CA2534949C - Stabilization of fluorinated silicone fuser release agents using mercapto functional silicones - Google Patents
Stabilization of fluorinated silicone fuser release agents using mercapto functional silicones Download PDFInfo
- Publication number
- CA2534949C CA2534949C CA 2534949 CA2534949A CA2534949C CA 2534949 C CA2534949 C CA 2534949C CA 2534949 CA2534949 CA 2534949 CA 2534949 A CA2534949 A CA 2534949A CA 2534949 C CA2534949 C CA 2534949C
- Authority
- CA
- Canada
- Prior art keywords
- release agent
- group
- fuser member
- alkyl
- carbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 37
- 125000003396 thiol group Chemical class [H]S* 0.000 title claims abstract description 30
- 230000006641 stabilisation Effects 0.000 title description 4
- 238000011105 stabilization Methods 0.000 title description 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 97
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 44
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 37
- 125000003118 aryl group Chemical group 0.000 claims abstract description 37
- 239000000203 mixture Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 31
- 239000000758 substrate Substances 0.000 claims abstract description 30
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 125000003282 alkyl amino group Chemical group 0.000 claims abstract description 23
- 239000011248 coating agent Substances 0.000 claims abstract description 23
- 229920002313 fluoropolymer Polymers 0.000 claims abstract description 13
- 239000004811 fluoropolymer Substances 0.000 claims abstract description 13
- -1 siloxane units Chemical group 0.000 claims description 49
- 229920001973 fluoroelastomer Polymers 0.000 claims description 29
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 23
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 16
- 229920002379 silicone rubber Polymers 0.000 claims description 16
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 16
- 238000012546 transfer Methods 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 9
- 239000004945 silicone rubber Substances 0.000 claims description 9
- 125000000524 functional group Chemical group 0.000 claims description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 8
- 229920001897 terpolymer Polymers 0.000 claims description 6
- 229920006029 tetra-polymer Polymers 0.000 claims description 6
- 238000011161 development Methods 0.000 claims description 5
- 239000004812 Fluorinated ethylene propylene Substances 0.000 claims description 3
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 claims description 3
- 229920009441 perflouroethylene propylene Polymers 0.000 claims description 3
- SKRWRXWNQFQGRU-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorooctane Chemical group CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SKRWRXWNQFQGRU-UHFFFAOYSA-N 0.000 claims description 2
- QHSJIZLJUFMIFP-UHFFFAOYSA-N ethene;1,1,2,2-tetrafluoroethene Chemical group C=C.FC(F)=C(F)F QHSJIZLJUFMIFP-UHFFFAOYSA-N 0.000 claims description 2
- 238000003384 imaging method Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 48
- 239000003921 oil Substances 0.000 description 46
- 229920002449 FKM Polymers 0.000 description 17
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- 229920003249 vinylidene fluoride hexafluoropropylene elastomer Polymers 0.000 description 8
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 7
- 239000011737 fluorine Substances 0.000 description 7
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- 239000011133 lead Substances 0.000 description 4
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
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- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
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- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
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- 231100001261 hazardous Toxicity 0.000 description 2
- PQPVPZTVJLXQAS-UHFFFAOYSA-N hydroxy-methyl-phenylsilicon Chemical compound C[Si](O)C1=CC=CC=C1 PQPVPZTVJLXQAS-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
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- 150000002739 metals Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 239000011701 zinc Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 101100537937 Caenorhabditis elegans arc-1 gene Proteins 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Chemical group 0.000 description 1
- 229920007925 Ethylene chlorotrifluoroethylene (ECTFE) Polymers 0.000 description 1
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- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
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- 229920006362 Teflon® Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
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- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
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- 238000001819 mass spectrum Methods 0.000 description 1
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- 230000009965 odorless effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000002524 organometallic group Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RPDJEKMSFIRVII-UHFFFAOYSA-N oxomethylidenehydrazine Chemical group NN=C=O RPDJEKMSFIRVII-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
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- 229910052720 vanadium Inorganic materials 0.000 description 1
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Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/20—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat
- G03G15/2003—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat
- G03G15/2014—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat using contact heat
- G03G15/2053—Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating
- G03G15/2057—Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating relating to the chemical composition of the heat element and layers thereof
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G2215/00—Apparatus for electrophotographic processes
- G03G2215/20—Details of the fixing device or porcess
- G03G2215/2003—Structural features of the fixing device
- G03G2215/2048—Surface layer material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Fixing For Electrophotography (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Rolls And Other Rotary Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/054,086 | 2005-02-08 | ||
| US11/054,086 US7381514B2 (en) | 2005-02-08 | 2005-02-08 | Stabilization of fluorinated silicone fuser release agents using mercapto functional silicones |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2534949A1 CA2534949A1 (en) | 2006-08-08 |
| CA2534949C true CA2534949C (en) | 2009-05-05 |
Family
ID=36499578
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2534949 Expired - Fee Related CA2534949C (en) | 2005-02-08 | 2006-02-01 | Stabilization of fluorinated silicone fuser release agents using mercapto functional silicones |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7381514B2 (enExample) |
| EP (1) | EP1688803B1 (enExample) |
| JP (1) | JP4587968B2 (enExample) |
| BR (1) | BRPI0600342A (enExample) |
| CA (1) | CA2534949C (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8318302B2 (en) * | 2008-03-12 | 2012-11-27 | Xerox Corporation | Fuser member release layer having nano-size copper metal particles |
| US8563116B2 (en) * | 2010-09-02 | 2013-10-22 | Xerox Corporation | Fuser manufacture and apparatus |
| CN116406328A (zh) * | 2020-11-04 | 2023-07-07 | 琳得科株式会社 | 剥离膜 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4029827A (en) * | 1974-07-24 | 1977-06-14 | Xerox Corporation | Mercapto functional polyorganosiloxane release agents for fusers in electrostatic copiers |
| US4251277A (en) * | 1978-04-24 | 1981-02-17 | Sws Silicones Corporation | Compositions containing thiofunctional polysiloxanes |
| US4515884A (en) * | 1982-09-21 | 1985-05-07 | Xerox Corporation | Fusing system with unblended silicone oil |
| US4968766A (en) * | 1989-01-12 | 1990-11-06 | Dow Corning Corporation | Fluorosilicone compounds and compositions for adhesive release liners |
| US5217837A (en) * | 1991-09-05 | 1993-06-08 | Xerox Corporation | Multilayered fuser member |
| US5366772A (en) * | 1993-07-28 | 1994-11-22 | Xerox Corporation | Fuser member |
| JPH07331226A (ja) * | 1993-08-27 | 1995-12-19 | Asahi Glass Co Ltd | 加熱定着ロール防汚用オイル |
| US5395725A (en) * | 1993-11-22 | 1995-03-07 | Xerox Corporation | Fuser oil compositions and processes thereof |
| JPH0850424A (ja) * | 1994-08-08 | 1996-02-20 | Fujitsu Ltd | 画像形成装置 |
| JP3369008B2 (ja) * | 1994-09-29 | 2003-01-20 | コニカ株式会社 | 定着装置 |
| US5627000A (en) * | 1994-10-07 | 1997-05-06 | Konica Corporation | Heat fixing method |
| US5636012A (en) * | 1994-12-13 | 1997-06-03 | Konica Corporation | Toner image fixing device |
| US5624780A (en) * | 1995-04-03 | 1997-04-29 | Konica Corporation | Toner image fixing method using fluorine containing silicone oil |
| US5757214A (en) * | 1995-07-19 | 1998-05-26 | Stoddard; Robert J. | PWM driver for an inductive load with detector of a not regulating PWM condition |
| US6197989B1 (en) * | 1996-07-18 | 2001-03-06 | Asahi Glass Company Ltd. | Fluorinated organosilicon compounds and process for the preparation thereof |
| US6808814B2 (en) * | 2003-03-18 | 2004-10-26 | Xerox Corporation | Blended fluorosilicone release agent for polymeric fuser members |
| US6830819B2 (en) * | 2003-03-18 | 2004-12-14 | Xerox Corporation | Fluorosilicone release agent for fluoroelastomer fuser members |
| US6808815B2 (en) * | 2003-03-18 | 2004-10-26 | Xerox Corporation | Blended fluorosilicone release agent for silicone fuser members |
-
2005
- 2005-02-08 US US11/054,086 patent/US7381514B2/en not_active Expired - Fee Related
-
2006
- 2006-01-13 EP EP20060100340 patent/EP1688803B1/en not_active Ceased
- 2006-02-01 CA CA 2534949 patent/CA2534949C/en not_active Expired - Fee Related
- 2006-02-08 JP JP2006031471A patent/JP4587968B2/ja not_active Expired - Fee Related
- 2006-02-08 BR BRPI0600342 patent/BRPI0600342A/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| JP4587968B2 (ja) | 2010-11-24 |
| BRPI0600342A (pt) | 2006-10-03 |
| CA2534949A1 (en) | 2006-08-08 |
| US20060177758A1 (en) | 2006-08-10 |
| JP2006221179A (ja) | 2006-08-24 |
| EP1688803A3 (en) | 2009-01-07 |
| US7381514B2 (en) | 2008-06-03 |
| EP1688803A2 (en) | 2006-08-09 |
| EP1688803B1 (en) | 2013-06-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20200203 |