CA2362609A1 - Microwave-transparent thermosetting resin compositions, electrical laminates obtained therefrom, and process of producing these - Google Patents
Microwave-transparent thermosetting resin compositions, electrical laminates obtained therefrom, and process of producing these Download PDFInfo
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- CA2362609A1 CA2362609A1 CA002362609A CA2362609A CA2362609A1 CA 2362609 A1 CA2362609 A1 CA 2362609A1 CA 002362609 A CA002362609 A CA 002362609A CA 2362609 A CA2362609 A CA 2362609A CA 2362609 A1 CA2362609 A1 CA 2362609A1
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- styrene
- organic residue
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C08L75/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/08—Impregnating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/067—Polyurethanes; Polyureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/032—Organic insulating material consisting of one material
- H05K1/0346—Organic insulating material consisting of one material containing N
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/202—Conductive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
- B32B2311/02—Noble metals
- B32B2311/04—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
- B32B2311/02—Noble metals
- B32B2311/08—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
- B32B2311/12—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
- B32B2311/24—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2375/00—Polyureas; Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/08—PCBs, i.e. printed circuit boards
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/24—Thermosetting resins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Laminated Bodies (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The present invention relates to a thermosetting resin composition with excellent electrical properties comprising (a) one or more terminally unsaturated urethane resins, (b) styrene, and (c) brominated styrene. The aforementioned composition finds great utility as a printed circuit board laminate suitable for use at microwave frequencies.
Description
MICROWA~IE-TRANSPARENT THERMOSETTING RESIN
COMPOSITIONS, ELECTRICAL LAMINATES OBTAINED THEREFROM, AND PROCESS OF PRODUCING THESE
BACKGROUND OF THE INVENTION
This is a regular application based on Provisional Application No. 60/032,288 filed December 3, 1996 and pursuant to 37 C.F.R. 1.53(b) this application claims the benefit of the filing date of same. The entire specification of Provisional Application No. 60/032,288 is herein incorporated by reference.
to FIELD OF THE INVENTION
The present invention relates to thermosetting resin compositions with excellent electrical properties; electrical laminates made therefrom; and methods of producing these.
BACKGROUND OF THE INVENTION
i5 All publications and patent applications herein are incorporated by reference to the same extent as if each individual publication or patent application was specifically and individually indicated to be incorporated by reference.
Electrical laminates such as circuit boards are produced by Zo laminating sheets of electrical conducting material onto a base substrate of insulation material. The performance of the finished circuit board is effected by the electrical characteristics of the base substrate material.
Commercially available thermoset resin systems with acceptable electrical performance at high frequencies (> 350 MHZ) are restricted in 25 their applications due to high cost. The lower cost alternatives that are available do not perform satisfactorily at high frequencies due to unacceptable electrical properties, such as high dielectric constant (Dk), high dissipation factor (Df), high variability of Dk and D, with frequency, and consistency of Dk and Df from lot to lot of production material.
3o Thermoplastic polymers such as polytetrafluoroethylene (PTFE) which have exceptional electrical performance at high frequencies are commercially available. The primary drawbacks associated with these materials are very high raw material costs and special processing considerations that add substantial cost to the final product. Because of the physical properties, very high laminating temperatures and pressures are also required to fabricate an electrical laminate from PTFE.
Furthermore, due to the inability to "wet" PTFE, costly and hazardous chemicals are required to modify its surface during fabrication of the circuit.
A thermoset material would have much greater mechanical io properties over a much broader temperature range. Additionally, since thermoset materials have better mechanical properties, this would allow the circuit board fabricator to use conventional cost effective processes.
A need exists for thermosetting resin compositions, and electrical laminates made therefrom, of low to moderate cost with acceptable electrical properties at frequencies up to at least 20 GHz. Such compositions would have great utility as circuit board substrates and the laminates made from these thermosetting resins can be utilized in many applications such as in the rapidly growing wireless communication market, in high speed computers, in high definition televisions, and in 2o various other electrical and related applications.
SUMMARY OF THE INVENTION
An object of the present invention is to provide a thermosetting resin composition which can be made flame retardant and which can be utilized in existing cost effective technologies to manufacture electrical laminates therefrom. Additionally, the present invention resin compositions can have utility as, for example, electrical insulators, encapsulants, insulating adhesives and in various other electrical and related applications generally know to those skilled in this art.
Accordingly, the present invention provides a thermosetting resin 3o composition comprising (a) a terminally unsaturated urethane resin selected from the group of 1 ):
_2_ O
~ ~i 11~ ~.-, ~ ~-~.,-C_.~-C,-I~.H R
nm.~-~,g where R, is H or CH3, RZ is an organic residue from a monohydric s alcohol and R3 is an organic residue from a diisocyanate;
and 2):
li HOC-' _ (~'-R ~-~~-C-NH-R~ R:~
rl=~-3 where R, is H or CH3, RZ is an organic residue from a monohydric alcohol, R3 is an organic residue from a diisocyanate, and R4 is an io isocyanurate compound of the following structure;
O
\N / \ N /
p \ N/C~O
and (b) an ethylenically unsaturated monomer from the group of 1) styrene and 2) bromostyrene with the following structures:
II
I I C=C.'H=
/ C'-CI I=
/ <
_ ( J3r]m Styrene Bromostyrene where m = 1 to 3.
Additionally, to achieve the desired properties (i.e., microwave transparency, fire retardation, and good thermal performance) the ratio of (a) to the sum of (b) 1 ) and (b)2) is less than 0.15, and the ratio of (b) 1 ) to io (b)2) is less than 1.2.
The composition resins may also further contain monomers which would, for example, aid in the adhesion of a metal foil to the laminate;
increase crosslink density and thermal performance; etc. Catalysts which, for example, induce free-radical cure may also be added. Other i 5 components may include moisture scavengers, compounds which increase or reduce the dielectric constant, and/or reduce the dissipation factor, polyethylene fillers, other fillers, organic or inorganic, which modify rheology, surface agents, viscosity and performance modifiers, wetting agents, air release agents, defoaming agents, flame retardant synergists, 2o adhesion promoters, and other additional monomers and conventional additives known in the art.
Other objects of the present invention are to provide electrical laminates, and methods for producing these laminates containing the composition resins of the present invention, which have excellent electrical properties and which may be flame retardant or heat resistant.
Accordingly, the present invention further provides electrical laminates from about 0.003 inches to about 0.120 inches thick which may or may not be clad with an electrical conducting material on one or both sides.
s The electrical laminates of the present invention are produced by (a) continuous lamination or (b) a batch process:
(a) The compositions of the present invention are uniquely suitable to the continuous lamination methods of Barrel et al. (U.S. Patent No.
4,587,161 and No. 4,803,022). The combination of materials in the lc outlined ratios provides lower viscosities then previous compositions, (U.S. Patent No. 4,420,509 and No. 4,446,173). Lower viscosities provide more rapid impregnation of reinforcements to allow higher line-speeds and consequently higher machine output. In the continuous lamination process, the desired composition is formulated with a free-radical source, i5 (i.e., peroxide, azo-compound, etc.) to initiate cure. Optionally, the material is postcured in a batch convection oven to further lower the dissipation factor of the laminate. Therefore, we have found the combination of continuous lamination with additional batch cure provides unexpected improvements in electrical performance. While the ao continuous lamination temperatures and times are known in the art, we have found the optimum secondary batch oven cure profile to be 350°F
for 1 hour dwell, (or range from 150°F for 3 hours to 450°F for 30 minutes).
(b) The method to manufacture the laminate with a batch process involves 25 1) A layer of carrier film, such as polyethylene terephthalate of 1.42 mills thick, was placed on a 1/4th inch thick glass plate of 1.25 by 1.25 ft. The dimensions of the film were large enough to protrude around the edges of the glass plate.
COMPOSITIONS, ELECTRICAL LAMINATES OBTAINED THEREFROM, AND PROCESS OF PRODUCING THESE
BACKGROUND OF THE INVENTION
This is a regular application based on Provisional Application No. 60/032,288 filed December 3, 1996 and pursuant to 37 C.F.R. 1.53(b) this application claims the benefit of the filing date of same. The entire specification of Provisional Application No. 60/032,288 is herein incorporated by reference.
to FIELD OF THE INVENTION
The present invention relates to thermosetting resin compositions with excellent electrical properties; electrical laminates made therefrom; and methods of producing these.
