CA2306889A1 - Method and device for producing combustible gas, synthesis gas and reducing gas from solid fuels - Google Patents

Method and device for producing combustible gas, synthesis gas and reducing gas from solid fuels Download PDF

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Publication number
CA2306889A1
CA2306889A1 CA002306889A CA2306889A CA2306889A1 CA 2306889 A1 CA2306889 A1 CA 2306889A1 CA 002306889 A CA002306889 A CA 002306889A CA 2306889 A CA2306889 A CA 2306889A CA 2306889 A1 CA2306889 A1 CA 2306889A1
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CA
Canada
Prior art keywords
combustion chamber
gas
synthesis
solid fuels
fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002306889A
Other languages
French (fr)
Other versions
CA2306889C (en
Inventor
Bodo Wolf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Original Assignee
Bodo Wolf
Choren Industries Gmbh
Linde Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bodo Wolf, Choren Industries Gmbh, Linde Ag filed Critical Bodo Wolf
Publication of CA2306889A1 publication Critical patent/CA2306889A1/en
Application granted granted Critical
Publication of CA2306889C publication Critical patent/CA2306889C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/50Fuel charging devices
    • C10J3/506Fuel charging devices for entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/485Entrained flow gasifiers
    • C10J3/487Swirling or cyclonic gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/52Ash-removing devices
    • C10J3/526Ash-removing devices for entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60Processes
    • C10J3/64Processes with decomposition of the distillation products
    • C10J3/66Processes with decomposition of the distillation products by introducing them into the gasification zone
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/04Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/15Details of feeding means
    • C10J2200/152Nozzles or lances for introducing gas, liquids or suspensions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/1223Heating the gasifier by burners

Abstract

The present invention relates to a process and an apparatus for generating fuel, synthesis and reduction gas. The reactor, according to the invention, comprises a combined fuel burner, a combustion chamber, an entrained flow gasifier, a heat compensating duct as well as a water bath, in which case the combined fuel burner is provided with means for the substoichiometric combustion of the gaseous low temperature carbonisation products and with vortex means flinging the liquid components towards the combustion chamber wall. The pulverised fuel can react endothermally with the gasifying agent from the combustion chamber into gasification gas, the residual coke being so swirled that it lowers the temperature of the combustion chamber wall below the slag melting temperature due to convective heat adsorption, a protective layer forming from solidified slag on the interior wall of the combustion chamber.
CA002306889A 1997-10-28 1998-10-06 Method and device for producing combustible gas, synthesis gas and reducing gas from solid fuels Expired - Fee Related CA2306889C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19747324.5 1997-10-28
DE19747324A DE19747324C2 (en) 1997-10-28 1997-10-28 Device for generating fuel, synthesis and reducing gas from renewable and fossil fuels, biomass, waste or sludge
PCT/EP1998/006342 WO1999021940A1 (en) 1997-10-28 1998-10-06 Method and device for producing combustible gas, synthesis gas and reducing gas from solid fuels

Publications (2)

Publication Number Publication Date
CA2306889A1 true CA2306889A1 (en) 1999-05-06
CA2306889C CA2306889C (en) 2008-12-16

Family

ID=7846707

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002306889A Expired - Fee Related CA2306889C (en) 1997-10-28 1998-10-06 Method and device for producing combustible gas, synthesis gas and reducing gas from solid fuels

Country Status (20)

Country Link
EP (1) EP1027407B1 (en)
JP (1) JP4112173B2 (en)
CN (1) CN1136299C (en)
AR (1) AR010952A1 (en)
AT (1) ATE200791T1 (en)
AU (1) AU754147B2 (en)
BR (1) BR9813292B1 (en)
CA (1) CA2306889C (en)
DE (2) DE19747324C2 (en)
DK (1) DK1027407T3 (en)
ES (1) ES2157673T3 (en)
GR (1) GR3036233T3 (en)
ID (1) ID21135A (en)
MY (1) MY127842A (en)
NO (1) NO328487B1 (en)
PL (1) PL190794B1 (en)
PT (1) PT1027407E (en)
TW (1) TW518363B (en)
WO (1) WO1999021940A1 (en)
ZA (1) ZA989759B (en)

Cited By (3)

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US7776114B2 (en) 2005-07-28 2010-08-17 Choren Industries Gmbh Process and apparatus for the endothermic gasification of carbon
CN102399590A (en) * 2011-10-08 2012-04-04 湖北双环科技股份有限公司 Rich oxygen gasification production method
DE102010033646B4 (en) * 2010-02-05 2012-05-24 Pyrox Gmbh Method and shaft carburetor for producing fuel gas from a solid fuel

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DE19906891C2 (en) * 1999-02-19 2002-07-18 Schwarze Pumpe Energiewerke Ag Process for recycling dusty and sludge-like carbonaceous substances in fixed bed gasification
DE102005006305B4 (en) * 2005-02-11 2015-11-26 Consulting & Management Friess Gbr (Vertretungsberechtigte Gesellschafter: Dietmar J. Friess 14532 Kleinmachnow, Jessica Friess 14532 Kleinmachnow) Process for the production of combustion and synthesis gases with high-pressure steam generation
US7819070B2 (en) 2005-07-15 2010-10-26 Jc Enviro Enterprises Corp. Method and apparatus for generating combustible synthesis gas
DE102005035988B4 (en) * 2005-07-28 2009-01-02 Wolf, Bodo Max, Dr.-Ing. Process for producing liquid hydrocarbons from gas
US20070225382A1 (en) * 2005-10-14 2007-09-27 Van Den Berg Robert E Method for producing synthesis gas or a hydrocarbon product
CN101331213B (en) * 2005-12-14 2015-05-13 国际壳牌研究有限公司 Method of producing synthesis gas
CN1935951B (en) * 2006-09-21 2010-12-08 武汉凯迪工程技术研究总院有限公司 High temperature gasifying apparatus for solid carbon raw material
DE102007012452B4 (en) 2007-03-15 2014-01-16 SynCraft Enegineering GmbH carburettor
FI122860B (en) * 2007-05-25 2012-08-15 Gasek Oy Procedure for gasification of solid fuel and co-stream gasifier
EP2238223B1 (en) 2008-01-28 2015-08-26 Shell Internationale Research Maatschappij B.V. Process to start-up a coal gasification reactor
DE102008027336B4 (en) * 2008-06-07 2010-07-08 Karlsruher Institut für Technologie Apparatus and method for determining a particle conversion intensity
DE102008033096A1 (en) * 2008-07-15 2010-02-11 Uhde Gmbh Method and device for igniting and operating burners in the gasification of carbonaceous fuels
DE102008035295B4 (en) * 2008-07-29 2013-10-17 Siemens Aktiengesellschaft Carbon monoxide conversion by means of stepped quenching
DE102008049716A1 (en) * 2008-09-30 2010-04-08 Siemens Aktiengesellschaft Use of the sensible heat of the raw gas in the flow stream gasification
US8357215B2 (en) 2009-03-04 2013-01-22 General Electric Company Method and apparatus of particulate removal from gasifier components
DE102009011174A1 (en) 2009-03-04 2010-09-09 Uhde Gmbh Synthesis gas manufacturing method, involves occurring of entrained gasification, via which temperature of gas to be discharged is reduced and enthalpy difference is utilized for additive gasification of raw materials to be re-accumulated
PL2403928T3 (en) 2009-03-04 2017-12-29 Thyssenkrupp Industrial Solutions Ag Process and apparatus for utilizing the enthalpy of a synthesis gas by means of additional and post-gassing of renewable fuels
DE102010008384A1 (en) 2010-02-17 2011-08-18 Uhde GmbH, 44141 Method for utilizing enthalpy of synthesis gas during endothermic gasification reaction of biological raw material, involves introducing fuel into gas so that thermal enthalpy of gas is utilized for gasification reaction of material
JP4486699B1 (en) * 2009-11-06 2010-06-23 株式会社リ・サイエンスシステム研究所 Method for reforming organic waste with generation of hydrogen gas and apparatus for reforming organic waste
KR101096632B1 (en) * 2009-12-10 2011-12-21 에스케이이노베이션 주식회사 Top feeding dual swirling gasifier
US8480769B2 (en) * 2010-07-29 2013-07-09 Air Products And Chemicals, Inc. Method for gasification and a gasifier
DE102011008187B4 (en) * 2011-01-10 2015-08-27 Suncoal Industries Gmbh Process for the production of fuel and synthesis gas
DE102011107726B4 (en) 2011-07-14 2016-06-30 Thyssenkrupp Industrial Solutions Ag Apparatus and method for introducing renewable fuels into the region of the radiation vessel wall of gasification reactors
US20130330236A1 (en) * 2012-06-12 2013-12-12 General Electric Company System for initiating a gasification reaction in a gasifier
CN103589460A (en) * 2012-08-16 2014-02-19 王庆 Waste heat boiler process water-cooled wall coal water slurry gasification furnace provided with ignition furnace end
DE102014219455B4 (en) 2013-09-25 2019-08-14 Technische Universität Bergakademie Freiberg Method and device for partial conversion of raw gases of entrained flow gasification
CN104019460B (en) * 2014-06-20 2016-08-24 航天长征化学工程股份有限公司 A kind of water wall gasifier dross method and apparatus
CN104403694B (en) * 2014-10-16 2017-02-15 煤炭科学技术研究院有限公司 Liquid-state continuous slag discharge device and slag discharge method of fixed bed gasification furnace
CN105482852B (en) * 2015-11-20 2018-03-30 新奥科技发展有限公司 A kind of gasification furnace and coal hydrogenation gasification method
US10781384B2 (en) * 2015-12-16 2020-09-22 Air Products And Chemicals, Inc. Gasification system and process
DE102017005627A1 (en) 2016-10-07 2018-04-12 Lennart Feldmann Method and system for improving the greenhouse gas emission reduction performance of biogenic fuels, heating fuels and / or for enrichment of agricultural land with Humus-C
CN107129833B (en) * 2017-06-23 2024-03-29 航天长征化学工程股份有限公司 Annular pulverized coal cavity
CN107892952B (en) * 2017-11-13 2019-09-06 煤炭科学技术研究院有限公司 A kind of two-part slag gasification furnace
CN107674712B (en) * 2017-11-13 2019-09-06 煤炭科学技术研究院有限公司 A kind of fixed bed slag gasification furnace
RO134445B1 (en) * 2020-05-18 2021-06-30 Bogdan-Sabin Frâncu Process and plant for gasification of heterogenous mixtures of organic substances and compounds

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DE4404673C2 (en) * 1994-02-15 1995-11-23 Entec Recycling Und Industriea Process for the production of fuel gas

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7776114B2 (en) 2005-07-28 2010-08-17 Choren Industries Gmbh Process and apparatus for the endothermic gasification of carbon
DE102010033646B4 (en) * 2010-02-05 2012-05-24 Pyrox Gmbh Method and shaft carburetor for producing fuel gas from a solid fuel
CN102399590A (en) * 2011-10-08 2012-04-04 湖北双环科技股份有限公司 Rich oxygen gasification production method
CN102399590B (en) * 2011-10-08 2014-02-19 湖北双环科技股份有限公司 Rich oxygen gasification production method

Also Published As

Publication number Publication date
ATE200791T1 (en) 2001-05-15
BR9813292B1 (en) 2009-12-01
CA2306889C (en) 2008-12-16
NO328487B1 (en) 2010-03-01
AR010952A1 (en) 2000-07-12
DE59800654D1 (en) 2001-05-31
PL190794B1 (en) 2006-01-31
GR3036233T3 (en) 2001-10-31
CN1278292A (en) 2000-12-27
ZA989759B (en) 1999-05-03
DE19747324C2 (en) 1999-11-04
DK1027407T3 (en) 2001-08-13
DE19747324A1 (en) 1999-04-29
PT1027407E (en) 2001-10-30
BR9813292A (en) 2000-08-22
JP4112173B2 (en) 2008-07-02
ID21135A (en) 1999-04-29
AU754147B2 (en) 2002-11-07
ES2157673T3 (en) 2001-08-16
WO1999021940A1 (en) 1999-05-06
EP1027407B1 (en) 2001-04-25
PL340217A1 (en) 2001-01-15
JP2001521056A (en) 2001-11-06
TW518363B (en) 2003-01-21
CN1136299C (en) 2004-01-28
NO20001993D0 (en) 2000-04-17
MY127842A (en) 2006-12-29
EP1027407A1 (en) 2000-08-16
NO20001993L (en) 2000-06-15
AU9542798A (en) 1999-05-17

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Effective date: 20181009