CA2556760A1 - Enhanced efficacy aluminum-zirconium antiperspirants - Google Patents
Enhanced efficacy aluminum-zirconium antiperspirants Download PDFInfo
- Publication number
- CA2556760A1 CA2556760A1 CA002556760A CA2556760A CA2556760A1 CA 2556760 A1 CA2556760 A1 CA 2556760A1 CA 002556760 A CA002556760 A CA 002556760A CA 2556760 A CA2556760 A CA 2556760A CA 2556760 A1 CA2556760 A1 CA 2556760A1
- Authority
- CA
- Canada
- Prior art keywords
- aluminum
- zirconium
- alcl3
- species
- activated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003213 antiperspirant Substances 0.000 title abstract description 30
- 230000001166 anti-perspirative effect Effects 0.000 title abstract description 29
- ZGUQGPFMMTZGBQ-UHFFFAOYSA-N [Al].[Al].[Zr] Chemical compound [Al].[Al].[Zr] ZGUQGPFMMTZGBQ-UHFFFAOYSA-N 0.000 title abstract description 18
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 52
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 44
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims abstract description 41
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 41
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 36
- DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical compound [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004471 Glycine Substances 0.000 claims abstract description 21
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 16
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract description 15
- -1 activated aluminum chlorohydrate Chemical class 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910002651 NO3 Inorganic materials 0.000 claims description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 5
- 150000001413 amino acids Chemical class 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 2
- 238000004128 high performance liquid chromatography Methods 0.000 claims 2
- 238000004910 27Al NMR spectroscopy Methods 0.000 claims 1
- 229910018580 Al—Zr Inorganic materials 0.000 claims 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 6
- LVYZJEPLMYTTGH-UHFFFAOYSA-H dialuminum chloride pentahydroxide dihydrate Chemical compound [Cl-].[Al+3].[OH-].[OH-].[Al+3].[OH-].[OH-].[OH-].O.O LVYZJEPLMYTTGH-UHFFFAOYSA-H 0.000 abstract description 4
- 239000002085 irritant Substances 0.000 abstract description 2
- 231100000021 irritant Toxicity 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 41
- 239000000178 monomer Substances 0.000 description 16
- 150000003839 salts Chemical class 0.000 description 14
- 238000005481 NMR spectroscopy Methods 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 230000032683 aging Effects 0.000 description 7
- 239000000539 dimer Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 3
- 230000007717 exclusion Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- ADGFKRMKSIAMAI-UHFFFAOYSA-L oxygen(2-);zirconium(4+);chloride;hydroxide Chemical compound [OH-].[O-2].[Cl-].[Zr+4] ADGFKRMKSIAMAI-UHFFFAOYSA-L 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 206010041235 Snoring Diseases 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229940030980 inova Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004890 malting Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/10—Pillows
- A47G9/1081—Pillows comprising a neck support, e.g. a neck roll
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/10—Pillows
- A47G9/1027—Details of inflatable pillows
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F23/00—Advertising on or in specific articles, e.g. ashtrays, letter-boxes
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G2009/003—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows with inflatable members
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/58—Metal complex; Coordination compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Otolaryngology (AREA)
- Pulmonology (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Theoretical Computer Science (AREA)
- Engineering & Computer Science (AREA)
- Cosmetics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/756,620 | 2004-02-17 | ||
| US10/756,620 US7060258B2 (en) | 2004-02-17 | 2004-02-17 | Method of making aluminum-zirconium antiperspirant of enhanced efficacy |
