CA2440237A1 - Conductivity paste, articles produced therewith having a conductive coating on glass, ceramic or enamelled steel, and process for production thereof - Google Patents
Conductivity paste, articles produced therewith having a conductive coating on glass, ceramic or enamelled steel, and process for production thereof Download PDFInfo
- Publication number
- CA2440237A1 CA2440237A1 CA002440237A CA2440237A CA2440237A1 CA 2440237 A1 CA2440237 A1 CA 2440237A1 CA 002440237 A CA002440237 A CA 002440237A CA 2440237 A CA2440237 A CA 2440237A CA 2440237 A1 CA2440237 A1 CA 2440237A1
- Authority
- CA
- Canada
- Prior art keywords
- conductivity
- glass
- particles
- paste according
- paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract 16
- 239000011248 coating agent Substances 0.000 title claims abstract 8
- 238000000576 coating method Methods 0.000 title claims abstract 8
- 229910000831 Steel Inorganic materials 0.000 title claims abstract 6
- 239000000919 ceramic Substances 0.000 title claims abstract 6
- 239000010959 steel Substances 0.000 title claims abstract 6
- 238000000034 method Methods 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000002245 particle Substances 0.000 claims abstract 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052802 copper Inorganic materials 0.000 claims abstract 3
- 239000010949 copper Substances 0.000 claims abstract 3
- 229910052709 silver Inorganic materials 0.000 claims abstract 3
- 239000004332 silver Substances 0.000 claims abstract 3
- 229910052725 zinc Inorganic materials 0.000 claims abstract 3
- 239000011701 zinc Substances 0.000 claims abstract 3
- 239000000956 alloy Substances 0.000 claims abstract 2
- 229910045601 alloy Inorganic materials 0.000 claims abstract 2
- 229910017052 cobalt Inorganic materials 0.000 claims abstract 2
- 239000010941 cobalt Substances 0.000 claims abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052742 iron Inorganic materials 0.000 claims abstract 2
- 239000010953 base metal Substances 0.000 claims 6
- 239000000758 substrate Substances 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 230000004048 modification Effects 0.000 claims 2
- 238000012986 modification Methods 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- 229910011255 B2O3 Inorganic materials 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 239000005388 borosilicate glass Substances 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 229910052681 coesite Inorganic materials 0.000 claims 1
- 229910052906 cristobalite Inorganic materials 0.000 claims 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical class OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 1
- 238000010304 firing Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 claims 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 229910052682 stishovite Inorganic materials 0.000 claims 1
- -1 terpene alcohols Chemical class 0.000 claims 1
- 235000007586 terpenes Nutrition 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 claims 1
- 229910052905 tridymite Inorganic materials 0.000 claims 1
- 239000010970 precious metal Substances 0.000 abstract 2
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/09—Use of materials for the conductive, e.g. metallic pattern
- H05K1/092—Dispersed materials, e.g. conductive pastes or inks
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
- C03C3/066—Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/5116—Ag or Au
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/88—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
- H01B1/16—Conductive material dispersed in non-conductive inorganic material the conductive material comprising metals or alloys
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00844—Uses not provided for elsewhere in C04B2111/00 for electronic applications
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Conductive Materials (AREA)
- Glass Compositions (AREA)
- Paints Or Removers (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Surface Treatment Of Glass (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to a conductive paste containing a glass frit, a paste-forming medium, conductive particles made of silver and particles containing non-precious metal, in order to produce a conductive coating on glass, ceramics or enameled steel, a method for producing said coating and articles coated therewith According to the invention, the conductive particles containing non-precious metal correspond to up to 80 wt. % of all conductive particles, and are essentially made up of iron, cobalt, nickel, copper, zinc or an alloy containing at least one of these elements, especially nickel, and have an average particle size d50 ranging from 0.1 -15 µm and a specific surface ranging from 0.5 -10m2/g.The glass frits begin to soften at 350 ~C -600 ~C and have a hemisphere temperature of 450 ~C - 700 ~C.
