CA2490403C - Process for steam cracking heavy hydrocarbon feedstocks - Google Patents

Process for steam cracking heavy hydrocarbon feedstocks Download PDF

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Publication number
CA2490403C
CA2490403C CA2490403A CA2490403A CA2490403C CA 2490403 C CA2490403 C CA 2490403C CA 2490403 A CA2490403 A CA 2490403A CA 2490403 A CA2490403 A CA 2490403A CA 2490403 C CA2490403 C CA 2490403C
Authority
CA
Canada
Prior art keywords
heated
vapor phase
steam
feedstock
heavy hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2490403A
Other languages
English (en)
French (fr)
Other versions
CA2490403A1 (en
Inventor
Richard C. Stell
Arthur R. Dinicolantonio
James Mitchell Frye
David B. Spicer
James N. Mccoy
Robert D. Strack
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/188,901 external-priority patent/US7090765B2/en
Priority claimed from US10/188,461 external-priority patent/US7138047B2/en
Priority claimed from US10/189,618 external-priority patent/US7097758B2/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of CA2490403A1 publication Critical patent/CA2490403A1/en
Application granted granted Critical
Publication of CA2490403C publication Critical patent/CA2490403C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00—Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02—Header boxes; End plates
    • F28F9/026—Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits
    • F28F9/0265—Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits by using guiding means or impingement means inside the header box
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1033—Oil well production fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1051—Kerosene having a boiling range of about 180 - 230 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1074—Vacuum distillates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1077—Vacuum residues
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • C10G2300/807—Steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Lubricants (AREA)
  • Separating Particles In Gases By Inertia (AREA)
CA2490403A 2002-07-03 2003-06-27 Process for steam cracking heavy hydrocarbon feedstocks Expired - Fee Related CA2490403C (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US10/188,901 2002-07-03
US10/188,901 US7090765B2 (en) 2002-07-03 2002-07-03 Process for cracking hydrocarbon feed with water substitution
US10/188,461 2002-07-03
US10/188,461 US7138047B2 (en) 2002-07-03 2002-07-03 Process for steam cracking heavy hydrocarbon feedstocks
US10/189,618 US7097758B2 (en) 2002-07-03 2002-07-03 Converting mist flow to annular flow in thermal cracking application
US10/189,618 2002-07-03
PCT/US2003/020378 WO2004005433A1 (en) 2002-07-03 2003-06-27 Process for steam cracking heavy hydrocarbon feedstocks

Publications (2)

Publication Number Publication Date
CA2490403A1 CA2490403A1 (en) 2004-01-15
CA2490403C true CA2490403C (en) 2011-06-07

Family

ID=30119026

Family Applications (3)

Application Number Title Priority Date Filing Date
CA2489876A Expired - Fee Related CA2489876C (en) 2002-07-03 2003-06-27 Converting mist flow to annular flow in thermal cracking application
CA2490403A Expired - Fee Related CA2490403C (en) 2002-07-03 2003-06-27 Process for steam cracking heavy hydrocarbon feedstocks
CA2489888A Expired - Fee Related CA2489888C (en) 2002-07-03 2003-06-27 Process for cracking hydrocarbon feed with water substitution

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CA2489876A Expired - Fee Related CA2489876C (en) 2002-07-03 2003-06-27 Converting mist flow to annular flow in thermal cracking application

Family Applications After (1)

Application Number Title Priority Date Filing Date
CA2489888A Expired - Fee Related CA2489888C (en) 2002-07-03 2003-06-27 Process for cracking hydrocarbon feed with water substitution

Country Status (9)

Country Link
EP (3) EP1639060B1 (ko)
JP (3) JP5166674B2 (ko)
KR (2) KR100979027B1 (ko)
CN (3) CN1281715C (ko)
AT (1) ATE396244T1 (ko)
AU (3) AU2003281371A1 (ko)
CA (3) CA2489876C (ko)
SG (1) SG177003A1 (ko)
WO (3) WO2004005433A1 (ko)

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US7097758B2 (en) 2002-07-03 2006-08-29 Exxonmobil Chemical Patents Inc. Converting mist flow to annular flow in thermal cracking application
US7090765B2 (en) 2002-07-03 2006-08-15 Exxonmobil Chemical Patents Inc. Process for cracking hydrocarbon feed with water substitution
US7138047B2 (en) 2002-07-03 2006-11-21 Exxonmobil Chemical Patents Inc. Process for steam cracking heavy hydrocarbon feedstocks
CN100564484C (zh) 2004-03-22 2009-12-02 埃克森美孚化学专利公司 蒸汽裂解重质烃原料的方法
US7488459B2 (en) 2004-05-21 2009-02-10 Exxonmobil Chemical Patents Inc. Apparatus and process for controlling temperature of heated feed directed to a flash drum whose overhead provides feed for cracking
US7408093B2 (en) 2004-07-14 2008-08-05 Exxonmobil Chemical Patents Inc. Process for reducing fouling from flash/separation apparatus during cracking of hydrocarbon feedstocks
US7481871B2 (en) 2004-12-10 2009-01-27 Exxonmobil Chemical Patents Inc. Vapor/liquid separation apparatus
US7247765B2 (en) 2004-05-21 2007-07-24 Exxonmobil Chemical Patents Inc. Cracking hydrocarbon feedstock containing resid utilizing partial condensation of vapor phase from vapor/liquid separation to mitigate fouling in a flash/separation vessel
US7351872B2 (en) 2004-05-21 2008-04-01 Exxonmobil Chemical Patents Inc. Process and draft control system for use in cracking a heavy hydrocarbon feedstock in a pyrolysis furnace
US7297833B2 (en) 2004-05-21 2007-11-20 Exxonmobil Chemical Patents Inc. Steam cracking of light hydrocarbon feedstocks containing non-volatile components and/or coke precursors
US7402237B2 (en) 2004-10-28 2008-07-22 Exxonmobil Chemical Patents Inc. Steam cracking of hydrocarbon feedstocks containing salt and/or particulate matter
US7312371B2 (en) 2004-05-21 2007-12-25 Exxonmobil Chemical Patents Inc. Steam cracking of hydrocarbon feedstocks containing non-volatile components and/or coke precursors
US7358413B2 (en) 2004-07-14 2008-04-15 Exxonmobil Chemical Patents Inc. Process for reducing fouling from flash/separation apparatus during cracking of hydrocarbon feedstocks
US7311746B2 (en) * 2004-05-21 2007-12-25 Exxonmobil Chemical Patents Inc. Vapor/liquid separation apparatus for use in cracking hydrocarbon feedstock containing resid
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KR100931792B1 (ko) 2007-05-25 2009-12-11 주식회사 엘지화학 탄화수소 수증기 열분해용 촉매, 그의 제조방법 및 이를이용한 올레핀의 제조방법
ITMI20071209A1 (it) * 2007-06-15 2008-12-16 Eni Spa Processo per la purificazione di una corrente acquosa proveniente dalla reazione di fischer-tropsch
KR100999304B1 (ko) 2007-07-05 2010-12-08 주식회사 엘지화학 올레핀 제조용 탄화수소 열분해 방법
CN101796167B (zh) * 2007-08-21 2013-05-01 埃克森美孚化学专利公司 烃原料的蒸汽裂化方法和设备
US8882991B2 (en) 2009-08-21 2014-11-11 Exxonmobil Chemical Patents Inc. Process and apparatus for cracking high boiling point hydrocarbon feedstock
MY163515A (en) * 2010-12-10 2017-09-15 Exxonmobil Chemical Patents Inc Method and apparatus for obtaining aromatics from diverse feedstock
US9181146B2 (en) 2010-12-10 2015-11-10 Exxonmobil Chemical Patents Inc. Process for the production of xylenes and light olefins
WO2013169774A2 (en) 2012-05-07 2013-11-14 Phononic Devices, Inc. Thermoelectric heat exchanger component including protective heat spreading lid and optimal thermal interface resistance
US20130291555A1 (en) 2012-05-07 2013-11-07 Phononic Devices, Inc. Thermoelectric refrigeration system control scheme for high efficiency performance
US9181147B2 (en) 2012-05-07 2015-11-10 Exxonmobil Chemical Patents Inc. Process for the production of xylenes and light olefins
CN103215071A (zh) * 2013-04-12 2013-07-24 大连理工大学 一种费托油催化提质方法
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EP1523534B1 (en) 2017-07-19
CA2489888A1 (en) 2004-01-15
KR100979027B1 (ko) 2010-08-30
AU2003247755A1 (en) 2004-01-23
CN1665910A (zh) 2005-09-07
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CA2489876C (en) 2011-04-19
JP2005531684A (ja) 2005-10-20
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JP4403071B2 (ja) 2010-01-20
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EP1639060B1 (en) 2008-05-21
JP2005531683A (ja) 2005-10-20
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CN1281715C (zh) 2006-10-25
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CA2489888C (en) 2011-07-12
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