CA2406991A1 - Method for producing floor and wall coverings with differential gloss decoration effect, and resulting products - Google Patents

Method for producing floor and wall coverings with differential gloss decoration effect, and resulting products Download PDF

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Publication number
CA2406991A1
CA2406991A1 CA002406991A CA2406991A CA2406991A1 CA 2406991 A1 CA2406991 A1 CA 2406991A1 CA 002406991 A CA002406991 A CA 002406991A CA 2406991 A CA2406991 A CA 2406991A CA 2406991 A1 CA2406991 A1 CA 2406991A1
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CA
Canada
Prior art keywords
protective layers
layer
underlying
differential
decoration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002406991A
Other languages
French (fr)
Other versions
CA2406991C (en
Inventor
Dung Dao Viet
Gabriel Houba
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tarkett SAS
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2406991A1 publication Critical patent/CA2406991A1/en
Application granted granted Critical
Publication of CA2406991C publication Critical patent/CA2406991C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F1/00Designs or pictures characterised by special or unusual light effects
    • B44F1/02Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0022Glass fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0002Wallpaper or wall covering on textile basis
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0871Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00Other substrates
    • B05D2203/20Wood or similar material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/04Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
    • B05D3/0406Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being air
    • B05D3/0413Heating with air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065After-treatment
    • B05D3/067Curing or cross-linking the coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/57Three layers or more the last layer being a clear coat
    • B05D7/576Three layers or more the last layer being a clear coat each layer being cured, at least partially, separately
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/58No clear coat specified
    • B05D7/586No clear coat specified each layer being cured, at least partially, separately
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00Floor coverings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/14Printing or colouring
    • B32B38/145Printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2207/00Treatments by energy or chemical effects
    • D06N2207/12Treatments by energy or chemical effects by wave energy or particle radiation
    • D06N2207/123Treatments by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation, e.g. IR, UV, actinic light, laser, X-ray, gamma-ray, microwave, radio frequency
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/08Properties of the materials having optical properties
    • D06N2209/0838Bright, glossy, shiny surface

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Textile Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • Laminated Bodies (AREA)
  • Floor Finish (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Finishing Walls (AREA)
  • Passenger Equipment (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)

Abstract

The invention concerns a method for floor-finish and wall-finish with differential gloss decoration effect characterised in that it consists in producing an undercoat (10) and then producing gloss effects by differentiated deposits (20, 22, 24) without total overlap of at least two topcoat type protective layers with different characteristics, in similar or different register, with the undercoat.

Claims (10)

1 CLAIMS AMENDED FOLLOWING THE PCT WRITTEN OPINION

1. Floor and wall coverings with a differential gloss decoration effect, comprising an underlying covering (10) comprising synthetic materials such as PVC and polyolefins, or semisynthetic materials of the linoleum type, characterised in that said underlying covering (10) is protected by at least two protective layers (20, 22, 24) of a thickness from 3 to 50 um and of different matting effect, said protective layer comprising polyurethane applied by heliographic roller, possibly in register with the underlying decoration or embossment , and in that said protective layers create a differential gloss effect ranging from 5 to 90 (under 60 degrees).
2. Coverings according to Claim 1, characterised in that the resin contained in said protective layers is chosen in particular among the resins, which may be cured with UV or with a beam of electrons, of the group consisting of the following resins: polyurethane, melamine, epoxy, acrylic or modified ionomer.
3. Method for producing floor and wall coverings with a differential gloss decoration effect, comprising the production of an underlying covering (10), characterised in that gloss effects are produced by differential applications (20, 22, 24) comprising a first layer (20) and a second layer (22, 24), said first layer being discontinuously applied onto said support (10) and then dried, said second layer (22) and/or (24) intended to partially or totally cover the first layer (20) of different matting effect being discontinuously applied without total overlapping of at least two protective layers of different characteristics, possibly in register with the underlying decoration and/or with the embossment of the product, the degree of gloss of said protective layers with differential gloss effects ranging between 5 and 90 (under 60 degrees) and the thickness of the layers thus applied ranging from 3 to 50 um.
4. Method according to Claim 3, characterised in that said underlying covering intended to receive the decoration with a differential gloss effect is smooth or embossed by chemical or mechanical Braining, and is in a flexible or rigid form.
5. Method according to Claim 3 or 4, characterised in that the decoration on the covering underlying the differential protective layers (20, 22, 24) is printed and/or made by inclusions of materials (inlaid).
6. Method according to any one of Claims 3 to 5, characterised in that complementary matting effects are obtained either following the partial overlapping of the first (20) and the second (22) layer, or by applying one or more additional protective layers (24).
7. Method according to any one of Claims 3 to 6, characterised in that, after each application of a protective layer, a drying operation is performed using hot air or by IR-irradiation.
8. Method according to any one of Claims 3 to 7, characterised in that said protective layers are coloured.
9. Method according to any one of Claims 1 to 8, characterised in that the application of the various protective layers of differential gloss is performed by at least one discontinuous technique chosen from the group:

