CA2267379A1 - Alkoxylated, quaternized polyamine detergent ingredients - Google Patents
Alkoxylated, quaternized polyamine detergent ingredients Download PDFInfo
- Publication number
- CA2267379A1 CA2267379A1 CA002267379A CA2267379A CA2267379A1 CA 2267379 A1 CA2267379 A1 CA 2267379A1 CA 002267379 A CA002267379 A CA 002267379A CA 2267379 A CA2267379 A CA 2267379A CA 2267379 A1 CA2267379 A1 CA 2267379A1
- Authority
- CA
- Canada
- Prior art keywords
- units
- alkyl
- formula
- mixtures
- moiety
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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- 239000003599 detergent Substances 0.000 title claims abstract description 155
- 229920000768 polyamine Polymers 0.000 title claims abstract description 21
- 239000004615 ingredient Substances 0.000 title claims description 58
- 239000000203 mixture Substances 0.000 claims abstract description 317
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 29
- 239000002689 soil Substances 0.000 claims description 138
- -1 alkyleneoxyalkylene Chemical group 0.000 claims description 136
- 239000002270 dispersing agent Substances 0.000 claims description 85
- 229920000642 polymer Polymers 0.000 claims description 61
- 239000004094 surface-active agent Substances 0.000 claims description 51
- 239000004744 fabric Substances 0.000 claims description 49
- 108010065511 Amylases Proteins 0.000 claims description 38
- 102000013142 Amylases Human genes 0.000 claims description 38
- 125000000217 alkyl group Chemical group 0.000 claims description 37
- 239000003795 chemical substances by application Substances 0.000 claims description 36
- 229920000742 Cotton Polymers 0.000 claims description 35
- 239000007788 liquid Substances 0.000 claims description 35
- 108090001060 Lipase Proteins 0.000 claims description 34
- 102000004882 Lipase Human genes 0.000 claims description 34
- 150000002148 esters Chemical class 0.000 claims description 33
- 150000003839 salts Chemical group 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 30
- 229920002873 Polyethylenimine Polymers 0.000 claims description 29
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims description 28
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 28
- 150000001768 cations Chemical class 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- 229920001577 copolymer Polymers 0.000 claims description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims description 19
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 16
- 125000000732 arylene group Chemical group 0.000 claims description 15
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 14
- 239000005977 Ethylene Substances 0.000 claims description 14
- 229920005646 polycarboxylate Polymers 0.000 claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 11
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 10
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 10
- 150000001450 anions Chemical class 0.000 claims description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 8
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 125000004450 alkenylene group Chemical group 0.000 claims description 6
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 5
- 229940077388 benzenesulfonate Drugs 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- 150000001346 alkyl aryl ethers Chemical group 0.000 claims description 3
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 3
- 229940044652 phenolsulfonate Drugs 0.000 claims description 3
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims description 2
- WLXGQMVCYPUOLM-UHFFFAOYSA-N 1-hydroxyethanesulfonic acid Chemical compound CC(O)S(O)(=O)=O WLXGQMVCYPUOLM-UHFFFAOYSA-N 0.000 claims description 2
- CLHYKAZPWIRRRD-UHFFFAOYSA-N 1-hydroxypropane-1-sulfonic acid Chemical group CCC(O)S(O)(=O)=O CLHYKAZPWIRRRD-UHFFFAOYSA-N 0.000 claims description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 2
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 2
- 125000000743 hydrocarbylene group Chemical group 0.000 claims description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 4
- 229910006067 SO3−M Inorganic materials 0.000 claims 2
- 125000004958 1,4-naphthylene group Chemical group 0.000 claims 1
- BYDRTKVGBRTTIT-UHFFFAOYSA-N 2-methylprop-2-en-1-ol Chemical compound CC(=C)CO BYDRTKVGBRTTIT-UHFFFAOYSA-N 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 150000002009 diols Chemical class 0.000 claims 1
- 150000002334 glycols Chemical class 0.000 claims 1
- 238000006277 sulfonation reaction Methods 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 description 69
- 102000004190 Enzymes Human genes 0.000 description 54
- 108090000790 Enzymes Proteins 0.000 description 54
- 229940088598 enzyme Drugs 0.000 description 54
- 238000004140 cleaning Methods 0.000 description 50
- 239000000463 material Substances 0.000 description 42
- 150000001875 compounds Chemical class 0.000 description 36
- 235000019418 amylase Nutrition 0.000 description 34
- 239000004382 Amylase Substances 0.000 description 30
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 29
- 239000011734 sodium Substances 0.000 description 29
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 28
- 229920001223 polyethylene glycol Polymers 0.000 description 28
- 239000012190 activator Substances 0.000 description 27
- 239000004367 Lipase Substances 0.000 description 26
- 150000001412 amines Chemical class 0.000 description 26
- 229940025131 amylases Drugs 0.000 description 26
- 235000019421 lipase Nutrition 0.000 description 26
- 229910052708 sodium Inorganic materials 0.000 description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 24
- 239000000047 product Substances 0.000 description 24
- 108091005804 Peptidases Proteins 0.000 description 22
- 102000035195 Peptidases Human genes 0.000 description 22
- 230000008901 benefit Effects 0.000 description 22
- 235000019441 ethanol Nutrition 0.000 description 22
- 238000005406 washing Methods 0.000 description 21
- 239000003054 catalyst Substances 0.000 description 20
- 239000004927 clay Substances 0.000 description 20
- 238000004061 bleaching Methods 0.000 description 19
- 235000014113 dietary fatty acids Nutrition 0.000 description 19
- 239000000194 fatty acid Substances 0.000 description 19
- 229930195729 fatty acid Natural products 0.000 description 19
- 230000002209 hydrophobic effect Effects 0.000 description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
- 239000000243 solution Substances 0.000 description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 18
- 239000007859 condensation product Substances 0.000 description 18
- 229920001296 polysiloxane Polymers 0.000 description 17
- 239000004365 Protease Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 16
- 238000009472 formulation Methods 0.000 description 16
- 238000004900 laundering Methods 0.000 description 16
- 239000002245 particle Substances 0.000 description 16
- 239000002304 perfume Substances 0.000 description 16
- 239000002253 acid Substances 0.000 description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 150000004665 fatty acids Chemical group 0.000 description 15
- 239000000178 monomer Substances 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- 239000002736 nonionic surfactant Substances 0.000 description 14
- 239000000460 chlorine Substances 0.000 description 13
- 238000004851 dishwashing Methods 0.000 description 13
- 239000000975 dye Substances 0.000 description 13
- 229910052700 potassium Inorganic materials 0.000 description 13
- 238000012546 transfer Methods 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 12
- 229920000728 polyester Polymers 0.000 description 12
- 239000011591 potassium Substances 0.000 description 12
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 11
- 239000011575 calcium Substances 0.000 description 11
- 229910052801 chlorine Inorganic materials 0.000 description 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 241000894007 species Species 0.000 description 11
- 239000000758 substrate Substances 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 10
- DMULVCHRPCFFGV-UHFFFAOYSA-N N,N-dimethyltryptamine Chemical compound C1=CC=C2C(CCN(C)C)=CNC2=C1 DMULVCHRPCFFGV-UHFFFAOYSA-N 0.000 description 10
- 239000002202 Polyethylene glycol Substances 0.000 description 10
- 229910052783 alkali metal Inorganic materials 0.000 description 10
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 10
- 230000006872 improvement Effects 0.000 description 10
- 230000003287 optical effect Effects 0.000 description 10
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 9
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 9
- 150000001204 N-oxides Chemical class 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 9
- 150000001413 amino acids Chemical group 0.000 description 9
- 239000002738 chelating agent Substances 0.000 description 9
- 239000008103 glucose Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 235000013772 propylene glycol Nutrition 0.000 description 9
- 150000004760 silicates Chemical class 0.000 description 9
- 239000010457 zeolite Substances 0.000 description 9
- 108010084185 Cellulases Proteins 0.000 description 8
- 102000005575 Cellulases Human genes 0.000 description 8
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 8
- 125000000129 anionic group Chemical group 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 229910052791 calcium Inorganic materials 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000007046 ethoxylation reaction Methods 0.000 description 8
- 229940093476 ethylene glycol Drugs 0.000 description 8
- 230000003203 everyday effect Effects 0.000 description 8
- 230000006870 function Effects 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
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- 229920001451 polypropylene glycol Polymers 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 239000000523 sample Substances 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 8
- 230000000087 stabilizing effect Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 7
- 241000193830 Bacillus <bacterium> Species 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 102000003992 Peroxidases Human genes 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
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- 229910000323 aluminium silicate Inorganic materials 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 150000007942 carboxylates Chemical class 0.000 description 7
- 229910017052 cobalt Inorganic materials 0.000 description 7
- 239000010941 cobalt Substances 0.000 description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
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- 239000011777 magnesium Substances 0.000 description 7
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 7
- 230000001590 oxidative effect Effects 0.000 description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 238000006467 substitution reaction Methods 0.000 description 7
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 241000223258 Thermomyces lanuginosus Species 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- 125000000539 amino acid group Chemical group 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 6
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- 230000002401 inhibitory effect Effects 0.000 description 6
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- FQUAWOQWQIVZLB-UHFFFAOYSA-M sodium;2-(2,3-dihydroxypropoxy)ethanesulfonate Chemical compound [Na+].OCC(O)COCCS([O-])(=O)=O FQUAWOQWQIVZLB-UHFFFAOYSA-M 0.000 description 6
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 6
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- XRQFJUYYMJOWCT-UHFFFAOYSA-M sodium;2-[2-(2-hydroxyethoxy)ethoxy]ethanesulfonate Chemical compound [Na+].OCCOCCOCCS([O-])(=O)=O XRQFJUYYMJOWCT-UHFFFAOYSA-M 0.000 description 5
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- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 4
- FKUPPRZPSYCDRS-UHFFFAOYSA-N Cyclopentadecanolide Chemical compound O=C1CCCCCCCCCCCCCCO1 FKUPPRZPSYCDRS-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical compound [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
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- 239000007790 solid phase Substances 0.000 description 1
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- 229910001220 stainless steel Inorganic materials 0.000 description 1
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- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003512 tertiary amines Chemical group 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical group NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-M toluenesulfonate group Chemical group C=1(C(=CC=CC1)S(=O)(=O)[O-])C LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
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- 229910052723 transition metal Inorganic materials 0.000 description 1
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- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
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- 230000002087 whitening effect Effects 0.000 description 1
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- FUQAYSQLAOJBBC-PAPYEOQZSA-N β-caryophyllene alcohol Chemical compound C1C[C@](C2)(C)CCC[C@]2(O)[C@H]2CC(C)(C)[C@@H]21 FUQAYSQLAOJBBC-PAPYEOQZSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3792—Amine oxide containing polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2790296P | 1996-10-07 | 1996-10-07 | |
| US60/027,902 | 1996-10-07 | ||
| PCT/US1997/017308 WO1998015608A2 (en) | 1996-10-07 | 1997-10-01 | Alkoxylated, quaternized polyamine detergent ingredients |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2267379A1 true CA2267379A1 (en) | 1998-04-16 |
Family
ID=21840426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002267379A Abandoned CA2267379A1 (en) | 1996-10-07 | 1997-10-01 | Alkoxylated, quaternized polyamine detergent ingredients |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP0929634A2 (es) |