Claims (13)
1. A conductivity paste for the purpose of producing a conductive coating on glass, ceramic or enamelled steel, comprising conductivity particles of silver, conductivity particles containing at least one base metal, one or more glass frits and a paste-forming medium, characterised in that the conductivity particles containing base metal consist substantially of iron, cobalt, nickel, copper, zinc or an alloy containing at least one of these elements and additionally may be coated with silver, the conductivity particles containing base metal exhibit a mean particle size d50 within the range from 0.1 µm to 15 µm and a specific surface within the range from 0.5 m2/g to 10 m2/g, up to 80 wt.% of all conductivity particles are conductivity particles containing base metal and the one or more glass frits exhibit a softening-temperature (heating microscope) within the range from 350 °C to 600 °C and a hemisphere temperature within the range from 450 °C to 700 °C.
2. Conductivity paste according to Claim 1, characterised in that by way of conductivity particles containing base metal it contains nickel particles or copper particles in a quantity of up to 50 wt.%, in particular 10 wt.% to 40 wt. %, relative to the sum of conductivity particles.
3. Conductivity paste according to Claim 1 or 2, characterised in that it contains more than 5 wt.%, in particular 10 wt.% to 35 wt. %, conductivity particles containing base metal, relative to the sum of all conductivity particles.
4. Conductivity paste according to any one of Claims 1 to 3, characterised in that it contains in wt.%:
conductivity particles : 40 - 85 glass frit (s) : 1 - 12 medium : 10 - 50 substances for modification : 0 - 15
conductivity particles : 40 - 85 glass frit (s) : 1 - 12 medium : 10 - 50 substances for modification : 0 - 15
5. Conductivity paste according to Claim 4, characterised in that it contains in wt.%:
conductivity particles : 50 - 80 glass frit(s) : 2 - 10 medium : 15 - 48 substances for modification : 0 - 15
conductivity particles : 50 - 80 glass frit(s) : 2 - 10 medium : 15 - 48 substances for modification : 0 - 15
6. Conductivity paste according to any one of Claims 1 to 5, characterised in that the glass frit(s) is/are lead-free and is/are selected from the series of the zinc-containing and/or bismuth-containing borosilicate glasses or glasses based on the principal components SiO2, B2O3, TiO2 and K2O.
7. Conductivity paste according to any one of Claims 1 to 6, characterised in that the glass frit(s) is/are fast-firable (2 - 5 min at 660 °C to 680 °C on glass).
8. Conductivity paste according to any one of Claims 1 to 7, characterised in that the conductivity particles exhibit a specific surface within the range from 1 m2/g to 5 m2/g.
9. Conductivity paste according to any one of Claims 1 to 8, characterised in that the paste-forming medium contains an organic binding agent, in particular a cellulose derivative, and one or more solvents, in particular glycol-ether compounds and terpene alcohols, or is substantially based on a thermoplastic polymer.
10. Conductivity paste according to any one of Claims 1 to 9, characterised in that the paste is screen-printable.
11. Use of the conductivity paste according to one of Claims 1 to 10 for the purpose of producing a conductive coating on a firable substrate, in particular glass, ceramic or enamelled steel.
12. A process for producing a conductive coating on a firable substrate, in particular glass, ceramic or enamelled steel, comprising applying a layer of a conductivity paste onto the substrate and firing the coated substrate at a temperature within the range from 450 °C to 700 °C, characterised in that use is made of a conductivity paste according to one of Claims 1 to 10.
13. Articles having a conductive coating on glass, ceramic or enamelled steel, characterised in that the coating is obtainable by using a conductivity paste according to any one of Claims 1 to 10.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10116653.2 | 2001-04-04 | ||
| DE10116653A DE10116653A1 (en) | 2001-04-04 | 2001-04-04 | Conductivity paste, articles thus produced with a conductive coating on glass, ceramic and enamelled steel and process for their production |
| PCT/EP2002/001652 WO2002082466A1 (en) | 2001-04-04 | 2002-02-15 | Conductive paste, article produced therewith with a conductive coating on glass, ceramics or enameled steel and method for the production thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2440237A1 true CA2440237A1 (en) | 2002-10-17 |
| CA2440237C CA2440237C (en) | 2012-08-14 |
Family
ID=7680265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2440237A Expired - Lifetime CA2440237C (en) | 2001-04-04 | 2002-02-15 | Conductivity paste, articles produced therewith having a conductive coating on glass, ceramic or enamelled steel, and process for production thereof |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20040155227A1 (en) |
| EP (1) | EP1377984B1 (en) |
| JP (1) | JP3960921B2 (en) |
| KR (1) | KR100838663B1 (en) |
| CN (1) | CN1238861C (en) |
| AT (1) | ATE359592T1 (en) |
| CA (1) | CA2440237C (en) |
| DE (2) | DE10116653A1 (en) |
| ES (1) | ES2283538T3 (en) |
| WO (1) | WO2002082466A1 (en) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6444617A (en) * | 1987-08-12 | 1989-02-17 | Seiko Epson Corp | Protecting circuit |
| ITMI20010807A1 (en) * | 2000-04-14 | 2002-10-13 | Saint Gobain | PROCEDURE FOR THE MANUFACTURE OF ELECTRO-CONDUCTOR TRACKS SUNUN TRANSPARENT SUBSTRATE AND SUBSTRATE OBTAINED |
| US7157023B2 (en) * | 2001-04-09 | 2007-01-02 | E. I. Du Pont De Nemours And Company | Conductor compositions and the use thereof |
| EP1783558B1 (en) * | 2004-07-09 | 2013-09-11 | Asahi Glass Company, Limited | Conductive toner and process for producing glass plate with conductive printed wire |
| US7435361B2 (en) * | 2005-04-14 | 2008-10-14 | E.I. Du Pont De Nemours And Company | Conductive compositions and processes for use in the manufacture of semiconductor devices |
| US7556748B2 (en) | 2005-04-14 | 2009-07-07 | E. I. Du Pont De Nemours And Company | Method of manufacture of semiconductor device and conductive compositions used therein |
| US7326367B2 (en) * | 2005-04-25 | 2008-02-05 | E.I. Du Pont De Nemours And Company | Thick film conductor paste compositions for LTCC tape in microwave applications |
| US7728260B2 (en) | 2005-06-07 | 2010-06-01 | Johnson Steven X | Warm window system |
| KR100719802B1 (en) * | 2005-12-28 | 2007-05-18 | 제일모직주식회사 | High Reliability Conductive Fine Particles for Anisotropic Conductive Connections |
| US8076570B2 (en) * | 2006-03-20 | 2011-12-13 | Ferro Corporation | Aluminum-boron solar cell contacts |
| US20070254796A1 (en) * | 2006-04-26 | 2007-11-01 | Kurtz Anthony D | Method and apparatus for preventing catastrophic contact failure in ultra high temperature piezoresistive sensors and transducers |
| CN101501864B (en) * | 2006-06-19 | 2012-08-08 | 卡伯特公司 | Photovoltaic conductive features and processes for forming same |
| US20090288709A1 (en) * | 2006-12-25 | 2009-11-26 | Hideyo Iida | Conductive paste for forming of electrode of crystalline silicon substrate |
| JPWO2008078374A1 (en) * | 2006-12-25 | 2010-04-15 | ナミックス株式会社 | Conductive paste for solar cell |
| KR101623597B1 (en) * | 2007-04-25 | 2016-05-23 | 헤레우스 프레셔스 메탈즈 노스 아메리카 콘쇼호켄 엘엘씨 | Thick film conductor formulations comprising silver and nickel or silver and nickel alloys and solar cells made therefrom |
| US7833439B2 (en) * | 2007-07-24 | 2010-11-16 | Ferro Corporation | Ultra low-emissivity (ultra low E) silver coating |
| WO2009052266A1 (en) * | 2007-10-18 | 2009-04-23 | E. I. Du Pont De Nemours And Company | Conductive compositions and processes for use in the manufacture of semiconductor devices: mg-containing additive |
| CN101816045A (en) * | 2007-10-18 | 2010-08-25 | E.I.内穆尔杜邦公司 | Lead-free conductive compositions and processes for use in the manufacture of semiconductor devices: Mg-containing additive |
| US7485245B1 (en) * | 2007-10-18 | 2009-02-03 | E.I. Du Pont De Nemours And Company | Electrode paste for solar cell and solar cell electrode using the paste |
| US8383011B2 (en) * | 2008-01-30 | 2013-02-26 | Basf Se | Conductive inks with metallo-organic modifiers |
| US7736546B2 (en) | 2008-01-30 | 2010-06-15 | Basf Se | Glass frits |
| US8308993B2 (en) * | 2008-01-30 | 2012-11-13 | Basf Se | Conductive inks |
| CN102056854A (en) * | 2008-06-26 | 2011-05-11 | E.I.内穆尔杜邦公司 | Glass compositions used in conductors for photovoltaic cells |
| JP5374788B2 (en) * | 2009-08-31 | 2013-12-25 | シャープ株式会社 | Conductive paste, solar cell electrode, solar cell, and method for manufacturing solar cell |
| WO2011035015A1 (en) * | 2009-09-17 | 2011-03-24 | E. I. Du Pont De Nemours And Company | Thick-film conductive compositions with nano-sized zinc additive |
| JP5685138B2 (en) * | 2011-05-11 | 2015-03-18 | 福田金属箔粉工業株式会社 | Conductive composition |
| KR101321368B1 (en) * | 2011-12-20 | 2013-10-28 | 금호석유화학 주식회사 | Conductive composite particle and conductive paste composition comprising same |
| US9039942B2 (en) | 2011-12-21 | 2015-05-26 | E I Du Pont De Nemours And Company | Lead-free conductive paste composition and semiconductor devices made therewith |
| US9441117B2 (en) * | 2012-03-20 | 2016-09-13 | Basf Se | Mixtures, methods and compositions pertaining to conductive materials |
| KR20130139022A (en) * | 2012-06-12 | 2013-12-20 | 주식회사 동진쎄미켐 | A conductive paste composition |
| TWI473119B (en) * | 2012-08-21 | 2015-02-11 | Giga Solar Materials Corp | Conductive silver paste with glass frit and method of increasing the adhesion force of the back side silver electrode on solar cells by thereof conductive silve paste |
| JP6242800B2 (en) * | 2012-10-19 | 2017-12-06 | ナミックス株式会社 | Sintered conductive paste |
| TWI509049B (en) * | 2013-01-15 | 2015-11-21 | Giga Solar Materials Corp | Conductive silver paste with glass frit |
| TWM512217U (en) | 2013-06-20 | 2015-11-11 | Plant PV | Solar battery |
| US9331216B2 (en) | 2013-09-23 | 2016-05-03 | PLANT PV, Inc. | Core-shell nickel alloy composite particle metallization layers for silicon solar cells |
| CN104658633A (en) * | 2013-11-20 | 2015-05-27 | 湖南利德电子浆料有限公司 | Formula and preparation method of conductive copper paste for automotive glass heater wire |
| KR102302357B1 (en) * | 2014-03-20 | 2021-09-16 | 나믹스 가부시끼가이샤 | Conductive paste, laminated ceramic component, printed circuit board, and electronic device |
| CN106133845B (en) * | 2014-04-02 | 2018-11-23 | 费罗公司 | Conductive paste with improved glass strength properties |
| CN103996424A (en) * | 2014-04-16 | 2014-08-20 | 池州市华硕电子科技有限公司 | Wear-resistant printed circuit board silver slurry and preparation method thereof |
| CN106463202A (en) | 2014-06-30 | 2017-02-22 | 株式会社村田制作所 | Conductive paste and glass article |
| KR102192757B1 (en) * | 2014-07-22 | 2020-12-18 | 알파 어셈블리 솔루션스 인크. | Stretchable interconnects for flexible electronic surfaces |
| KR102093157B1 (en) * | 2014-12-01 | 2020-03-25 | 삼성전기주식회사 | Multi-layer ceramic substrate |
| WO2016126801A1 (en) | 2015-02-04 | 2016-08-11 | E I Du Pont De Nemours And Company | Conductive paste composition and semiconductor devices made therewith |
| WO2017035103A1 (en) | 2015-08-25 | 2017-03-02 | Plant Pv, Inc | Core-shell, oxidation-resistant particles for low temperature conductive applications |
| US10418497B2 (en) | 2015-08-26 | 2019-09-17 | Hitachi Chemical Co., Ltd. | Silver-bismuth non-contact metallization pastes for silicon solar cells |
| US10233338B2 (en) | 2015-11-24 | 2019-03-19 | PLANT PV, Inc. | Fired multilayer stacks for use in integrated circuits and solar cells |
| CN108650873B (en) * | 2018-05-15 | 2021-03-02 | 河南科技大学第一附属医院 | An environmental protection device for eliminating the radiation hazards of nuclear magnetic resonance to human body |
| KR102396584B1 (en) * | 2019-06-12 | 2022-05-10 | 엘지전자 주식회사 | The surface heater and the manufacturing method for the same |
| GB201910100D0 (en) | 2019-07-15 | 2019-08-28 | Johnson Matthey Plc | Composition, paste and methods |
| CN112071465B (en) * | 2020-09-18 | 2022-04-08 | 西安宏星电子浆料科技股份有限公司 | Silver migration resistant sheet resistor front electrode slurry containing nickel-containing alloy powder |
| JP7424340B2 (en) * | 2021-04-02 | 2024-01-30 | 株式会社村田製作所 | Conductive paste, manufacturing method for multilayer ceramic capacitors, multilayer ceramic capacitors |
| JP7732503B2 (en) | 2021-06-01 | 2025-09-02 | 株式会社村田製作所 | Conductive paste and glass article |
| DE102021116028A1 (en) * | 2021-06-21 | 2022-12-22 | Technische Universität Bergakademie Freiberg | Electronically conductive enamel coating |
| CN116217090B (en) * | 2022-09-09 | 2024-12-03 | 湖南洪康新材料科技有限公司 | Coated glass tube and preparation method and application thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1506450A (en) * | 1974-09-18 | 1978-04-05 | Siemens Ag | Pastes for the production of thick-film conductor paths |
| US4122232A (en) | 1975-04-21 | 1978-10-24 | Engelhard Minerals & Chemicals Corporation | Air firable base metal conductors |
| US4514321A (en) * | 1983-08-25 | 1985-04-30 | E. I. Du Pont De Nemours And Company | Thick film conductor compositions |
| FR2798509B1 (en) * | 1999-09-13 | 2001-11-16 | Thomson Multimedia Sa | MIXTURE FOR PRODUCING ELECTRODES AND METHOD FOR FORMING ELECTRODES ON A TRANSPARENT SUBSTRATE |
| DE19945866A1 (en) * | 1999-09-24 | 2001-03-29 | Dmc2 Degussa Metals Catalysts | Process for the production of a conductive coating on glass or enamelled steel and substrates coated thereafter |
-
2001
- 2001-04-04 DE DE10116653A patent/DE10116653A1/en not_active Ceased
-
2002
- 2002-02-15 JP JP2002580345A patent/JP3960921B2/en not_active Expired - Lifetime
- 2002-02-15 CN CNB028075269A patent/CN1238861C/en not_active Expired - Lifetime
- 2002-02-15 DE DE50209921T patent/DE50209921D1/en not_active Expired - Lifetime
- 2002-02-15 WO PCT/EP2002/001652 patent/WO2002082466A1/en not_active Ceased
- 2002-02-15 KR KR1020037012993A patent/KR100838663B1/en not_active Expired - Fee Related
- 2002-02-15 AT AT02714165T patent/ATE359592T1/en not_active IP Right Cessation
- 2002-02-15 US US10/473,715 patent/US20040155227A1/en not_active Abandoned
- 2002-02-15 ES ES02714165T patent/ES2283538T3/en not_active Expired - Lifetime
- 2002-02-15 CA CA2440237A patent/CA2440237C/en not_active Expired - Lifetime
- 2002-02-15 EP EP02714165A patent/EP1377984B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1377984A1 (en) | 2004-01-07 |
| CN1238861C (en) | 2006-01-25 |
| KR100838663B1 (en) | 2008-06-16 |
| ATE359592T1 (en) | 2007-05-15 |
| US20040155227A1 (en) | 2004-08-12 |
| JP3960921B2 (en) | 2007-08-15 |
| EP1377984B1 (en) | 2007-04-11 |
| CN1500276A (en) | 2004-05-26 |
| ES2283538T3 (en) | 2007-11-01 |
| JP2004525490A (en) | 2004-08-19 |
| KR20040030562A (en) | 2004-04-09 |
| DE10116653A1 (en) | 2002-10-10 |
| WO2002082466A1 (en) | 2002-10-17 |
| DE50209921D1 (en) | 2007-05-24 |
| CA2440237C (en) | 2012-08-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1069349A (en) | Metallizing compositions | |
| JP3960921B2 (en) | Conductive paste, article having conductive coating on glass, ceramics or enameled steel produced using the same, and method for producing the same | |
| JP3276961B2 (en) | Lead-free thick film paste composition | |
| US6105394A (en) | Glass enamel for automotive applications | |
| US5783507A (en) | Partially crystallizing lead-free enamel composition for automobile glass | |
| JP5366989B2 (en) | Process for producing conductive coating and support provided with the coating | |
| US5677251A (en) | Partially crystallizing enamel containing crystalline zinc borate seed material | |
| JP2006206430A (en) | Lead-free and cadmium-free glass for glazing, enameling and decoration of glass or glass-ceramic | |
| CA2566279A1 (en) | Lead-free and cadmium-free conductive copper thick film pastes | |
| CN111344261A (en) | Glass raw materials for ion exchange glass | |
| TW202222726A (en) | Enamel paste compositions and methods of coating and chemical strengthening glass substrates | |
| AU595454B2 (en) | Use of a paste containing precious metals for the production of browning dishes for microwave ovens | |
| JP2003089546A (en) | Lead-free enamel compositions, corresponding enamel and glass ceramic products, new lead-free mineral glass | |
| JP2004311438A (en) | Conductor composition for using in electronic circuit | |
| JPH11116266A (en) | Glass composition, glass frit, glass enamel composition, and non-porous substrate coated with enamel composition | |
| KR20230173715A (en) | Enamel paste composition, enamel coated product, and method for manufacturing the same (ENAMEL PASTE COMPOSITIONS, ENAMEL COATED PRODUCTS, AND METHODS OF MANUFACTURING THE SAME) | |
| GB2050051A (en) | Temperature sensitive electrical element and method and material for making the same | |
| EP0296312B1 (en) | Microwave resistant precious metal decoration | |
| JP2026015254A (en) | Glass paste and its uses | |
| JP2026015255A (en) | Glass paste and its uses | |
| JP2026015253A (en) | Glass paste and its uses | |
| JP2870367B2 (en) | Glass flux for porcelain gilding and method of manufacturing gilded porcelain | |
| WO2006099950A1 (en) | Process for producing dishwasher-resistant, scratch- and abrasion-resistant precious metal decorations | |
| WO2006102217A1 (en) | Silicon alloys materials as silver migration inhibitors |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20220215 |