BACKGROUND OF THE INVENTION
i5 All publications and patent applications herein are incorporated by reference to the same extent as if each individual publication or patent application was specifically and individually indicated to be incorporated by reference.
Electrical laminates such as circuit boards are produced by Zo laminating sheets of electrical conducting material onto a base substrate of insulation material. The performance of the finished circuit board is effected by the electrical characteristics of the base substrate material.
Commercially available thermoset resin systems with acceptable electrical performance at high frequencies (> 350 MHZ) are restricted in 25 their applications due to high cost. The lower cost alternatives that are available do not perform satisfactorily at high frequencies due to unacceptable electrical properties, such as high dielectric constant (Dk), high dissipation factor (Df), high variability of Dk and D, with frequency, and consistency of Dk and Df from lot to lot of production material.
3o Thermoplastic polymers such as polytetrafluoroethylene (PTFE) which have exceptional electrical performance at high frequencies are commercially available. The primary drawbacks associated with these materials are very high raw material costs and special processing considerations that add substantial cost to the final product. Because of the physical properties, very high laminating temperatures and pressures are also required to fabricate an electrical laminate from PTFE.
Furthermore, due to the inability to "wet" PTFE, costly and hazardous chemicals are required to modify its surface during fabrication of the circuit.
A thermoset material would have much greater mechanical io properties over a much broader temperature range. Additionally, since thermoset materials have better mechanical properties, this would allow the circuit board fabricator to use conventional cost effective processes.
A need exists for thermosetting resin compositions, and electrical laminates made therefrom, of low to moderate cost with acceptable electrical properties at frequencies up to at least 20 GHz. Such compositions would have great utility as circuit board substrates and the laminates made from these thermosetting resins can be utilized in many applications such as in the rapidly growing wireless communication market, in high speed computers, in high definition televisions, and in 2o various other electrical and related applications.
SUMMARY OF THE INVENTION
An object of the present invention is to provide a thermosetting resin composition which can be made flame retardant and which can be utilized in existing cost effective technologies to manufacture electrical laminates therefrom. Additionally, the present invention resin compositions can have utility as, for example, electrical insulators, encapsulants, insulating adhesives and in various other electrical and related applications generally know to those skilled in this art.
Accordingly, the present invention provides a thermosetting resin 3o composition comprising (a) a terminally unsaturated urethane resin selected from the group of 1 ):
_2_ O
~ ~i 11~ ~.-, ~ ~-~.,-C_.~-C,-I~.H R
nm.~-~,g where R, is H or CH3, RZ is an organic residue from a monohydric s alcohol and R3 is an organic residue from a diisocyanate;
and 2):
li HOC-' _ (~'-R ~-~~-C-NH-R~ R:~
rl=~-3 where R, is H or CH3, RZ is an organic residue from a monohydric alcohol, R3 is an organic residue from a diisocyanate, and R4 is an io isocyanurate compound of the following structure;
O
\N / \ N /
p \ N/C~O
and (b) an ethylenically unsaturated monomer from the group of 1) styrene and 2) bromostyrene with the following structures:
II
I I C=C.'H=
/ C'-CI I=
/ <
_ ( J3r]m Styrene Bromostyrene where m = 1 to 3.
Additionally, to achieve the desired properties (i.e., microwave transparency, fire retardation, and good thermal performance) the ratio of (a) to the sum of (b) 1 ) and (b)2) is less than 0.15, and the ratio of (b) 1 ) to io (b)2) is less than 1.2.
The composition resins may also further contain monomers which would, for example, aid in the adhesion of a metal foil to the laminate;
increase crosslink density and thermal performance; etc. Catalysts which, for example, induce free-radical cure may also be added. Other i 5 components may include moisture scavengers, compounds which increase or reduce the dielectric constant, and/or reduce the dissipation factor, polyethylene fillers, other fillers, organic or inorganic, which modify rheology, surface agents, viscosity and performance modifiers, wetting agents, air release agents, defoaming agents, flame retardant synergists, 2o adhesion promoters, and other additional monomers and conventional additives known in the art.
Other objects of the present invention are to provide electrical laminates, and methods for producing these laminates containing the composition resins of the present invention, which have excellent electrical properties and which may be flame retardant or heat resistant.
Accordingly, the present invention further provides electrical laminates from about 0.003 inches to about 0.120 inches thick which may or may not be clad with an electrical conducting material on one or both sides.
s The electrical laminates of the present invention are produced by (a) continuous lamination or (b) a batch process:
(a) The compositions of the present invention are uniquely suitable to the continuous lamination methods of Barrel et al. (U.S. Patent No.
4,587,161 and No. 4,803,022). The combination of materials in the lc outlined ratios provides lower viscosities then previous compositions, (U.S. Patent No. 4,420,509 and No. 4,446,173). Lower viscosities provide more rapid impregnation of reinforcements to allow higher line-speeds and consequently higher machine output. In the continuous lamination process, the desired composition is formulated with a free-radical source, i5 (i.e., peroxide, azo-compound, etc.) to initiate cure. Optionally, the material is postcured in a batch convection oven to further lower the dissipation factor of the laminate. Therefore, we have found the combination of continuous lamination with additional batch cure provides unexpected improvements in electrical performance. While the ao continuous lamination temperatures and times are known in the art, we have found the optimum secondary batch oven cure profile to be 350°F
for 1 hour dwell, (or range from 150°F for 3 hours to 450°F for 30 minutes).
(b) The method to manufacture the laminate with a batch process involves 25 1) A layer of carrier film, such as polyethylene terephthalate of 1.42 mills thick, was placed on a 1/4th inch thick glass plate of 1.25 by 1.25 ft. The dimensions of the film were large enough to protrude around the edges of the glass plate.
2) A one foot square piece of 1 oz. per sq. foot weight of 3o copper foil was placed treatment side up on the carrier film.
3) A film of a resin composition, prepared according to the present invention, was metered onto the copper foil by using a wire-wound rod designed to provide a coating of the target thickness of the laminate.
Wire-wound rods are well known throughout the coatings industry.
Wire-wound rods are well known throughout the coatings industry.
4) A layer of glass cloth, woven or nonwoven, was laid onto the s resin film and allowed to saturate for approximately 2 minutes. If a plurality of layers were used, the layers were placed onto the resin film approximately 2 minutes apart to allow the resin mixture to saturate the glass.
5) An additional layer of copper foil, of the same size and to weight as 2), was placed treatment side down on the laminate so as to align the edges with the first sheet of copper foil.
6) Another layer of carrier film, of the same size and dimensions as 1 ), was placed on top of the copper foil.
7) Two '/Z inch wide by 12 inches long shims of the target is laminate thickness were placed on opposing sides of the laminate, on top of the carrier film, but still on the glass plate.
8) A rod of '/2 inch thick steel was placed on the shims at one edge of the laminate and gently pulled to the opposing edge while being forced by hand to ride on the shims. As the rod moved across the 20 laminate, excess resin composition was allowed to drain out of the laminate.
9) Another plate of glass of equivalent dimensions as 1 ), was placed on top of the laminate.
10) The laminate was placed in a forced air convection oven at 2s 150-250°F for 15 minutes to 1 hour.
11) The laminate, still between the glass plates, was removed from the oven and allowed to cool to room temperature. At this time, the two glass plates and two layers of carrier film were removed.
12) Post cure from 350°F for 1 hour in a forced air convention 30 oven.
The thermosetting resin composition may also further contain the The thermosetting resin composition may also further contain the above mentioned added components and may be cured by electron beam processing, radiation, heat with or without pressure, ultra violet light processing, and other conventional curing methods in conjunction with the s appropriate initiators. The electrical laminates may further comprise an electrical conductive cladding on at least one side.
One skilled in the art can easily make any necessary adjustments in accordance with the necessities of the particular situation.