| JP (1) | JP2000505139A (es) |
| CN (1) | CN1239985A (es) |
| AR (1) | AR011243A1 (es) |
| AU (1) | AU4653297A (es) |
| BR (1) | BR9712496A (es) |
| CA (1) | CA2267379A1 (es) |
| HU (1) | HUP0000235A3 (es) |
| MA (1) | MA24367A1 (es) |
| TR (1) | TR199900790T2 (es) |
| WO (1) | WO1998015608A2 (es) |
| ZA (1) | ZA978601B (es) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2001243202A1 (en) * | 2000-02-23 | 2001-09-03 | The Procter And Gamble Company | Laundry detergent compositions comprising zwitterionic polyamines and xyloglucanase |
| CN1237162C (zh) | 2000-02-23 | 2006-01-18 | 宝洁公司 | 具有增强泥土清除益处的液体衣用洗涤剂组合物 |
| BRPI0610717A2 (pt) * | 2005-04-15 | 2010-07-20 | Procter & Gamble | composições detergentes lìquidas para lavagem de roupas com polìmeros de polietileno imina modificada e enzima lipase |
| DE602006020853D1 (de) * | 2006-07-07 | 2011-05-05 | Procter & Gamble | Waschmittelzusammensetzungen |
| WO2009153184A1 (en) * | 2008-06-16 | 2009-12-23 | Unilever Plc | Improvements relating to fabric cleaning |
| GB0810881D0 (en) * | 2008-06-16 | 2008-07-23 | Unilever Plc | Improvements relating to fabric cleaning |
| EP3023483A1 (en) | 2009-02-02 | 2016-05-25 | The Procter and Gamble Company | Liquid hand diswashing detergent composition |
| EP2216392B1 (en) * | 2009-02-02 | 2013-11-13 | The Procter and Gamble Company | Liquid hand dishwashing detergent composition |
| EP2213714B1 (en) | 2009-02-02 | 2014-06-11 | The Procter and Gamble Company | Liquid hand dishwashing detergent composition |
| EP2476743B1 (en) * | 2011-04-04 | 2013-04-24 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Method of laundering fabric |
| US9994799B2 (en) | 2012-09-13 | 2018-06-12 | Ecolab Usa Inc. | Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use |
| US9023784B2 (en) | 2012-09-13 | 2015-05-05 | Ecolab Usa Inc. | Method of reducing soil redeposition on a hard surface using phosphinosuccinic acid adducts |
| US9752105B2 (en) | 2012-09-13 | 2017-09-05 | Ecolab Usa Inc. | Two step method of cleaning, sanitizing, and rinsing a surface |
| US8871699B2 (en) | 2012-09-13 | 2014-10-28 | Ecolab Usa Inc. | Detergent composition comprising phosphinosuccinic acid adducts and methods of use |
| US20140308162A1 (en) | 2013-04-15 | 2014-10-16 | Ecolab Usa Inc. | Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing |
| DE102012223336A1 (de) * | 2012-12-17 | 2014-06-18 | Henkel Ag & Co. Kgaa | Wasch- und Reinigungsmittel mit polyalkoxyliertem Polyamin und angepasstem Niotensid |
| EP3039109B1 (en) | 2013-08-26 | 2017-09-13 | The Procter and Gamble Company | Compositions comprising alkoxylated polyamines having low melting points |
| JP6684558B2 (ja) * | 2015-09-03 | 2020-04-22 | ライオン株式会社 | 衣料用液体洗浄剤 |
| EP3386937B1 (en) | 2015-12-07 | 2021-06-23 | Uop Llc | Two-bed paraffin to olefin enhancement process |
| US20190177665A1 (en) * | 2016-08-08 | 2019-06-13 | Basf Se | Liquid laundry formulation |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8512638D0 (en) * | 1985-05-18 | 1985-06-19 | Procter & Gamble | Laundry detergent compositions |
| GB8627915D0 (en) * | 1986-11-21 | 1986-12-31 | Procter & Gamble | Detergent compositions |
| BR9710661A (pt) * | 1996-05-03 | 1999-08-17 | Procter & Gamble | Composi-{es detergentes l¡quidas compreendendo pol¡meros de poliamina modificados especialmente selecionados |
-
1997
- 1997-09-25 ZA ZA9708601A patent/ZA978601B/xx unknown
- 1997-10-01 TR TR1999/00790T patent/TR199900790T2/xx unknown
- 1997-10-01 BR BR9712496-6A patent/BR9712496A/pt not_active Application Discontinuation
- 1997-10-01 CN CN97180361A patent/CN1239985A/zh active Pending
- 1997-10-01 HU HU0000235A patent/HUP0000235A3/hu unknown
- 1997-10-01 EP EP97945301A patent/EP0929634A2/en not_active Withdrawn
- 1997-10-01 JP JP10517566A patent/JP2000505139A/ja active Pending
- 1997-10-01 WO PCT/US1997/017308 patent/WO1998015608A2/en not_active Application Discontinuation
- 1997-10-01 CA CA002267379A patent/CA2267379A1/en not_active Abandoned
- 1997-10-01 AU AU46532/97A patent/AU4653297A/en not_active Abandoned
- 1997-10-06 MA MA24825A patent/MA24367A1/fr unknown
- 1997-10-07 AR ARP970104623A patent/AR011243A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO1998015608A3 (en) | 1998-05-22 |
| TR199900790T2 (xx) | 1999-07-21 |
| MA24367A1 (fr) | 1998-07-01 |
| AU4653297A (en) | 1998-05-05 |
| HUP0000235A2 (hu) | 2000-06-28 |
| ZA978601B (en) | 1998-03-26 |
| BR9712496A (pt) | 2002-01-15 |
| EP0929634A2 (en) | 1999-07-21 |
| WO1998015608A2 (en) | 1998-04-16 |
| JP2000505139A (ja) | 2000-04-25 |
| AR011243A1 (es) | 2000-08-16 |
| HUP0000235A3 (en) | 2001-11-28 |
| CN1239985A (zh) | 1999-12-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |