CA2293223A1 - Electrochemical method for determinating lignin content of pulp - Google Patents

Electrochemical method for determinating lignin content of pulp Download PDF

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Publication number
CA2293223A1
CA2293223A1 CA002293223A CA2293223A CA2293223A1 CA 2293223 A1 CA2293223 A1 CA 2293223A1 CA 002293223 A CA002293223 A CA 002293223A CA 2293223 A CA2293223 A CA 2293223A CA 2293223 A1 CA2293223 A1 CA 2293223A1
Authority
CA
Canada
Prior art keywords
pulp
lignin
voltammetric
kappa
redox
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002293223A
Other languages
French (fr)
Other versions
CA2293223C (en
Inventor
Michael G. Paice
Robert Bourbonnais
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pulp and Paper Research Institute of Canada
Original Assignee
Pulp and Paper Research Institute of Canada
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA002293223A priority Critical patent/CA2293223C/en
Application filed by Pulp and Paper Research Institute of Canada filed Critical Pulp and Paper Research Institute of Canada
Priority to EP00984729A priority patent/EP1240384B1/en
Priority to AT00984729T priority patent/ATE252177T1/en
Priority to PT00984729T priority patent/PT1240384E/en
Priority to JP2001548803A priority patent/JP2003518613A/en
Priority to PCT/CA2000/001518 priority patent/WO2001048307A1/en
Priority to ES00984729T priority patent/ES2208445T3/en
Priority to BR0016663-4A priority patent/BR0016663A/en
Priority to AU21373/01A priority patent/AU2137301A/en
Priority to DE60005997T priority patent/DE60005997D1/en
Publication of CA2293223A1 publication Critical patent/CA2293223A1/en
Priority to US10/157,601 priority patent/US20020144795A1/en
Application granted granted Critical
Publication of CA2293223C publication Critical patent/CA2293223C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/1026—Other features in bleaching processes
    • D21C9/1052—Controlling the process
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/1021—Electrochemical processes

Abstract

This invention describes a new method to measure kappa number or lignin content of kraft pulps based on the voltammetric measurement of catalytic reactions involving lignin and redox mediators. This method comprises measuring the rate of regeneration of a lignin redox catalyst in the presence of pulp following its oxidation at a voltammetric electrode.

The intensity of the catalytic current generated at the electrode surface is shown to be proportional to the amount of lignin present in a pulp. Within pulp types (softwood, hardwood or oxygen delignified) linear relationships can be obtained between the intensities of the generated current and a range of kappa numbers. The redox characteristics and concentration of the mediator, and the voltage sweep rate of the voltammetric procedure, are among parameters that can be tuned to obtained linear relationships with kappa number of various pulps. Automation of this method can lead to development of a novel on-line electro-kappa analyzer to be used for either pulping or bleaching process control.
CA002293223A 1999-12-23 1999-12-23 Electrochemical method for determinating lignin content of pulp Expired - Fee Related CA2293223C (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
CA002293223A CA2293223C (en) 1999-12-23 1999-12-23 Electrochemical method for determinating lignin content of pulp
AU21373/01A AU2137301A (en) 1999-12-23 2000-12-19 Electrochemical method for determinating lignin content of pulp
PT00984729T PT1240384E (en) 1999-12-23 2000-12-19 ELECTROCHEMICAL METHOD FOR DETERMINING THE CONTENT OF LENHINA PASTE
JP2001548803A JP2003518613A (en) 1999-12-23 2000-12-19 An electrochemical method for determining the lignin content of pulp
PCT/CA2000/001518 WO2001048307A1 (en) 1999-12-23 2000-12-19 Electrochemical method for determinating lignin content of pulp
ES00984729T ES2208445T3 (en) 1999-12-23 2000-12-19 ELCTROCHEMICAL PROCEDURE TO DETERMINE THE LIGNIN CONTENT OF THE CELLULOSE PASTE.
EP00984729A EP1240384B1 (en) 1999-12-23 2000-12-19 Electrochemical method for determining lignin content of pulp
AT00984729T ATE252177T1 (en) 1999-12-23 2000-12-19 ELECTROCHEMICAL METHOD FOR DETERMINING THE LIGNIN CONTENT IN PULP
DE60005997T DE60005997D1 (en) 1999-12-23 2000-12-19 ELECTROCHEMICAL METHOD FOR DETERMINING THE LIGNIN CONTENT IN PULP
BR0016663-4A BR0016663A (en) 1999-12-23 2000-12-19 Methods to determine a pulp's cover number or lignin content, and to analyze a pulp's lignin content, and automated online procedure for determining the cover number
US10/157,601 US20020144795A1 (en) 1999-12-23 2002-05-30 Electrochemical method for determinating lignin content of pulp

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA002293223A CA2293223C (en) 1999-12-23 1999-12-23 Electrochemical method for determinating lignin content of pulp

Publications (2)

Publication Number Publication Date
CA2293223A1 true CA2293223A1 (en) 2001-06-23
CA2293223C CA2293223C (en) 2004-02-10

Family

ID=4164977

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002293223A Expired - Fee Related CA2293223C (en) 1999-12-23 1999-12-23 Electrochemical method for determinating lignin content of pulp

Country Status (11)

Country Link
US (1) US20020144795A1 (en)
EP (1) EP1240384B1 (en)
JP (1) JP2003518613A (en)
AT (1) ATE252177T1 (en)
AU (1) AU2137301A (en)
BR (1) BR0016663A (en)
CA (1) CA2293223C (en)
DE (1) DE60005997D1 (en)
ES (1) ES2208445T3 (en)
PT (1) PT1240384E (en)
WO (1) WO2001048307A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10043893A1 (en) * 2000-09-06 2002-03-14 Voith Paper Patent Gmbh Process for carrying out a flotation, bleaching and / or dispersing process used for fiber or paper production
EP2548955A1 (en) 2006-02-14 2013-01-23 Verenium Corporation Xylanases, nucleic acids encoding them and methods for making and using them
JP5744518B2 (en) 2007-10-03 2015-07-08 ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド Xylanase, nucleic acids encoding xylanase and methods for producing and using them
GB2476237B (en) * 2009-12-15 2012-01-11 Schlumberger Holdings Calibration of electrochemical sensor
CN107607596B (en) * 2017-08-08 2019-09-06 福建农林大学 A kind of online test method and device of the sulfate pulping process paper pulp kappa number based on flow analysis
CN107589158B (en) * 2017-08-08 2019-09-06 福建农林大学 A kind of online test method and device of the sulfate pulping process paper pulp kappa number based on double electrochemical sensors

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4065348A (en) * 1975-04-23 1977-12-27 Westvaco Corporation Method and apparatus for detecting and controlling the caustic in paper pulp bleaching
FI80526C (en) * 1986-09-08 1990-06-11 Savcor Consulting Oy Method for controlling cellulose boiling
DD280790A1 (en) * 1987-04-14 1990-07-18 Akad Wissenschaften Ddr BIOSENSOR AND METHOD FOR DETERMINING MEDIATORS
US5220172A (en) * 1991-09-23 1993-06-15 The Babcock & Wilcox Company Fluorescence analyzer for lignin
US5389356A (en) * 1993-01-05 1995-02-14 Utah State University Foundation Compounds and methods for generating oxygen free radicals used in general oxidation and reduction reactions
US5486915A (en) * 1994-04-12 1996-01-23 The Babcock & Wilcox Company On-line measurement of lignin in wood pulp by color shift of fluorescence
DE19742748A1 (en) * 1997-09-27 1999-04-01 Degussa Process for delignifying and bleaching pulps using electrochemically oxidizable organic compounds
US5953111A (en) * 1997-12-11 1999-09-14 Honeywell Inc. Continuous in-line kappa measurement system
ATE224476T1 (en) * 1998-04-16 2002-10-15 Pulp Paper Res Inst METHOD FOR PULP AND DYE OXIDATION USING OXIDASE

Also Published As

Publication number Publication date
CA2293223C (en) 2004-02-10
ATE252177T1 (en) 2003-11-15
PT1240384E (en) 2004-03-31
WO2001048307A8 (en) 2002-01-24
BR0016663A (en) 2002-09-03
DE60005997D1 (en) 2003-11-20
JP2003518613A (en) 2003-06-10
ES2208445T3 (en) 2004-06-16
US20020144795A1 (en) 2002-10-10
AU2137301A (en) 2001-07-09
EP1240384B1 (en) 2003-10-15
EP1240384A1 (en) 2002-09-18
WO2001048307A1 (en) 2001-07-05

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