CA2287648A1 - Amorphous metal/metallic glass electrodes for electrochemical processes - Google Patents

Amorphous metal/metallic glass electrodes for electrochemical processes Download PDF

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Publication number
CA2287648A1
CA2287648A1 CA002287648A CA2287648A CA2287648A1 CA 2287648 A1 CA2287648 A1 CA 2287648A1 CA 002287648 A CA002287648 A CA 002287648A CA 2287648 A CA2287648 A CA 2287648A CA 2287648 A1 CA2287648 A1 CA 2287648A1
Authority
CA
Canada
Prior art keywords
metallic glass
amorphous metal
alloy
represent
aqueous electrolyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002287648A
Other languages
French (fr)
Other versions
CA2287648C (en
Inventor
Donald W. Kirk
Steven J. Thorpe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA002287648A priority Critical patent/CA2287648C/en
Application filed by Individual filed Critical Individual
Priority to JP2001533216A priority patent/JP2003513170A/en
Priority to MXPA02002673A priority patent/MXPA02002673A/en
Priority to AU10135/01A priority patent/AU1013501A/en
Priority to EP00971182A priority patent/EP1230412A2/en
Priority to BR0014994-2A priority patent/BR0014994A/en
Priority to KR1020027004542A priority patent/KR20020037772A/en
Priority to PCT/CA2000/001251 priority patent/WO2001031085A2/en
Priority to CN00814770A priority patent/CN1382229A/en
Publication of CA2287648A1 publication Critical patent/CA2287648A1/en
Priority to NO20020957A priority patent/NO20020957L/en
Priority to ZA200201857A priority patent/ZA200201857B/en
Application granted granted Critical
Publication of CA2287648C publication Critical patent/CA2287648C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C33/00—Making ferrous alloys
    • C22C33/003—Making ferrous alloys making amorphous alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C45/00—Amorphous alloys
    • C22C45/04—Amorphous alloys with nickel or cobalt as the major constituent
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/061—Metal or alloy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

Metallic glass / amorphous metal electrodes produced by rapid solidification (i) having a structure that is either amorphous or nanocrystalline, (ii) containing the principal alloying element as Ni, (iii) containing alloying additions of Co and at least one member of group IVB, VB, VIB VIIB and/or VIIIB, preferably Cr and V, in the range of 0 to 20 at. %, and when combined with Ni, represent 0.75 to 0.85 of the atomic fraction of the alloy, and (iv) containing metalloid elements compris ed preferably of one or more of the elements C, B, Si and P either singly or in combination to represent 0.15 to 0.25 atomic faction of the alloy. The electrodes have excellent thermal stability, improved stability in an aqueous electrolyte and can provide improved current efficiency - anodic overpotential performance. They are used in the electrolysis of aqueous electrolyte solutions such as mixtures of caustic and water in th e production of oxygen and hydrogen.
CA002287648A 1999-10-26 1999-10-26 Amorphous metal/metallic glass electrodes for electrochemical processes Expired - Fee Related CA2287648C (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
CA002287648A CA2287648C (en) 1999-10-26 1999-10-26 Amorphous metal/metallic glass electrodes for electrochemical processes
CN00814770A CN1382229A (en) 1999-10-26 2000-10-23 Amorphous metal/metallic glass electrodes for electrochemical processes
AU10135/01A AU1013501A (en) 1999-10-26 2000-10-23 Amorphous metal/metallic glass electrodes for electrochemical processes
EP00971182A EP1230412A2 (en) 1999-10-26 2000-10-23 Amorphous metal/metallic glass electrodes for electrochemical processes
BR0014994-2A BR0014994A (en) 1999-10-26 2000-10-23 Metallic glass for use in electrochemical processes, electrode for use in an electrochemical cell, and, process for the electrochemical production of oxygen and hydrogen from an aqueous solution in an electrochemical cell
KR1020027004542A KR20020037772A (en) 1999-10-26 2000-10-23 Amorphous metal/metallic glass electrodes for electrochemical processes
JP2001533216A JP2003513170A (en) 1999-10-26 2000-10-23 Amorphous metal / metallic glass electrodes for electrochemical methods
MXPA02002673A MXPA02002673A (en) 1999-10-26 2000-10-23 Amorphous metal metallic glass electrodes for electrochemical processes.
PCT/CA2000/001251 WO2001031085A2 (en) 1999-10-26 2000-10-23 Amorphous metal/metallic glass electrodes for electrochemical processes
NO20020957A NO20020957L (en) 1999-10-26 2002-02-27 Amorphous metal / metal flap electrodes for electrochemical processes
ZA200201857A ZA200201857B (en) 1999-10-26 2002-03-06 Amorphous metal/metallic glass electrodes for electrochemical process.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA002287648A CA2287648C (en) 1999-10-26 1999-10-26 Amorphous metal/metallic glass electrodes for electrochemical processes

Publications (2)

Publication Number Publication Date
CA2287648A1 true CA2287648A1 (en) 2001-04-26
CA2287648C CA2287648C (en) 2007-06-19

Family

ID=4164494

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002287648A Expired - Fee Related CA2287648C (en) 1999-10-26 1999-10-26 Amorphous metal/metallic glass electrodes for electrochemical processes

Country Status (11)

Country Link
EP (1) EP1230412A2 (en)
JP (1) JP2003513170A (en)
KR (1) KR20020037772A (en)
CN (1) CN1382229A (en)
AU (1) AU1013501A (en)
BR (1) BR0014994A (en)
CA (1) CA2287648C (en)
MX (1) MXPA02002673A (en)
NO (1) NO20020957L (en)
WO (1) WO2001031085A2 (en)
ZA (1) ZA200201857B (en)

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KR100647672B1 (en) 2004-12-24 2006-11-23 삼성에스디아이 주식회사 A transparent electrode with thermal stability, a fabrication method of the same and a dye-sensitized solar cell comprising the same
JP4992085B2 (en) * 2007-02-23 2012-08-08 国立大学法人東京工業大学 Film-like catalyst composition for electroless plating
EP2217744A2 (en) * 2007-11-16 2010-08-18 Akzo Nobel N.V. Electrode
EP2325848B1 (en) 2009-11-11 2017-07-19 Samsung Electronics Co., Ltd. Conductive paste and solar cell
US9947809B2 (en) 2009-11-11 2018-04-17 Samsung Electronics Co., Ltd. Conductive paste and electronic device and solar cell including an electrode formed using the conductive paste
EP2596141B1 (en) 2010-07-21 2014-11-12 Rolex Sa Amorphous metal alloy
WO2012010941A1 (en) * 2010-07-21 2012-01-26 Rolex S.A. Watch-making or clock-making component comprising an amorphous metal alloy
KR101741683B1 (en) 2010-08-05 2017-05-31 삼성전자주식회사 Conductive paste and electronic device and solar cell including an electrode formed using the conductive paste
US8668847B2 (en) 2010-08-13 2014-03-11 Samsung Electronics Co., Ltd. Conductive paste and electronic device and solar cell including an electrode formed using the conductive paste
US8987586B2 (en) 2010-08-13 2015-03-24 Samsung Electronics Co., Ltd. Conductive paste and electronic device and solar cell including an electrode formed using the conductive paste
KR101741682B1 (en) 2010-08-24 2017-05-31 삼성전자주식회사 Conductive paste and electronic device and solar cell including an electrode formed using the conductive paste
US8974703B2 (en) 2010-10-27 2015-03-10 Samsung Electronics Co., Ltd. Conductive paste and electronic device and solar cell including an electrode formed using the same
US9105370B2 (en) 2011-01-12 2015-08-11 Samsung Electronics Co., Ltd. Conductive paste, and electronic device and solar cell including an electrode formed using the same
US8940195B2 (en) 2011-01-13 2015-01-27 Samsung Electronics Co., Ltd. Conductive paste, and electronic device and solar cell including an electrode formed using the same
KR101814014B1 (en) 2011-03-25 2018-01-03 삼성전자주식회사 Conductive paste and electronic device and solar cell including an electrode formed using the conductive paste
KR101796658B1 (en) 2011-03-28 2017-11-13 삼성전자주식회사 Conductive paste and electronic device and solar cell including an electrode formed using the conductive paste
WO2013029186A1 (en) 2011-09-01 2013-03-07 Trudel Simon Electrocatalytic materials and methods for manufacturing same
KR101985929B1 (en) 2011-12-09 2019-06-05 삼성전자주식회사 Conductive paste and electronic device and solar cell including an electrode formed using the conductive paste
JP5822235B2 (en) * 2012-06-08 2015-11-24 住友金属鉱山エンジニアリング株式会社 Method for removing oxidized nitrogen
KR101999795B1 (en) 2012-06-27 2019-07-12 삼성전자주식회사 Conductive paste and electronic device and solar cell including an electrode formed using the conductive paste
WO2015005932A1 (en) * 2013-07-12 2015-01-15 Hewlett-Packard Development Company, L.P. Amorphous thin metal film
JP5949792B2 (en) * 2014-01-15 2016-07-13 株式会社豊田中央研究所 Crystalline electrode material and insoluble electrode
US10177310B2 (en) 2014-07-30 2019-01-08 Hewlett Packard Enterprise Development Lp Amorphous metal alloy electrodes in non-volatile device applications
US10399166B2 (en) 2015-10-30 2019-09-03 General Electric Company System and method for machining workpiece of lattice structure and article machined therefrom
CN108660474B (en) * 2018-06-01 2020-02-07 北京航空航天大学 (FeaCobNic)xMyRzOxygen evolution catalytic material and application thereof on anode oxygen evolution electrode
KR102092346B1 (en) * 2019-09-23 2020-03-23 삼성전자주식회사 Transparent conductor and method of manufacturing the same and electronic device including the transparent conductor
CN114192749B (en) * 2020-09-17 2023-08-01 南京理工大学 Method for preparing nano material by electrodeposition based on corrosion amorphous alloy anode material
CN114672716B (en) * 2022-04-11 2022-11-01 大连理工大学 CoCrNi with high strength and toughness in heat treatment state2(V2B)xEutectic high-entropy alloy and preparation method thereof
CN115558951A (en) * 2022-10-18 2023-01-03 海南大学 Amorphous nano porous nickel alloy integrated electrode, preparation method and application thereof

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Also Published As

Publication number Publication date
NO20020957D0 (en) 2002-02-27
WO2001031085A3 (en) 2001-09-20
JP2003513170A (en) 2003-04-08
CA2287648C (en) 2007-06-19
BR0014994A (en) 2002-06-18
NO20020957L (en) 2002-04-24
WO2001031085A2 (en) 2001-05-03
ZA200201857B (en) 2002-12-24
AU1013501A (en) 2001-05-08
KR20020037772A (en) 2002-05-22
EP1230412A2 (en) 2002-08-14
CN1382229A (en) 2002-11-27
MXPA02002673A (en) 2003-10-14

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Effective date: 20121026