CA2429392A1 - Zeolite additive for animal feed and method of using same - Google Patents

Zeolite additive for animal feed and method of using same Download PDF

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Publication number
CA2429392A1
CA2429392A1 CA002429392A CA2429392A CA2429392A1 CA 2429392 A1 CA2429392 A1 CA 2429392A1 CA 002429392 A CA002429392 A CA 002429392A CA 2429392 A CA2429392 A CA 2429392A CA 2429392 A1 CA2429392 A1 CA 2429392A1
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CA
Canada
Prior art keywords
zeolite
fish
fish feed
ammonia
fishes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002429392A
Other languages
French (fr)
Inventor
Michael Florian
Brad Hicks
David Groves
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAPLOW VENTURES Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2429392A1 publication Critical patent/CA2429392A1/en
Abandoned legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K50/00Feeding-stuffs specially adapted for particular animals
    • A23K50/80Feeding-stuffs specially adapted for particular animals for aquatic animals, e.g. fish, crustaceans or molluscs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K40/00Shaping or working-up of animal feeding-stuffs
    • A23K40/25Shaping or working-up of animal feeding-stuffs by extrusion
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/20Inorganic substances, e.g. oligoelements
    • A23K20/28Silicates, e.g. perlites, zeolites or bentonites
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K40/00Shaping or working-up of animal feeding-stuffs
    • A23K40/20Shaping or working-up of animal feeding-stuffs by moulding, e.g. making cakes or briquettes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Animal Husbandry (AREA)
  • Insects & Arthropods (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Birds (AREA)
  • Inorganic Chemistry (AREA)
  • Fodder In General (AREA)
  • Feed For Specific Animals (AREA)

Abstract

Method of reducing the level of ammonia in an aquatic environment used for commercially raising and harvesting fish. A fish feed composed of the usual materials is combined with a zeolite additive. The combination forms a composition which is fed to the fishes and allows for the increased removal of ammonia from the fish enclosure in both non-circulating and recirculating aquatic or aquacultural systems. The removal of the ammonia has several advantages which allows increased production, particularly in aquacultural fish harvesting systems where water is recirculated.