- air knife;
- screen-printing application;
- heliographic application;
- flexographic application;
- roller coater.
10. Method according to Claim 9, characterised in that the various protective layers are applied during a manufacturing step that is separate from that of the underlying support (10).
CA2406991A 2000-04-25 2000-10-17 Method for producing floor and wall coverings with differential gloss decoration effect, and resulting products Expired - Fee Related CA2406991C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP00870084A EP1149712A1 (en) 2000-04-25 2000-04-25 Method of producing coatings for floors and walls showing a differential shiny decoration and the product produced by this method
EP00870084.1 2000-04-25
PCT/BE2000/000125 WO2001081102A1 (en) 2000-04-25 2000-10-17 Method for producing floor-finish and wall-finish with differential gloss decoration effect and resulting products

Publications (2)

Publication Number Publication Date
CA2406991A1 true CA2406991A1 (en) 2001-11-01
CA2406991C CA2406991C (en) 2010-08-10

Family

ID=8175736

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2406991A Expired - Fee Related CA2406991C (en) 2000-04-25 2000-10-17 Method for producing floor and wall coverings with differential gloss decoration effect, and resulting products

Country Status (18)

Country Link
EP (2) EP1149712A1 (en)
AT (1) ATE257092T1 (en)
AU (1) AU2001211212A1 (en)
BG (1) BG65622B1 (en)
CA (1) CA2406991C (en)
CZ (1) CZ20023350A3 (en)
DE (1) DE60007560T2 (en)
ES (1) ES2210007T3 (en)
GE (1) GEP20053562B (en)
HR (1) HRP20020806B1 (en)
HU (1) HUP0300597A2 (en)
MX (1) MXPA02010523A (en)
PL (1) PL202221B1 (en)
RS (1) RS49805B (en)
RU (1) RU2249505C2 (en)
SK (1) SK286500B6 (en)
UA (1) UA72043C2 (en)
WO (1) WO2001081102A1 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012175198A1 (en) * 2011-06-24 2012-12-27 Armstrong DLW GmbH Heterogenous linoleum or korkment sheet material
US8394462B2 (en) 2002-10-08 2013-03-12 Scientific Games International, Inc. Methods for applying coating compositions to an article and articles produced thereof
US10059084B2 (en) 2014-07-16 2018-08-28 Valinge Innovation Ab Method to produce a thermoplastic wear resistant foil
US10344379B2 (en) 2010-04-13 2019-07-09 Valinge Innovation Ab Powder overlay
US11141759B2 (en) 2017-06-13 2021-10-12 Hymmen GmbH Maschinen- und Anlagesbas Method and apparatus for producing a decorative surface
US11559824B2 (en) 2019-05-03 2023-01-24 Hymmen Gmbh Maschinen-Und Anlagenbau Method for producing a structure on a surface
US11913226B2 (en) 2015-01-14 2024-02-27 Välinge Innovation AB Method to produce a wear resistant layer with different gloss levels

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US7419716B2 (en) 2003-05-30 2008-09-02 Awi Licensing Company Multiple gloss level surface coverings and method of making
US7364091B2 (en) 2003-12-19 2008-04-29 Scientific Games International, Inc. Embedded optical signatures in documents
AU2005302662B2 (en) 2004-10-28 2010-12-16 Scientific Games Holdings Limited Lottery game played on a geometric figure using indicia with variable point values
WO2006074423A2 (en) 2005-01-07 2006-07-13 Scientific Games International, Inc. Lottery game utilizing nostalgic game themes
US7662038B2 (en) 2005-01-07 2010-02-16 Scientific Games International, Inc. Multi-matrix lottery
KR20070103442A (en) 2005-01-11 2007-10-23 사이언티픽 게임스 인터내셔널, 아이엔씨. On-line lottery game in which supplemental lottery-selected indicia are available for purchase
US8262453B2 (en) 2005-02-09 2012-09-11 Scientific Games International, Inc. Combination lottery and raffle game
US7874902B2 (en) 2005-03-23 2011-01-25 Scientific Games International. Inc. Computer-implemented simulated card game
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CN1903532B (en) * 2006-08-14 2010-05-12 徐建国 Method for producing multiple color ancient-imitation wood floorings
EP2080629A3 (en) 2007-07-04 2011-11-30 debolon dessauer bodenbeläge GmbH & Co. KG Method for manufacturing a decorative, elastic floor coating and floor coating
BE1018156A3 (en) * 2008-05-20 2010-06-01 Flooring Ind Ltd Sarl METHOD FOR MANUFACTURING COATED PANELS AND COATED PANEL.
DE102009004482B4 (en) * 2009-01-09 2012-03-29 Fritz Egger Gmbh & Co. Component made of wood-based material with imprinted décor and varying degrees of gloss
EP2221190A1 (en) 2009-02-23 2010-08-25 Tarkett GDL Flooring
US8460081B2 (en) 2010-05-14 2013-06-11 Scientific Games International, Inc. Grid-based multi-lottery game and associated method
US8808080B2 (en) 2010-05-14 2014-08-19 Scientific Games International, Inc. Grid-based lottery game and associated method
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CN108691401A (en) * 2017-03-08 2018-10-23 天津奇才科技发展有限公司 A kind of UV fluorine carbon plate
PL3415318T3 (en) * 2017-06-13 2020-08-24 Hymmen GmbH Maschinen- und Anlagenbau Workpiece and method and device for forming a decorative workpiece
PL3415317T5 (en) * 2017-06-13 2023-11-27 Hymmen GmbH Maschinen- und Anlagenbau Method and device for producing a decorative surface

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8394462B2 (en) 2002-10-08 2013-03-12 Scientific Games International, Inc. Methods for applying coating compositions to an article and articles produced thereof
US10344379B2 (en) 2010-04-13 2019-07-09 Valinge Innovation Ab Powder overlay
WO2012175198A1 (en) * 2011-06-24 2012-12-27 Armstrong DLW GmbH Heterogenous linoleum or korkment sheet material
US11820112B2 (en) 2014-07-16 2023-11-21 Välinge Innovation AB Method to produce a thermoplastic wear resistant foil
US10059084B2 (en) 2014-07-16 2018-08-28 Valinge Innovation Ab Method to produce a thermoplastic wear resistant foil
US10493731B2 (en) 2014-07-16 2019-12-03 Valinge Innovation Ab Method to produce a thermoplastic wear resistant foil
US10780676B2 (en) 2014-07-16 2020-09-22 Valinge Innovation Ab Method to produce a thermoplastic wear resistant foil
US11376824B2 (en) 2014-07-16 2022-07-05 Valinge Innovation Ab Method to produce a thermoplastic wear resistant foil
US11913226B2 (en) 2015-01-14 2024-02-27 Välinge Innovation AB Method to produce a wear resistant layer with different gloss levels
US11420229B2 (en) 2017-06-13 2022-08-23 Hymmen GmbH Maschinen—und Anlagenbau Method and apparatus for producing a decorative surface
US11717850B2 (en) 2017-06-13 2023-08-08 Hymmen Gmbh Maschinen-Und Anlagenbau Method and apparatus for producing a decorative workpiece and workpiece
US11717851B2 (en) 2017-06-13 2023-08-08 Hymmen GmbH Maschinen—und Anlagenbau Method and apparatus for producing a decorative workpiece and workpiece
US11511318B2 (en) 2017-06-13 2022-11-29 Hymmen GmbH Maschinen- und Anlagenbau Method and apparatus for producing a decorative workpiece and workpiece
US11883843B2 (en) 2017-06-13 2024-01-30 Hymmen Gmbh Maschinen-Und Anlagenbau Method for producing a structured surface
US11141759B2 (en) 2017-06-13 2021-10-12 Hymmen GmbH Maschinen- und Anlagesbas Method and apparatus for producing a decorative surface
US12090511B2 (en) 2017-06-13 2024-09-17 Hymmen GmbH Maschinen—und Anlagenbau Method and apparatus for producing a decorative surface
US11559824B2 (en) 2019-05-03 2023-01-24 Hymmen Gmbh Maschinen-Und Anlagenbau Method for producing a structure on a surface

Also Published As

Publication number Publication date
DE60007560T2 (en) 2004-12-16
AU2001211212A1 (en) 2001-11-07
HRP20020806A2 (en) 2005-10-31
EP1276621B1 (en) 2004-01-02
PL358056A1 (en) 2004-08-09
UA72043C2 (en) 2005-01-17
CZ20023350A3 (en) 2003-04-16
WO2001081102A1 (en) 2001-11-01
BG65622B1 (en) 2009-03-31
HUP0300597A2 (en) 2007-12-28
EP1149712A1 (en) 2001-10-31
CA2406991C (en) 2010-08-10
YU80002A (en) 2003-10-31
BG107280A (en) 2003-07-31
SK14672002A3 (en) 2003-06-03
MXPA02010523A (en) 2003-03-10
GEP20053562B (en) 2005-07-11
EP1276621A1 (en) 2003-01-22
DE60007560D1 (en) 2004-02-05
ES2210007T3 (en) 2004-07-01
HRP20020806B1 (en) 2009-12-31
RU2249505C2 (en) 2005-04-10
PL202221B1 (en) 2009-06-30
RS49805B (en) 2008-06-05
SK286500B6 (en) 2008-11-06
ATE257092T1 (en) 2004-01-15

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