Further objects and advantages of the present invention will be clear io from the description that follows.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is an enlarged cross-sectional view of a part of an electrical laminate which comprises an electrically conductive metal layer 1 and a cross linked thin-wall body of the invented composition 2.
15 Fig. 2 is an enlarged cross-sectional view of an electrical laminate which exemplifies a double-sided metal clad electrical laminate, further provided with two metal conductive layers 1, and an electrically insulating thin-wall body of the invented composition 2.
Fig. 3 is an enlarged cross-sectional view of an electrical laminate zo which exemplifies a multilayered electrical laminate, of the structure of a combination of single-sided and double sided metal clad electrical laminates as illustrated in Fig. 1 and Fig. 2.
Fig. 4 is an enlarged cross-sectional view of an electrical laminate which comprises an electrically conductive layer 1, a crosslinked thin-wall 25 body of the invented composition 2, and an uniformly dispersed inorganic or organic filler 3.
Fig. 5 is an enlarged cross-sectional view of an electrical laminate which comprises an electrically conductive metal layer 1, a crosslinked thin-wall body of invented composition 2, and nonwoven glass fibers 4.
3o Fig. 6 is an enlarged cross-sectional view of an electrical laminate which comprises an electrically conductive metal layer 1, a crosslinked thin-wall body of invented composition 2, and woven glass cloth 5.
Fig. 7 is an enlarged cross-section view of part of an example of a double-sided metal clad electrical laminate of Fig. 6 further provided with an electrically conductive metal layer 1 on the other surface.
Fig. 8 is an enlarged cross-sectional view of an electrical laminate which comprises an electrically conductive metal layer 1, a crosslinked thin-wall body of the invented composition 2, and an aramid non-woven sheet 6.
DETAILED DESCRIPTION OF THE INVENTION
.o Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention, the preferred i5 methods and materials are described.
The present invention comprises resin compositions of moderate cost with excellent electrical properties up to at least 20 GHz which may be flame retardant and heat resistant. The present compositions have utility as electrical insulators, electrical laminates, electrically insulating ~o encapsulants, electrically insulating adhesives and other electrical and related applications.
One component of these compositions is a terminally unsaturated urethane resin, known in the industry as a urethane vinyl ester:
~L
_ I
7 ~ ~.~-!'~-t )-C
( '1 za= i . )-_.~' where R, is H or CH3, RZ is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate. This resin is _g_ manufactured by reacting a diisocyanate with two molar equivalents of monohydric alcohol containing a vinylidene group in the presence of a polar solvent (typically styrene) which also acts as a reactive monomer for crosslinking. Examples of this art are well known throughout the industry.
s The diisocyanate utilized may be aromatic or aliphatic, monomeric or polymeric, etc. The only requirements are that the diisocyanate contain isocyanate groups capable of reacting with the monohydric alcohol and not interfere with the subsequent crosslinking reactions. Examples of the diisocyanate are 2,4 toluene diisocyanate, 2,6 toluene diisocyanate, 2,4'-lo diphenylmethane diisocyanate, and 2,6'-diphenyl methane diisocynate.
Examples of the monohydric alcohol that contains a vinylidene group are hydroxyethyl methacrylate, hydroxyethyl acrylate, hydroxypropyl methacrylate, and hydroxypropyl acrylate.
Another component of these compositions is a terminally 15 unsaturated urethane resin, known in the industry as an isocyanurate vinyl ester:
Rl O
HC = C'.-F~.~-C)-C-'~H-R_~ R:~
Il=~' -~
_g_ where R, is H or CH3, RZ is an organic residue from a monohydric alcohol, R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure;
w i~~ i N N
c c.
o~ w ~/ ~o s I
This resin is manufactured by the methods of Kuehn et al. (U.S.
Patent No. 4,145,544 and No. 4,243,788). For examples of these resins refer to the aforementioned patents.
It has been found that a combination of one or more of these resins to with styrene and dibromostyrene in certain ratios will yield a composition with excellent properties suitable as a matrix resin for high frequency electrical applications. The main embodiment thereof, is a printed circuit board laminate suitable for microwave antennas and the like. The preferred ratio for terminally unsaturated urethane resin to ethylenically is unsaturated monomer has been determined to be less than 0.15. Or in the case where 1 mole of 2,4'-toluene diisocyanate is reacted with 2 moles of hydroxylpropyl methacrylate, less than 27% by weight of this resin (without monomer) is desired in ethylenically unsaturated monomer. In the case where an isocyanurate vinyl ester is manufactured from the same 2o materials in different ratios, less than about 35% by weight of resin (without monomer) is desired in ethylenically unsaturated monomer.
One skilled in the art can readily obtain the aforementioned ratios from molecular weight and weight percent information. Examples 2 & 3 of TABLE 1 contain a urethane modified vinyl ester with a molecular weight 25 Of approximately 4200, styrene monomer of molecular weight 104.15, and dibromostryene of average molecular weight 263.95. Using this information, the ratios of urethane modified vinyl ester to total monomer would be 0.01 and 0.02 for Examples 2 & 3 respectively. Additionally, the ratio of styrene to dibromostyrene would be 0.50, and 1.16 for Examples 2 & 3 respectively.
The second main component of these compositions is an ethylenically unsaturated monomer from the group of 1) styrene and 2) bromostyrene. Examples of bromostyrene include monobromostyrene, dibromostyrene, and tribromostyrene. Additionally, the ideal molar ratio of styrene to bromostyrene has been found to be less than 1.2. Maintaining the desired ratios provides a composition with excellent electrical io properties at microwave frequencies along with desirable thermal and mechanical properties.
An optional component may be divinyl benzene (referred herein as DVB), or any other ethylenically multiunsaturated monomer. DVB can be about 0.1 % to about 10% by weight; preferably about 0.5% to about 5%
by weight of the total composition; more preferably about 1 % to about 4%
- by weight of the total composition and most preferably about 2.5% by weight of the total composition. Divinyl benzene increases the crosslink density and therefore thermal performance of the composition. Other polyfunctional crosslinking monomers may also be used such as divinyl 2o toluene and the like.
The third and fourth components contribute to the mechanical and thermal properties of a composition but do not need to be present to obtain the excellent electrical properties.
Catalysts and polymerization and U.V. initiators may also be 2s components of the compositions of the present invention. There are many choices available; particularly, catalyst which induce free-radical cure. The preferred catalyst is t-butyl peroctoate at about 0.1 to about 2% by weight of the total composition (preferably about 0.2% by weight of the total composition); benzoate at about 0.1 to about 2% by weight of the total 3o composition (preferably 0.25% by weight of the total composition).
Alternate catalysts include benzoyl peroxide, cumene hydrogen peroxide and others known to those skilled in this art. Combination of catalysts may also be used. Curing mechanisms may be utilized including electron beam processing and ultra-violet light processing in conjunction with UV
initiators, radiation, heating with or without pressure, and other conventional curing methods in conjunction with the appropriate initiators.
Additional components, such as moisture scavengers may also be added. Free moisture in the composition will negatively affect the dissipation factor. Therefore a component, such as 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine (available from Angus Chemical Co.) can be o added to minimize the free water in the composition. The oxazolidine compound will chemically react with the water to eliminate it. Alternately, a molecular sieve could be utilized. Molecular sieves are well known as moisture reducers throughout the coatings industry. Molecular sieves function by physically trapping the free water.
~s Another additional component may be titanium dioxide which increases the dielectric constant, but reduces the dissipation factor. This combination of electrical properties is desirable for some specific high frequency applications. The titanium dioxide may be in a range of from about 1 to about 60% by weight of the total composition; preferably about to about 40% by weight of the total composition; more preferably about 25% by weight of the total composition.
Another component which may be added is polyethylene filler, (such as expanded polyethylene compound, available from American Fillers and Abrasives). The polyethylene will lower both the dielectric constant and dissipation factor. The polyethylene may be in a range of from about 1 to about 60% by weight of the total composition; preferably about 5 to about 40% by weight of the total composition; more preferably about 10% by weight of the total composition.
Other optional additives include organic and/or inorganic fillers, for ~o example, calcined kaolin, to modify rheology; surface active agents, to aid processing; other monomers, such as methyl methacrylate to modify viscosity and possibly performance; epoxies; colorants; fluorescent dyes;
U.V. blocking agents; wetting agents; air release agents; defoaming agents; flame retardant synergists (for example, antimony compounds);
adhesion promoters (for example, epoxy resin "EPON 828" Shell s Chemical Co.); additional monomers including styrene, vinyl toluene, t-butyl styrene, para-methyl styrene, diallyl phthalate, 2,4-ethyl-methyl imidazole, and other conventional additives.
The present invention further comprises electrical laminates utilizing the thermosetting resin compositions herein described which have io excellent electrical properties and which may be flame retardant and heat resistant. The present thermosetting resin compositions can also be utilized in existing cost effective technologies to manufacture various types of electrical laminates. Examples of these technologies include, but are not limited to, continuous lamination, such as that described in U.S.
i5 Patent No. 4,803,022 to Barell et al. which is incorporated herein by reference; production of printed circuit boards, such as described in U.S.
Patents Nos. 4,671,984 and 4,751,146 to Masahiko Maeda et al. which are incorporated herein by reference; production of electrical laminates such as described in U.S. Patent No. 4,336,297 to Yasuo Fushiki et al.
2o and U.S. Patent No. 5,009,949 to Kazuyuki Tanaka et al. which are both incorporated herein by reference; continuous belt press lamination, such as the equipment offered by GreCon Corp.; and traditional press or vacuum press lamination.
An electrical laminate of the present invention is produced by 25 infiltrating or impregnating at least one substrate, or multiple substrates, with a resin composition of the present invention to prepare resin-infiltrated or resin-impregnated substrates which are laminated by passage between rolls while removing interlaminar gas bubbles.
Subsequently, the resulting laminate is heated, with or without pressure, 3o to cure the resin composition whereby the electrical laminate is obtained.
The thermosetting resin composition may also further contain the The thermosetting resin composition may also further contain the above mentioned added components and may be cured by electron beam processing, radiation, heat with or without pressure, ultra violet light processing, and other conventional curing methods in conjunction with the s appropriate initiators. The electrical laminates may further comprise an electrical conductive cladding on at least one side.
One skilled in the art can easily make any necessary adjustments in accordance with the necessities of the particular situation.
Further objects and advantages of the present invention will be clear io from the description that follows.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is an enlarged cross-sectional view of a part of an electrical laminate which comprises an electrically conductive metal layer 1 and a cross linked thin-wall body of the invented composition 2.
15 Fig. 2 is an enlarged cross-sectional view of an electrical laminate which exemplifies a double-sided metal clad electrical laminate, further provided with two metal conductive layers 1, and an electrically insulating thin-wall body of the invented composition 2.
Fig. 3 is an enlarged cross-sectional view of an electrical laminate zo which exemplifies a multilayered electrical laminate, of the structure of a combination of single-sided and double sided metal clad electrical laminates as illustrated in Fig. 1 and Fig. 2.
Fig. 4 is an enlarged cross-sectional view of an electrical laminate which comprises an electrically conductive layer 1, a crosslinked thin-wall 25 body of the invented composition 2, and an uniformly dispersed inorganic or organic filler 3.
Fig. 5 is an enlarged cross-sectional view of an electrical laminate which comprises an electrically conductive metal layer 1, a crosslinked thin-wall body of invented composition 2, and nonwoven glass fibers 4.
3o Fig. 6 is an enlarged cross-sectional view of an electrical laminate which comprises an electrically conductive metal layer 1, a crosslinked thin-wall body of invented composition 2, and woven glass cloth 5.
Fig. 7 is an enlarged cross-section view of part of an example of a double-sided metal clad electrical laminate of Fig. 6 further provided with an electrically conductive metal layer 1 on the other surface.
Fig. 8 is an enlarged cross-sectional view of an electrical laminate which comprises an electrically conductive metal layer 1, a crosslinked thin-wall body of the invented composition 2, and an aramid non-woven sheet 6.
DETAILED DESCRIPTION OF THE INVENTION
.o Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention, the preferred i5 methods and materials are described.
The present invention comprises resin compositions of moderate cost with excellent electrical properties up to at least 20 GHz which may be flame retardant and heat resistant. The present compositions have utility as electrical insulators, electrical laminates, electrically insulating ~o encapsulants, electrically insulating adhesives and other electrical and related applications.
One component of these compositions is a terminally unsaturated urethane resin, known in the industry as a urethane vinyl ester:
~L
_ I
7 ~ ~.~-!'~-t )-C
( '1 za= i . )-_.~' where R, is H or CH3, RZ is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate. This resin is _g_ manufactured by reacting a diisocyanate with two molar equivalents of monohydric alcohol containing a vinylidene group in the presence of a polar solvent (typically styrene) which also acts as a reactive monomer for crosslinking. Examples of this art are well known throughout the industry.
s The diisocyanate utilized may be aromatic or aliphatic, monomeric or polymeric, etc. The only requirements are that the diisocyanate contain isocyanate groups capable of reacting with the monohydric alcohol and not interfere with the subsequent crosslinking reactions. Examples of the diisocyanate are 2,4 toluene diisocyanate, 2,6 toluene diisocyanate, 2,4'-lo diphenylmethane diisocyanate, and 2,6'-diphenyl methane diisocynate.
Examples of the monohydric alcohol that contains a vinylidene group are hydroxyethyl methacrylate, hydroxyethyl acrylate, hydroxypropyl methacrylate, and hydroxypropyl acrylate.
Another component of these compositions is a terminally 15 unsaturated urethane resin, known in the industry as an isocyanurate vinyl ester:
Rl O
HC = C'.-F~.~-C)-C-'~H-R_~ R:~
Il=~' -~
_g_ where R, is H or CH3, RZ is an organic residue from a monohydric alcohol, R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure;
w i~~ i N N
c c.
o~ w ~/ ~o s I
This resin is manufactured by the methods of Kuehn et al. (U.S.
Patent No. 4,145,544 and No. 4,243,788). For examples of these resins refer to the aforementioned patents.
It has been found that a combination of one or more of these resins to with styrene and dibromostyrene in certain ratios will yield a composition with excellent properties suitable as a matrix resin for high frequency electrical applications. The main embodiment thereof, is a printed circuit board laminate suitable for microwave antennas and the like. The preferred ratio for terminally unsaturated urethane resin to ethylenically is unsaturated monomer has been determined to be less than 0.15. Or in the case where 1 mole of 2,4'-toluene diisocyanate is reacted with 2 moles of hydroxylpropyl methacrylate, less than 27% by weight of this resin (without monomer) is desired in ethylenically unsaturated monomer. In the case where an isocyanurate vinyl ester is manufactured from the same 2o materials in different ratios, less than about 35% by weight of resin (without monomer) is desired in ethylenically unsaturated monomer.
One skilled in the art can readily obtain the aforementioned ratios from molecular weight and weight percent information. Examples 2 & 3 of TABLE 1 contain a urethane modified vinyl ester with a molecular weight 25 Of approximately 4200, styrene monomer of molecular weight 104.15, and dibromostryene of average molecular weight 263.95. Using this information, the ratios of urethane modified vinyl ester to total monomer would be 0.01 and 0.02 for Examples 2 & 3 respectively. Additionally, the ratio of styrene to dibromostyrene would be 0.50, and 1.16 for Examples 2 & 3 respectively.
The second main component of these compositions is an ethylenically unsaturated monomer from the group of 1) styrene and 2) bromostyrene. Examples of bromostyrene include monobromostyrene, dibromostyrene, and tribromostyrene. Additionally, the ideal molar ratio of styrene to bromostyrene has been found to be less than 1.2. Maintaining the desired ratios provides a composition with excellent electrical io properties at microwave frequencies along with desirable thermal and mechanical properties.
An optional component may be divinyl benzene (referred herein as DVB), or any other ethylenically multiunsaturated monomer. DVB can be about 0.1 % to about 10% by weight; preferably about 0.5% to about 5%
by weight of the total composition; more preferably about 1 % to about 4%
- by weight of the total composition and most preferably about 2.5% by weight of the total composition. Divinyl benzene increases the crosslink density and therefore thermal performance of the composition. Other polyfunctional crosslinking monomers may also be used such as divinyl 2o toluene and the like.
The third and fourth components contribute to the mechanical and thermal properties of a composition but do not need to be present to obtain the excellent electrical properties.
Catalysts and polymerization and U.V. initiators may also be 2s components of the compositions of the present invention. There are many choices available; particularly, catalyst which induce free-radical cure. The preferred catalyst is t-butyl peroctoate at about 0.1 to about 2% by weight of the total composition (preferably about 0.2% by weight of the total composition); benzoate at about 0.1 to about 2% by weight of the total 3o composition (preferably 0.25% by weight of the total composition).
Alternate catalysts include benzoyl peroxide, cumene hydrogen peroxide and others known to those skilled in this art. Combination of catalysts may also be used. Curing mechanisms may be utilized including electron beam processing and ultra-violet light processing in conjunction with UV
initiators, radiation, heating with or without pressure, and other conventional curing methods in conjunction with the appropriate initiators.
Additional components, such as moisture scavengers may also be added. Free moisture in the composition will negatively affect the dissipation factor. Therefore a component, such as 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine (available from Angus Chemical Co.) can be o added to minimize the free water in the composition. The oxazolidine compound will chemically react with the water to eliminate it. Alternately, a molecular sieve could be utilized. Molecular sieves are well known as moisture reducers throughout the coatings industry. Molecular sieves function by physically trapping the free water.
~s Another additional component may be titanium dioxide which increases the dielectric constant, but reduces the dissipation factor. This combination of electrical properties is desirable for some specific high frequency applications. The titanium dioxide may be in a range of from about 1 to about 60% by weight of the total composition; preferably about to about 40% by weight of the total composition; more preferably about 25% by weight of the total composition.
Another component which may be added is polyethylene filler, (such as expanded polyethylene compound, available from American Fillers and Abrasives). The polyethylene will lower both the dielectric constant and dissipation factor. The polyethylene may be in a range of from about 1 to about 60% by weight of the total composition; preferably about 5 to about 40% by weight of the total composition; more preferably about 10% by weight of the total composition.
Other optional additives include organic and/or inorganic fillers, for ~o example, calcined kaolin, to modify rheology; surface active agents, to aid processing; other monomers, such as methyl methacrylate to modify viscosity and possibly performance; epoxies; colorants; fluorescent dyes;
U.V. blocking agents; wetting agents; air release agents; defoaming agents; flame retardant synergists (for example, antimony compounds);
adhesion promoters (for example, epoxy resin "EPON 828" Shell s Chemical Co.); additional monomers including styrene, vinyl toluene, t-butyl styrene, para-methyl styrene, diallyl phthalate, 2,4-ethyl-methyl imidazole, and other conventional additives.
The present invention further comprises electrical laminates utilizing the thermosetting resin compositions herein described which have io excellent electrical properties and which may be flame retardant and heat resistant. The present thermosetting resin compositions can also be utilized in existing cost effective technologies to manufacture various types of electrical laminates. Examples of these technologies include, but are not limited to, continuous lamination, such as that described in U.S.
i5 Patent No. 4,803,022 to Barell et al. which is incorporated herein by reference; production of printed circuit boards, such as described in U.S.
Patents Nos. 4,671,984 and 4,751,146 to Masahiko Maeda et al. which are incorporated herein by reference; production of electrical laminates such as described in U.S. Patent No. 4,336,297 to Yasuo Fushiki et al.
2o and U.S. Patent No. 5,009,949 to Kazuyuki Tanaka et al. which are both incorporated herein by reference; continuous belt press lamination, such as the equipment offered by GreCon Corp.; and traditional press or vacuum press lamination.
An electrical laminate of the present invention is produced by 25 infiltrating or impregnating at least one substrate, or multiple substrates, with a resin composition of the present invention to prepare resin-infiltrated or resin-impregnated substrates which are laminated by passage between rolls while removing interlaminar gas bubbles.
Subsequently, the resulting laminate is heated, with or without pressure, 3o to cure the resin composition whereby the electrical laminate is obtained.
Other cure mechanisms can also be utilized. The electrical laminate of this invention can be continuously produced.
For curing the resin composition, organic peroxides can be used as curing catalysts. The organic peroxides include, for example, t-butyl s perbenzoate, t-butyl peroxide, benzoyl peroxide, t-butyl peroctoate, t-butyl peroxy benzoate, dicumyl peroxide, etc. If necessary, the curing can be controlled by use of curing accelerators or polymerization inhibitors.
Characteristics of the resin composition can be improved by incorporating therein to plasticizers, stabilizers, thickeners, fillers, coloring agents, io lubricants, etc.
A copper-clad laminate can be obtained by subjecting substrates impregnated with an uncured resin composition and copper foil to laminated molding to unite them in a body, or by inserting an adhesive between substrates impregnated with an uncured resin and copper foil i5 and then subjecting them to laminated molding to unite them in a body. A.
copper-clad laminate can be obtained by also preparing a laminate by laminate molding and then unite this laminate and a copper foil laminate in a body through an adhesive. Adhesives such as epoxy resins, butyryl-modified epoxy resins, etc. can be used.
Zo The present electrical laminates may be from about 0.001 to about 0.25 inches thick and may be metal clad on one or both sides or not clad in metal. A preferred embodiment is about 0.002 to about 0.20 inches thick. A more preferred embodiment is about 0.003 to about 0.120 inches thick.
2s Suitable cladding metals include aluminum, silver, gold, brass and most preferably copper. The metal cladding may be in various forms and weight. The weight may range from about 0.25 to about 5 oz/ft2 The form can be any conventional type, such as, foil, an electrodeposited layer or rolled annealed metal, such as for example, rolled annealed copper.
3o A preferred embodiment comprises a copper clad electrical laminate suitable for subsequent processing as a circuit board, stripline, microstripline microwave components and other related applications. The preferred embodiment of this composition is an electrical laminate from 0.003 to 0.120 inches thick with metal foil clad on one or both sides.
Suitable reinforcement components include organic or inorganic s fillers, woven fiberglass, glass paper, glass mat, glass cloth, polyimide paper (such as "THERMOUNT" from DuPont), woven polymeric fibers and non-woven polymer fiber reinforcements and the like. The reinforcement components of the laminates of the present invention may be in the range of about 25% to 75% by weight of the total laminate, preferably about 30%
i o tQ about 40%, and more preferably about 35%.
The performance of this composition differs from similar materials mainly in electrical performance. These properties, especially dissipation factor, are very important when considering high frequency applications.
Typical electrical properties of an 0.030" thick laminate of approximate i5 20% (by weight) of fiberglass reinforcement are:
Frequency (GHz): 2.5 10.0 Dielectric constant: 3.20 3.22 Dissipation factor: 0.0031 0.0048 2o The electrical properties of the same laminate at 1 MHZ are:
Dielectric constant: 3.20 Dissipation factor: 0.0029 The above data shows the consistency of the dielectric constant and 25 dissipation factor of a laminate comprising the inventive compositions across a wide range of frequencies. This feature is highly desirable for compositions utilized as dielectric materials.
This embodiment of the present invention is clearly superior in electrical properties over presently available compositions.
3o The invention will be further clarified by a consideration of the following examples which are to be considered as illustrative of the present invention. It should be understood that the invention is not limited to the specific details of the examples.
EXAMPLES
The unsaturated urethane resins are manufactured according to U.S.
Patent Nos. 4,587,161 and 4,803,022 of Kuehn et al., manufactured according to methods known in the art, or commercially available as Palatal 48001 KR (BASF, Germany) or 580-05 (Reichold Chemicals Inc., USA) in the case of a urethane vinyl ester, and as ITP 1041 and ITP 1070 (Reichold Chemicals Inc., USA), in the case of a isocyanurate vinyl ester.
i~ The ethylenically unsaturated monomers styrene and dibromonostyrene are commercially available.
The general method of preparing the resin compositions is as follows.
1) The ingredients, (listed in TABLE 1), are added to a mixing 1 s vessel.
2) The ingredients are mixed for 5 to 15 minutes with a Cowles dissolver operating at high shear, about 100 to 500 rpm), at room temperature. Higher shear rates may be used, but could entrain air.
Optionally, the mixture could be degassed in a vacuum (25 -29 ~o inches of Hg).
3) At this point, the composition is ready for use. The typical cure schedule for the thermoset resin is:
a. 20 minutes at 210 degrees F, optionally up to 225 degrees F. Temperatures greater than 250°F produce 25 undesirable reactions during cure and yield poor quality product. Lower temperatures than 210°F may be used with longer times.
b. Depending upon the desired product, a post-cure is often necessary to optimize the electrical properties.
3o One to three hours at 350°F is preferred.
For curing the resin composition, organic peroxides can be used as curing catalysts. The organic peroxides include, for example, t-butyl s perbenzoate, t-butyl peroxide, benzoyl peroxide, t-butyl peroctoate, t-butyl peroxy benzoate, dicumyl peroxide, etc. If necessary, the curing can be controlled by use of curing accelerators or polymerization inhibitors.
Characteristics of the resin composition can be improved by incorporating therein to plasticizers, stabilizers, thickeners, fillers, coloring agents, io lubricants, etc.
A copper-clad laminate can be obtained by subjecting substrates impregnated with an uncured resin composition and copper foil to laminated molding to unite them in a body, or by inserting an adhesive between substrates impregnated with an uncured resin and copper foil i5 and then subjecting them to laminated molding to unite them in a body. A.
copper-clad laminate can be obtained by also preparing a laminate by laminate molding and then unite this laminate and a copper foil laminate in a body through an adhesive. Adhesives such as epoxy resins, butyryl-modified epoxy resins, etc. can be used.
Zo The present electrical laminates may be from about 0.001 to about 0.25 inches thick and may be metal clad on one or both sides or not clad in metal. A preferred embodiment is about 0.002 to about 0.20 inches thick. A more preferred embodiment is about 0.003 to about 0.120 inches thick.
2s Suitable cladding metals include aluminum, silver, gold, brass and most preferably copper. The metal cladding may be in various forms and weight. The weight may range from about 0.25 to about 5 oz/ft2 The form can be any conventional type, such as, foil, an electrodeposited layer or rolled annealed metal, such as for example, rolled annealed copper.
3o A preferred embodiment comprises a copper clad electrical laminate suitable for subsequent processing as a circuit board, stripline, microstripline microwave components and other related applications. The preferred embodiment of this composition is an electrical laminate from 0.003 to 0.120 inches thick with metal foil clad on one or both sides.
Suitable reinforcement components include organic or inorganic s fillers, woven fiberglass, glass paper, glass mat, glass cloth, polyimide paper (such as "THERMOUNT" from DuPont), woven polymeric fibers and non-woven polymer fiber reinforcements and the like. The reinforcement components of the laminates of the present invention may be in the range of about 25% to 75% by weight of the total laminate, preferably about 30%
i o tQ about 40%, and more preferably about 35%.
The performance of this composition differs from similar materials mainly in electrical performance. These properties, especially dissipation factor, are very important when considering high frequency applications.
Typical electrical properties of an 0.030" thick laminate of approximate i5 20% (by weight) of fiberglass reinforcement are:
Frequency (GHz): 2.5 10.0 Dielectric constant: 3.20 3.22 Dissipation factor: 0.0031 0.0048 2o The electrical properties of the same laminate at 1 MHZ are:
Dielectric constant: 3.20 Dissipation factor: 0.0029 The above data shows the consistency of the dielectric constant and 25 dissipation factor of a laminate comprising the inventive compositions across a wide range of frequencies. This feature is highly desirable for compositions utilized as dielectric materials.
This embodiment of the present invention is clearly superior in electrical properties over presently available compositions.
3o The invention will be further clarified by a consideration of the following examples which are to be considered as illustrative of the present invention. It should be understood that the invention is not limited to the specific details of the examples.
EXAMPLES
The unsaturated urethane resins are manufactured according to U.S.
Patent Nos. 4,587,161 and 4,803,022 of Kuehn et al., manufactured according to methods known in the art, or commercially available as Palatal 48001 KR (BASF, Germany) or 580-05 (Reichold Chemicals Inc., USA) in the case of a urethane vinyl ester, and as ITP 1041 and ITP 1070 (Reichold Chemicals Inc., USA), in the case of a isocyanurate vinyl ester.
i~ The ethylenically unsaturated monomers styrene and dibromonostyrene are commercially available.
The general method of preparing the resin compositions is as follows.
1) The ingredients, (listed in TABLE 1), are added to a mixing 1 s vessel.
2) The ingredients are mixed for 5 to 15 minutes with a Cowles dissolver operating at high shear, about 100 to 500 rpm), at room temperature. Higher shear rates may be used, but could entrain air.
Optionally, the mixture could be degassed in a vacuum (25 -29 ~o inches of Hg).
3) At this point, the composition is ready for use. The typical cure schedule for the thermoset resin is:
a. 20 minutes at 210 degrees F, optionally up to 225 degrees F. Temperatures greater than 250°F produce 25 undesirable reactions during cure and yield poor quality product. Lower temperatures than 210°F may be used with longer times.
b. Depending upon the desired product, a post-cure is often necessary to optimize the electrical properties.
3o One to three hours at 350°F is preferred.
Examples 1 to 9 The general method of preparing electrical laminates from the resin compositions is as follows. The specific electrical laminates embodied in Examples 1 to 9 were made as indicated below and as further indicated in TABLE 1 which follows below. All laminates are 30 mil dielectric thickness with 18-20% by weight E-glass reinforcement.
1) The ingredients, listed in TABLE 1, are added to a mixing vessel.
2) The ingredients are mixed for 5 to 15 minutes with a Cowles to dissolver operating at high shear, (about 100 to 500 rpm), at room temperature. Higher shear rates may be used, but could entrain air.
Optionally, the mixture could be degassed in a vacuum (25 -29 inches of Hg).
3) The mixture is heated to 85-100 degrees Fahrenheit, or any i5 temperature below the point at which the catalyst undergoes considerable decomposition to form free radicals. The resin mixture is heated to facilitate impregnating the reinforcement.
4) The composition is utilized with one of the following processes:
2o a. The resin mixture is used to impregnate the reinforcements) in the lab according to the method outlined in application No. 08/483,086, incorporated herein by reference.
The residence times and temperatures can be found in TABLE 1. It has been discovered, that when using this 25 lamination process, temperatures above 250°F will produce poor quality laminates, and thus should be avoided b. the resin composition is used to impregnate the reinforcements) in the lab according to the same method as above (a), with the following exceptions. Rather than curing 3o the laminate in an oven, the appropriate catalysts and promoters are chosen, and the laminate is left undisturbed _»_ and allowed to cure at room temperature for 1 to 24 hours.
The catalyst half-life, quantity of catalyst, and type and amount of promoters will dictate the amount of time needed to cure at room temperature. These examples can be found in TABLE 1 under "Room Temp." Cure Method.
c. Alternately, the composition can impregnate the reinforcement by our patented continuous lamination process, (Barrell et al. U.S. Patent No. 4,803,022). These examples can be found in TABLE 1 under "Continuous" Cure Method.
io 5) The laminate is post-cured for 1 hour at 350°F. Post-cure reduces the dissipation factor of the laminate. Therefore, a post-cure is desirable, but not required.
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~II° I~I
m a a v ~r, tn Z m Z
N O
N O C _O
N
~
( c . p u d G
-~ C O m N
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tL U a a ~ o ~I ~i SUBSTITUTE SHEET (RULE 26) Although the invention has been described in conjunction with specific embodiments, it is evident that many alternatives and variations will be apparent to those skilled in the art in light of the foregoing description. Accordingly, the invention is intended to embrace all of the alternatives and variations that fall within the spirit and scope of the appended claims.
1) The ingredients, listed in TABLE 1, are added to a mixing vessel.
2) The ingredients are mixed for 5 to 15 minutes with a Cowles to dissolver operating at high shear, (about 100 to 500 rpm), at room temperature. Higher shear rates may be used, but could entrain air.
Optionally, the mixture could be degassed in a vacuum (25 -29 inches of Hg).
3) The mixture is heated to 85-100 degrees Fahrenheit, or any i5 temperature below the point at which the catalyst undergoes considerable decomposition to form free radicals. The resin mixture is heated to facilitate impregnating the reinforcement.
4) The composition is utilized with one of the following processes:
2o a. The resin mixture is used to impregnate the reinforcements) in the lab according to the method outlined in application No. 08/483,086, incorporated herein by reference.
The residence times and temperatures can be found in TABLE 1. It has been discovered, that when using this 25 lamination process, temperatures above 250°F will produce poor quality laminates, and thus should be avoided b. the resin composition is used to impregnate the reinforcements) in the lab according to the same method as above (a), with the following exceptions. Rather than curing 3o the laminate in an oven, the appropriate catalysts and promoters are chosen, and the laminate is left undisturbed _»_ and allowed to cure at room temperature for 1 to 24 hours.
The catalyst half-life, quantity of catalyst, and type and amount of promoters will dictate the amount of time needed to cure at room temperature. These examples can be found in TABLE 1 under "Room Temp." Cure Method.
c. Alternately, the composition can impregnate the reinforcement by our patented continuous lamination process, (Barrell et al. U.S. Patent No. 4,803,022). These examples can be found in TABLE 1 under "Continuous" Cure Method.
io 5) The laminate is post-cured for 1 hour at 350°F. Post-cure reduces the dissipation factor of the laminate. Therefore, a post-cure is desirable, but not required.
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tL U a a ~ o ~I ~i SUBSTITUTE SHEET (RULE 26) Although the invention has been described in conjunction with specific embodiments, it is evident that many alternatives and variations will be apparent to those skilled in the art in light of the foregoing description. Accordingly, the invention is intended to embrace all of the alternatives and variations that fall within the spirit and scope of the appended claims.
Claims (47)
1. A thermosetting resin composition, comprising:
(a) One or more terminally unsaturated urethanes selected from the group of:
1) one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate;
2) and one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure:
and (b) Styrene monomer; and (c) Bromostyrene, characterized by the formula:
wherein, the ratio of the sum of components (a) to the sum of components (b) and (c) is less than 0.2, and the ratio of (b) to (c) is less than 1.5.
(a) One or more terminally unsaturated urethanes selected from the group of:
1) one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate;
2) and one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure:
and (b) Styrene monomer; and (c) Bromostyrene, characterized by the formula:
wherein, the ratio of the sum of components (a) to the sum of components (b) and (c) is less than 0.2, and the ratio of (b) to (c) is less than 1.5.
2. The composition according to claim 1 further comprising a catalyst in about 0.1 % to about 2% by weight of the total composition.
3. The composition according to claim 2 wherein the catalyst is selected from the group consisting of the t-butyl peroctoate, t-butyl peroxy benzoate, dicumyl peroxide, benzoyl peroxide, cumene hydrogen peroxide, t-butyl perbenzoate, t-butyl peroxide and combinations thereof.
4. The composition according to claim 3 wherein the catalyst comprises t-butyl peroctoate in about 0.2% by weight of the total composition.
5. The composition according to claim 3 wherein the catalyst comprises t-butyl peroxy benzoate in about 0.25% by weight of the total composition.
6. The composition according to claim 3 wherein the catalyst comprises dicumyl peroxide in about 0.25% by weight of the total composition.
7. The composition according to claim 1 wherein said styrene monomer is selected from the group consisting of styrene, halogenated styrene, and an alpha alkyl styrene.
8. The composition of claim 7 wherein said styrene monomer is an alpha alkyl styrene.
9. The composition of claim 7 wherein said styrene monomer is a halogenated styrene.
10. The composition of claim 9 wherein said halogenated styrene monomer is selected from the group consisting of dibromostyrene, tribromostyrene and pentabromobenzyl acrylate.
11. The composition of claim 1 further comprising divinyl benzene in about 0.1% to about 10% by weight of the total composition.
12. The composition of claim 11 wherein the divinyl benzene is from about 0.5% to about 5% by weight of the total composition.
13. The composition of claim 12 wherein the divinyl benzene is from about 1% to about 4% by weight of the total composition.
14. The composition of claim 1 further comprising additives selected from the group consisting of moisture scavengers, molecular sieves, organic fillers, inorganic fillers, oxides, polyethylene fillers, rheology modification fillers, surface active agents, monomers which modify viscosity and performance, colorants, fluorescent dyes, U.V.
blockers, wetting agents, air release agents, defoamers, adhesion promoters, flame retardant synergists, styrene, vinyl toluene, t-butyl-styrene, paramethyl styrene, diallyl phthalate, 2,4,ethyl-methylimidazole, 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine and combinations thereof.
blockers, wetting agents, air release agents, defoamers, adhesion promoters, flame retardant synergists, styrene, vinyl toluene, t-butyl-styrene, paramethyl styrene, diallyl phthalate, 2,4,ethyl-methylimidazole, 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine and combinations thereof.
15. The composition of claim 14 wherein the oxide comprises titanium dioxide.
16. The composition of claim 14 wherein the oxide comprises expanded polyethylene compounds.
17. The composition of claim 14 wherein the filler which modifies rheology is calcined kaolin.
18. The composition of claim 14 wherein the monomer which modifies viscosity and performance comprises methyl methacrylate.
19. A method of producing an electrical laminate comprising the steps of (1) impregnating at least one substrate with a thermosetting resin composition comprising (a) one or more terminally unsaturated urethanes selected from the group of 1) one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate;
2) and one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure:
and (b) styrene monomer; and (c) bromostyrene, characterized by the formula:
wherein, the ratio of the sum of components (a) to the sum of components (b) and (c) is less than 0.2, and the ratio of (b) to (c) is less than 1.5. wherein said thermosetting resin composition further comprises catalysts which induce free radical cure, polymerization, or UV initiation, in about 0.1 % to about 2% by weight of the total composition; and (2) curing the resin impregnated substrate to produce an electrical laminate.
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate;
2) and one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure:
and (b) styrene monomer; and (c) bromostyrene, characterized by the formula:
wherein, the ratio of the sum of components (a) to the sum of components (b) and (c) is less than 0.2, and the ratio of (b) to (c) is less than 1.5. wherein said thermosetting resin composition further comprises catalysts which induce free radical cure, polymerization, or UV initiation, in about 0.1 % to about 2% by weight of the total composition; and (2) curing the resin impregnated substrate to produce an electrical laminate.
20. The method of claim 19 wherein the curing mechanism is selected from the group consisting of heating without pressure, heating with pressure, electron beam processing, and ultra-violet light processing in conjunction with U.V. initiators.
21. The method of claim 19 wherein the substrates are materials selected from the group consisting of organic or inorganic fillers, woven fiberglass, glass paper, glass cloth, glass mat, polyimide paper, woven polymeric fibers and non-woven polymer fiber reinforcements.
22. The method of claim 19 further comprising cladding an electrically conductive layer on at least one side of the impregnated substrate before curing.
23. The method of claim 19 further comprising cladding an electrically conductive layer on at least one side of the impregnated substrate after curing.
24. The method of claim 22 wherein the electrically conductive layer is a metal selected from the group of aluminum, silver, gold, brass and copper.
25. The method of claim 23 wherein the electrically conductive layer is a metal selected from the group consisting of aluminum, silver, gold, brass and copper.
26. The method of claim 19 wherein the impregnating step involves more than one substrate and the method further comprises laminating the substrates before the curing step.
27. The method of claim 26 wherein the curing mechanism is selected from the group consisting of heating without pressure, heating with pressure, electron beam processing, and ultra-violet light processing in conjunction with U.V. initiators.
28. The method of claim 26 wherein the substrates are materials selected from the group consisting of organic or inorganic fillers, woven fiberglass, glass paper, glass cloth, glass mat, polyimide paper, woven polymeric fibers and non-woven polymer fiber reinforcements.
29. The method of claim 26 further comprising cladding an electrically conductive layer on at least one side of the impregnated substrate before curing.
30. The method of claim 19 further comprising cladding an electrically conductive layer on at least one side of the impregnated substrate after curing.
31. The method of claim 29 wherein the electrically conductive layer is a metal selected from the group of aluminum, silver, gold, brass and copper.
32. The method of claim 30 wherein the electrically conductive layer is a metal selected from the group consisting of aluminum, silver, gold, brass and copper.
33. An electrical laminate obtained by (1) impregnating at least one substrate with a thermosetting resin composition comprising:
One or more terminally unsaturated urethanes selected from the group of:
1) one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate;
(2) and one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure:
and (b) Styrene monomer; and (c) Bromostyrene, characterized by the formula:
wherein, the ratio of the sum of components (a) to the sum of components (b) and (c) is less than 0.2, and the ratio of (b) to (c) is less than 1.5; and (d) catalysts which induce free radical cure, polymerization, or UV initiation, in about 0.1% to about 2% by weight of the total composition; and (2) curing the resin impregnated substrate to produce an electrical laminate.
One or more terminally unsaturated urethanes selected from the group of:
1) one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate;
(2) and one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure:
and (b) Styrene monomer; and (c) Bromostyrene, characterized by the formula:
wherein, the ratio of the sum of components (a) to the sum of components (b) and (c) is less than 0.2, and the ratio of (b) to (c) is less than 1.5; and (d) catalysts which induce free radical cure, polymerization, or UV initiation, in about 0.1% to about 2% by weight of the total composition; and (2) curing the resin impregnated substrate to produce an electrical laminate.
34. The laminate of claim 33 wherein the composition resin further comprises a halogenated vinyl functional monomer.
35. The laminate of claim 34 wherein the composition further comprises glacial methacrylic acid.
36. The laminate of claim 35 wherein the composition further comprises divinyl benzene.
37. The laminate of claim 36 wherein the composition further comprises additional components selected from the group consisting of moisture scavengers, molecular sieves, organic fillers, inorganic fillers, monomers to increase or decrease the dielectric constant, monomer to reduce the dissipation factor, polyethylene fillers, monomers to modify rheology, surface active agents, monomers to modify viscosity and performance, colorants, fluorescent dye, U.V. blockers, wetting agents, air release agents, defoaming agents, flame retardant synergists, adhesion promoters, epoxies, styrene, vinyl toluene, t-butyl styrene, paramethyl styrene, diallyl phthalate, and 2,4,ethyl-methyl imidazole, 3-ethyl-2-methyl-2-3(3-methylbutyl)-1,3-oxazolidine, methyl methacrylate and combinations thereof.
38. The laminate of claim 37 wherein the substrates are materials selected from the group consisting of organic or inorganic fillers, woven fiberglass, glass paper, glass cloth, glass mat, polyimide paper, woven polymeric fibers and non-woven polymer fiber reinforcements.
39. The laminate of claim 38 further comprising an electrically conductive layer clad on at least one side of the cured impregnated substrate.
40. The laminate of claim 39 wherein the electrically conductive layer is a metal selected from the group of aluminum, silver, gold, brass and copper.
41. The laminate of claim 38 wherein more than one substrate is impregnated with the thermosetting resin and are laminated together before the curing step.
42. The laminate of claim 41 having an electrical conductive layer clad on at least one side of the laminated cured substrates.
43. The laminate of claim 42 wherein the electrical conductive layer is a metal selected from the group of aluminum, silver, gold, brass and copper.
44. An electrical laminate, comprising at least one reinforcement substrate and a crossed linked, thin wall thermosetting resin composition comprising:
(a) One or more terminally unsaturated urethanes selected from the group of:
1) one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate;
2) and one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure:
and (b) Styrene monomer; and (c) Bromostyrene, characterized by the formula:
wherein, the ratio of the sum of components (a) to the sum of components (b) and (c) is less than 0.2, and the ratio of (b) to (c) is less than 1.5;
and (d) catalysts which induce free radical cure, polymerization, or UV
initiation, in about 0.1 % to about 2% by weight of the total composition.
(a) One or more terminally unsaturated urethanes selected from the group of:
1) one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate;
2) and one characterized by the formula:
where R1 is H or CH3, R2 is an organic residue from a monohydric alcohol and R3 is an organic residue from a diisocyanate, and R4 is an isocyanurate compound of the following structure:
and (b) Styrene monomer; and (c) Bromostyrene, characterized by the formula:
wherein, the ratio of the sum of components (a) to the sum of components (b) and (c) is less than 0.2, and the ratio of (b) to (c) is less than 1.5;
and (d) catalysts which induce free radical cure, polymerization, or UV
initiation, in about 0.1 % to about 2% by weight of the total composition.
45. The laminate of claim 44 further comprising an electrically conductive cladding on at least one side.
46. A multilayer electrical laminate comprising a combination of single sided and double sided laminates according to the laminate of claim 45.
47. The laminate of claim 44 wherein the thickness range is from about 0.003 to about 0.120 inches thick.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1999/002964 WO2000047655A1 (en) | 1999-02-12 | 1999-02-12 | Microwave-transparent thermosetting resin compositions, electrical laminates obtained therefrom, and process of producing these |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2362609A1 true CA2362609A1 (en) | 2000-08-17 |
Family
ID=22272166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002362609A Abandoned CA2362609A1 (en) | 1999-02-12 | 1999-02-12 | Microwave-transparent thermosetting resin compositions, electrical laminates obtained therefrom, and process of producing these |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP1173501A1 (en) |
| JP (1) | JP2002536518A (en) |
| KR (1) | KR20020013499A (en) |
| AU (1) | AU2672299A (en) |
| CA (1) | CA2362609A1 (en) |
| MX (1) | MXPA01008222A (en) |
| WO (1) | WO2000047655A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10662304B2 (en) | 2013-12-31 | 2020-05-26 | Saint-Gobain Performance Plastics Corporation | Composites for protecting signal transmitters/receivers |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115368725B (en) * | 2021-05-18 | 2023-08-11 | 万华化学集团股份有限公司 | Thermoplastic polyurethane elastomer composite material with high dielectric constant and low dielectric loss and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4126826A1 (en) * | 1991-08-14 | 1993-02-18 | Basf Ag | TOOTH-MODIFIED VINYLESTERURETHANE RESINS |
| US5741872A (en) * | 1996-04-10 | 1998-04-21 | Hehr International Inc. | Multifunctional polyacrylate-polyurethane oligomer and method |
| US5747552A (en) * | 1996-04-10 | 1998-05-05 | Hehr International Inc. | Radiant energy curable acrylic urethane prepolymer resin compositions and method |
| WO1998006783A1 (en) * | 1996-08-12 | 1998-02-19 | Ucb, S.A. | Radiation hardening resin compositions |
-
1999
- 1999-02-12 CA CA002362609A patent/CA2362609A1/en not_active Abandoned
- 1999-02-12 WO PCT/US1999/002964 patent/WO2000047655A1/en not_active Application Discontinuation
- 1999-02-12 MX MXPA01008222A patent/MXPA01008222A/en unknown
- 1999-02-12 JP JP2000598567A patent/JP2002536518A/en active Pending
- 1999-02-12 AU AU26722/99A patent/AU2672299A/en not_active Abandoned
- 1999-02-12 KR KR1020017010200A patent/KR20020013499A/en not_active Application Discontinuation
- 1999-02-12 EP EP99906926A patent/EP1173501A1/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10662304B2 (en) | 2013-12-31 | 2020-05-26 | Saint-Gobain Performance Plastics Corporation | Composites for protecting signal transmitters/receivers |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002536518A (en) | 2002-10-29 |
| WO2000047655A1 (en) | 2000-08-17 |
| KR20020013499A (en) | 2002-02-20 |
| EP1173501A1 (en) | 2002-01-23 |
| AU2672299A (en) | 2000-08-29 |
| MXPA01008222A (en) | 2002-10-23 |
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