CA2350201A1 - Particules d'oxyde metallique - Google Patents

Particules d'oxyde metallique Download PDF

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Publication number
CA2350201A1
CA2350201A1 CA002350201A CA2350201A CA2350201A1 CA 2350201 A1 CA2350201 A1 CA 2350201A1 CA 002350201 A CA002350201 A CA 002350201A CA 2350201 A CA2350201 A CA 2350201A CA 2350201 A1 CA2350201 A1 CA 2350201A1
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CA
Canada
Prior art keywords
particles
manganese oxide
collection
lithium
average diameter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002350201A
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English (en)
Inventor
Sujeet Kumar
Xiangxin Bi
Craig R. Horne
Hariklia Dris Reitz
James T. Gardner
Ronald J. Mosso
Nobuyuki Kambe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanogram Corp
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/188,768 external-priority patent/US6607706B1/en
Priority claimed from US09/188,770 external-priority patent/US6506493B1/en
Priority claimed from US09/203,414 external-priority patent/US6136287A/en
Priority claimed from US09/334,203 external-priority patent/US6482374B1/en
Application filed by Individual filed Critical Individual
Publication of CA2350201A1 publication Critical patent/CA2350201A1/fr
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/02—Oxides; Hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G31/00—Compounds of vanadium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1242—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [Mn2O4]-, e.g. LiMn2O4, Li[MxMn2-x]O4
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/02—Amorphous compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C01P2004/52—Particles with a specific particle size distribution highly monodisperse size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Des particules d'oxyde de manganèse et des particules d'oxyde de lithium-manganèse, d'un diamètre moyen inférieur à environ 500 nm, ont été produites. Ces particules présentent un degré élevé d'uniformité possédant une répartition très serrée des tailles des particules. L'invention concerne des procédés permettant de produire des oxydes métalliques par réaction d'un aérosol renfermant un précurseur de métal. Les particules peuvent être formées, en particulier, par pyrolyse au laser. Les particules d'oxyde de lithium-manganèse peuvent être formées par traitement thermique de nanoparticules d'oxyde de manganèse. Selon un autre mode de réalisation, les particules d'oxyde de lithium-manganèse peuvent être formées directement par pyrolyse au laser. Lesdites particules d'oxyde de lithium-manganèse sont utiles comme matériaux actifs dans les électrodes positives des batteries à base de lithium. Ces batteries améliorées résultent de l'utilisation des particules d'oxyde de lithium-manganèse uniformes de taille nanométrique.
CA002350201A 1998-11-09 1999-11-08 Particules d'oxyde metallique Abandoned CA2350201A1 (fr)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US09/188,768 US6607706B1 (en) 1998-11-09 1998-11-09 Composite metal oxide particles
US09/188,768 1998-11-09
US09/188,770 US6506493B1 (en) 1998-11-09 1998-11-09 Metal oxide particles
US09/188,770 1998-11-09
US09/203,414 US6136287A (en) 1998-11-09 1998-12-02 Lithium manganese oxides and batteries
US09/203,414 1998-12-02
US09/334,203 1999-06-16
US09/334,203 US6482374B1 (en) 1999-06-16 1999-06-16 Methods for producing lithium metal oxide particles
PCT/US1999/026343 WO2000027754A1 (fr) 1998-11-09 1999-11-08 Particules d'oxyde metallique

Publications (1)

Publication Number Publication Date
CA2350201A1 true CA2350201A1 (fr) 2000-05-18

Family

ID=27497771

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002350201A Abandoned CA2350201A1 (fr) 1998-11-09 1999-11-08 Particules d'oxyde metallique

Country Status (5)

