CA2565090A1 - Method for forming a hardened surface on a substrate - Google Patents
Method for forming a hardened surface on a substrate Download PDFInfo
- Publication number
- CA2565090A1 CA2565090A1 CA002565090A CA2565090A CA2565090A1 CA 2565090 A1 CA2565090 A1 CA 2565090A1 CA 002565090 A CA002565090 A CA 002565090A CA 2565090 A CA2565090 A CA 2565090A CA 2565090 A1 CA2565090 A1 CA 2565090A1
- Authority
- CA
- Canada
- Prior art keywords
- metallic glass
- substrate
- forming
- metallic
- glass coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
- C22C45/02—Amorphous alloys with iron as the major constituent
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/003—Making ferrous alloys making amorphous alloys
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/02—Coating starting from inorganic powder by application of pressure only
- C23C24/04—Impact or kinetic deposition of particles
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/067—Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plasma & Fusion (AREA)
- Physics & Mathematics (AREA)
- Coating By Spraying Or Casting (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Physical Vapour Deposition (AREA)
Abstract
The invention encompasses a method of forming a metallic coating. A metallic glass coating is formed over a metallic substrate. After formation of the coating, at least a portion of the metallic glass can be converted into a crystalline material having a nanocrystalline grain size. The steps of this process are shown diagrammatically in Figure 1. The invention also encompasses metallic coatings comprising metallic glass. Additionally, the invention encompasses metallic coatings comprising crystalline metallic materials, with at least some of the crystalline metallic material having a nanocrystalline grain size.
Claims (13)
1. ~A method of forming a hardened surface on a substrate, comprising:
providing a substrate; and forming a molten alloy and cooling said alloy to form a metallic glass coating on the substrate, the forming comprising forming a successive buildup of metallic glass layers, the metallic glass coating having a hardness of at least about 9.2 GPa, and comprising an alloy containing one or more elements selected from the group comprising iron and chromium, one or more elements selected from the group containing boron and phosphorous, and wherein said alloy contains one or both of molybdenum and tungsten.
providing a substrate; and forming a molten alloy and cooling said alloy to form a metallic glass coating on the substrate, the forming comprising forming a successive buildup of metallic glass layers, the metallic glass coating having a hardness of at least about 9.2 GPa, and comprising an alloy containing one or more elements selected from the group comprising iron and chromium, one or more elements selected from the group containing boron and phosphorous, and wherein said alloy contains one or both of molybdenum and tungsten.
2. ~A method of forming a hardened surface on a substrate, comprising:
providing a substrate;
forming a molten alloy and cooling said alloy to form a metallic glass coating on the substrate and having a first hardness of at least about 9.2 GPa, the metallic glass comprising one or more elements selected from the group comprising iron and chromium, one or more elements selected from the group containing boron and phosphorous; and converting at least a portion of the metallic glass coating to a crystalline material having a nanocrystalline grain size and a second hardness of at least about 9.2 GPa
providing a substrate;
forming a molten alloy and cooling said alloy to form a metallic glass coating on the substrate and having a first hardness of at least about 9.2 GPa, the metallic glass comprising one or more elements selected from the group comprising iron and chromium, one or more elements selected from the group containing boron and phosphorous; and converting at least a portion of the metallic glass coating to a crystalline material having a nanocrystalline grain size and a second hardness of at least about 9.2 GPa
3. ~The method of claim 1 wherein the substrate is a metallic material.
4. ~The method of claim 1 wherein the substrate is a ceramic material.
5. ~The method of claim 2 wherein the first hardness is at least about 10.0 GPa.
6. ~The method of claim 1 wherein the metallic glass coating is applied to the substrate as a plasma spray.
7. ~The method of claim 1 wherein the forming the metallic glass coating comprises an application of an atomized powder of a metallic glass material over the substrate.
8. ~The method of claim 2 wherein the forming a metallic glass coating comprises forming a successive buildup of continuous layers.
9. ~The method of claim 2 wherein the converting comprises heating the metallic glass to above a crystallization temperature of the metallic glass.
10. ~The method of claim 10 wherein the heating comprises heating to a temperature of at least about 600°C and below a melting temperature of the metallic glass.
11. ~The method of claim 2 wherein the second hardness is at least about 10.0 GPa.
12. ~The method of claim 1 wherein the metallic glass coating is applied to the substrate by a plasma spray system.
13. ~The method of claim 1 wherein the forming the metallic glass coating comprises an application of an atomized powder of a metallic glass material over the substrate.
31~
31~
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/841,873 | 2004-05-06 | ||
| US10/841,873 US7323071B1 (en) | 2000-11-09 | 2004-05-06 | Method for forming a hardened surface on a substrate |
| PCT/US2005/015365 WO2005116286A2 (en) | 2004-05-06 | 2005-05-02 | Method for forming a hardened surface on a substrate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2565090A1 true CA2565090A1 (en) | 2005-12-08 |
| CA2565090C CA2565090C (en) | 2012-01-24 |
Family
ID=35451487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2565090A Expired - Fee Related CA2565090C (en) | 2004-05-06 | 2005-05-02 | Method for forming a hardened surface on a substrate |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP1749113A4 (en) |
| JP (1) | JP4619405B2 (en) |
| KR (1) | KR100908937B1 (en) |
| CN (1) | CN1997765B (en) |
| AU (1) | AU2005248324B2 (en) |
| CA (1) | CA2565090C (en) |
| WO (1) | WO2005116286A2 (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007084901A (en) * | 2005-09-26 | 2007-04-05 | Akihisa Inoue | Metal glass thin film laminated body |
| JP4895561B2 (en) * | 2005-09-26 | 2012-03-14 | 国立大学法人東北大学 | Metal glass spray coating and method for forming the same |
| RU2533982C2 (en) * | 2009-04-30 | 2014-11-27 | Шеврон Ю.Эс.Эй.Инк. | Processing of amorphous coating surface |
| JP5638809B2 (en) * | 2010-01-12 | 2014-12-10 | 株式会社中山アモルファス | Metal material with amorphous film and method for forming amorphous film |
| ES2686928T3 (en) * | 2012-05-16 | 2018-10-22 | Max-Planck-Institut Für Eisenforschung GmbH | Process for the production of a mesoporous carbide |
| US10392685B2 (en) | 2013-10-31 | 2019-08-27 | The Regents Of The University Of Michigan | Composite metal alloy material |
| US20150231763A1 (en) * | 2014-02-14 | 2015-08-20 | The Nanosteel Company, Inc. | Shot Material and Shot Peening Method |
| CA2949389C (en) * | 2014-05-16 | 2023-06-20 | The Nanosteel Company, Inc. | Layered construction of metallic materials |
| TWI532855B (en) | 2015-12-03 | 2016-05-11 | 財團法人工業技術研究院 | Iron-based alloy coating and method for manufacturing the same |
| CN105547051A (en) * | 2015-12-12 | 2016-05-04 | 西安交通大学 | Metal glass enhanced gradient-density armored protection device |
| NL1041641B1 (en) * | 2015-12-22 | 2017-07-03 | Bosch Gmbh Robert | Transverse element provided with a nanocrystalline surface layer for a drive belt for a continuously variable transmission and method for producing it. |
| CN106893963B (en) * | 2017-01-20 | 2019-02-15 | 中国人民解放军装甲兵工程学院 | A kind of powder cored filament material being used to prepare Al-Fe-Nb-Cr amorphous coating |
| CN110387542B (en) * | 2019-08-23 | 2021-04-20 | 兰州城市学院 | High-wear-resistance metal ceramic coating preparation equipment |
| CN113174547B (en) * | 2021-04-30 | 2022-11-04 | 郑州大学 | Iron-based amorphous alloy powder, preparation method thereof and application thereof in laser cladding |
| CN113652625B (en) * | 2021-08-17 | 2023-05-05 | 上海浦海求实电力新技术股份有限公司 | Electric power grid inner surface spraying material for diamond-type power distribution network and preparation method thereof |
| CN114854959A (en) * | 2022-05-11 | 2022-08-05 | 广西玉柴机器配件制造有限公司 | Ultrahigh-strength high-elongation thick nodular iron casting and heat treatment method thereof |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4210443A (en) * | 1978-02-27 | 1980-07-01 | Allied Chemical Corporation | Iron group transition metal-refractory metal-boron glassy alloys |
| US4133679A (en) * | 1978-01-03 | 1979-01-09 | Allied Chemical Corporation | Iron-refractory metal-boron glassy alloys |
| DE2861328D1 (en) * | 1978-01-03 | 1982-01-14 | Allied Corp | Iron group transition metal-refractory metal-boron glassy alloys |
| US4606977A (en) * | 1983-02-07 | 1986-08-19 | Allied Corporation | Amorphous metal hardfacing coatings |
| JPH0610105A (en) * | 1986-12-15 | 1994-01-18 | Hitachi Metals Ltd | Fe base soft magnetic alloy |
| JPH0641700A (en) * | 1986-12-15 | 1994-02-15 | Hitachi Metals Ltd | Thin magnetic film |
| US4881989A (en) * | 1986-12-15 | 1989-11-21 | Hitachi Metals, Ltd. | Fe-base soft magnetic alloy and method of producing same |
| JPS6479342A (en) * | 1986-12-15 | 1989-03-24 | Hitachi Metals Ltd | Fe-base soft magnetic alloy and its production |
| JPH0711396A (en) * | 1986-12-15 | 1995-01-13 | Hitachi Metals Ltd | Fe base soft magnetic alloy |
| JPH0610104A (en) * | 1986-12-15 | 1994-01-18 | Hitachi Metals Ltd | Fe base soft magnetic alloy |
| JPS63241135A (en) * | 1987-03-27 | 1988-10-06 | Hitachi Metals Ltd | High-hardness alloy and its production |
| US5032469A (en) * | 1988-09-06 | 1991-07-16 | Battelle Memorial Institute | Metal alloy coatings and methods for applying |
| CN1030970C (en) * | 1993-05-31 | 1996-02-14 | 冶金工业部钢铁研究总院 | Method for large-area built-up welding on metal surface |
| JPH07256363A (en) * | 1994-03-16 | 1995-10-09 | Kawasaki Heavy Ind Ltd | Metal mold for molding sheet material and method for molding oxide dipsersion strenghened alloy sheet material by using this metal mold |
| US6258185B1 (en) * | 1999-05-25 | 2001-07-10 | Bechtel Bwxt Idaho, Llc | Methods of forming steel |
| JP4093688B2 (en) * | 1999-10-07 | 2008-06-04 | Ｊｆｅスチール株式会社 | Continuous casting mold |
| JP3805601B2 (en) * | 2000-04-20 | 2006-08-02 | 独立行政法人科学技術振興機構 | High corrosion resistance and high strength Fe-Cr based bulk amorphous alloy |
| US6689234B2 (en) * | 2000-11-09 | 2004-02-10 | Bechtel Bwxt Idaho, Llc | Method of producing metallic materials |
| CA2526990C (en) * | 2003-05-23 | 2014-01-14 | The Nanosteel Company | Layered metallic material formed from iron based glass alloys |
-
2005
- 2005-05-02 KR KR1020097001052A patent/KR100908937B1/en active IP Right Grant
- 2005-05-02 CA CA2565090A patent/CA2565090C/en not_active Expired - Fee Related
- 2005-05-02 JP JP2007511510A patent/JP4619405B2/en not_active Expired - Fee Related
- 2005-05-02 WO PCT/US2005/015365 patent/WO2005116286A2/en active Application Filing
- 2005-05-02 EP EP05780050A patent/EP1749113A4/en not_active Ceased
- 2005-05-02 AU AU2005248324A patent/AU2005248324B2/en not_active Ceased
- 2005-05-02 CN CN2005800225593A patent/CN1997765B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2565090C (en) | 2012-01-24 |
| WO2005116286A3 (en) | 2006-09-08 |
| AU2005248324A1 (en) | 2005-12-08 |
| JP2007536430A (en) | 2007-12-13 |
| CN1997765A (en) | 2007-07-11 |
| WO2005116286A2 (en) | 2005-12-08 |
| EP1749113A4 (en) | 2009-04-15 |
| EP1749113A2 (en) | 2007-02-07 |
| KR20090014422A (en) | 2009-02-10 |
| KR100908937B1 (en) | 2009-07-22 |
| JP4619405B2 (en) | 2011-01-26 |
| CN1997765B (en) | 2012-05-30 |
| AU2005248324B2 (en) | 2008-08-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2565090A1 (en) | Method for forming a hardened surface on a substrate | |
| CN106834974B (en) | Iron-based alloy coating and method for forming the same | |
| CN100503843C (en) | Hard metallic materials, hard metallic coatings, methods of processing metallic materials and methods of producing metallic coatings | |
| KR101463089B1 (en) | A thermal spraying material, a thermally sprayed coating, a thermal spraying method and also a thermally coated workpiece | |
| Marple et al. | Thermal spraying of nanostructured cermet coatings | |
| WO2013042635A1 (en) | Laminate and laminate manufacturing method | |
| CA2556786C (en) | Process and apparatus for the manufacture of sputtering targets | |
| US6984255B2 (en) | Thermal spraying powder and method of forming a thermal sprayed coating using the same | |
| WO2006085995A3 (en) | Method of producing metal article having internal passage coated with a ceramic coating | |
| SG123725A1 (en) | Laser enhancements of cold sprayed deposits | |
| MX2007003631A (en) | Bearing materials and method for the production thereof. | |
| US5230755A (en) | Protective layer for a metal substrate and a method of producing same | |
| US4562090A (en) | Method for improving the density, strength and bonding of coatings | |
| CN104846307B (en) | Refractory ceramics coating and its spraying method for Metal Substrate thermal spraying | |
| WO2009045324A3 (en) | Method for coating fuel system components | |
| CN101239844A (en) | Composite carbon-resisting coat and method for preparing the same on substrate | |
| CN105603374B (en) | One kind prepares Si on polysilicon ingot crucible3N4The method of film | |
| KR20170089855A (en) | Powder for thermal spray, thermal spray coating film, coating film and roll in molten metal bath | |
| CN111424229B (en) | Preparation method of composite coating resistant to liquid metal alloy etching | |
| KR100489304B1 (en) | Resistance-heated boat and manufacturing method thereof | |
| CN105164303B (en) | The method of deposit attack protective coating | |
| KR101922805B1 (en) | Method of plasma spray coated layer for improving the bond strength between the coating layer and substrate | |
| JP5400194B2 (en) | Molten zinc corrosion resistant metallic glass | |
| CN103849870A (en) | Method of preparing titanium nitride/chromium nitride/aluminum nitride coating based on microwave technology | |
| KR101282766B1 (en) | Method of recycling crucible for melting and crucible manufactured by the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20210503 |