Description

TITHE
ZEOhITE ADDITIVE FOR ANIMAh FEED AND METHOD OF USING SAME
INTRODUCTION
This invention relates to an animal feed and, more particularly, to a zeolite additive for fish feed Which additive thereby reduces ammonia in the water inhabited by the fishes within the enclosure in which the fish feed and the zeolite additive are used.
BACKGROUND OF THE INVENTION
The use of a hydrous aluminosilicate sorbent composition as an animal feed supplement is described in United States Patent 5,140,949 (Chu et al) entitled ZEOLITE-ChAY COMPOSITION AND USES THEREOF, the contents of which are incorporated herein by reference. The composition comprises a non-fibrous naturally occurring clay and a non-fibrous crystalline zeolite. The composition is stated to have a synergistic effect in binding ammonium rations at both high and low levels of available ammonia. The use of the dietary supplement is stated to result in improved performance (i.e., better weight gain and general improvement in health) of the animals.
The purpose of such a supplement, however, is to increase the growth rates and general health of various animals including fish, fowl, swine and chicken. It is believed that by suppressing ammonia formation in the gastrointestinal tract of mammals, the growth rate is stimulated. Others have presented similar findings by adding zeolites to animal feed which showed benefits in weight gain and general health improvements in the animals.
It is speculated that a possible physiological explanation a.s the known binding effect of NH4 ions by zeolites and the reduction of portal blood ammonia by dietary zeolites.
In fish farms or aquaculture generally where water supply is usually a limiting factor for fish production, the presence of ammonia in the water within which the fish are raised is a problem of significant concern. If the ammonia buildup can be reduced, additional fish can be raised since the buildup of ammonia is often the limiting factor for fish production. In recirculation systems which rely on biological filters to detoxify ammonia, the efficiency of the system can be improved by decreasing the amount of ammonia that has to be detoxified. Adsorption of ammonia by zeolite and removal of the zeolite in a microscreen prior to the biological filter effectively decreases the load of ammonia on the filter. Because the zeolite is perpetually added to the feed and is concurrently being removed by the microscreen filter it functions similarly to an ammonia sink. When recireulation systems are used for recirculating water, the above-identified problems axe exacerbated since recirculation type systems have high capital and operating costs. Significant reductions in production costs could be realised by increasing fish production.
SUMMARY OF THE INVENTION
According to one aspect of the invention, there is provided a method for reducing the ammonia toxicity in an environment where ammonia is excreted by an animal, said method comprising adding an effective amount of zeolite as a component of or as a supplement to a feed or foodstuff.
According to a further aspect of the invention, there is provided a method for reducing the quantity of ammonia in a recirculating water type fish enclosure wherein fish are raised for harvesting,, said method comprising adding an effective amount of zeolite to a fish feed to form a composition and feeding said composition of said zeolite and said fish feed to fishes within said recirculating type fish enclosure thereby to reduce said quantity of said ammonia in said recirculated water.
According to yet a further aspect of the invention, there is provided a method for increasing the sedimentation rate of feces from fishes raised for harvesting within an enclosure with water therein Wherein said water of said enclosure i.s recirculated, said method comprising adding an effective amount of zeolite to a fish feed to form a composition and feeding said composition of said fish feed and zeolite to said fish in said enclosure.
According to still yet a further aspect of the invention, there is provided a method for decreasing the use of oxygen in oxidation of ammonia a.n an environment for raising fishes comprising the steps of feeding said fishes a fish feed which includes an effective quantity of zeolite for increasing ammonia removal from said environment thereby reducing said use of said oxygen in said oxidation of said ammonia.
According to a further aspect of the invention, there is provided a method of forming a composition used for the feeding of fishes comprising adding an effective amount of zeolite to a fish feed.
According to yet a further aspect of the invention, there is provided a product produced by one of the foregoing methods.
According to still yet a further aspect of the invention, there is provided a fish feed used for consumption by fishes being raised for harvesting in an enclosure containing water, said fish feed comprising a composition of nutritionally balanced and edible ingredients and including an effective amount of zeolite as a supplement to said composition of nutritionally balanced and edible ,ingredients.
According to a further aspect of the invention, there is provided a method of manufacturing a fish feed and zeolite composition comprising adding said fish feed and said zeolite to a hopper, mixing said fix feed and said zeolite, grinding said fish feed and said zeolite to obtain g _ uniform size particles of said fish feed and said zeolite, adding an appropriate quantity of liquid to said uniform size particles of said fish feed and said zeolite, extruding said fish feed and said zeolite through holes to form cylindrical extrusions, severing said extruded fish feed and zeolite to form pellets, drying said pellets and storing said dried pellets of fish feed and zeolite.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
Specific embodiments of the invention will now be described, by way of example only, with the use of drawings in which:
Figure 1 is a diagrammatic view of an aquaculture environment where fish are being raised for commercial harvesting utilising the composition of fish feed and zeolite in a system wherein recirculation takes place and wherein both microscreen and biological type filters are used to cleanse and purify the recirculated water; and Figure 2 a.s diagrammatic view illustrating, inter alia, the processes used in creating the composition according to the invention which comprises a fish feed With an added and effective amount of'zeolite.

DESCRIPTION OF SPECIFIC EMBODIMENT
Referring now to the drawings, an environment for raising fish is generally illustrated at 100 in Figure 1.
It comprises a tank diagrammatically illustrated at 101 within which fish generally illustrated at 102 are present.
The water within the tank or enclosure 101 is recirculated.
A microscreen filter 104 and a biological filter 110 are provided in the recirculation loop to cleanse the water being recirculated. Fish feed, as described in greater detail hereafter, is conveniently intermittently added to the water from feeder 111 above the tank 101 for the fish~
although manual feeding could of course could also be used which would likewise include the benefits of the invention.
The ingredients typically making up the feed used for the fishes include fish meal and fish oil which, together, comprise approximately seventy-five percent(75~) by Weight of the fish feed. In addition, wheat, corn gluten meal, soy bean meal, blood meal, methionine, various' vitamins and minerals and sorbic acid are typical ingredients as is known in the art. It will be appreciated that the quantities used can vary depending upon the size of the fish which are being fed with less feed being used for smaller fishes and more feed being used for larger growth _ g _ fishes. Likewise, it will be understood that the ratio between the various ingredients can change depending, for example, upon the age of the fish being raised in the tank 101. However, the general quantity of the ingredients and the specific identification of the ingredients is variable and is well known to those skilled in the art and need not be specifically defined here.
The combination of the aforementioned ingredients together With the addition of a zeolite additive are added to a hopper 112 (Figure 2) where they then pass to a feed mixer 113. In experiments to date, a 2~ by weight quantity of naturally occurring zeolite is added to the fish feed and has been found effective. The mixture is then passed to a grinder 114. The ground and thoroughly mixed ingredients are subsequently formed into pellets of sizes dependent upon the application intended at a forming machine 120. The formed pellets then pass to a storage hopper 121 where they may be bagged or otherwise packaged for shipment. As illustrated in Figure 2, other processing steps may be added if desired and only the principal steps have been described, The pellets of the fish feed are placed in the feeder 111 (Figure 1) located above the tank or enclosure 101. The feeder 111 is automatically activated by a _ g _ suitable timer and disperses a predetermined quantity of pellets into the tank 101 to feed the fishes 102 at desired intervals.
OPERATION
The byproducts from the fish 102 include oxygen deprived water from the gills, urine and feces. These byproducts enter the water which passes to the microscreen filter 104. The solids with ammonia adsorbed by the zeolite are removed by the microscreen filter 104 and become waste 130. The microscreen filter thereby acts as a continuous ammonia sink.
The solubles which include ammonia pass to the biofilter 110 where oxygen is added at 131 to replenish the oxygen previously used by the fishes 102 and also so that proper nitrification can occur. With nitrification completed, the non-toxic nitrates return to the environment at 132.
The zeolite Which is added to the fish feed has several significant benefits. First, since the zeolite excreted by the fishes 102 in the waste products directly absorbs ammonia from the water, the amount of ammonia a.n the water is initially and inherently reduced. This ammonia removal alone allows a greater quantity of fishes to be raised in the enclosure or tank 101 because, ordinarily, the amount of ammonia found initially in the water a.s an important limiting factor for fish production.
Second, the addition of zeolite to fish feed increases the sedimentation rate of the feces from the fishes prior to feces removal by the microscreen filter 104.
This feces removal Will reduce the loading on the biofilter 110 which will allow more fish to be raised in and harvested from the tank 101.
A third benefit is that in recirculation type fish growing systems, such as the system 100, zeolite will increase the density of the feces which will "bulk up" the fish feces making the microscreen filter 104 used in the recirculation loop more effective by increasing the quantity of fecal material being removed from the water within enclosure 101 through the micro screen 104. This decreases the loading on the microscreen filter 104.
Fourth, zeolite has a relatively high surface area that readily accepts a biofilm. This increases the rate at which nitrification takes place at the biofilter 110 in _ 11 _ recirculation systems since the increased surface area for nitrogenous bacteria will increase the number of bacterial available for nitrification. This will increase the efficiency of the systems and allows for greater fish production since an increase in nitrification results in an increase in the rate at which ammonia is removed from the system. This allows for increased loading of the system and a concomitant increase in production.
Fifth, although the zeolite is removed by the microscreen 7.04 with the bound ammonium ions, zeolite is continuously renewed through the fish feed which is execrated by the fishes. The execrated zeolite thereby continuously acts to remove ammonia from the recirculation system by providing a perpetual sink for the ammonia. This again improves the productivity of the recirculation system.
Finally, recirculation systems such as the system 100 are highly capital intensive with similarly high operating costs. Small increases in operating efficiency which allows small increases in production will have a disproportionate effect on decreasing the cost of production. The addition of zeolite that has heretofore been explained will therefor assist in decreasing the cost of production by increasing fish production.

Although the benefits of the invention are particularly applicable and significant to recirculation type fish production environments, the benefits also accrue to other environments in which fishes may be raised such as open water environments as exist in lakes and oceans and enclosed type environments such as quarries and the like, raceways as used in governmental . Indeed, although the benefits of the invention are particularly applicable to fish harvesting environments, they may also apply to any 3.0 environment where feces contamination is of concern. Such environments would include hobble activities where fish are bred or grown, aquariums, zoos where fish are displayed and fish hatcheries Where fry are raised.
Where the toxicity of a non-aquatic environment may result from the presence of excessive or objectionable ammonia excreted by animals including mammals, birds such as are present in chicken farms and the like, it is contemplated that the ammonia toxicity, including the toxicity of objectionable odor, may be reduced by the presence of zeolite as a component of or as supplement in feed or foodstuffs.
The use of zeolite as a feed component increases the density of the feces from the fishes. Since the increased density will allow better separation of the feces from the water, the man made enclosed systems can remove the feces more easily and will thereby work more efficiently.
While specific embodiments of the invention have been described, various modifications and/or improvements will readily occur to those skilled in the art to which the invention relates. The invention should be limited, therefore, only in accordance with the accompanying claims.

Claims (30)

WE CLAIM:
1. Method for reducing the ammonia toxicity in all environment where ammonia is excreted by an animal, said method comprising adding an effective amount of zeolite as a component of or as a supplement to a feed or foodstuff.
2. Method of reducing ammonia toxicity as in claim 1 wherein said ammonia toxicity is in an aquatic environment where fishes are raised for production, said method comprising the steps of adding said effective amount of zeolite to a fish feed to form a composition and feeding said zeolite and fish feed composition to said fishes in a predetermined quantity thereby reducing the ammonia produced by said fish and entering said aquatic environment.
3. Method as in claim 2 wherein said fishes are raised for commercial production.
4. Method as in claim 3 wherein said aquatic environment is a recirculating type fish enclosure.
5. Method as in claim 3 wherein said aquatic environment is an open water type enclosure including lakes, quarries and/or oceans.
6. Method as in claim 1 wherein said animal is birds.
7. Method as in claim 1 wherein said animal is mammals.
8. Method as in claim 7 Wherein said mammal is humans.
9. Method as in claim 1 wherein said animal is reptiles.
10. Method as in claim 1 wherein said animal is fishes.
11. Method as in claim 10 wherein said fishes are crustaceans.
12. Method as in claim 11 wherein said crustaceans are one of crabs, lobsters, prawns or shrimp.
13. Method for reducing the quantity of ammonia in a recirculating water type fish enclosure wherein fish are raised for harvesting, said method comprising adding an effective amount of zeolite to a fish feed to form a composition and feeding said composition of said zeolite and said fish feed to fishes within said recirculating type fish enclosure thereby to reduce said quantity of said ammonia in said recirculated water.
14. Method as in claim 13 wherein said harvesting is commercial harvesting.
15. Method for increasing the sedimentation rate of feces from fishes raised for harvesting within an enclosure with water therein wherein said water of said enclosure is recirculated, said method comprising adding an effective amount of zeolite to a fish feed to form a composition and feeding said composition of said fish feed and zeolite to said fish in said enclosure.
16. Method as in claim 15 wherein said harvesting is commercial harvesting.
17. Method for decreasing the use of oxygen in oxidation of ammonia in an environment for raising fishes comprising the steps of feeding said fishes a fish feed which includes an effective quantity of zeolite for increasing ammonia removal from said environment thereby reducing said use of said oxygen in said oxidation of said ammonia.
18. Method of forming a composition used for the feeding of fishes comprising adding an effective amount of zeolite to a fish feed.
19. Method of forming a composition as in claim 18 wherein said effective amount of zeolite is approximately 2% by weight of said fish feed.
20. Method as in claim 19 wherein said zeolite is naturally occurring zeolite.
21 Method as in claim 19 wherein said zeolite is synthetic zeolite.
22. Product produced by any one of the methods of claims 18 through 21.
23. Fish feed used for consumption by fishes being raised for harvesting in an enclosure containing water, said fish feed comprising a composition of nutritionally balanced and edible ingredients and including an effective amount of zeolite as a supplement to said composition of nutritionally balanced and edible ingredients.
24. Fish feed as in claim 23 wherein said zeolite comprises approximately 2% by weight of said composition of nutritionally balanced and edible ingredients.
25. Method as in claim 3 wherein said aquatic environment is a man made enclosure.
26. Method as in claim 25 wherein said man made enclosure a hatchery raceway, a floating cage or a land based tank.
27. Method as in claim 13 wherein said harvesting may be conducted by governmental organisation.
28. Method as in claim 27 wherein said governmental organisation is a fish hatchery.
29. Method of manufacturing a fish feed and zeolite composition comprising adding said fish feed and said zeolite to a hopper, mixing said fix feed and said zeolite, grinding said fish feed and said zeolite to obtain uniform size particles of said fish feed and said zeolite, adding an appropriate quantity of liquid to said uniform size particles of said fish feed and said zeolite, extruding said fish feed and said zeolite through holes to form cylindrical extrusions, severing said extruded fish feed and zeolite to form pellets, drying said pellets and storing said dried pellets of fish feed and zeolite.
30. Product produced by the method of claim 29.
CA002429392A 2000-11-22 2001-11-22 Zeolite additive for animal feed and method of using same Abandoned CA2429392A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US72152500A 2000-11-22 2000-11-22
US09/721,525 2000-11-22
PCT/CA2001/001639 WO2002041703A2 (en) 2000-11-22 2001-11-22 Zeolite additive for animal feed and method of using same

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CA2429392A1 true CA2429392A1 (en) 2002-05-30

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CA (1) CA2429392A1 (en)
WO (1) WO2002041703A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7713562B2 (en) 2003-09-04 2010-05-11 Rose Acre Farms, Inc. Animal feed and methods for reducing ammonia and phosphorus levels in manure
US10694722B1 (en) 2015-05-21 2020-06-30 Atlantic Sapphire IP, L.L.C. Systems and methods of intensive recirculating aquaculture
US11484015B2 (en) 2015-05-21 2022-11-01 Atlantic Sapphire Ip, Llc Systems and methods of intensive recirculating aquaculture
US11627729B2 (en) 2015-05-21 2023-04-18 Atlantic Sapphire Ip, Llc Transfer assembly and system for aquaculture
US11596132B2 (en) 2015-05-21 2023-03-07 Atlantic Sapphire Ip, Llc Transfer assembly and system for aquaculture
US10959411B2 (en) 2018-01-04 2021-03-30 Atlantic Sapphire IP, L.L.C. Bottom grading apparatuses for aquaculture systems
US11425895B2 (en) 2020-03-05 2022-08-30 Atlantic Sapphire Ip, Llc Method for optimization of filtration in an aquaculture system
US11662291B1 (en) 2021-02-03 2023-05-30 Atlantic Sapphire Ip, Llc System and method for feed validation measurement

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59113853A (en) * 1982-12-20 1984-06-30 Toshihisa Mori Additive for fish feed
US5140949A (en) * 1989-09-19 1992-08-25 Mobil Oil Corporation Zeolite-clay composition and uses thereof
JPH05276879A (en) * 1992-04-02 1993-10-26 Shinkiyou Sangyo Kk Feed for marine product
AU696420B2 (en) * 1993-10-14 1998-09-10 Westway Feed Products, Inc. Process for preparing rigid animal feedblocks
JPH07115916A (en) * 1993-10-29 1995-05-09 Nippon Oil & Fats Co Ltd Feed composition
JP3428126B2 (en) * 1993-12-20 2003-07-22 株式会社秋田食肉卸センター Livestock rearing methods and feed
CN1269154A (en) * 1999-04-02 2000-10-11 王洪章 Concentrated layer feed

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AU2002221372A1 (en) 2002-06-03
WO2002041703A3 (en) 2002-09-06

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FZDE Discontinued
FZDE Discontinued

Effective date: 20051122