Country Link
EP (1) EP1165442A1 (fr)
KR (1) KR100696972B1 (fr)
CN (1) CN1286733C (fr)
CA (1) CA2350201A1 (fr)
WO (1) WO2000027754A1 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6225007B1 (en) 1999-02-05 2001-05-01 Nanogram Corporation Medal vanadium oxide particles
US6849334B2 (en) 2001-08-17 2005-02-01 Neophotonics Corporation Optical materials and optical devices
US6749648B1 (en) 2000-06-19 2004-06-15 Nanagram Corporation Lithium metal oxides
EP1163703A4 (fr) * 1999-02-05 2004-12-29 Greatbatch W Technologies Particules metalliques a l'oxyde de vanadium
KR100457824B1 (ko) * 2001-08-10 2004-11-18 한국화학연구원 용액 열분해법에 의한 나노 크기 2가 금속 산화물 분말의제조
JP4541900B2 (ja) * 2003-05-20 2010-09-08 アイトゲネシッシェ テヒニッシェ ホーホシューレ チューリッヒ ナノ粒子製造用金属供給システム
JP3785543B2 (ja) * 2003-08-26 2006-06-14 松下電器産業株式会社 マンガン酸化物ナノ構造体の製造方法とそのマンガン酸化物ナノ構造体を用いた酸素還元電極
CN1942396B (zh) 2004-03-15 2010-09-01 苏黎世联合高等工业学校 金属盐纳米颗粒，特别是包含钙和磷酸根的纳米颗粒的火焰合成
JP5732638B2 (ja) 2011-05-23 2015-06-10 中国科学院▲寧▼波材料技▲術▼▲与▼工程研究所 リチウムイオン電池用正極材料の作製方法
WO2012167010A2 (fr) * 2011-06-02 2012-12-06 Cornell University Nanoparticules d'oxyde de manganèse, procédés et applications s'y rapportant
TWI464789B (zh) * 2011-12-28 2014-12-11 Univ Nat Sun Yat Sen 調整金屬氧化物薄膜功函數之方法
FI124942B (fi) 2013-08-28 2015-03-31 Inkron Ltd Siirtymämetallioksidipartikkelit ja menetelmä niiden valmistamiseksi
CN107078291A (zh) 2014-08-28 2017-08-18 英克罗恩有限公司 结晶过渡氧化物颗粒及制备该结晶过渡氧化物颗粒的连续方法
CN111450654B (zh) * 2020-04-01 2021-03-23 华中科技大学 一种双通道高压光热催化反应装置
CN113262737A (zh) * 2021-06-17 2021-08-17 江阴讯安新材料科技有限公司 一种纳米氧化铋的激光诱导合成设备及其合成方法
CN116168956A (zh) * 2023-01-06 2023-05-26 广西大学 一种uv光热辅助制备金属氧化物电极材料的方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3739002A1 (de) * 1987-11-17 1989-05-24 Veba Oel Ag Metallmischoxidpulver, deren mischungen, metalloxidpulver und deren verwendung bei der katalytischen dehydrierung von kohlenwasserstoffen
CA1331506C (fr) * 1988-07-12 1994-08-23 Michael Makepeace Thackeray Methode pour la synthese d'oxyde de manganese et de lithium
US5958361A (en) * 1993-03-19 1999-09-28 Regents Of The University Of Michigan Ultrafine metal oxide powders by flame spray pyrolysis
US5618640A (en) * 1993-10-22 1997-04-08 Fuji Photo Film Co., Ltd. Nonaqueous secondary battery
DE69409352T2 (de) * 1993-12-24 1998-07-23 Sharp Kk Nichtwässrige Sekundärbatterie, aktives Material für positive Elektrode und Verfahren zu dessen Herstellung
US5807646A (en) * 1995-02-23 1998-09-15 Tosoh Corporation Spinel type lithium-mangenese oxide material, process for preparing the same and use thereof
US5874058A (en) * 1995-10-06 1999-02-23 Kerr-Mcgee Chemical Llc Method of preparing Li1+x MN2-x O4 for use as secondary battery electrode
US5604057A (en) * 1995-11-27 1997-02-18 General Motors Corporation Secondary cell having a lithium intercolating manganese oxide
US5770018A (en) * 1996-04-10 1998-06-23 Valence Technology, Inc. Method for preparing lithium manganese oxide compounds
US5883032A (en) * 1996-11-21 1999-03-16 Uop Llc Selective multimetallic multigradient reforming catalyst

Also Published As

Publication number Publication date
CN1286733C (zh) 2006-11-29
WO2000027754A1 (fr) 2000-05-18
CN1329575A (zh) 2002-01-02
KR100696972B1 (ko) 2007-03-20
KR20010087386A (ko) 2001-09-15
EP1165442A1 (fr) 2002-01-02

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Effective date: 20051108