| PCT/US2005/001711 WO2005081751A2 (en) | 2004-02-17 | 2005-01-19 | Enhanced efficacy aluminum-zirconium antiperspirants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2556760A1 true CA2556760A1 (en) | 2005-09-09 |
Family
ID=34837754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002556760A Abandoned CA2556760A1 (en) | 2004-02-17 | 2005-01-19 | Enhanced efficacy aluminum-zirconium antiperspirants |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7060258B2 (enExample) |
| EP (1) | EP1715831A2 (enExample) |
| JP (1) | JP2007522260A (enExample) |
| KR (1) | KR20060042042A (enExample) |
| CN (1) | CN1929808A (enExample) |
| AR (1) | AR051532A1 (enExample) |
| AU (1) | AU2005215984A1 (enExample) |
| CA (1) | CA2556760A1 (enExample) |
| MX (1) | MXPA06009406A (enExample) |
| PE (1) | PE20050895A1 (enExample) |
| RU (1) | RU2006129895A (enExample) |
| WO (1) | WO2005081751A2 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040091436A1 (en) * | 2002-11-12 | 2004-05-13 | Zijun Li | Antiperspirant compositions of enhanced efficacy containing strontium |
| US7014843B2 (en) * | 2004-03-24 | 2006-03-21 | Reheis, Inc. | Enhanced efficacy basic aluminum halides/metal cation salt, antiperspirants actives and compositions containing such materials and methods for making |
| ES2418131T3 (es) | 2007-09-21 | 2013-08-12 | Colgate-Palmolive Company | Sales de oxo-zirconio hexámero-octaaminoácido antitranspirantes |
| MX344223B (es) | 2009-12-23 | 2016-12-07 | Colgate-Palmolive Company * | Metodo para elaborar una composicion antitranspirante anhidra liquida. |
| US9572758B2 (en) | 2015-06-30 | 2017-02-21 | Gulbrandsen Technologies, Inc. | Method of making high performance activated aluminum sesquichlorohydrate powders |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4359456A (en) * | 1976-01-14 | 1982-11-16 | Lever Brothers Company | Antiperspirant activity of basic aluminum compounds |
| EP0006739B1 (en) * | 1978-06-23 | 1982-10-13 | Unilever Plc | Antiperspirant composition and methods for its preparation and use |
| US4775528A (en) | 1983-08-16 | 1988-10-04 | The Gillette Company | Antiperspirant composition |
| US4871525A (en) | 1986-10-24 | 1989-10-03 | Westwood Chemical Corporation | Antiperspirant composition and method of preparation |
| CA2090861C (en) * | 1990-09-07 | 2002-06-25 | Jawahar C. Parekh | Basic aluminum and aluminum/zirconium antiperspirants and method of making the same |
| FR2712286B1 (fr) | 1993-11-12 | 1995-12-22 | Oreal | Nouveaux N-mercaptoalkyl alcanediamines et leur utilisation. |
| US6375937B1 (en) | 2000-10-20 | 2002-04-23 | Colgate-Palmolive Company | Antiperspirant salts for enhanced cosmetic products |
| US6436381B1 (en) | 2000-10-25 | 2002-08-20 | The Gillette Company | Aluminum-zirconium antiperspirant salts with high peak 5 al content |
-
2004
- 2004-02-17 US US10/756,620 patent/US7060258B2/en not_active Expired - Fee Related
-
2005
- 2005-01-05 PE PE2005000039A patent/PE20050895A1/es not_active Application Discontinuation
- 2005-01-07 AR ARP050100048A patent/AR051532A1/es not_active Application Discontinuation
- 2005-01-19 EP EP05711666A patent/EP1715831A2/en not_active Withdrawn
- 2005-01-19 JP JP2006554097A patent/JP2007522260A/ja active Pending
- 2005-01-19 WO PCT/US2005/001711 patent/WO2005081751A2/en not_active Ceased
- 2005-01-19 CN CNA200580008227XA patent/CN1929808A/zh active Pending
- 2005-01-19 MX MXPA06009406A patent/MXPA06009406A/es unknown
- 2005-01-19 CA CA002556760A patent/CA2556760A1/en not_active Abandoned
- 2005-01-19 RU RU2006129895/15A patent/RU2006129895A/ru not_active Application Discontinuation
- 2005-01-19 AU AU2005215984A patent/AU2005215984A1/en not_active Abandoned
- 2005-02-17 KR KR1020050013109A patent/KR20060042042A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| KR20060042042A (ko) | 2006-05-12 |
| JP2007522260A (ja) | 2007-08-09 |
| WO2005081751A3 (en) | 2006-06-01 |
| PE20050895A1 (es) | 2006-01-02 |
| WO2005081751A2 (en) | 2005-09-09 |
| EP1715831A2 (en) | 2006-11-02 |
| US20050180934A1 (en) | 2005-08-18 |
| CN1929808A (zh) | 2007-03-14 |
| AU2005215984A1 (en) | 2005-09-09 |
| MXPA06009406A (es) | 2007-04-10 |
| US7060258B2 (en) | 2006-06-13 |
| AR051532A1 (es) | 2007-01-24 |
| RU2006129895A (ru) | 2008-02-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |