CA2338454C - A novel formulation useful as a nitrification and urease inhibitor and a method of producing the same - Google Patents
A novel formulation useful as a nitrification and urease inhibitor and a method of producing the same Download PDFInfo
- Publication number
- CA2338454C CA2338454C CA002338454A CA2338454A CA2338454C CA 2338454 C CA2338454 C CA 2338454C CA 002338454 A CA002338454 A CA 002338454A CA 2338454 A CA2338454 A CA 2338454A CA 2338454 C CA2338454 C CA 2338454C
- Authority
- CA
- Canada
- Prior art keywords
- fertilizer
- oil
- urea
- formulation
- nitrification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 238000009472 formulation Methods 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000002601 urease inhibitor Substances 0.000 title claims abstract description 5
- 229940090496 Urease inhibitor Drugs 0.000 title abstract description 4
- 239000003921 oil Substances 0.000 claims abstract description 47
- 235000001405 Artemisia annua Nutrition 0.000 claims abstract description 18
- 240000000011 Artemisia annua Species 0.000 claims abstract description 18
- 239000004359 castor oil Substances 0.000 claims abstract description 16
- 235000019438 castor oil Nutrition 0.000 claims abstract description 16
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 16
- 239000000618 nitrogen fertilizer Substances 0.000 claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 126
- 239000004202 carbamide Substances 0.000 claims description 64
- 239000003337 fertilizer Substances 0.000 claims description 42
- 239000011248 coating agent Substances 0.000 claims description 33
- 238000000576 coating method Methods 0.000 claims description 33
- 235000003826 Artemisia Nutrition 0.000 claims description 32
- 235000003261 Artemisia vulgaris Nutrition 0.000 claims description 32
- 244000030166 artemisia Species 0.000 claims description 32
- 235000009052 artemisia Nutrition 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 31
- 108010046334 Urease Proteins 0.000 claims description 23
- 239000003112 inhibitor Substances 0.000 claims description 21
- 230000002401 inhibitory effect Effects 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- 239000001166 ammonium sulphate Substances 0.000 claims description 3
- 239000000834 fixative Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 239000002689 soil Substances 0.000 abstract description 34
- 230000000694 effects Effects 0.000 abstract description 11
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 39
- 238000002474 experimental method Methods 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 15
- 238000011084 recovery Methods 0.000 description 12
- 238000009825 accumulation Methods 0.000 description 10
- 238000011534 incubation Methods 0.000 description 9
- 229930014626 natural product Natural products 0.000 description 9
- 230000009466 transformation Effects 0.000 description 9
- 241000186361 Actinobacteria <class> Species 0.000 description 7
- 241000605159 Nitrobacter Species 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 235000013500 Melia azadirachta Nutrition 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 238000002386 leaching Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 244000245214 Mentha canadensis Species 0.000 description 4
- 235000016278 Mentha canadensis Nutrition 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 230000000979 retarding effect Effects 0.000 description 4
- 240000005343 Azadirachta indica Species 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 2
- NPTGVVKPLWFPPX-UHFFFAOYSA-N 2-amino-4-chloro-6-methylpyrimidine Chemical compound CC1=CC(Cl)=NC(N)=N1 NPTGVVKPLWFPPX-UHFFFAOYSA-N 0.000 description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 2
- 244000237986 Melia azadirachta Species 0.000 description 2
- 235000006679 Mentha X verticillata Nutrition 0.000 description 2
- 235000018978 Mentha arvensis Nutrition 0.000 description 2
- 235000002899 Mentha suaveolens Nutrition 0.000 description 2
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 2
- 235000004443 Ricinus communis Nutrition 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000003190 augmentative effect Effects 0.000 description 2
- 230000033558 biomineral tissue development Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229940041616 menthol Drugs 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000001546 nitrifying effect Effects 0.000 description 2
- 230000010076 replication Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 241001131796 Botaurus stellaris Species 0.000 description 1
- 101100298222 Caenorhabditis elegans pot-1 gene Proteins 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 244000037433 Pongamia pinnata Species 0.000 description 1
- 235000004599 Pongamia pinnata Nutrition 0.000 description 1
- 240000000528 Ricinus communis Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000013000 chemical inhibitor Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000003053 completely randomized design Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000009363 floriculture Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005706 microflora Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002018 neem oil Substances 0.000 description 1
- DCUJJWWUNKIJPH-UHFFFAOYSA-N nitrapyrin Chemical compound ClC1=CC=CC(C(Cl)(Cl)Cl)=N1 DCUJJWWUNKIJPH-UHFFFAOYSA-N 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- TZLVRPLSVNESQC-UHFFFAOYSA-N potassium azide Chemical compound [K+].[N-]=[N+]=[N-] TZLVRPLSVNESQC-UHFFFAOYSA-N 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004856 soil analysis Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000012622 synthetic inhibitor Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
- C05C3/005—Post-treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
- C05C9/005—Post-treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IN2000/000032 WO2001072665A1 (en) | 2000-03-28 | 2000-03-28 | Formulation useful as a nitrification and urease inhibitor and a method of producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2338454A1 CA2338454A1 (en) | 2001-09-28 |
| CA2338454C true CA2338454C (en) | 2004-12-14 |
Family
ID=11076233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002338454A Expired - Fee Related CA2338454C (en) | 2000-03-28 | 2000-03-28 | A novel formulation useful as a nitrification and urease inhibitor and a method of producing the same |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN1248989C (zh) |
| AU (1) | AU779660B2 (zh) |
| CA (1) | CA2338454C (zh) |
| WO (1) | WO2001072665A1 (zh) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2264386B1 (es) * | 2005-06-07 | 2007-11-16 | Inabonos, S.A. | Nuevas formulaciones con la capacidad de inhibir la actividad ureasa y potencial uso agronomico. |
| FR2925826B1 (fr) | 2007-12-31 | 2010-01-29 | Agrofinance Internationale | Composition inhibitrice d'urease et de nitrification |
| WO2016070184A1 (en) | 2014-10-31 | 2016-05-06 | Koch Agronomic Services, Llc | Nitrification inhibitor compositions and methods of making thereof |
| TW201626888A (zh) * | 2014-12-11 | 2016-08-01 | 陶氏農業科學公司 | 硝化抑制劑組成物及其製備方法 |
| EP3130578B1 (en) | 2015-08-14 | 2019-03-13 | Fertinagro Biotech, S.L. | Fertilizing composition which includes an inhibitor of urease activity |
| CN107955619A (zh) * | 2017-11-20 | 2018-04-24 | 郑州搜趣信息技术有限公司 | 一种复合土壤改良剂及其制备方法 |
| LT6961B (lt) | 2021-05-06 | 2022-12-12 | Akcinė bendrovė „ACHEMA“ | Preparatas, naudojamas kaip ureazės inhibitorius, jo gavimo būdas ir karbamido trąšos |
| WO2023135341A1 (es) | 2022-01-12 | 2023-07-20 | Fertinagro Biotech, S.L. | Composición inhibidora de la ureasa y utilización de la misma |
| CN116621646B (zh) * | 2023-05-10 | 2024-02-06 | 中国科学院沈阳应用生态研究所 | 环戊酮作为抑制剂在土壤中减少n2o排放的应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1592593A1 (de) * | 1966-06-28 | 1971-01-14 | Baerlocher Chem | Verfahren zur Granulierung von Duengemitteln |
| FR2529195B1 (fr) * | 1982-06-29 | 1990-05-11 | Clement Henri | Engrais sous forme de batonnets |
| JPS62270485A (ja) * | 1986-05-19 | 1987-11-24 | 亀井 豊 | 害虫駆除効果のすぐれた肥料組成物の製造方法 |
| JPH0819595A (ja) * | 1994-07-05 | 1996-01-23 | Maruzen Pharmaceut Co Ltd | アンモニア発生防止剤 |
-
2000
- 2000-03-28 CA CA002338454A patent/CA2338454C/en not_active Expired - Fee Related
- 2000-03-28 AU AU54250/00A patent/AU779660B2/en not_active Ceased
- 2000-03-28 WO PCT/IN2000/000032 patent/WO2001072665A1/en active Application Filing
- 2000-03-28 CN CNB008011567A patent/CN1248989C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1354736A (zh) | 2002-06-19 |
| CA2338454A1 (en) | 2001-09-28 |
| WO2001072665A1 (en) | 2001-10-04 |
| AU5425000A (en) | 2001-10-08 |
| CN1248989C (zh) | 2006-04-05 |
| AU779660B2 (en) | 2005-02-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20140328 |