CA2463776A1 - Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts - Google Patents

Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts Download PDF

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Publication number
CA2463776A1
CA2463776A1 CA002463776A CA2463776A CA2463776A1 CA 2463776 A1 CA2463776 A1 CA 2463776A1 CA 002463776 A CA002463776 A CA 002463776A CA 2463776 A CA2463776 A CA 2463776A CA 2463776 A1 CA2463776 A1 CA 2463776A1
Authority
CA
Canada
Prior art keywords
catalyst
set forth
copper
iron
supporting structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002463776A
Other languages
English (en)
French (fr)
Inventor
David A. Morgenstern
James P. Coleman
James M. Allman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Technology LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2463776A1 publication Critical patent/CA2463776A1/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • B01J25/02—Raney nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA002463776A 2001-10-18 2002-10-16 Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts Abandoned CA2463776A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US33022601P 2001-10-18 2001-10-18
US60/330,226 2001-10-18
PCT/US2002/032953 WO2003033140A2 (en) 2001-10-18 2002-10-16 Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts

Publications (1)

Publication Number Publication Date
CA2463776A1 true CA2463776A1 (en) 2003-04-24

Family

ID=23288828

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002463776A Abandoned CA2463776A1 (en) 2001-10-18 2002-10-16 Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts

Country Status (10)

Country Link
US (1) US7126024B2 (enExample)
EP (1) EP1436080A2 (enExample)
CN (1) CN1729052A (enExample)
AR (1) AR037115A1 (enExample)
AU (1) AU2002362929B2 (enExample)
BR (1) BR0213428A (enExample)
CA (1) CA2463776A1 (enExample)
IN (1) IN2004CH00786A (enExample)
MX (1) MX244781B (enExample)
WO (1) WO2003033140A2 (enExample)

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US6376708B1 (en) * 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
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EP1551755A1 (en) * 2002-10-18 2005-07-13 Monsanto Technology LLC Use of metal supported copper catalysts for reforming alcohols
PL2150342T3 (pl) * 2007-05-29 2018-07-31 Evonik Degussa Gmbh Aktywowane katalizatory z metali nieszlachetnych
EP2148741A1 (en) * 2007-05-29 2010-02-03 Evonik Degussa GmbH Activated base metal catalysts
WO2008145181A1 (en) * 2007-05-29 2008-12-04 Evonik Degussa Gmbh Activated base metal catalysts
JP5473923B2 (ja) * 2007-10-15 2014-04-16 エボニック デグサ ゲーエムベーハー 高速ろ過粉末触媒混合物
DE102008013474B4 (de) * 2008-03-10 2013-08-08 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Katalytisches Verfahren zur Gewinnung von chemischen Grundstoffen aus nachwachsenden Rohstoffen
GB0807904D0 (en) * 2008-04-30 2008-06-04 Invista Technologies Srl Oxidation reactions
WO2011101287A1 (de) 2010-02-19 2011-08-25 Basf Se Verfahren zur herstellung von ethercarboxylaten
US9062278B2 (en) 2010-02-19 2015-06-23 Basf Se Preparing ether carboxylates
US8309759B2 (en) 2010-02-19 2012-11-13 Basf Se Preparing ether carboxylates
AU2011217307B2 (en) 2010-02-19 2016-07-28 Basf Se Method for the production of ether carboxylates
JP5149364B2 (ja) 2010-11-08 2013-02-20 国立大学法人群馬大学 炭素触媒及びその製造方法並びにこれを用いた電極及び電池
WO2017066454A2 (en) 2015-10-14 2017-04-20 X-Therma, Inc. Compositions and methods for reducing ice crystal formation
WO2022066160A1 (en) 2020-09-24 2022-03-31 Iowa Corn Promotion Board Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
US20240158423A1 (en) * 2021-03-04 2024-05-16 Monsanto Technology Llc Two-compartment bipolar membrane electrodialysis of salts of amino acids
CN117797803B (zh) * 2022-09-26 2026-05-29 中国石油化工股份有限公司 一种具有强Lewis酸性的催化剂及其制备方法和应用

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Also Published As

Publication number Publication date
AR037115A1 (es) 2004-10-20
MX244781B (es) 2007-04-03
WO2003033140A2 (en) 2003-04-24
AU2002362929A1 (en) 2003-04-28
MXPA04003658A (es) 2004-07-22
AU2002362929B2 (en) 2007-08-09
CN1729052A (zh) 2006-02-01
IN2004CH00786A (enExample) 2006-01-13
US7126024B2 (en) 2006-10-24
EP1436080A2 (en) 2004-07-14
US20050043566A1 (en) 2005-02-24
WO2003033140A3 (en) 2003-07-17
BR0213428A (pt) 2005-12-20

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Legal Events

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EEER Examination request
FZDE Discontinued
FZDE Discontinued

Effective date: 20110726