606307 A1 CA 2606307A1 CA 002606307 A CA002606307 A CA 002606307A CA 2606307 A CA2606307 A CA 2606307A CA 2606307 A1 CA2606307 A1 CA 2606307A1
- Authority
- CA
- Canada
- Prior art keywords
- solution
- porous structure
- ysz
- infiltration
- lsm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000001764 infiltration Methods 0.000 title claims abstract description 79
- 230000008595 infiltration Effects 0.000 title claims abstract description 79
- 239000002243 precursor Substances 0.000 title claims abstract description 45
- 238000000576 coating method Methods 0.000 title description 13
- 238000000034 method Methods 0.000 claims abstract description 67
- 150000003839 salts Chemical class 0.000 claims abstract description 39
- 239000004094 surface-active agent Substances 0.000 claims abstract description 35
- 229910052751 metal Inorganic materials 0.000 claims abstract description 33
- 239000002184 metal Substances 0.000 claims abstract description 33
- 239000002131 composite material Substances 0.000 claims abstract description 30
- 239000004020 conductor Substances 0.000 claims abstract description 28
- 239000011148 porous material Substances 0.000 claims abstract description 21
- 238000010438 heat treatment Methods 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000002923 metal particle Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 239000001301 oxygen Substances 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000011533 mixed conductor Substances 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 90
- 239000000243 solution Substances 0.000 description 89
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 45
- 239000003792 electrolyte Substances 0.000 description 41
- 239000010410 layer Substances 0.000 description 40
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Inorganic materials [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 34
- 239000013504 Triton X-100 Substances 0.000 description 29
- 229920004890 Triton X-100 Polymers 0.000 description 29
- 150000002823 nitrates Chemical class 0.000 description 29
- 239000000203 mixture Substances 0.000 description 26
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 24
- 239000000463 material Substances 0.000 description 22
- 239000000725 suspension Substances 0.000 description 22
- 235000021323 fish oil Nutrition 0.000 description 20
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 18
- 238000001816 cooling Methods 0.000 description 17
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 16
- 239000007787 solid Substances 0.000 description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
- 239000000446 fuel Substances 0.000 description 15
- 229910002804 graphite Inorganic materials 0.000 description 15
- 239000010439 graphite Substances 0.000 description 15
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 15
- 239000012528 membrane Substances 0.000 description 14
- 239000011230 binding agent Substances 0.000 description 13
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 13
- 238000012545 processing Methods 0.000 description 13
- 238000003801 milling Methods 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 238000003556 assay Methods 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 10
- HBTFASPVVFSRRI-UHFFFAOYSA-N manganese(2+);dinitrate;hydrate Chemical compound O.[Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O HBTFASPVVFSRRI-UHFFFAOYSA-N 0.000 description 10
- 239000012071 phase Substances 0.000 description 9
- 241000273930 Brevoortia tyrannus Species 0.000 description 8
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 8
- 238000010304 firing Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 229910052697 platinum Inorganic materials 0.000 description 8
- 239000000443 aerosol Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 6
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium nitrate Inorganic materials [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(II) nitrate Inorganic materials [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- IBMCQJYLPXUOKM-UHFFFAOYSA-N 1,2,2,6,6-pentamethyl-3h-pyridine Chemical compound CN1C(C)(C)CC=CC1(C)C IBMCQJYLPXUOKM-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 238000001453 impedance spectrum Methods 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(II) nitrate Inorganic materials [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- 229920006002 poly(vinyl butyral-co-vinyl alcohol-co-vinyl acetate) Polymers 0.000 description 5
- 238000003825 pressing Methods 0.000 description 5
- 229910002543 FeCrAlY Inorganic materials 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012018 catalyst precursor Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000010344 co-firing Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000002939 deleterious effect Effects 0.000 description 3
- 239000010411 electrocatalyst Substances 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 239000002001 electrolyte material Substances 0.000 description 3
- LDWZIXQSZWFRGT-UHFFFAOYSA-N gadolinium(3+);trinitrate;hydrate Chemical compound O.[Gd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O LDWZIXQSZWFRGT-UHFFFAOYSA-N 0.000 description 3
- MWFSXYMZCVAQCC-UHFFFAOYSA-N gadolinium(III) nitrate Inorganic materials [Gd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O MWFSXYMZCVAQCC-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- SZQUEWJRBJDHSM-UHFFFAOYSA-N iron(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O SZQUEWJRBJDHSM-UHFFFAOYSA-N 0.000 description 3
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(III) nitrate Inorganic materials [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 3
- -1 oxygen ions Chemical class 0.000 description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 229910017372 Fe3Al Inorganic materials 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 229910021320 cobalt-lanthanum-strontium oxide Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910002119 nickel–yttria stabilized zirconia Inorganic materials 0.000 description 2
- 238000010943 off-gassing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 2
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JYCQQPHGFMYQCF-UHFFFAOYSA-N 4-tert-Octylphenol monoethoxylate Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCO)C=C1 JYCQQPHGFMYQCF-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- UOACKFBJUYNSLK-XRKIENNPSA-N Estradiol Cypionate Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H](C4=CC=C(O)C=C4CC3)CC[C@@]21C)C(=O)CCC1CCCC1 UOACKFBJUYNSLK-XRKIENNPSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910015372 FeAl Inorganic materials 0.000 description 1
- 102000020897 Formins Human genes 0.000 description 1
- 108091022623 Formins Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910003168 MnCo2O4 Inorganic materials 0.000 description 1
- 229910001005 Ni3Al Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- GGGMJWBVJUTTLO-UHFFFAOYSA-N [Co]=O.[Sr].[La] Chemical compound [Co]=O.[Sr].[La] GGGMJWBVJUTTLO-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000011195 cermet Substances 0.000 description 1
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium nitrate Inorganic materials [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 1
- GVHCUJZTWMCYJM-UHFFFAOYSA-N chromium(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GVHCUJZTWMCYJM-UHFFFAOYSA-N 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000002003 electrode paste Substances 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 150000004687 hexahydrates Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Inorganic materials [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- OQUOOEBLAKQCOP-UHFFFAOYSA-N nitric acid;hexahydrate Chemical compound O.O.O.O.O.O.O[N+]([O-])=O OQUOOEBLAKQCOP-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920002113 octoxynol Polymers 0.000 description 1
- AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- HDCOFJGRHQAIPE-UHFFFAOYSA-N samarium(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Sm+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HDCOFJGRHQAIPE-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Ceramic Engineering (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US67413005P | 2005-04-21 | 2005-04-21 | |
US60/674,130 | 2005-04-21 | ||
PCT/US2006/015196 WO2006116153A2 (en) | 2005-04-21 | 2006-04-21 | Precursor infiltration and coating method |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2606307A1 true CA2606307A1 (en) | 2006-11-02 |
Family
ID=37215316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002606307A Abandoned CA2606307A1 (en) | 2005-04-21 | 2006-04-21 | Precursor infiltration and coating method |
Country Status (11)
Country | Link |
---|---|
US (1) | US20080193803A1 (no) |
EP (1) | EP1875534A4 (no) |
JP (1) | JP2008538543A (no) |
KR (1) | KR20080003874A (no) |
CN (1) | CN101223656A (no) |
AU (1) | AU2006239925B2 (no) |
BR (1) | BRPI0608374A2 (no) |
CA (1) | CA2606307A1 (no) |
NO (1) | NO20075566L (no) |
RU (1) | RU2403655C9 (no) |
WO (1) | WO2006116153A2 (no) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2005327925B2 (en) | 2004-11-30 | 2011-01-27 | The Regents Of The University Of California | Joining of dissimilar materials |
WO2006127045A2 (en) | 2004-11-30 | 2006-11-30 | The Regents Of The University Of California | Sealed joint structure for electrochemical device |
AU2006346775A1 (en) | 2006-07-28 | 2008-02-07 | The Regents Of The University Of California | Joined concentric tubes |
JP5112711B2 (ja) * | 2007-02-09 | 2013-01-09 | 日本電信電話株式会社 | 固体酸化物形燃料電池用電極の製造方法及び固体酸化物形燃料電池 |
US8367273B2 (en) * | 2007-05-31 | 2013-02-05 | Elcogen As | Method for preparation of the solid oxide fuel cell single cell |
EP2254180A1 (en) | 2007-08-31 | 2010-11-24 | Technical University of Denmark | Ceria and strontium titanate based electrodes |
ES2367885T3 (es) | 2007-08-31 | 2011-11-10 | Technical University Of Denmark | Electrodos que se basan en óxido de cerio y un acero inoxidable. |
EP2031679A3 (en) * | 2007-08-31 | 2009-05-27 | Technical University of Denmark | Composite electrodes |
WO2009064391A2 (en) * | 2007-11-13 | 2009-05-22 | Bloom Energy Corporation | Electrolyte supported cell designed for longer life and higher power |
US9246184B1 (en) | 2007-11-13 | 2016-01-26 | Bloom Energy Corporation | Electrolyte supported cell designed for longer life and higher power |
JP5370981B2 (ja) * | 2008-03-19 | 2013-12-18 | 日産自動車株式会社 | 多孔質膜積層体 |
JP5335068B2 (ja) | 2008-04-18 | 2013-11-06 | ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア | 電気化学装置構成及びその製法 |
EP2194597B1 (en) * | 2008-12-03 | 2014-03-05 | Technical University of Denmark | Solid oxide cell and solid oxide cell stack |
EP2244322A1 (en) * | 2009-04-24 | 2010-10-27 | Technical University of Denmark | Composite oxygen electrode and method for preparing same |
US8802316B1 (en) * | 2009-07-16 | 2014-08-12 | U.S. Department Of Energy | Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts |
US20110111309A1 (en) * | 2009-11-10 | 2011-05-12 | Point Source Power, Inc. | Fuel cell system |
US20110251053A1 (en) * | 2010-04-09 | 2011-10-13 | The Regents Of The University Of California | Solvent-based infiltration of porous structures |
DE102013200759A1 (de) * | 2013-01-18 | 2014-07-24 | Siemens Aktiengesellschaft | Wiederaufladbarer elektrischer Energiespeicher |
EP2814099A1 (en) * | 2013-06-12 | 2014-12-17 | Topsøe Fuel Cell A/S | Electrochemical cell |
DE102013214284A1 (de) * | 2013-07-22 | 2015-01-22 | Siemens Aktiengesellschaft | Speicherstruktur und Verfahren zur Herstellung |
DE102014019259B4 (de) * | 2014-12-19 | 2017-08-03 | Airbus Defence and Space GmbH | Kompositelektrolyt für eine Festoxidbrennstoffzelle, Abgassonde oder Hochtemperatur-Gassensor und Verfahren zur Herstellung eines Kompositelektrolyten |
WO2016154198A1 (en) | 2015-03-24 | 2016-09-29 | Bloom Energy Corporation | Perimeter electrolyte reinforcement layer composition for solid oxide fuel cell electrolytes |
WO2018017662A1 (en) * | 2016-07-20 | 2018-01-25 | The Trustees Of Boston University | Nanoparticle deposition in porous and on planar substrates |
US11283084B2 (en) * | 2017-05-03 | 2022-03-22 | The Regents Of The University Of California | Fabrication processes for solid state electrochemical devices |
CN109468661B (zh) * | 2018-12-18 | 2020-06-30 | 中南大学 | 一种固体氧化物电解池用复合氧电极及其制备方法 |
US11417891B2 (en) | 2019-08-23 | 2022-08-16 | Nissan North America, Inc. | Cathode including a tandem electrocatalyst and solid oxide fuel cell including the same |
CN110828669A (zh) * | 2019-11-15 | 2020-02-21 | 中南大学 | 一种低温介孔碳基钙钛矿太阳能电池及其制备方法 |
US20230092683A1 (en) * | 2021-09-10 | 2023-03-23 | Utility Global, Inc. | Method of making an electrode |
Family Cites Families (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4702971A (en) * | 1986-05-28 | 1987-10-27 | Westinghouse Electric Corp. | Sulfur tolerant composite cermet electrodes for solid oxide electrochemical cells |
US4767518A (en) * | 1986-06-11 | 1988-08-30 | Westinghouse Electric Corp. | Cermet electrode |
JPH0834311B2 (ja) * | 1987-06-10 | 1996-03-29 | 日本電装株式会社 | 半導体装置の製造方法 |
US4885078A (en) * | 1988-12-07 | 1989-12-05 | Westinghouse Electric Corp. | Devices capable of removing silicon and aluminum from gaseous atmospheres |
US5021304A (en) * | 1989-03-22 | 1991-06-04 | Westinghouse Electric Corp. | Modified cermet fuel electrodes for solid oxide electrochemical cells |
US4971830A (en) * | 1990-02-01 | 1990-11-20 | Westinghouse Electric Corp. | Method of electrode fabrication for solid oxide electrochemical cells |
US5366770A (en) * | 1990-04-17 | 1994-11-22 | Xingwu Wang | Aerosol-plasma deposition of films for electronic cells |
JPH05135787A (ja) * | 1991-03-28 | 1993-06-01 | Ngk Insulators Ltd | 固体電解質膜の製造方法及び固体電解質型燃料電池の製造方法 |
US5328799A (en) * | 1992-07-31 | 1994-07-12 | Polaroid Corporation | Thermographic and photothermographic imaging materials |
US5589285A (en) * | 1993-09-09 | 1996-12-31 | Technology Management, Inc. | Electrochemical apparatus and process |
JPH08236123A (ja) * | 1994-12-28 | 1996-09-13 | Tokyo Gas Co Ltd | 燃料電池用電極及びその製造方法 |
US5543239A (en) * | 1995-04-19 | 1996-08-06 | Electric Power Research Institute | Electrode design for solid state devices, fuel cells and sensors |
US6117582A (en) * | 1995-11-16 | 2000-09-12 | The Dow Chemical Company | Cathode composition for solid oxide fuel cell |
US5670270A (en) * | 1995-11-16 | 1997-09-23 | The Dow Chemical Company | Electrode structure for solid state electrochemical devices |
US6548203B2 (en) * | 1995-11-16 | 2003-04-15 | The Dow Chemical Company | Cathode composition for solid oxide fuel cell |
US5993986A (en) * | 1995-11-16 | 1999-11-30 | The Dow Chemical Company | Solide oxide fuel cell stack with composite electrodes and method for making |
US5753385A (en) * | 1995-12-12 | 1998-05-19 | Regents Of The University Of California | Hybrid deposition of thin film solid oxide fuel cells and electrolyzers |
ATE191815T1 (de) * | 1996-02-02 | 2000-04-15 | Sulzer Hexis Ag | Hochtemperatur-brennstoffzelle mit einem dünnfilm-elektrolyten |
TW404079B (en) * | 1996-08-27 | 2000-09-01 | Univ New York State Res Found | Gas diffusion electrodes based on polyethersulfone carbon blends |
US5993989A (en) * | 1997-04-07 | 1999-11-30 | Siemens Westinghouse Power Corporation | Interfacial material for solid oxide fuel cell |
AU2994397A (en) * | 1997-04-30 | 1998-11-24 | Dow Chemical Company, The | Electrode structure for solid state electrochemical devices |
US6165553A (en) * | 1998-08-26 | 2000-12-26 | Praxair Technology, Inc. | Method of fabricating ceramic membranes |
US6358567B2 (en) * | 1998-12-23 | 2002-03-19 | The Regents Of The University Of California | Colloidal spray method for low cost thin coating deposition |
JP3230156B2 (ja) * | 1999-01-06 | 2001-11-19 | 三菱マテリアル株式会社 | 固体酸化物型燃料電池の電極とその製造方法 |
US6589680B1 (en) * | 1999-03-03 | 2003-07-08 | The Trustees Of The University Of Pennsylvania | Method for solid oxide fuel cell anode preparation |
US6368383B1 (en) * | 1999-06-08 | 2002-04-09 | Praxair Technology, Inc. | Method of separating oxygen with the use of composite ceramic membranes |
US6682842B1 (en) * | 1999-07-31 | 2004-01-27 | The Regents Of The University Of California | Composite electrode/electrolyte structure |
US7553573B2 (en) * | 1999-07-31 | 2009-06-30 | The Regents Of The University Of California | Solid state electrochemical composite |
US6379626B1 (en) * | 1999-09-03 | 2002-04-30 | Array Biopharma | Reactor plate clamping system |
CA2391894C (en) * | 1999-12-06 | 2007-11-06 | Hitachi Chemical Company, Ltd. | Fuel cell, fuel cell separator, and method of manufacture thereof |
DK174654B1 (da) * | 2000-02-02 | 2003-08-11 | Topsoe Haldor As | Faststofoxid brændselscelle og anvendelser heraf |
US6767662B2 (en) * | 2000-10-10 | 2004-07-27 | The Regents Of The University Of California | Electrochemical device and process of making |
DE60141041D1 (de) * | 2000-11-09 | 2010-02-25 | Univ Pennsylvania | Verwendung von schwefelhaltigen brennstoffen für direktoxidationsbrennstoffzellen |
KR100424194B1 (ko) * | 2001-11-01 | 2004-03-24 | 한국과학기술연구원 | 다공성 이온 전도성 세리아 막 코팅으로 삼상 계면이 확장된 미세구조의 전극부 및 그의 제조방법 |
JP2003257437A (ja) * | 2002-03-04 | 2003-09-12 | Mitsubishi Materials Corp | 固体酸化物形燃料電池の電極および固体酸化物形燃料電池 |
CN1672283A (zh) * | 2002-06-06 | 2005-09-21 | 宾夕法尼亚州大学理事会 | 陶瓷阳极及其制造方法 |
US7090938B2 (en) * | 2003-01-15 | 2006-08-15 | Curators Of The University Of Missouri | Method of preparing a solid oxide fuel cell |
US6958196B2 (en) * | 2003-02-21 | 2005-10-25 | Trustees Of The University Of Pennsylvania | Porous electrode, solid oxide fuel cell, and method of producing the same |
US7476460B2 (en) * | 2003-10-29 | 2009-01-13 | Hewlett-Packard Development Company, L.P. | Thin metal oxide film and method of making the same |
US7476461B2 (en) * | 2003-12-02 | 2009-01-13 | Nanodynamics Energy, Inc. | Methods for the electrochemical optimization of solid oxide fuel cell electrodes |
US20050238796A1 (en) * | 2004-04-22 | 2005-10-27 | Armstong Tad J | Method of fabricating composite cathodes for solid oxide fuel cells by infiltration |
JP4984401B2 (ja) * | 2005-02-25 | 2012-07-25 | 大日本印刷株式会社 | 固体酸化物形燃料電池用電極層の製造方法 |
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- 2006-04-21 BR BRPI0608374-9A patent/BRPI0608374A2/pt not_active IP Right Cessation
- 2006-04-21 EP EP06751048A patent/EP1875534A4/en not_active Withdrawn
- 2006-04-21 CA CA002606307A patent/CA2606307A1/en not_active Abandoned
- 2006-04-21 CN CNA2006800221489A patent/CN101223656A/zh active Pending
- 2006-04-21 RU RU2007142380/09A patent/RU2403655C9/ru not_active IP Right Cessation
- 2006-04-21 US US11/911,959 patent/US20080193803A1/en not_active Abandoned
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WO2006116153A2 (en) | 2006-11-02 |
RU2403655C9 (ru) | 2011-04-20 |
WO2006116153A3 (en) | 2007-09-20 |
EP1875534A2 (en) | 2008-01-09 |
NO20075566L (no) | 2008-01-15 |
AU2006239925B2 (en) | 2010-07-22 |
US20080193803A1 (en) | 2008-08-14 |
EP1875534A4 (en) | 2011-09-14 |
RU2403655C2 (ru) | 2010-11-10 |
CN101223656A (zh) | 2008-07-16 |
RU2007142380A (ru) | 2009-05-27 |
JP2008538543A (ja) | 2008-10-30 |
BRPI0608374A2 (pt) | 2010-11-16 |
AU2006239925A1 (en) | 2006-11-02 |
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